TW201711694A - Method for producing processed ginger product, processed ginger product and method for enriching shogaols - Google Patents

Method for producing processed ginger product, processed ginger product and method for enriching shogaols Download PDF

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TW201711694A
TW201711694A TW105125458A TW105125458A TW201711694A TW 201711694 A TW201711694 A TW 201711694A TW 105125458 A TW105125458 A TW 105125458A TW 105125458 A TW105125458 A TW 105125458A TW 201711694 A TW201711694 A TW 201711694A
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ginger
processed product
freezing
producing
gingerol
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TWI617314B (en
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Junko Sendo
Masatsugu Abe
Kaori Nagata
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Nla Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof

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Abstract

Provided is a method for producing a processed ginger product, in which shogaols are enriched, at a high productivity. The method for producing a processed ginger product comprises: a freezing step for freezing ginger that is used as a starting material; and a steam heating step for heating the frozen ginger in the coexistence of steam at a temperature of 100-150 DEG C inclusive until the concentration of shogaols contained in the ginger exceeds the concentration of gingerols contained therein.

Description

生薑加工物之製造方法 Method for manufacturing ginger processed product

本國際申請案係基於2015年8月12日向日本特許廳申請之專利申請案日本特願2015-159640,主張其優先權,將日本特願2015-159640的全部內容援用於本國際申請案以供參照。 This international application is based on the patent application filed by the Japan Patent Office on August 12, 2015. Japan's special offer 2015-159640, which asserts its priority and applies the entire contents of Japan's special offer 2015-159640 to this international application. Reference.

本發明係有關於一種富含生薑醇類的生薑加工物之製造方法及生薑加工物、以及生薑醇類之富化方法。 The present invention relates to a method for producing a ginger-rich ginger-processed product, a ginger processed product, and a method for enriching ginger alcohol.

屬生薑之辣味成分的生薑醇類不僅被利用於作為食品香料,其中還具有解熱作用、鎮痛作用、抗炎症作用、抗氧化作用、前列腺素之生合成抑制作用、促進血液循環作用、體溫上昇作用等,甚而,亦已知有治療、預防糖尿病及肥胖等的生活習慣所導致的疾病等效果。因此,可望將生薑醇類及含有其之原料活用於機能性食品、化妝料等。 Ginger alcohol which is a spicy ingredient of ginger is not only used as a food flavor, but also has antipyretic action, analgesic action, anti-inflammatory action, anti-oxidation effect, synthesis inhibition of prostaglandin, promotion of blood circulation, In addition, effects such as diseases caused by living habits such as treatment and prevention of diabetes and obesity are known. Therefore, it is expected that ginger alcohols and raw materials containing the same can be used for functional foods, cosmetics, and the like.

另一方面,屬薑科之代表性植物的生薑中係含有薑酚類或生薑醇類作為具辣味之成分。 On the other hand, ginger which is a representative plant of the family Zingiberaceae contains gingerol or ginger alcohol as a component having a spicy taste.

生薑在生的未加工狀態下富含下述所示結構之化合物的薑酚類,生薑醇類僅有微量存在,但藉由從薑酚類使水脫離的脫水反應可獲得生薑醇類。 Ginger phenols which are rich in compounds of the structure shown below in the unprocessed state of ginger, ginger alcohols are only present in trace amounts, but ginger alcohol can be obtained by dehydration reaction of phenolic phenols from water. class.

(式(1)中,n表示1以上10以下之整數)。 (In the formula (1), n represents an integer of 1 or more and 10 or less).

屬生薑所含成分的生薑醇類係指下述所示結構之化合物,主要作為生薑醇類,係指相當於n=4,6,8的6-生薑醇、8-生薑醇、或10-生薑醇。 The ginger alcohol which is a component contained in ginger refers to a compound of the structure shown below, mainly as a ginger alcohol, and refers to 6-gingerol, 8-ginger equivalent to n=4,6,8. Alcohol, or 10-glycol alcohol.

(式(2)中,n表示1以上10以下之整數)。 (In the formula (2), n represents an integer of 1 or more and 10 or less).

此外,在生薑中,作為薑酚類係含有相當於n=4,6,8的6-薑酚、8-薑酚、10-薑酚,其中6-薑酚為主成分。因此,由6-薑酚向6-生薑醇的轉換為主反應。 Further, in ginger, as the gingerol group, 6-gingerol, 8-gingerol, and 10-gingerol corresponding to n = 4, 6, 8 are contained, and among them, 6-gingerol is a main component. Therefore, the conversion of 6-gingerol to 6-gingerol is the main reaction.

於如此情況下,有人探討將生薑中所含的薑酚類轉換成生薑醇類,而使其富含生薑醇類的方法。 Under such circumstances, a method of converting ginger phenols contained in ginger into ginger alcohols and enriching them with ginger alcohol has been discussed.

例如,專利文獻1中報導一種藉由將薑酚類在酸觸媒的存在下加熱而獲得生薑醇類的方法。然而,就專利文獻1之方法,由於使用了甲苯等的有機溶劑,而有對人體之安全性方面的疑慮。 For example, Patent Document 1 reports a method of obtaining ginger alcohol by heating gingerol in the presence of an acid catalyst. However, in the method of Patent Document 1, since an organic solvent such as toluene is used, there is a concern about the safety of the human body.

又,也有人報導不使用有機溶劑的薑酚類之富化方法。例如,專利文獻2中揭示一種生薑醇類之富化方法,其係包含將生薑之超臨界CO2萃取物在乳酸的存在下、110℃~150℃下加熱的步驟。又,專利文獻3中揭示一種生薑醇類之富化方法,其係包含將生薑之超臨界CO2萃取物在選自檸檬酸、琥珀酸及蘋果酸之有機酸的存在下、110℃~150℃下加熱的步驟。又,本案申請人也在專利文獻4中報導一種生薑醇類之富化方法,其係包含將生薑與發酵液混合後,在溫度30℃~90℃、濕度50%~90%的條件下加熱的步驟。 Further, there has been reported an enrichment method of gingerol which does not use an organic solvent. For example, Patent Document 2 discloses a method for enriching ginger alcohols, which comprises the step of heating a supercritical CO 2 extract of ginger in the presence of lactic acid at 110 ° C to 150 ° C. Further, Patent Document 3 discloses a method for enriching ginger alcohol, which comprises supercritical CO 2 extract of ginger in the presence of an organic acid selected from the group consisting of citric acid, succinic acid and malic acid at 110 ° C. The step of heating at ~150 °C. Moreover, the applicant of the present application also reported in Patent Document 4 a method for enriching ginger alcohol, which comprises mixing ginger and a fermentation broth at a temperature of 30 ° C to 90 ° C and a humidity of 50% to 90%. The step of heating down.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特開平8-40970號公報 [Patent Document 1] Japanese Patent Laid-Open No. Hei 8-40970

[專利文獻2]日本特開2015-10083號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2015-10083

[專利文獻3]日本特開2015-44766號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2015-44766

[專利文獻4]日本專利第5297294號公報 [Patent Document 4] Japanese Patent No. 5297294

專利文獻2~4中所揭示之生薑醇類之富化方法由於不使用有機溶劑,而屬於對人體之安全性優良的方法,但作為原料,除生薑以外亦須使用乳酸(專利文獻2)、檸檬酸等的有機酸(專利文獻3)、發酵液(專利文獻4)等的生薑以外的成分。因此,製成的生薑加工品中必然會帶有來自前述生薑以外之成分的風味。從而,有所謂因生薑以外之成分的風味而損及生薑原本的風味之虞。 The method for enriching gingerols disclosed in Patent Documents 2 to 4 is a method which is excellent in safety to human body without using an organic solvent, but as a raw material, lactic acid must be used in addition to ginger (Patent Document 2) A component other than ginger such as an organic acid such as citric acid (Patent Document 3) and a fermentation broth (Patent Document 4). Therefore, the processed ginger product must have a flavor derived from the ingredients other than the above ginger. Therefore, there is a so-called flavor that is harmful to the original flavor of ginger due to the flavor of ingredients other than ginger.

