TW201521605A - Hygiene management method for food processing equipment or cooking utensils - Google Patents

Hygiene management method for food processing equipment or cooking utensils Download PDF

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TW201521605A
TW201521605A TW103135876A TW103135876A TW201521605A TW 201521605 A TW201521605 A TW 201521605A TW 103135876 A TW103135876 A TW 103135876A TW 103135876 A TW103135876 A TW 103135876A TW 201521605 A TW201521605 A TW 201521605A
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detergent composition
mass
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food processing
management method
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TWI665971B (en
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Noboru Matsuo
Kiyoaki Yoshikawa
Takashi Ootani
Kaoru Takamura
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Kao Corp
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46N-acyl derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463Organic compounds; Microorganisms; Enzymes
    • A23L3/3481Organic compounds containing oxygen
    • A23L3/3508Organic compounds containing oxygen containing carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

A hygiene management method for food processing equipment or cooking utensils, having a process C in which steps 1, 2, and 3 are performed and a process D in which step 4 is performed at least once. After step 3 in process C, the initial step 4 is performed in process D, in a state in which at least one type of compound selected from a group comprising polylysine and protamine are in contact. Step 1: A step in which the food processing equipment or cooking utensils are cleaned. Step 2: A step in which, after step 1, a composition (A) containing at least one type of compound selected from a group comprising polylysine and protamine is caused to come in contact with the food processing equipment or the cooking utensils. Step 3: A step in which, after step 2, the state in which the at least one type of compound selected from a group comprising polylysine and protamine is caused to be in contact is held for at least four hours. Step 4: A step in which the food processing equipment or the cooking utensils are used.

Description

食品加工設備或調理器具之衛生管理方法 Sanitary management method for food processing equipment or conditioning equipment

本發明係關於一種食品加工設備或調理器具之衛生管理方法。 The present invention relates to a method of sanitary management of a food processing device or conditioning device.

關於餐館之廚房等中所使用之廚刀、砧板、瀝水籃(draining basket)等調理器具類,食品工廠或飲料工廠等中所使用之製造或加工食品或飲料之機器或設備等與食品直接接觸之器具、機器或設備類,為了保持衛生度,每天於生產食品或飲料後,進行所使用之器具、機器或設備之洗淨作業。 For food processing equipment such as kitchen knives, chopping boards, and draining baskets used in restaurant kitchens, etc., food or equipment used in food factories or beverage factories, etc. In order to maintain hygiene, the appliance, machine or equipment is used to clean the appliance, machine or equipment used after the production of food or beverage.

該等器具、機器或設備之硬質表面形狀為各種各樣,且有較小之間隙或傷痕、手無法觸及之複雜形狀。於該等之洗淨時,存在海綿或毛刷等之機械力未充分到達之部位。於此種部位中容易殘留無法澈底去除之污垢、或無法澈底去除或無法澈底消滅之微生物。因此,存在因所殘留之微生物再次增殖而成為不衛生之狀態之情形。 The hard surface shapes of such appliances, machines or equipment are varied and have small gaps or scars and complex shapes that are inaccessible to the hand. At the time of such washing, there is a portion where the mechanical force such as a sponge or a brush is not sufficiently reached. In such a place, it is easy to leave the dirt which cannot be removed at the bottom, or the microorganism which cannot be removed at the bottom or which cannot be completely eliminated. Therefore, there is a case where the remaining microorganisms re-grow and become unsanitary.

於洗淨器具、機器或設備後,大多情況下為了對未經洗淨澈底去除之微生物進行殺菌而使用次氯酸鈉。然而,於使用次氯酸鈉之情形時,擔心源自次氯酸鈉之氯氣味自器具、機器或設備轉移至食材,因此於使用次氯酸鈉後,為了去除次氯酸鈉,必須充分地清洗器具、機器或設備。次氯酸鈉與器具、機器或設備接觸之期間雖可獲得殺菌效果,但其效果為暫時性。因此,藉由清洗器具、機器或設備而去除次氯酸鈉後,由次氯酸鈉所得之殺菌效果完全未波及器具、機器或設備。因此,於使用次氯酸鈉之情形時,存在殘存之微生物進行再增 殖,結果成為菌數較高之不衛生之狀態之情形。 After washing the appliance, machine or equipment, in most cases, sodium hypochlorite is used in order to sterilize the microorganisms that have not been washed and removed. However, in the case of using sodium hypochlorite, there is concern that the chlorine odor derived from sodium hypochlorite is transferred from the appliance, machine or equipment to the foodstuff, and therefore, after the use of sodium hypochlorite, it is necessary to sufficiently clean the appliance, the machine or the equipment in order to remove the sodium hypochlorite. Although the bactericidal effect can be obtained during the contact of sodium hypochlorite with the appliance, machine or equipment, the effect is temporary. Therefore, after the sodium hypochlorite is removed by washing the appliance, machine or equipment, the bactericidal effect obtained by the sodium hypochlorite does not affect the appliance, the machine or the equipment at all. Therefore, in the case of using sodium hypochlorite, there is a residual microbe to re-increase The result is a state in which the number of bacteria is unsanitary.

另一方面,業界亦提出並非暫時性之效果而強調持續性之制菌、殺菌或抑菌之方案。例如,於日本專利特開平4-18003號公報及日本專利特開2002-322009號公報中,提出有使用聚離胺酸、魚精蛋白來改良制菌、殺菌或抑菌效果之持續性的除菌劑組合物。US-A 2005/0049181揭示有包含聚離胺酸或魚精蛋白之生物膜(biofilm)抑制劑組合物。 On the other hand, the industry has also proposed a solution that does not have a temporary effect and emphasizes continuous bacteriostatic, bactericidal or bacteriostatic effects. For example, Japanese Patent Laid-Open No. Hei 4-108003 and Japanese Patent Laid-Open Publication No. 2002-322009 disclose the use of polylysine and protamine to improve the persistence of bacteriostatic, bactericidal or bacteriostatic effects. Bacterial composition. US-A 2005/0049181 discloses biofilm inhibitor compositions comprising polyaminic acid or protamine.

本發明係關於一種食品加工設備或調理器具之衛生管理方法,其包括如下製程:製程C,其進行下述步驟1、步驟2及步驟3;及製程D,其進行1次以上之下述步驟4,且於製程C之步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下,進行製程D之最初之步驟4。 The present invention relates to a food processing apparatus or a sanitary management method for a conditioning apparatus, comprising the following process: Process C, which performs the following steps 1, Step 2 and Step 3; and Process D, which performs the following steps one or more times 4. After the step 3 of the process C, the first step 4 of the process D is carried out in a state in which one or more compounds selected from the group consisting of polylysine and protamine are contacted.

[製程C] [Process C]

步驟1:洗淨食品加工設備或調理器具之步驟 Step 1: Steps to wash the food processing equipment or conditioning equipment

步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟 Step 2: After step 1, the step of contacting composition A containing one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus

步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟 Step 3: After step 2, the step of contacting one or more compounds selected from the group consisting of poly-lysine and protamine with the above-mentioned food processing equipment or conditioning apparatus for 4 hours or more

[製程D] [Process D]

步驟4:使用上述食品加工設備或調理器具之步驟 Step 4: Steps of using the food processing equipment or conditioning apparatus described above

於日本專利特開平4-18003號公報或日本專利特開2002-322009號公報中,關於主要著眼於將源自食材之油或蛋白等食材污垢去除之具體的衛生管理方法,並未提及。因此可認為,於尚大量存在殘留污垢之狀態下,即便應用日本專利特開平4-18003號公報之殺菌用組合物或日本專利特開2002-322009號公報之除菌劑,亦存在未充分地達到其效果之情形。因此,業界期待亦在基於洗淨步驟之基礎上,實現綜合性之衛生管理方法。於US-A 2005/0049181中,關於簡便有效、且尤其以食品加工設備作為對象之衛生管理方法,並未提及。 In the Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 2002-322009, a specific hygiene management method focusing on the removal of foodstuffs such as oil or protein derived from foodstuffs is not mentioned. Therefore, in the state in which a large amount of residual dirt is present, the sterilizing composition of JP-A-4-18003 or the sterilizing agent of JP-A-2002-322009 is not sufficiently used. The situation to achieve its effect. Therefore, the industry expects to implement a comprehensive approach to hygiene management based on the washing step. In US-A 2005/0049181, there is no mention of a sanitary management method that is simple and effective, and in particular for food processing equipment.

本發明提供一種簡便且有效之食品加工設備或調理器具之衛生管理方法,其無需清洗如次氯酸鈉般之殺菌劑之勞力及時間,且即便混入菌亦可抑制菌數之增加。 The invention provides a simple and effective method for sanitary management of a food processing device or a conditioning device, which does not need to clean the labor and time of a bactericide such as sodium hypochlorite, and can inhibit the increase of the number of bacteria even if mixed with bacteria.

根據本發明,提供一種簡便且有效之食品加工設備或調理器具之衛生管理方法,其無需清洗殺菌劑之勞力及時間,且即便混入菌亦可抑制菌數之增加。具體而言,本發明係關於一種用以將食品或飲料所接觸之調理器具或製造機器、設備等之硬質表面高效率地洗淨殺菌,而減少因微生物所引起之危害之衛生管理方法。 According to the present invention, there is provided a simple and effective method for sanitary management of a food processing device or a conditioning device which does not require labor and time for cleaning the sterilizing agent, and which suppresses an increase in the number of bacteria even if mixed with bacteria. More specifically, the present invention relates to a sanitary management method for efficiently cleaning and sterilizing a hard surface to which a food or beverage is contacted, or a hard surface of a manufacturing machine, equipment, or the like, to reduce the damage caused by microorganisms.

[製程C] [Process C]

於本發明之製程C中,進行下述步驟1、步驟2、及步驟3。 In the process C of the present invention, the following steps 1, 2, and 3 are carried out.

步驟1:洗淨食品加工設備或調理器具之步驟 Step 1: Steps to wash the food processing equipment or conditioning equipment

步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟 Step 2: After step 1, the step of contacting composition A containing one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus

步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟 Step 3: After step 2, the step of contacting one or more compounds selected from the group consisting of poly-lysine and protamine with the above-mentioned food processing equipment or conditioning apparatus for 4 hours or more

製程C可作為於操作停止期間中進行之步驟而實施。於本發明中,所謂操作停止期間,表示長時間、例如4小時以上不使用食品加工設備或調理器具之期間。又,於本發明中,所謂操作期間,為連續地或間歇地使用食品加工設備或調理器具之期間。於間歇地使用之情形時,表示使用與使用之間隔為短時間、例如未達4小時之期間,係自於該條件下之最初使用至最後使用為止之期間。 Process C can be implemented as a step performed during the operation stop period. In the present invention, the period during which the operation is stopped indicates a period in which the food processing equipment or the conditioning apparatus is not used for a long period of time, for example, 4 hours or longer. Further, in the present invention, the period during the operation is a period in which the food processing equipment or the conditioning apparatus is continuously or intermittently used. In the case of intermittent use, the period between the use and use is short, for example, less than 4 hours, from the initial use to the last use under the conditions.