再者,就專利文獻2,3之方法,其並非以生薑本身,而是以生薑之萃取物作為原料,因此需要萃取步驟,因萃取步驟而成為高成本的原因之一。又,就專利文獻4之方法,其雖可將生薑直接作為原料使用,但作為從薑酚類至生薑醇類的轉換所需之充分的加熱時間需加熱120小時~500小時。因此,用在加熱的時間增長,在生產性或製造成本方面尚有改善的空間。 Further, in the methods of Patent Documents 2 and 3, the ginger extract itself is not used as the raw material, and therefore the extraction step is required, which is one of the causes of high cost due to the extraction step. Further, in the method of Patent Document 4, although ginger can be directly used as a raw material, it is necessary to heat for 120 hours to 500 hours as a sufficient heating time required for conversion from gingerol to ginger alcohol. Therefore, there is still room for improvement in terms of productivity or manufacturing cost as the time for heating increases.

於所述情況下,本發明目的在於提供一種不會損及生薑的風味,可縮短將薑酚類轉換成生薑醇類的製造時間,可改善生產效率之富含生薑醇類的生薑加工物之製造方法。 In view of the above, an object of the present invention is to provide a ginger-rich food which can improve the production efficiency without reducing the flavor of ginger, shortening the production time of converting gingerol into ginger alcohol, and improving production efficiency. A method of manufacturing ginger processed matter.

本案發明人為解決上述課題而致力反覆研究的結果發現,藉由將進行過冷凍處理的生薑,在水蒸氣共存下且特定的溫度下進行蒸氣加熱處理,即使未添加生薑以外的成分,也可將生薑所含的薑酚類高效率地轉換成生 薑醇類。進一步發現,藉由對蒸氣加熱處理後的生薑重複進行乾燥處理與冷凍處理並使用塊狀之生薑作為原料,可抑制生薑加工品所含有之生薑醇類的絕對量的降低,而達成本發明。 In order to solve the above problems, the inventors of the present invention have made it possible to carry out the steam heat treatment in a coexistence of water vapor at a specific temperature in order to solve the above-mentioned problems, and it has been found that the ginger is not subjected to the addition of components other than ginger. The ginger phenols contained in ginger can be efficiently converted into raw Ginger alcohols. Further, it has been found that by repeating the drying treatment and the freezing treatment of the ginger after the steam heat treatment and using the block-shaped ginger as a raw material, it is possible to suppress the decrease in the absolute amount of the ginger alcohol contained in the ginger processed product. The invention has been achieved.

亦即,本發明係涉及以下之生薑加工物之製造方法者。 That is, the present invention relates to the following method for producing a ginger processed product.

<1>一種生薑加工物之製造方法,其特徵為具有下述步驟:將作為原料的生薑進行冷凍處理之冷凍步驟;及將冷凍步驟後的生薑,在水蒸氣共存下且溫度100℃以上150℃以下的條件下進行加熱處理至生薑所含之生薑醇類的濃度高於薑酚類的濃度之蒸氣加熱步驟。 <1> A method for producing a ginger processed product, comprising the steps of: freezing a raw ginger as a raw material; and cooling the ginger after the freezing step at a temperature of 100 The heat treatment is carried out under the conditions of ° C or more and 150 ° C or less until the concentration of the ginger alcohol contained in the ginger is higher than the concentration of the ginger phenol.

<2>如前述<1>之生薑加工物之製造方法,其中前述冷凍步驟中的溫度為-10℃以下。 <2> The method for producing a ginger processed product according to the above <1>, wherein the temperature in the freezing step is -10 ° C or lower.

<3>如<1>或<2>之生薑加工物之製造方法,其中前述蒸氣加熱步驟中的溫度為110℃以上130℃以下,且壓力為0.12MPa以上0.30MPa以下。 <3> The method for producing a ginger processed product according to <1> or <2>, wherein the temperature in the steam heating step is 110° C. or higher and 130° C. or lower, and the pressure is 0.12 MPa or more and 0.30 MPa or less.

<4>如<1>至<3>中任一項之生薑加工物之製造方法,其中前述蒸氣加熱步驟中的處理時間為3小時以上。 The method for producing a ginger processed product according to any one of the above aspects, wherein the processing time in the steam heating step is 3 hours or longer.

<5>如<1>至<4>中任一項之生薑加工物之製造方法,其係具有將前述蒸氣加熱步驟後的生薑進行乾燥之乾燥步驟。 The method for producing a ginger processed product according to any one of <1> to <4>, which further comprises a drying step of drying the ginger after the steam heating step.

<6>如<5>之生薑加工物之製造方法,其中在前 述乾燥步驟中,對前述蒸氣加熱步驟後的生薑重複進行乾燥處理與冷凍處理,而使其乾燥至成為既定的水分含量以下為止。 <6> A method for producing a ginger processed product such as <5>, wherein In the drying step, the ginger after the steam heating step is repeatedly subjected to a drying treatment and a freezing treatment, and is dried until the predetermined moisture content is equal to or lower.

<7>如<6>之生薑加工物之製造方法,其中乾燥處理為減壓乾燥,冷凍處理中的溫度為-10℃以下。 <7> The method for producing a ginger processed product according to <6>, wherein the drying treatment is drying under reduced pressure, and the temperature in the freezing treatment is -10 ° C or lower.

<8>如<1>至<7>中任一項之生薑加工物之製造方法,其中作為原料的生薑為塊狀之生薑。 <8> The method for producing a ginger processed product according to any one of <1> to <7> wherein the ginger as a raw material is a block-shaped ginger.

又,本發明其他形態係涉及利用上述之生薑加工物之製造方法的以下之發明者。 Further, another aspect of the present invention relates to the following inventors of the method for producing a ginger processed product described above.

<9>一種生薑加工物,其係以如<1>至<8>中任一項之製造方法製造而成。 <9> A ginger processed product produced by the production method according to any one of <1> to <8>.

<10>一種組成物,其係含有如<9>之生薑加工物。 <10> A composition comprising a ginger processed product such as <9>.

<11>一種機能性食品,其係含有如<9>之生薑加工物。 <11> A functional food comprising a ginger processed product such as <9>.

<12>一種生薑所含之生薑醇類之富化方法,其係具有將經冷凍處理的生薑,在水蒸氣共存下且溫度100℃以上150℃以下的條件下進行加熱處理至生薑所含之生薑醇類的濃度高於薑酚類的濃度之蒸氣加熱步驟。 <12> A method for enriching ginger alcohol contained in ginger, which comprises heating the frozen ginger to a living condition under the condition of coexistence of water vapor and a temperature of 100 ° C or more and 150 ° C or less. The steam heating step in which the concentration of ginger alcohol contained in ginger is higher than the concentration of gingerol.

根據本發明之生薑加工物之製造方法,由於可在不損及生薑的風味下將生薑所含之薑酚類轉換成生薑醇類,而能夠生產性良好地製造富含生薑醇類的生薑加工 物。 According to the method for producing a ginger processed product of the present invention, the ginger phenols contained in the ginger can be converted into ginger alcohols without impairing the flavor of the ginger, and the ginger-rich can be produced with good productivity. Alcohol processing of alcohol Things.

[實施發明之形態] [Formation of the Invention]

以下,示出例示物等就本發明詳細加以說明,惟本發明不限定於以下之例示物等,在不悖離本發明要旨的範圍可任意地變更而實施。 In the following, the present invention is described in detail with reference to the accompanying drawings, and the present invention is not limited to the following examples, and may be arbitrarily changed without departing from the scope of the invention.

本發明之生薑加工物之製造方法(以下有記載為「本發明之製造方法」),其特徵為具有以下步驟:將作為原料的生薑進行冷凍處理之冷凍步驟;及將冷凍步驟後的生薑,在水蒸氣共存下且溫度100℃以上150℃以下的條件下進行加熱處理至生薑所含之生薑醇類的濃度高於薑酚類的濃度之蒸氣加熱步驟。 The method for producing a ginger processed product of the present invention (hereinafter referred to as "the method for producing the present invention"), characterized in that the step of freezing the ginger as a raw material, and the freezing step after the freezing step Ginger is subjected to heat treatment under the conditions of coexistence of steam and a temperature of 100 ° C or more and 150 ° C or less until the concentration of the ginger alcohol contained in the ginger is higher than the concentration of the ginger phenol.