<步驟1> <Step 1>

步驟1係洗淨食品加工設備或調理器具之步驟。就洗淨性之觀點而言,步驟1較佳為藉由含有界面活性劑之洗淨劑組合物洗淨食品加工設備或調理器具之步驟。 Step 1 is a step of washing the food processing equipment or conditioning apparatus. From the viewpoint of detergency, the step 1 is preferably a step of washing the food processing device or the conditioning device by the detergent composition containing the surfactant.

成為本發明之對象之食品加工設備可列舉:食用肉切片機、製麵機、油炸鍋(frier)、電飯煲等大型機器。又,成為本發明之對象之調理器具可列舉:砧板、廚刀、瀝水籃等。對於設置於食品加工設備上的網帶輸送機或帶式輸送機或者砧板或瀝水籃等存在傷痕、裂縫或間隙等微小空間之食品加工設備或調理器具而言,簡便地抑制菌之增殖的本發明之效果亦有效地發揮作用。 Examples of the food processing equipment to be the object of the present invention include large-scale machines such as a meat slicer, a noodle maker, a fryer, and a rice cooker. Further, examples of the conditioning tool to be the object of the present invention include a cutting board, a kitchen knife, a drain basket, and the like. For food processing equipment or conditioning equipment such as mesh belt conveyors or belt conveyors or cutting boards or drain baskets that are placed on food processing equipment, such as scratches, cracks, or gaps, simply inhibit the proliferation of bacteria. The effects of the invention also work effectively.

就高效率地減少菌數之觀點而言,步驟1中之食品加工設備或調理器具之洗淨較佳為使用洗淨劑組合物進行。作為洗淨劑組合物,可列舉:含有界面活性劑、具體而言選自由非離子界面活性劑、陽離子界面活性劑、兩性界面活性劑及陰離子界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物。 From the viewpoint of efficiently reducing the number of bacteria, the washing of the food processing equipment or the conditioning apparatus in the step 1 is preferably carried out using a detergent composition. The detergent composition may be one or more selected from the group consisting of a surfactant, specifically, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and an anionic surfactant. A detergent composition for a surfactant.

作為非離子界面活性劑,可列舉:烷基葡糖苷、聚氧伸烷基烷基醚、聚氧伸烷基烯基醚、烷基甘油醚等。 Examples of the nonionic surfactant include alkyl glucosides, polyoxyalkylene alkyl ethers, polyoxyalkylene alkyl alkenyl ethers, and alkyl glyceryl ethers.

作為陽離子界面活性劑,可列舉:氯化單烷基三甲基銨(MTAC,Mono-alkyl Trimethyl Ammonium Chloride)或氯化二烷基二甲基銨(DDAC,Dialkyl Dimethyl Ammonium Chloride)、氯化苄烷 銨、苄索氯銨、聚六亞甲基雙胍(PHMB,Polyhexamethylene Biguanide)、烷基氯化吡啶鎓鹽。 The cationic surfactant may, for example, be monoalkylammonium chloride (MTAC) or Dialkyl Dimethyl Ammonium Chloride (DDAC) or benzyl chloride. alkyl Ammonium, benzethonium chloride, polyhexamethylene biguanide (PHMB, Polyhexamethylene Biguanide), alkyl pyridinium chloride.

作為兩性界面活性劑,可列舉:磺基甜菜鹼、羰基甜菜鹼等甜菜鹼系界面活性劑,氧化胺等。 Examples of the amphoteric surfactant include a betaine-based surfactant such as sulfobetaine or carbonyl betaine, and an amine oxide.

作為陰離子界面活性劑,可列舉:具有烴基之硫酸酯鹽、具有烴基之磺酸鹽、脂肪酸鹽、脂肪酸酯鹽、具有烴基之磷酸酯鹽及胺基酸鹽。具體而言,可列舉:烷基硫酸酯鹽、烯基硫酸酯鹽、聚氧伸烷基烷基醚硫酸酯鹽、聚氧伸烷基烯基醚硫酸酯鹽等具有烴基之硫酸酯鹽,烷基苯磺酸鹽、烯烴磺酸鹽、烷磺酸鹽等具有烴基之磺酸鹽,α-磺基脂肪酸鹽等具有烴基之脂肪酸鹽,α-磺基脂肪酸酯鹽等具有烴基之脂肪酸酯鹽,烷基磷酸酯鹽、聚氧伸烷基烷基醚磷酸酯鹽等具有烴基之磷酸酯鹽,醯基麩胺酸鹽、丙胺酸衍生物、甘胺酸衍生物、精胺酸衍生物等具有烴基之胺基酸鹽等。 Examples of the anionic surfactant include a sulfate salt having a hydrocarbon group, a sulfonate having a hydrocarbon group, a fatty acid salt, a fatty acid ester salt, a phosphate salt having a hydrocarbon group, and an amino acid salt. Specific examples thereof include a sulfate salt having a hydrocarbon group such as an alkyl sulfate salt, an alkenyl sulfate salt, a polyoxyalkylene alkyl ether sulfate salt, or a polyoxyalkylene ether sulfate salt. a sulfonate having a hydrocarbon group such as an alkylbenzenesulfonate, an olefin sulfonate or an alkanesulfonate, a fatty acid salt having a hydrocarbon group such as an α-sulfo fatty acid salt, or a fat having a hydrocarbon group such as an α-sulfofatty acid ester salt a phosphate salt having a hydrocarbon group such as an acid ester salt, an alkyl phosphate salt or a polyoxyalkylene alkyl phosphate phosphate salt, a mercapto glutamate, an alanine derivative, a glycine derivative, a arginine An amine acid salt or the like having a hydrocarbon group such as a derivative.