在本發明之製造方法中,係藉由將作為原料的生薑冷凍後,在水蒸氣共存下且上述特定的溫度條件下進行蒸氣加熱處理,與以往未進行冷凍處理即進行蒸氣加熱處理的情形相比,可格外提升從生薑所含之薑酚類向生薑醇類的轉換效率,而能夠生產性良好地製造富含生薑醇類的生薑加工物。 In the production method of the present invention, after the ginger as a raw material is frozen, the steam heat treatment is performed under the above-described specific temperature conditions in the presence of steam, and the steam heat treatment is performed without performing the freezing treatment. In contrast, the conversion efficiency of the gingerols contained in the ginger to the ginger alcohol can be particularly improved, and the ginger processed product rich in ginger alcohol can be produced with good productivity.

以下,更詳細地說明本發明之製造方法。 Hereinafter, the production method of the present invention will be described in more detail.

(原料生薑) (raw ginger)

作為本發明之生薑加工物的原料之生薑(原料生薑)為薑科植物,係表示屬於薑目薑科薑屬的生薑(Zingiber officinale)。原料生薑依其大小而分類的大生薑、中生薑、小生薑之任一者皆可使用。作為原料生薑的品種,可舉出例如金時生薑、三州生薑、黃金生薑、近江生薑、谷中生薑、靜岡4號、黃生薑、土生薑、Otahuku生薑等。特別是此等當中,金時生薑及三州生薑由於富含薑酚類而較佳。又,黃金生薑在本發明之製造方法中亦為合適者。 Ginger (raw ginger) which is a raw material of the ginger processed product of the present invention is a ginger family, and is a ginger belonging to the genus Ginger (Zingiber). Officinale). Any of the raw ginger, medium ginger, and small ginger, which are classified according to their size, can be used. Examples of the raw ginger include, for example, Jinshi ginger, Sanzhou ginger, gold ginger, Omi ginger, Guzhong ginger, Shizuoka No. 4, yellow ginger, native ginger, and Otahuku ginger. Especially among these, Jinshi ginger and Sanzhou ginger are preferred because they are rich in gingerol. Further, gold ginger is also suitable in the production method of the present invention.

就原料生薑而言,可為剛採收後之生薑,也可為採收後經過保存的生薑。又,就使用之原料生薑的部位而言,可選擇適宜的部位,根莖因薑酚的含量較多而較佳。 In the case of raw ginger, it may be ginger that has just been harvested, or ginger that has been preserved after harvesting. Further, as for the portion of the raw ginger to be used, an appropriate portion can be selected, and the rhizome is preferably used in a large amount of gingerol.

原料生薑可未經處理而使用整個生的生薑,也可使用經過粉碎者。又,就原料生薑之形態而言,可選用適宜者,例如可為呈塊狀、薄片狀、經切細者等。又,將生的生薑壓縮而得之萃取物亦為原料生薑之一形態。 Raw ginger can be used as raw ginger without treatment, or it can be used. Further, as for the form of the raw ginger, it may be selected as appropriate, and for example, it may be in the form of a block, a flake, or a shred. Further, the extract obtained by compressing the raw ginger is also in the form of one of raw ginger.

原料生薑之形態特別是塊狀之生薑時,由於可抑制薑酚類(及生薑醇類)在加工中(尤為加熱中或乾燥中)的蒸散,因而較佳。 In the form of raw ginger, especially in the form of chunky ginger, it is preferred because it inhibits the evaporation of gingerol (and ginger alcohol) during processing (especially during heating or drying).

此外,此處所稱「塊狀之生薑」,不僅包含整個生薑,亦包含4cm見方左右之大小者。為了進一步抑制薑酚類(及生薑醇類)的蒸散,較佳為盡可能未經裁切的塊狀之生薑。 In addition, the term "blocky ginger" as used herein includes not only the entire ginger but also the size of about 4 cm square. In order to further suppress evapotranspiration of gingerol (and ginger alcohol), it is preferred to use ginger which is not cut as much as possible.

(冷凍步驟) (freezing step)

未加工、或經處理成適當形態的原料生薑係供予至冷 凍步驟。 Raw ginger, unprocessed or processed into a suitable form, is supplied to the cold Frozen step.

冷凍步驟中的冷凍溫度只要為0℃以下即可,較佳為-10℃以下,更佳為-15℃以下。冷凍溫度的下限無特別限制,由於解凍需耗費多餘的能源及時間,因此通常為-25℃以上。 The freezing temperature in the freezing step may be 0 ° C or lower, preferably -10 ° C or lower, more preferably -15 ° C or lower. The lower limit of the freezing temperature is not particularly limited, and since it requires extra energy and time for thawing, it is usually -25 ° C or higher.

就冷凍時間,只要具有屬本發明效果的使其富含生薑醇類之效果則可設為適宜的長度;通常為1小時以上,較佳為5小時以上,更佳為10小時以上。 The freezing time may be an appropriate length as long as it has an effect of enriching the ginger alcohol which is an effect of the present invention, and is usually 1 hour or longer, preferably 5 hours or longer, more preferably 10 hours or longer.

作為進行冷凍步驟的手段,只要可調節冷凍的溫度則可選用適宜者,可使用例如一般市售的冷凍庫。又,亦可使用大型之經設備化的冷凍設施。只要可調節溫度,例如,可使用自然的寒冷環境而非電氣式者。 As means for performing the freezing step, as long as the temperature of the freezing can be adjusted, a suitable one can be used, and for example, a commercially available freezer can be used. In addition, large-scale equipment-based refrigeration facilities can also be used. As long as the temperature can be adjusted, for example, a natural cold environment can be used instead of an electric one.

在冷凍步驟中,可將作為原料的生薑直接收納於冷凍庫;待進行冷凍時,可在生的狀態下整個予以冷凍保存,也可剝皮後切成圓片、磨成泥、切絲、或切成便於使用的大小後裝入夾鏈袋中。若將生薑裝入塑膠袋中則生薑的色調或風味不易發生變化,屬較佳者。 In the freezing step, the raw ginger can be directly stored in the freezer; when it is frozen, it can be frozen and stored in the raw state, or can be peeled, cut into a round, ground into a mud, shredded, Or cut into sized pockets for easy use. If the ginger is placed in a plastic bag, the color tone or flavor of the ginger is not easily changed, which is preferable.

(蒸氣加熱步驟) (steam heating step)

蒸氣加熱步驟係將供予至冷凍步驟之冷凍步驟後的生薑,在水蒸氣共存下且溫度100℃以上150℃以下的條件下進行加熱處理至生薑所含之生薑醇類的濃度高於薑酚類的濃度的步驟。 The steam heating step is to heat the ginger after the freezing step to the freezing step, and to heat the mixture in the presence of steam at a temperature of 100 ° C or more and 150 ° C or less until the concentration of the ginger alcohol contained in the ginger is high. The step of concentration of ginger phenols.

此外,供予至蒸氣加熱步驟之冷凍步驟後的 生薑可為經冷凍狀態的生薑,也可為冷凍後經解凍的生薑。又,冷凍步驟與蒸氣加熱步驟未必有連續進行之必要,在此等步驟之間亦可包含其他步驟。再者,亦可在分別不同的場所進行冷凍步驟、與蒸氣加熱步驟。 In addition, after the freezing step of the steam heating step Ginger can be either ginger in a frozen state or ginger that is thawed after freezing. Further, the freezing step and the steam heating step are not necessarily required to be continuously performed, and other steps may be included between the steps. Further, the freezing step and the steam heating step may be performed at different places.