作為含有陰離子界面活性劑之洗淨劑組合物,例如可列舉下述實施例之洗淨劑1。 Examples of the detergent composition containing an anionic surfactant include the detergent 1 of the following examples.

又,作為含有非離子界面活性劑之洗淨劑,例如可列舉下述實施例之洗淨劑2。 Further, examples of the detergent containing a nonionic surfactant include the detergent 2 of the following examples.

作為步驟1中所使用之洗淨劑組合物,就表現出本發明之效果之觀點而言,較佳為如洗淨劑2般之含有非離子界面活性劑、且陰離子界面活性劑之含量較少之洗淨劑組合物。 As a detergent composition used in the step 1, from the viewpoint of exhibiting the effects of the present invention, it is preferred to contain a nonionic surfactant as in the detergent 2, and the content of the anionic surfactant is higher. Less detergent composition.

作為步驟1中所使用之洗淨劑組合物,就簡便性之觀點而言,較佳為下述洗淨劑組合物B。洗淨劑組合物B之較佳態樣係如下述步驟5。 The detergent composition used in the step 1 is preferably the following detergent composition B from the viewpoint of simplicity. A preferred embodiment of detergent composition B is as shown in step 5 below.

洗淨劑組合物B:陰離子界面活性劑之含量為10質量%以下之洗淨劑組合物;或包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合 物;或陰離子界面活性劑之含量為10質量%以下,且包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物 Detergent composition B: a detergent composition having an anionic surfactant content of 10% by mass or less; or a group selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant A detergent combination of more than one surfactant The content of the anionic surfactant is 10% by mass or less, and includes at least one surfactant selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant. Agent composition

關於洗淨劑組合物B中之陰離子界面活性劑之含量,就更有效地發揮組合物A之效果之觀點而言,較佳為10質量%以下,更佳為5質量%以下,進而佳為3質量%以下,進而更佳為2質量%以下,進一步佳為1質量%以下,進一步更佳為0質量%,即,洗淨劑組合物B不含陰離子界面活性劑。 The content of the anionic surfactant in the detergent composition B is preferably 10% by mass or less, more preferably 5% by mass or less, from the viewpoint of more effectively exhibiting the effect of the composition A, and further preferably 3 mass % or less, more preferably 2 mass % or less, further preferably 1 mass % or less, further more preferably 0 mass %, that is, the detergent composition B does not contain an anionic surfactant.

洗淨劑組合物B較佳為包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物。洗淨劑組合物B亦可為實質上不含陰離子界面活性劑之洗淨劑組合物。此處,關於洗淨劑組合物B,所謂「實質上不含」陰離子界面活性劑,係指陰離子界面活性劑之含量於組合物中為10質量%以下。 The detergent composition B is preferably a detergent composition containing at least one surfactant selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant. The detergent composition B can also be a detergent composition that is substantially free of anionic surfactants. Here, the "substantially free" anionic surfactant in the detergent composition B means that the content of the anionic surfactant is 10% by mass or less in the composition.

於洗淨劑組合物B中,可將選自由烷基苯磺酸鹽、聚氧伸烷基烷基醚硫酸酯鹽、及聚氧伸烷基烯基醚硫酸酯鹽所組成之群中之1種以上陰之離子界面活性劑的含量限制於上述範圍內。 In the detergent composition B, it may be selected from the group consisting of an alkylbenzenesulfonate, a polyoxyalkylene alkylsulfate salt, and a polyoxyalkylene ether sulfate salt. The content of one or more kinds of anionic surfactants is limited to the above range.

於本發明中,較佳為藉由洗淨劑組合物B來洗淨製程D之步驟4、較佳為最後之步驟4中所使用之食品加工設備或調理器具。 In the present invention, it is preferred to wash the food processing equipment or conditioning apparatus used in the step 4 of the process D, preferably the final step 4, by the detergent composition B.

步驟1中之食品加工設備或調理器具之洗淨並無特別限制,例如可列舉:浸漬洗淨或使用海綿、毛刷或硬毛刷等洗淨用具之擦洗之洗淨等。 The washing of the food processing equipment or the conditioning apparatus in the step 1 is not particularly limited, and examples thereof include immersion washing or scrubbing using a sponge such as a sponge, a brush or a bristle brush.

於步驟1中,可進行複數次洗淨,亦可其後進行清洗、乾燥等操作。於該情形時,洗淨時亦可使用洗淨劑組合物B。 In the step 1, the cleaning may be performed plural times, or may be followed by washing, drying, and the like. In this case, the detergent composition B can also be used for washing.

<步驟2> <Step 2>

步驟2係於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成 之群中之1種以上之化合物的組合物A與食品加工設備或調理器具接觸之步驟。 Step 2 is followed by step 1, and the composition is selected from the group consisting of poly-lysine and protamine. The step of contacting the composition A of one or more of the compounds in the group with a food processing device or a conditioning device.

例如,步驟2中,於步驟1後使上述組合物A與食品加工設備或調理器具接觸,而使選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物附著於食品加工設備或調理器具上。 For example, in the step 2, after the step 1, the composition A is brought into contact with a food processing device or a conditioning device, and one or more compounds selected from the group consisting of polylysine and protamine are attached to the food. Processing equipment or conditioning equipment.

作為聚離胺酸,並無特別限定,例如為作為必需胺基酸之L-離胺酸以直鏈狀進行聚合而成之聚胺基酸,可列舉藉由化學合成而製造之α-聚離胺酸與藉由醱酵法而製造之ε-聚離胺酸等。就進一步提高殺菌性之觀點而言,聚離胺酸較佳為ε-聚離胺酸。就進一步提高殺菌性之觀點而言,聚離胺酸之分子量較佳為3,000以上,更佳為4,000以上,並且較佳為10,000以下,更佳為8,000以下,進而佳為6,000以下,進而更佳為5,000以下。該分子量係藉由GPC-LALLS(Gel Permeation Chromatography-Low Angle Laser Light Scattering,凝膠滲透層析-低角度雷射光散射)法測得之重量平均分子量。又,就安全性之觀點而言,較佳為可用作食品添加物之品質水準之聚離胺酸。 The polyamino acid is not particularly limited, and examples thereof include a polyamino acid obtained by linearly polymerizing L-isoamine acid as an essential amino acid, and α-poly which is produced by chemical synthesis. An lysine and an ε-polyamine acid produced by a fermentation method. From the viewpoint of further improving the bactericidal property, the polylysine is preferably ε-polyamine. The molecular weight of the polylysine is preferably 3,000 or more, more preferably 4,000 or more, and is preferably 10,000 or less, more preferably 8,000 or less, still more preferably 6,000 or less, and further preferably from the viewpoint of further improving bactericidal property. It is 5,000 or less. The molecular weight is a weight average molecular weight measured by a GPC-LALLS (Gel Permeation Chromatography - Low Angle Laser Light Scattering) method. Further, from the viewpoint of safety, it is preferably a polylysine which can be used as a quality level of a food additive.

作為魚精蛋白,並無特別限定,例如可列舉:對自以下之群所獲得的1種以上之魚之魚精(soft roe)進行酸處理,藉此自存在於各魚之精子核中之核魚精蛋白(nucleoprotamine)純化之魚精蛋白等,所述群為由以鮭魚、鯡魚(herring)、虹鱒、鮪魚為代表之約50種以上之魚所組成之群。就進一步提高殺菌性之觀點,且就安全性、經濟性及獲取性之觀點而言,較佳為自鮭魚、鯡魚、虹鱒、鮪魚、烏魚(mullet)之魚精所獲得之魚精蛋白,更佳為自鮭魚之魚精所獲得之魚精蛋白。又,就安全性之觀點而言,較佳為可用作食品或食品添加物之品質水準之魚精蛋白。 The protamine is not particularly limited, and for example, an acid roe of one or more kinds of fish obtained from the following group is subjected to acid treatment, thereby being present in the sperm nuclei of each fish. A nucleoprotamine-purified protamine or the like, which is a group consisting of about 50 species of fish represented by salmon, herring, rainbow trout, and squid. From the viewpoint of further improving bactericidal properties, and preferably from the viewpoints of safety, economy, and accessibility, protamine obtained from fish carp, carp, rainbow trout, carp, and mullet More preferably, it is a protamine obtained from the fish of the squid. Further, from the viewpoint of safety, it is preferably a protamine which can be used as a quality level of food or food additives.

魚精蛋白可列舉游離魚精蛋白、魚精蛋白酸鹽。就進一步提高殺菌性及調配性之觀點而言,魚精蛋白較佳為魚精蛋白酸鹽。更佳為 選自由魚精蛋白硫酸鹽及魚精蛋白鹽酸鹽所組成之群中之1種以上。就獲取之容易性之觀點而言,更佳為魚精蛋白鹽酸鹽。 The protamine may be exemplified by free protamine and protamine. The protamine is preferably a protamine salt from the viewpoint of further improving bactericidal property and formulation. Better One or more of the group consisting of protamine sulfate and protamine hydrochloride are selected. From the viewpoint of easiness of obtaining, it is more preferred to be protamine hydrochloride.

就殺菌性之觀點而言,組合物A較佳為含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物及水。關於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的含量,就進一步提高殺菌性之觀點而言,於組合物A中,較佳為0.05質量%以上,更佳為0.1質量%以上,並且較佳為1質量%以下,更佳為0.7質量%以下。 From the viewpoint of bactericidal properties, the composition A preferably contains one or more compounds selected from the group consisting of poly-lysine and protamine, and water. With respect to the content of the compound selected from the group consisting of poly (L-amino acid) and protamine, it is preferably 0.05% by mass or more, and more preferably 0.05% by mass or more, from the viewpoint of further improving the bactericidal property. It is preferably 0.1% by mass or more, and preferably 1% by mass or less, more preferably 0.7% by mass or less.

就進一步提高殺菌性之觀點而言,組合物A較佳為含有聚離胺酸及魚精蛋白。於該情形時,就進一步提高殺菌性之觀點而言,組合物A中之(聚離胺酸之質量)/(魚精蛋白之質量)之比較佳為0.1以上,更佳為0.15以上,進而佳為0.2以上,進而更佳為0.5以上,並且較佳為10以下,更佳為5以下,進而佳為2以下。 From the viewpoint of further improving bactericidal properties, the composition A preferably contains poly-lysine and protamine. In this case, from the viewpoint of further improving the bactericidal property, the ratio of (the mass of the polylysine acid) / (the mass of the protamine) in the composition A is preferably 0.1 or more, more preferably 0.15 or more, and further It is preferably 0.2 or more, more preferably 0.5 or more, and is preferably 10 or less, more preferably 5 or less, and still more preferably 2 or less.