又,亦可在冷凍設備中保存冷凍生薑,並將其視為冷凍步驟。於此情況下,在生產生薑加工物時,將經冷凍之適當量的冷凍生薑供予至蒸氣加熱步驟,可製造生薑加工物,且蒸氣加熱步驟的時間為實質上的製造時間。 Further, frozen ginger can also be stored in a freezing apparatus and regarded as a freezing step. In this case, when a ginger processed product is produced, a frozen amount of frozen ginger is supplied to the steam heating step to produce a ginger processed product, and the steam heating step is a substantially manufacturing time.

蒸氣加熱步驟的溫度為100℃以上150℃以下,基於可進一步提高向生薑醇類之轉換速度的觀點,較佳為110℃以上130℃以下。 The temperature in the steam heating step is 100° C. or higher and 150° C. or lower, and is preferably 110° C. or higher and 130° C. or lower from the viewpoint of further increasing the conversion rate to the ginger alcohol.

就蒸氣加熱步驟中的壓力,為0.12MPa以上,基於可進一步提高向生薑醇類之轉換速度的觀點,較佳為0.13MPa以上。作為壓力的上限,係於不損及本發明之效果的範圍內決定,較佳為0.3MPa以下。 The pressure in the steam heating step is 0.12 MPa or more, and is preferably 0.13 MPa or more from the viewpoint of further increasing the conversion rate to ginger alcohol. The upper limit of the pressure is determined within a range that does not impair the effects of the present invention, and is preferably 0.3 MPa or less.

蒸氣加熱步驟的時間係斟酌生薑的種類及大小等而決定,係於可充分引起生薑醇類之富化的範圍內決定。例如以10分鐘的短時間也可看出生薑醇類的富化效果本身,但為了獲得作成製品之足量的生薑醇類(亦即生薑所含之生薑醇類的濃度高於薑酚類的濃度),則為例如1小時以上、3小時以上、5小時以上。蒸氣加熱步驟的時間的上限無限制,時間若過長則有所含之生薑醇類(及薑酚類)蒸散的傾向,因此通常為20小時以下、10小時以下。 The time of the steam heating step is determined depending on the type and size of the ginger, and is determined within a range in which the ginger alcohol can be sufficiently enriched. For example, the enrichment effect of the ginger alcohols can be seen in a short time of 10 minutes, but in order to obtain a sufficient amount of ginger alcohols for the preparation of the product (that is, the concentration of the ginger alcohol contained in the ginger is higher than that of the ginger. The concentration of the phenol is, for example, 1 hour or longer, 3 hours or longer, or 5 hours or longer. The upper limit of the time of the steam heating step is not limited, and if the time is too long, the ginger alcohol (and ginger phenol) contained therein tends to evaporate, and therefore it is usually 20 hours or shorter and 10 hours or shorter.

作為進行蒸氣加熱步驟的手段,只要是市售之高壓釜、壓力鍋、或者壓力釜等可設定‧調節蒸氣、壓力與溫度者,則可使用適宜者。又,就蒸氣加熱而言,由於可進行高壓蒸氣殺菌,因此,本發明之生薑加工物之製造方法,除生薑醇類之富化之效果外,還可將本發明之生薑加工物殺菌或使其清潔。作為進行蒸氣加熱步驟的手段,可使用用於殺菌袋裝食品的殺菌器,而此時亦可獲得同樣的滅菌‧殺菌效果。 As a means for performing the steam heating step, any commercially available autoclave, pressure cooker, or autoclave can be used to adjust the vapor, pressure, and temperature. Further, in the case of steam heating, since the high-pressure steam sterilization can be performed, the method for producing a ginger processed product of the present invention can further produce the ginger processed product of the present invention in addition to the effect of enriching the ginger alcohol. Sterilize or clean it. As a means for performing the steam heating step, a sterilizer for sterilizing the packaged food can be used, and at the same time, the same sterilization and sterilization effect can be obtained.

諸如上述,在本發明之製造方法中,係藉由將經過冷凍步驟的生薑,在蒸氣加熱步驟中進行處理,比起習知方法縱使加熱時間較短,仍可提升從薑酚類向生薑醇類的轉換效率,而能夠使其富含生薑醇類。 For example, in the manufacturing method of the present invention, the ginger which has undergone the freezing step is treated in the steam heating step, and the heating time is shorter than that of the conventional method, and the ginger phenol is still promoted. The conversion efficiency of gingerols can make them rich in ginger alcohols.

例如,在本申請人所提出之專利文獻4的製造方法中,在將原料生薑與發酵液混合後,在溫度30℃~90℃、濕度50%~90%的條件下進行加熱處理之際,為了從薑酚類轉換成生薑醇類,而需要120小時以上的加熱;然而,在本發明之製造方法中,藉由將冷凍後的生薑供予至1小時以上的蒸氣加熱步驟,可獲得相同程度的轉換效率,因此,可生產性更良好地獲得富含生薑醇類的生薑加工物。 For example, in the production method of Patent Document 4 proposed by the present applicant, after the raw ginger and the fermentation liquid are mixed, the heat treatment is carried out at a temperature of 30 ° C to 90 ° C and a humidity of 50% to 90%. In order to convert ginger phenols to ginger alcohols, it takes more than 120 hours to heat; however, in the production method of the present invention, by supplying the frozen ginger to a steam heating step of 1 hour or longer, The same degree of conversion efficiency can be obtained, and therefore, the ginger-rich ginger-rich processed product can be obtained more satisfactorily.

(其他步驟) (other steps)

本發明之製造方法,除上述之冷凍步驟與蒸氣加熱步驟外,還可適宜近一步加入其他步驟。又,也可重複冷凍 步驟與蒸氣加熱步驟數次。 In the production method of the present invention, in addition to the above-described freezing step and steam heating step, it is also possible to further add other steps. Also, it can be repeated frozen The steps are followed by a steam heating step several times.

作為其他步驟,可舉出例如乾燥步驟。 As another step, for example, a drying step can be mentioned.

(乾燥步驟) (drying step)

乾燥步驟係將蒸氣加熱步驟後的生薑加工物進行乾燥的步驟。藉由進行乾燥步驟,可進一步提升生薑加工品的保存性,而且,可使生薑加工品更容易使用於後述之應用品。雖視生薑加工物的使用用途而異,惟,係使其乾燥至含水率通常為30重量%以下,較佳為10重量%以下為止。 The drying step is a step of drying the ginger processed product after the steam heating step. By carrying out the drying step, the storage property of the ginger processed product can be further improved, and the ginger processed product can be more easily used for the application product described later. Although the ginger processed product is used depending on the intended use, it is dried to a moisture content of usually 30% by weight or less, preferably 10% by weight or less.

作為用於乾燥步驟的手段,只要無損使其富含生薑醇類的效果則無特別限制,只要採用周知之乾燥方法即可。乾燥條件只要以使生薑加工物達到目標含水量的方式來決定即可。例如,有在溫度70℃~90℃加熱乾燥12小時~30小時的方法。 The means for the drying step is not particularly limited as long as it does not impair the effect of enriching the ginger alcohol, and a known drying method can be employed. The drying conditions may be determined so that the ginger processed product reaches a target water content. For example, there is a method of heating and drying at a temperature of 70 ° C to 90 ° C for 12 hours to 30 hours.

又,作為較佳之乾燥方法,有在乾燥步驟中,對前述蒸氣加熱步驟後的生薑重複進行乾燥處理與冷凍處理,而使其乾燥至成為既定的水分含量以下為止的方法。根據此方法,可抑制生薑加工品所含有之生薑醇類的減少,最終生薑加工品所含之生薑醇類的絕對量會由加熱乾燥而變多。 Further, as a preferred drying method, in the drying step, the ginger after the steam heating step is repeatedly subjected to a drying treatment and a freezing treatment, and dried to a predetermined moisture content or lower. According to this method, the reduction of the ginger alcohol contained in the ginger processed product can be suppressed, and the absolute amount of the ginger alcohol contained in the ginger processed product is increased by heating and drying.