就進一步提高殺菌性之觀點及安全性之觀點而言,組合物A較佳為含有苄醇。於該情形時,就進一步提高殺菌性之觀點而言,苄醇之含量於組合物A中較佳為0.01質量%以上,更佳為0.05質量%以上,進而佳為0.075質量%以上,進而更佳為0.1質量%以上,進一步佳為0.15質量%以上,並且較佳為5質量%以下,更佳為3質量%以下,進而佳為1質量%以下,進而更佳為0.5質量%以下,進一步佳為0.35質量%以下,進一步較佳為0.3質量%以下,進一步更佳為0.25質量%以下,進一步更佳為0.22質量%以下。 From the viewpoint of further improving the bactericidal viewpoint and safety, the composition A preferably contains benzyl alcohol. In this case, the content of the benzyl alcohol is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.075% by mass or more, and further preferably from the viewpoint of further improving the bactericidal property in the composition A. It is preferably 0.1% by mass or more, more preferably 0.15% by mass or more, and is preferably 5% by mass or less, more preferably 3% by mass or less, still more preferably 1% by mass or less, still more preferably 0.5% by mass or less, further The content is preferably 0.35 mass% or less, more preferably 0.3 mass% or less, still more preferably 0.25 mass% or less, still more preferably 0.22 mass% or less.

於組合物A含有苄醇之情形時,聚離胺酸與魚精蛋白之合計含量相對於苄醇之含量之質量比以(聚離胺酸與魚精蛋白之合計含量)/(苄醇之含量)計,就進一步提高殺菌性之觀點而言,較佳為0.1以上,更佳為0.2以上,進而佳為0.3以上,進而更佳為0.5以上,進一步佳為0.8以上。並且較佳為10以下,更佳為5以下,進而佳為3以下。 In the case where the composition A contains benzyl alcohol, the mass ratio of the total content of polylysine and protamine to the content of benzyl alcohol is (the total content of poly(amino acid and protamine) / (benzyl alcohol) In terms of further improving the bactericidal property, the content is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.3 or more, still more preferably 0.5 or more, and still more preferably 0.8 or more. It is preferably 10 or less, more preferably 5 or less, and still more preferably 3 or less.

組合物A之形態較佳為液體組合物。組合物A更佳為含有水之液 體組合物。於為含有水之液體組合物之情形時,就使用時之安全性之觀點而言,20℃之pH值較佳為5以上,更佳為6以上,並且較佳為9以下,更佳為8以下。 The form of the composition A is preferably a liquid composition. Composition A is more preferably a liquid containing water Body composition. In the case of a liquid composition containing water, the pH at 20 ° C is preferably 5 or more, more preferably 6 or more, and preferably 9 or less, more preferably from the viewpoint of safety at the time of use. 8 or less.

組合物A亦可於不損及本發明之效果及安全性之範圍內含有其他成分,例如界面活性劑、香料、防腐劑、pH調整劑、著色料等。 Composition A may also contain other ingredients such as surfactants, perfumes, preservatives, pH adjusters, coloring materials, etc., within the scope not impairing the effects and safety of the present invention.

組合物A較佳為含有水。水之含量於組合物中較佳為50質量%以上,更佳為70質量%以上,進而佳為90質量%以上,並且較佳為未達100質量%,更佳為99.9質量%以下,進而佳為99.8質量%以下,進而更佳為99.7質量%以下。 Composition A preferably contains water. The content of water in the composition is preferably 50% by mass or more, more preferably 70% by mass or more, further preferably 90% by mass or more, and preferably less than 100% by mass, more preferably 99.9% by mass or less. Preferably, it is 99.8 mass% or less, and more preferably 99.7% by mass or less.

就操作容易性之觀點而言,組合物A之25℃之黏度較佳為0.1mPa.s以上,更佳為0.5mPa.s以上,並且較佳為10mPa.s以下,更佳為5mPa.s以下。再者,黏度可使用BM型黏度計(轉子No.M1,轉速60r/min,自攪拌開始後起1分鐘後)進行測定。 From the viewpoint of ease of handling, the viscosity of the composition A at 25 ° C is preferably 0.1 mPa. Above s, more preferably 0.5mPa. Above s, and preferably 10 mPa. Below s, more preferably 5mPa. s below. Further, the viscosity can be measured using a BM type viscometer (rotor No. M1, rotation speed: 60 r/min, one minute after the start of stirring).

就易用性及殺菌效果之觀點而言,組合物A較佳為均勻透明之液體。 Composition A is preferably a uniformly transparent liquid from the viewpoints of ease of use and bactericidal effect.

組合物A之製造方法並無特別限定,較佳為最初添加構成組成之大部分之水,其後以任意順序添加各成分,然後進行攪拌直至變得均勻透明為止。較理想為其後測定pH值,以成為特定之pH值之方式使用無機酸進行調整。 The method for producing the composition A is not particularly limited, and it is preferred to initially add water which constitutes a large part of the composition, and then add each component in an arbitrary order, and then stir until it becomes uniform and transparent. It is preferred to adjust the pH afterwards and adjust it with a mineral acid in such a manner as to be a specific pH.

作為於步驟2中使組合物A與食品加工設備或調理器具接觸之方法,可列舉噴霧、塗佈、浸漬等方法。於步驟2中,就操作性之觀點而言,較佳為噴霧或塗佈組合物A而使其與食品加工設備或調理器具接觸。於步驟2中,可進行1次以上之使組合物A與食品加工設備或調理器具接觸之操作。 As a method of bringing the composition A into contact with the food processing equipment or the conditioning apparatus in the step 2, methods such as spraying, coating, and immersion may be mentioned. In step 2, from the standpoint of workability, it is preferred to spray or coat composition A to contact the food processing equipment or conditioning apparatus. In step 2, the operation of bringing the composition A into contact with the food processing equipment or conditioning apparatus may be performed more than once.

於步驟2中,關於組合物A對食品加工設備或調理器具之接觸量,就進一步提高殺菌性之觀點而言,較佳為0.002g/cm2以上,更佳 為0.003g/cm2以上,進而佳為0.004g/cm2以上,進而更佳為0.005g/cm2以上,並且較佳為0.04g/cm2以下,更佳為0.030g/cm2以下,進而佳為0.025g/cm2以下,進而更佳為002g/cm2以下。該接觸量於組合物A中之選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的含量為上述範圍之情形時較佳。 In the second step, the contact amount of the composition A with the food processing equipment or the conditioning device is preferably 0.002 g/cm 2 or more, and more preferably 0.003 g/cm 2 or more from the viewpoint of further improving the bactericidal property. Further, it is preferably 0.004 g/cm 2 or more, more preferably 0.005 g/cm 2 or more, and is preferably 0.04 g/cm 2 or less, more preferably 0.030 g/cm 2 or less, and still more preferably 0.025 g/cm 2 . Hereinafter, it is more preferably 002 g/cm 2 or less. The amount of the contact is preferably in the case where the content of the compound selected from the group consisting of polylysine and protamine in the composition A is in the above range.

又,於步驟2中,關於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物對食品加工設備或調理器具之接觸量,就進一步提高殺菌性之觀點而言,較佳為4×10-6g/cm2以上,更佳為6×10-6g/cm2以上,進而佳為8×10-6g/cm2以上,進而更佳為1×10-5g/cm2以上,進一步佳為3×10-5g/cm2以上,並且較佳為8×10-5g/cm2以下,更佳為6×10-5g/cm2以下,進而佳為5×10-5g/cm2以下,進而更佳為4×10-5g/cm2以下。較佳為以成為該接觸量之方式使組合物A與食品加工設備或調理器具接觸。 Further, in the step 2, the contact amount of one or more compounds selected from the group consisting of polylysine and protamine to the food processing equipment or the conditioning device is further improved in terms of bactericidal properties. It is preferably 4 × 10 -6 g / cm 2 or more, more preferably 6 × 10 -6 g / cm 2 or more, further preferably 8 × 10 -6 g / cm 2 or more, and further preferably 1 × 10 - 5 g/cm 2 or more, further preferably 3 × 10 -5 g/cm 2 or more, and preferably 8 × 10 -5 g / cm 2 or less, more preferably 6 × 10 -5 g / cm 2 or less, Further, it is preferably 5 × 10 -5 g / cm 2 or less, and more preferably 4 × 10 -5 g / cm 2 or less. Preferably, composition A is contacted with a food processing device or conditioning device in such a manner as to be in contact.

<步驟3> <Step 3>

為了充分地表現出選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的殺菌效果,於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與食品加工設備或調理器具接觸的狀態保持4小時以上。於本發明之步驟3中,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與食品加工設備或調理器具接觸的狀態保持之時間較佳為5小時以上,更佳為6小時以上,進而佳為7小時以上,進而更佳為8小時以上,進一步佳為9小時以上,進一步較佳為10小時以上,進一步更佳為11小時以上,進一步更佳為12小時以上,進一步更佳為16小時以上,並且就作業效率之觀點而言,較佳為5天以下,更佳為3天以下,進而佳為2天以下,進而更佳為24小時以下,進一步佳為20小時以下,進一步較佳為10小時以下,進一步更佳為5小時以下。 In order to sufficiently exhibit the bactericidal effect of one or more compounds selected from the group consisting of polylysine and protamine, after step 2, a group selected from the group consisting of polylysine and protamine The state in which one or more of the compounds are in contact with the food processing equipment or the conditioning apparatus is maintained for more than 4 hours. In the step 3 of the present invention, the state in which one or more compounds selected from the group consisting of polylysine and protamine are kept in contact with the food processing equipment or the conditioning device is preferably maintained for 5 hours or longer. More preferably, it is 6 hours or more, further preferably 7 hours or longer, more preferably 8 hours or longer, further preferably 9 hours or longer, further preferably 10 hours or longer, further more preferably 11 hours or longer, and still more preferably 12 hours. More preferably, it is more than 16 hours or more, and it is preferably 5 days or less, more preferably 3 days or less, more preferably 2 days or less, still more preferably 24 hours or less, from the viewpoint of work efficiency. It is preferably 20 hours or shorter, more preferably 10 hours or shorter, still more preferably 5 hours or shorter.

於步驟2中進行複數次使選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的操作之情形時,可自最後操作之結束起保持上述時間。 When the operation of contacting one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus is carried out in the step 2, the end of the last operation may be performed. Keep up the above time.