於此方法中,較佳的是乾燥處理為減壓乾燥,且冷凍處理中的溫度為-10℃以下。將減壓乾燥的時間設為1~10小時、冷凍時間設為5~20小時,予以重複至成為目標的 水分量為止(通常重複2~5次)。藉此,可在不使生薑加工物的品質劣化之下,使水分量達既定量(例如10重量%以下)。於此方法中,較佳使用塊狀之生薑。若採用切片或切細之生薑,在減壓乾燥之際生薑醇類會蒸散,而有含量減少的傾向。 In this method, it is preferred that the drying treatment is drying under reduced pressure, and the temperature in the freezing treatment is -10 ° C or lower. Set the time for decompression drying to 1 to 10 hours, and set the freezing time to 5 to 20 hours. Repeat until the target is reached. The amount of water is up to (usually repeated 2 to 5 times). Thereby, the amount of water can be made quantitative (for example, 10% by weight or less) without deteriorating the quality of the ginger processed product. In this method, blocky ginger is preferably used. If sliced or shredded ginger is used, the ginger alcohol will evaporate when it is dried under reduced pressure, and the content tends to decrease.

(生薑醇類之富化方法) (Ginger alcohol enrichment method)

本發明之生薑醇類之富化方法係將經冷凍處理的生薑,在水蒸氣共存下且溫度100℃以上、150℃以下的條件下進行加熱處理,而將生薑所含的薑酚類轉換成生薑醇類的生薑醇類之富化方法。該生薑醇類之富化方法係為與上述之生薑加工物之製造方法同樣地將原料生薑進行冷凍處理、進行蒸氣加熱處理,而使其富含生薑所含之生薑醇類的方法,由於較佳之條件等係相同,故省略其細節。 The method for enriching the ginger alcohol of the present invention is to heat the frozen ginger in the presence of steam at a temperature of 100 ° C or more and 150 ° C or less, and to heat the ginger. An enrichment method for converting ginger alcohols into gingerols. The method for enriching the ginger alcohol is to freeze the raw ginger and perform steam heat treatment in the same manner as the method for producing the ginger processed product described above, thereby enriching the ginger alcohol contained in the ginger. The method is omitted because the preferred conditions are the same.

<生薑加工物> <Ginger Processing>

藉由本發明之生薑之製造方法所製造的生薑加工物(以下有記載為「本發明之生薑加工物」)可直接使用,亦可進一步進行萃取、粉碎等的加工。又,也可組合生薑加工物與任意之成分,而調成含有生薑加工物的組成物。任意成分的摻混比例可視其目的適宜選擇而決定。 The ginger processed product (hereinafter referred to as "the ginger processed product of the present invention") produced by the method for producing ginger according to the present invention can be used as it is, and can be further processed by extraction or pulverization. Further, the ginger processed product and any of the components may be combined to form a composition containing the ginger processed product. The blending ratio of the optional components can be determined depending on the appropriate choice of the purpose.

本發明之生薑加工物所含有的生薑醇類係一種具有解熱、鎮痛、抗炎症、前列腺素之生合成抑制、促進血液循環、體溫上昇、脂連蛋白表現之上昇等各種的藥 理作用,而且對於因糖尿病或肥胖等而誘發之代謝症候群的預防亦屬有效的成分。因此,包含本發明之生薑加工物或生薑加工物的組成物係如以下所說明般可適用於作為身體保養製品、機能性食品等的原料。此外,以下係針對身體保養製品、機能性食品、補充食品加以說明,惟本發明之生薑加工物的用途非限定於此等用途,例如,亦可使用於醫藥品用途。 The ginger alcohol contained in the ginger processed product of the present invention is a medicine having antipyretic, analgesic, anti-inflammatory, prostaglandin biosynthesis inhibition, promotion of blood circulation, body temperature rise, and adiponectin expression. It is also an effective ingredient for the prevention of metabolic syndrome induced by diabetes or obesity. Therefore, the composition containing the ginger processed product or the ginger processed product of the present invention can be suitably used as a raw material for a body care product, a functional food or the like as described below. In addition, the following is a description of the body care product, the functional food, and the supplementary food, but the use of the ginger processed product of the present invention is not limited to such use, and for example, it can also be used for pharmaceutical use.

(身體保養製品) (body care products)

本發明之生薑加工物可作為身體保養製品使用。此外,此處所稱「身體保養製品」,係指化妝品,此外尚指沐浴劑或洗髮精、肥皂等保護或洗淨皮膚之製品。 The ginger processed product of the present invention can be used as a body care product. In addition, the term "body care products" as used herein refers to cosmetics, and is also referred to as a bath or shampoo, soap, and the like for protecting or washing skin.

本發明之生薑加工物可摻混於沐浴劑、體用香皂、洗髮精等的沐浴用組成物中使用,作為劑型,可調成一般所使用的水溶液、W/O型或O/W型乳液,或使用適當的賦形劑等而製成顆粒劑以外的粉末、錠劑等。又,亦可作成幕斯或生髮用等的護髮劑使用。 The ginger processed product of the present invention can be blended into a bathing composition such as a body wash, a body soap or a shampoo, and can be used as a dosage form to be adjusted into a commonly used aqueous solution, W/O type or O/W. The emulsion is prepared into a powder, a tablet or the like other than the granules by using an appropriate excipient or the like. Moreover, it can also be used as a hair conditioner such as a curtain or a hair.

將本發明之生薑加工物調成化妝料組成物時,可適宜摻混慣用之化妝料基材,而製成所要的劑型。其形態無特別限制,可舉出凝膠、乳液、乳霜等的形態。又,調製成此等形態之際,可進一步添加藥草或天然精油等。亦可進一步添加供皮膚的保濕或美容用的適宜之成分、例如玻尿酸、或輔酶Q10等。 When the ginger processed product of the present invention is adjusted into a cosmetic composition, a conventional cosmetic base material can be suitably blended to prepare a desired dosage form. The form is not particularly limited, and examples thereof include a gel, an emulsion, and a cream. Further, when these forms are prepared, a herb or a natural essential oil or the like can be further added. Further suitable ingredients for moisturizing or cosmetic use of the skin, such as hyaluronic acid or coenzyme Q10, may be further added.

作為化妝料基材,可配合目標之劑型而適宜 選擇水、水溶性有機溶劑、油脂、蠟、高級脂肪酸、高級醇、酯類等向來周知之化妝料基材。 As a cosmetic substrate, it can be combined with the target dosage form. A well-known cosmetic base material such as water, a water-soluble organic solvent, fats and oils, waxes, higher fatty acids, higher alcohols, and esters is selected.

又,本發明之化妝料組成物中,在不損及本發明之效果的範圍內可添加一般在化妝料或皮膚外用醫藥使用的任意成分。作為所述任意成分的具體例,可舉出增黏/膠化劑、抗氧化劑、紫外線吸收劑、色素劑、鉗合劑、防腐劑、pH調整劑、香料、蜜蠟等。此等任意成分的摻混比例可視其目的適宜選擇而決定。又,在不損及本發明之效果的範圍內亦可添加其他的藥效植物萃取物。 Further, in the cosmetic composition of the present invention, any component generally used in cosmetics or skin external medicine can be added to the extent that the effects of the present invention are not impaired. Specific examples of the optional component include a thickening/gelling agent, an antioxidant, an ultraviolet absorber, a coloring agent, a chelating agent, a preservative, a pH adjuster, a fragrance, and beeswax. The blending ratio of such optional components can be determined according to the appropriate choice of the purpose. Further, other medicinal plant extracts may be added to the extent that the effects of the present invention are not impaired.

(機能性食品) (functional food)

本發明之生薑加工物亦可使其含於食品、飲料而作成機能性食品。 The ginger processed product of the present invention can also be used as a functional food in foods and beverages.

此處所稱「機能性食品」,係指一般食品,此外尚指健康食品、營養輔助食品、營養機能食品、營養保健食品等以維持健康為目的而攝取之食品或飲料。另外,作為機能性食品予以製品化時,亦可添加用於食品的各種添加劑,具體而言為著色料、保存料、增黏安定劑、抗氧化劑漂白劑、防菌防黴劑、酸味料、調味料、乳化劑、強化劑、製造用劑、香料等。 The term "functional food" as used herein refers to general foods, and refers to foods or beverages that are ingested for the purpose of maintaining health, such as health foods, nutritional supplements, nutritional functional foods, and nutraceutical foods. In addition, when functionalized as a functional food, various additives for foods may be added, specifically, coloring materials, preservatives, viscosity-enhancing stabilizers, antioxidant bleaching agents, antibacterial and antifungal agents, sour materials, Seasonings, emulsifiers, fortifiers, manufacturing agents, perfumes, and the like.

屬機能性食品之對象的食品、飲料不特別限定,特佳為添加了生薑的風味而更適口的食品、飲料。例如,食品可舉出香腸、火腿、海鮮加工品、果凍、糖果、口香糖等的食品類。又,飲料可舉出各種的茶類、清涼飲 料水、酒類、營養飲料等。 The foods and beverages which are the target of the functional food are not particularly limited, and foods and beverages which are more palatable with the flavor of ginger are particularly preferred. For example, the food may be a food such as sausage, ham, seafood processed product, jelly, candy, or chewing gum. Also, the drinks can be exemplified by various teas and refreshing drinks. Water, alcohol, nutritious drinks, etc.

(補充食品) (supplementary food)

本發明之補充食品係含有本發明之生薑加工物。本發明之補充食品的形態不特別限制,可為錠劑、散劑、顆粒劑、膠囊劑、糖衣錠、膜劑、片劑、嚼錠劑、溶液、乳濁液、懸浮液等的任意之形態。 The supplementary food of the present invention contains the ginger processed product of the present invention. The form of the supplementary food of the present invention is not particularly limited, and may be any form of a tablet, a powder, a granule, a capsule, a sugar-coated tablet, a film, a tablet, a chewable tablet, a solution, an emulsion, a suspension, or the like.

本發明之補充食品,除本發明之生薑加工物以外,亦可含有作為補充食品而通常使用的任意成分。作為此種成分,可舉出例如胺基酸、胜肽;維生素E、維生素C、維生素A、維生素B、葉酸等的維生素類;礦物質類;糖類;無機鹽類;檸檬酸或其鹽;茶萃取物;油脂;蜂膠、蜂王乳、牛磺酸等的滋養強壯成分;生薑萃取物、高麗人參萃取物等的生藥萃取物;草藥類:膠原蛋白等。 The supplementary food of the present invention may contain, in addition to the ginger processed product of the present invention, any component which is usually used as a supplementary food. Examples of such a component include amino acids, peptides, vitamins such as vitamin E, vitamin C, vitamin A, vitamin B, and folic acid; minerals; sugars; inorganic salts; citric acid or a salt thereof; Tea extract; oil; prototrophic and strong ingredients such as propolis, royal jelly, taurine, etc.; raw extracts of ginger extract, Korean ginseng extract, etc.; herbal: collagen.

[實施例] [Examples]

以下舉出實施例對本發明之方法更具體地加以說明。此外,本發明並非僅限定於以下之實施例。 The method of the present invention will be more specifically described below by way of examples. Further, the present invention is not limited to the following embodiments.

(實施例1) (Example 1)

將作為原料生薑的高知縣產之大生薑的根莖保存於維持在溫度-18℃的冷凍庫(HOSHIZAKI INVERTER)15小時,而得到經冷凍的生薑(冷凍步驟)。其次,將經冷凍的生薑以頂蓋自動開閉式高壓蒸氣滅菌器(HICLAVE HG- 50,平山製作所(股)製),在水蒸氣共存下、溫度121℃、壓力0.15MPa下進行5小時蒸氣加熱處理(蒸氣加熱步驟)。接著,將經蒸氣加熱處理的生薑,以乾燥器(小型食品乾燥器SM7S-EH木原製作所(股)製)在溫度80℃乾燥24小時(乾燥步驟),而得到實施例1之生薑加工物。 The rhizome of the large ginger produced in Kochi Prefecture, which is the raw material ginger, was stored in a freezer (HOSHIZAKI INVERTER) maintained at a temperature of -18 ° C for 15 hours to obtain frozen ginger (freezing step). Secondly, the frozen ginger is automatically opened and closed with a top cover high pressure steam sterilizer (HICLAVE HG- 50, manufactured by Hirayama Seisakusho Co., Ltd., steam heat treatment (vapor heating step) was carried out for 5 hours under the coexistence of steam at a temperature of 121 ° C and a pressure of 0.15 MPa. Next, the steam-heated ginger was dried in a desiccator (small food dryer SM7S-EH Kurohara Seisakusho Co., Ltd.) at a temperature of 80 ° C for 24 hours (drying step) to obtain the ginger processing of Example 1. Things.

(比較例1) (Comparative Example 1)

將與實施例1相同的高知縣產之大生薑的根莖保存於維持在溫度-18℃的冷凍庫(HOSHIZAKI INVERTER)15小時,而得到比較例1之生薑加工物。 The rhizome of the large ginger produced in Kochi Prefecture, which was the same as in Example 1, was stored in a freezer (HOSHIZAKI INVERTER) maintained at a temperature of -18 ° C for 15 hours to obtain a ginger processed product of Comparative Example 1.

(比較例2) (Comparative Example 2)

將與實施例1相同的高知縣產之大生薑的根莖,以頂蓋自動開閉式高壓蒸氣滅菌器(HICLAVE HG-50,平山製作所(股)製),在水蒸氣共存下、溫度121℃、壓力0.15~0.2MPa下進行15分鐘蒸氣加熱處理(蒸氣加熱步驟)。接著,將經蒸氣加熱處理的生薑,以乾燥器(小型食品乾燥器SM7S-EH木原製作所(股)製)在溫度80℃乾燥24小時(乾燥步驟),而得到比較例2之生薑加工物。 The rhizome of the large ginger produced in Kochi Prefecture, which is the same as in Example 1, was autoclaved with a top cover, and was placed in a high-pressure steam sterilizer (HICLAVE HG-50, manufactured by Hirayama Seisakusho Co., Ltd.) at a temperature of 121 ° C in the presence of steam. The steam heat treatment (vapor heating step) was carried out for 15 minutes at a pressure of 0.15 to 0.2 MPa. Next, the steam-heated ginger was dried at a temperature of 80 ° C for 24 hours in a desiccator (small food dryer SM7S-EH Kurohara Seisakusho Co., Ltd.) (drying step) to obtain ginger processing of Comparative Example 2. Things.

<生薑加工物中的6-薑酚及6-生薑醇含量的評定> <Evaluation of 6-gingerol and 6-gingerol content in ginger processing>

將以上述方法所得之各生薑加工物浸漬於甲醇100%溶劑2小時,其後以3000rpm進行離心10分鐘,再將上清液以0.45μm濾器進行過濾處理而製作萃取液,並分析 該萃取液之6-薑酚及6-生薑醇的含量。 Each ginger processed product obtained by the above method was immersed in a methanol 100% solvent for 2 hours, and then centrifuged at 3000 rpm for 10 minutes, and the supernatant was filtered through a 0.45 μm filter to prepare an extract, and analyzed. The content of 6-gingerol and 6-gingerol in the extract.

分析係以Waters公司製Alliance HPLC系統進行。使用管柱為Wakosil-II 5C18 HG,溶劑係使用乙腈與水,隨時間改變溶劑比率。流速係以1ml/min進行,吸光度係以280nm進行。由6-薑酚、6-生薑醇之各者的峰面積與濃度比作成檢量線,進行定量分析。 The analysis was carried out using an Alliance HPLC system manufactured by Waters. The column was Wakosil-II 5C18 HG, and the solvent was acetonitrile and water, and the solvent ratio was changed over time. The flow rate was carried out at 1 ml/min, and the absorbance was carried out at 280 nm. A peak area and a concentration ratio of each of 6-gingerol and 6-gingerol were used as a calibration curve for quantitative analysis.

(評定結果) (Evaluation Results)

表1示出各生薑加工物1g中的6-薑酚及6-生薑醇的含量(mg/g)及6-生薑醇與6-薑酚的比率(6-生薑醇/6-薑酚)。此外,比較例1中使用的生薑加工物(冷凍生薑)未進行乾燥處理,含有進行過乾燥處理的實施例1,比較例2之生薑加工物的約10倍的水分。 Table 1 shows the contents of 6-gingerol and 6-gingerol (mg/g) and the ratio of 6-gingerol to 6-gingerol in 1 g of each ginger processed product (6-gingerol/6 - gingerol). Further, the ginger processed product (frozen ginger) used in Comparative Example 1 was not subjected to a drying treatment, and contained about 10 times of water content of the ginger processed product of Example 1 and Comparative Example 2 which had been subjected to the drying treatment.

如表1所示,可知實施過冷凍處理、蒸氣加熱處理的實施例1之生薑加工物,與僅實施過冷凍處理的比較例1之生薑加工物、僅實施過蒸氣加熱處理的比較例2之生薑加工物相比,6-生薑醇對6-薑酚的比例遠大於此兩者。如此表示,藉由組合冷凍處理與蒸氣加熱處理,可製造生薑醇的含量及比例較多的生薑加工物。 As shown in Table 1, the ginger processed product of Example 1 subjected to the freezing treatment and the steam heat treatment, and the ginger processed product of Comparative Example 1 which had only been subjected to the freezing treatment, and the comparative example in which only the steam heat treatment was performed were known. Compared with the ginger processed product, the ratio of 6-gingerol to 6-gingerol is much larger than the two. As described above, by combining the freezing treatment and the steam heat treatment, it is possible to produce a ginger processed product having a high content and a large proportion of ginger alcohol.

以下,作為參考例,示出「根據生薑加工方法的差異之製造時間的比較(參考例1)」、「冷凍處理對生薑帶來的效果(參考例2)」的評定結果。 In the following, as a reference example, the results of the evaluation of "comparation of the manufacturing time according to the difference of the ginger processing method (Reference Example 1)" and "the effect of the freezing treatment on the ginger (Reference Example 2)" are shown.

參考例1:「根據生薑加工方法的差異之製造時間的比較」 Reference Example 1: "Comparison of manufacturing time based on differences in ginger processing methods"

針對本發明之生薑加工物之製造方法、與本案發明人等在專利文獻4(專利第5297294號公報)所報導之使用習知發酵液的生薑加工物之製造方法,就製造時間與6-生薑醇含量加以評定。 The method for producing a ginger processed product according to the present invention, and the method for producing a ginger processed product using a conventional fermentation liquid reported in Patent Document 4 (Patent No. 5297294), the manufacturing time and the manufacturing time. - Ginger alcohol content is assessed.

由於本發明之生薑加工物之製造方法係與上述實施例1相同,故省略其詳細說明。 Since the method for producing the ginger processed product of the present invention is the same as that of the above-described first embodiment, the detailed description thereof will be omitted.

使用習知發酵液的參考例1之生薑加工物之製造方法如下。 The method for producing the ginger processed product of Reference Example 1 using the conventional fermentation broth is as follows.

首先,藉由將使糙米發酵而得到的糙米發酵物(酒粕)與水,以重量比1:9,攪拌至呈均勻,而調製成發酵液。 First, a brown rice fermented product (wine cellar) obtained by fermenting brown rice and water were stirred at a weight ratio of 1:9 to be uniform to prepare a fermentation liquid.

其次,作為發酵步驟,係在不鏽鋼製之容器中添加原料生薑(切成一半的三州生薑(黃生薑))100g、與以上述方法製造的發酵液60mL,將原料生薑浸漬於發酵液中,在常溫下保持24小時,而得到發酵生薑。接著,將該發酵生薑置入具備遠紅外線作為熱源的蒸煮器中,花費50小時由30℃使溫度上昇至78℃,在維持78℃的狀態下,於濕度70%下保持300小時予以蒸透。其後,將該生薑由 78℃緩緩冷卻,花費50小時回至室溫。熟成步驟需要合計400小時。熟成後,使該生薑進行乾燥1個月,由此得到參考例1之生薑加工物(發酵黑生薑)。 Next, as a fermentation step, 100 g of raw ginger (cut into half of Sanzhou ginger (yellow ginger)) and 60 mL of the fermentation liquid produced by the above method were added to a container made of stainless steel, and the raw ginger was immersed in In the fermentation broth, it was kept at normal temperature for 24 hours to obtain fermented ginger. Next, the fermented ginger was placed in a digester equipped with far infrared rays as a heat source, and the temperature was raised to 78 ° C from 30 ° C for 50 hours, and steamed at 70 ° C for 300 hours while maintaining the temperature at 78 ° C. through. Thereafter, the ginger is Slowly cool at 78 ° C and take 50 hours to return to room temperature. The ripening step requires a total of 400 hours. After the ripening, the ginger was dried for one month to obtain a ginger processed product (fermented black ginger) of Reference Example 1.

表2示出實施例1及參考例1之生薑加工物的製造時間、及6-生薑醇的含量。 Table 2 shows the production time of the ginger processed product of Example 1 and Reference Example 1, and the content of 6-gingerol.

此外,6-生薑醇的含量的評定方法係與上述<生薑加工物中的6-薑酚及6-生薑醇含量的評定>相同。 Further, the method for evaluating the content of 6-gingerol is the same as the evaluation of the content of 6-gingerol and 6-gingerol in the above-mentioned <Ginger processed product>.

於實施例1中,製造時間,以冷凍步驟及蒸氣加熱步驟的合計時間計為20小時(再加上乾燥步驟24小時)、6-生薑醇的含量為3.21mg/g。另一方面,於參考例1中,製造時間,以發酵步驟及熟成步驟的合計計為424小時(再加上乾燥步驟1個月)、6-生薑醇的含量為3.09mg/g。 In Example 1, the production time was 20 hours in the total of the freezing step and the steam heating step (plus the drying step for 24 hours), and the content of 6-gingerol was 3.21 mg/g. On the other hand, in Reference Example 1, the production time was 424 hours (plus one drying step) and the content of 6-gingerol was 3.09 mg/g in total of the fermentation step and the ripening step.

由此結果可知,根據本發明之生薑加工物之製造方法,可在極短時間內製造含有與以使用習知發酵液的製造方法所得之生薑加工物同等或其以上之6-生薑醇的生薑加工物。 As a result, according to the method for producing a ginger processed product of the present invention, it is possible to produce 6-glycine which is equivalent to or higher than the ginger processed product obtained by the production method using the conventional fermentation liquid in a very short time. A ginger processed product of alcohol.

參考例2:「冷凍處理對生薑帶來的效果」 Reference Example 2: "The effect of freezing on ginger"

為了探討對原料生薑進行冷凍處理所產生的作用,而評定將高知縣產之大生薑的根莖保存於維持在溫度-18℃的冷凍庫(HOSHIZAKI INVERTER)15小時所得之冷凍處理生薑中的6-薑酚及6-生薑醇的含量。 In order to investigate the effect of the freezing treatment of the raw ginger, the roots of the large ginger produced in Kochi Prefecture were evaluated in 6 of the frozen processed ginger obtained by maintaining the HOSHIZAKI INVERTER at a temperature of -18 ° C for 15 hours. - content of gingerol and 6-gingerol.

此外,對於採一般的保存方法之保存在溫度為5℃~7℃的冰箱(HOSHIZAKI INVERTER)15小時的高知縣大生薑亦進行同樣的評定。 In addition, Kochi Prefecture Ginger, which was stored in a refrigerator (HOSHIZAKI INVERTER) at a temperature of 5 ° C to 7 ° C for 15 hours, was also subjected to the same evaluation.

表3示出進行過冷凍處理的生薑(有冷凍處理)、與未進行冷凍處理的生薑(無冷凍處理)其各者每1g之6-薑酚與6-生薑醇的含量(mg/g)。又,表3中分別示出有冷凍處理之生薑與無冷凍處理之生薑中的6-薑酚與6-生薑醇的比率(有冷凍處理/無冷凍處理)。 Table 3 shows the content of 6-gingerol and 6-gingerol per 1 g of ginger (with freezing treatment) and ginger (without freezing treatment) which were not subjected to freezing treatment (mg) /g). Further, Table 3 shows the ratio of 6-gingerol to 6-gingerol in the ginger which was subjected to the freezing treatment and the ginger which was not subjected to the freezing treatment (there was a freezing treatment/freezing treatment).

由表3可知,有冷凍處理之生薑,與無冷凍處理之生薑相比,6-薑酚的含量明顯較多。又,可知6-生薑醇的含量也較多。由此意味藉由冷凍處理,使6-生薑醇及6-薑酚的含量增加。 As can be seen from Table 3, the amount of 6-gingerol was significantly higher in the ginger which had been subjected to the freezing treatment than the ginger which was not subjected to the freezing treatment. Further, it is understood that the content of 6-gingerol is also large. This means that the content of 6-gingerol and 6-gingerol is increased by the freezing treatment.

(實施例2) (Example 2)

將作為原料生薑的高知縣產之大生薑的根莖,未予切 割而是整個保存於維持在溫度-18℃的冷凍庫14小時,得到經冷凍的生薑(冷凍步驟)。 The rhizome of the large ginger produced in Kochi Prefecture, which is the raw material of ginger, was not cut. The whole was stored in a freezer maintained at a temperature of -18 ° C for 14 hours to obtain frozen ginger (freezing step).

其次,將經冷凍的生薑(塊狀)以蒸煮鍋(SOS120/10SV,Samsung),在水蒸氣共存下且溫度121℃下進行4小時蒸氣加熱處理(蒸氣加熱步驟)。 Next, the frozen ginger (blocky) was subjected to steam heat treatment (steam heating step) in a steaming pot (SOS120/10SV, Samsung) in the presence of steam at a temperature of 121 ° C for 4 hours.

其次,將經蒸氣加熱處理的生薑,以減壓乾燥器(南極防熱,訂製品),在溫度80℃下進行4小時減壓乾燥(乾燥步驟1)。接著,以上述冷凍庫再度進行14小時冷凍(冷凍步驟2)。接著,再度以減壓乾燥器(南極防熱,訂製品),在溫度80℃下進行4小時乾燥(乾燥步驟2)並重複上述(冷凍步驟2)~(乾燥步驟2)0至5次,而得到實施例2之生薑加工物。 Next, the steam-heated ginger was dried under reduced pressure (drying step 1) at a temperature of 80 ° C for 4 hours in a vacuum dryer (Antarctic heat-proof, ordered product). Next, the above freezer was again subjected to freezing for 14 hours (freezing step 2). Then, again, using a vacuum dryer (Antarctic heat prevention, ordered product), drying at a temperature of 80 ° C for 4 hours (drying step 2) and repeating the above (freezing step 2) ~ (drying step 2) 0 to 5 times, and The ginger processed product of Example 2 was obtained.

(實施例3) (Example 3)

除將高知縣產之大生薑的根莖薄切成3mm左右以外係以與實施例2同樣的方式得到實施例3之生薑加工物。 The ginger processed product of Example 3 was obtained in the same manner as in Example 2 except that the rhizome of the large ginger produced in Kochi Prefecture was thinly cut into about 3 mm.

將評定實施例2及實施例3之生薑加工物中的6-薑酚及6-生薑醇的含量的結果示於表4。 The results of evaluating the contents of 6-gingerol and 6-gingerol in the ginger processed products of Example 2 and Example 3 are shown in Table 4.

由與實施例1(80℃、24小時加熱乾燥)的對比確認,藉由實施例2,3中所採用之重複減壓乾燥與冷凍處理的方法,可增加生薑加工品所含的6-生薑醇(及6-薑酚)。特別是在使用塊狀之生薑的實施例2之方法中,含有2倍以上之6-生薑醇的絕對量,可抑制加工中之6-生薑醇的蒸散,確認可獲得含有大量之6-生薑醇的生薑加工品。 From the comparison with Example 1 (80 ° C, heating and drying for 24 hours), it was confirmed that the method of repeated vacuum drying and freezing treatment used in Examples 2 and 3 can increase the 6- contained in the ginger processed product. Ginger alcohol (and 6-gingerol). In particular, in the method of Example 2 using bulk ginger, the absolute amount of 6-glycol alcohol containing 2 times or more can suppress the evapotranspiration of 6-gingerol in processing, and it is confirmed that a large amount can be obtained. 6-Ginger processed ginger.

[產業上可利用性] [Industrial availability]

本發明之生薑加工物之製造方法,對於以高濃度含有作為身體保養製品、機能性食品、補充食品等的素材,具有有效性備受期待之優良的生理活性‧藥理作用的生薑醇類之生薑加工物可縮短加工時間,工業上效果可期。 The method for producing a ginger processed product of the present invention is a ginger alcohol having excellent physiological activity and pharmacological action which is expected to be highly effective in containing materials such as body care products, functional foods, and supplementary foods at a high concentration. The ginger processed material can shorten the processing time, and the industrial effect can be expected.

Claims (10)

一種生薑加工物之製造方法,其特徵為具有下述步驟:將作為原料的生薑進行冷凍處理之冷凍步驟;及將冷凍步驟後的生薑,在水蒸氣共存下且溫度100℃以上150℃以下的條件下進行加熱處理至生薑所含之生薑醇類的濃度高於薑酚類的濃度之蒸氣加熱步驟。 A method for producing a ginger processed product, comprising the steps of: freezing a raw material as a raw material for freezing; and cooling the ginger after the freezing step at a temperature of 100 ° C or more and 150 The heat treatment is carried out under the conditions of ° C or less until the concentration of the ginger alcohol contained in the ginger is higher than the concentration of the ginger phenol. 如請求項1之生薑加工物之製造方法,其中前述冷凍步驟中的溫度為-10℃以下。 The method for producing a ginger processed product according to claim 1, wherein the temperature in the freezing step is -10 ° C or lower. 如請求項1之生薑加工物之製造方法,其中前述蒸氣加熱步驟中的溫度為110℃以上130℃以下,且壓力為0.12MPa以上0.30MPa以下。 The method for producing a ginger processed product according to claim 1, wherein the temperature in the steam heating step is 110° C. or higher and 130° C. or lower, and the pressure is 0.12 MPa or more and 0.30 MPa or less. 如請求項1之生薑加工物之製造方法,其中前述蒸氣加熱步驟中的處理時間為3小時以上。 The method for producing a ginger processed product according to claim 1, wherein the treatment time in the steam heating step is 3 hours or longer. 如請求項1之生薑加工物之製造方法,其係具有將前述蒸氣加熱步驟後的生薑進行乾燥之乾燥步驟。 A method for producing a ginger processed product according to claim 1, comprising the step of drying the ginger after the steam heating step. 如請求項5之生薑加工物之製造方法,其中在前述乾燥步驟中,對前述蒸氣加熱步驟後的生薑重複進行乾燥處理與冷凍處理,而使其乾燥至成為既定的水分含量以下為止。 The method for producing a ginger processed product according to claim 5, wherein in the drying step, the ginger after the steam heating step is repeatedly subjected to a drying treatment and a freezing treatment, and dried until the predetermined moisture content is equal to or lower. 如請求項6之生薑加工物之製造方法,其中乾燥處理為減壓乾燥,冷凍處理中的溫度為-10℃以下。 The method for producing a ginger processed product according to claim 6, wherein the drying treatment is drying under reduced pressure, and the temperature in the freezing treatment is -10 ° C or lower. 如請求項1至7中任一項之生薑加工物之製造方法,其中作為原料的生薑為塊狀之生薑。 The method for producing a ginger processed product according to any one of claims 1 to 7, wherein the ginger as a raw material is a block-shaped ginger. 一種生薑加工物,其係以如請求項8之製造方法製造而成。 A ginger processed product produced by the manufacturing method of claim 8. 一種機能性食品,其係含有如請求項9之生薑加工物。 A functional food comprising the ginger processed product of claim 9.
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