選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態之保持能以開放系統、密閉系統之任一種進行。又,關於保持選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態之溫度,就進一步提高殺菌性之觀點而言,較佳為5℃以上,更佳為10℃以上,並且就作業效率之觀點而言,較佳為50℃以下,更佳為40℃以下,進而佳為30℃以下。 The state in which one or more of the compounds selected from the group consisting of poly-aminic acid and protamine is contacted can be maintained in either an open system or a closed system. In addition, the temperature at which the one or more compounds selected from the group consisting of poly-amino acid and protamine are kept in contact with each other is preferably 5° C. or more, and more preferably from the viewpoint of further improving bactericidal properties. It is 10 ° C or more, and from the viewpoint of work efficiency, it is preferably 50 ° C or lower, more preferably 40 ° C or lower, and still more preferably 30 ° C or lower.

[製程D] [Process D]

本發明之製程D進行1次以上之下述步驟4。 The process D of the present invention is carried out one or more times in the following step 4.

步驟4:使用上述食品加工設備或調理器具之步驟 Step 4: Steps of using the food processing equipment or conditioning apparatus described above

本發明之特徵在於:於製程C之步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下進行製程D之最初之步驟4。於本發明中,可重複進行製程C與製程D。 The present invention is characterized in that, after the step 3 of the process C, the first step 4 of the process D is carried out in a state in which one or more compounds selected from the group consisting of polylysine and protamine are contacted. In the present invention, Process C and Process D can be repeated.

<步驟4> <Step 4>

製程D之步驟4係使用操作期間之食品加工設備或調理器具之步驟。食品加工設備或調理器具之使用只要進行與各自相對應之通常使用即可。 Step 4 of Process D is the use of food processing equipment or conditioning equipment during the operation. The use of the food processing equipment or the conditioning apparatus may be carried out as usual in accordance with each.

通常,藉由使用食品加工設備或調理器具,源自食品等之菌與食品加工設備或調理器具接觸。 Generally, bacteria derived from foods and the like are brought into contact with a food processing device or a conditioning device by using a food processing device or a conditioning device.

於本發明中,就進一步提高殺菌性之觀點而言,為了使於步驟2中接觸之選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物充分地殘留於食品加工設備或調理器具上,較佳為於製程C之步驟3後,不清洗組合物A而進行製程D之最初之步驟4。 In the present invention, in order to further improve the bactericidal property, one or more compounds selected from the group consisting of poly-lysine and protamine which are contacted in the step 2 are sufficiently left in the food processing. Preferably, in the apparatus or conditioning apparatus, after the step 3 of the process C, the first step 4 of the process D is carried out without cleaning the composition A.

<步驟5> <Step 5>

就洗淨性及菌之增殖抑制性之觀點而言,本發明之製程D更佳為包括下述步驟5。即,較佳為藉由洗淨劑組合物洗淨步驟4中所使用之食品加工設備或調理器具。 The process D of the present invention preferably comprises the following step 5 from the viewpoints of detergency and inhibition of proliferation of bacteria. That is, it is preferred to wash the food processing equipment or conditioning apparatus used in the step 4 by the detergent composition.

步驟5:於步驟4後,使用洗淨劑組合物洗淨食品加工設備或調理器具之步驟 Step 5: After step 4, the steps of washing the food processing equipment or conditioning apparatus using the detergent composition

就洗淨性及菌之增殖抑制性之觀點而言,步驟5之洗淨劑組合物較佳為下述洗淨劑組合物B。 The detergent composition of the step 5 is preferably the following detergent composition B from the viewpoint of detergency and inhibition of proliferation of bacteria.

洗淨劑組合物B:陰離子界面活性劑之含量為10質量%以下之洗淨劑組合物;或包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物;或陰離子界面活性劑之含量為10質量%以下,且包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物 Detergent composition B: a detergent composition having an anionic surfactant content of 10% by mass or less; or a group selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant a detergent composition of one or more kinds of surfactants; or an anionic surfactant content of 10% by mass or less, and comprising a group selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant Detergent composition of one or more surfactants

非離子界面活性劑、陽離子界面活性劑、兩性界面活性劑、及陰離子界面活性劑分別可使用步驟1之洗淨劑組合物B中所說明者。洗淨劑組合物B亦可為實質上不含陰離子界面活性劑之洗淨劑組合物。洗淨劑組合物B較佳為含有非離子界面活性劑。 The nonionic surfactant, the cationic surfactant, the amphoteric surfactant, and the anionic surfactant can be used as described in the detergent composition B of the first step. The detergent composition B can also be a detergent composition that is substantially free of anionic surfactants. The detergent composition B preferably contains a nonionic surfactant.

就更有效地發揮組合物A之效果之觀點而言,洗淨劑組合物B中之陰離子界面活性劑之含量較佳為10質量%以下,更佳為5質量%以下,進而佳為3質量%以下,進而更佳為2質量%以下,進一步佳為1質量%以下,進一步較佳為0.5質量%以下,進一步更佳為0質量%,即,洗淨劑組合物B不含陰離子界面活性劑。 The content of the anionic surfactant in the detergent composition B is preferably 10% by mass or less, more preferably 5% by mass or less, and further preferably 3%, from the viewpoint of more effectively exerting the effect of the composition A. % or less, more preferably 2% by mass or less, further preferably 1% by mass or less, further preferably 0.5% by mass or less, still more preferably 0% by mass, that is, the detergent composition B does not contain an anionic interface activity. Agent.

洗淨劑組合物B以合計量計,較佳為含有9質量%以上的選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑,更佳為含有16質量%以上,進而佳為含有25質量%以上,並且較佳為含有60質量%以下,更佳為含有50質量% 以下,進而佳為含有40質量%以下。 The detergent composition B preferably contains at least 9% by mass of a surfactant selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant in a total amount of 9% by mass or more. More preferably, it is contained in an amount of 16% by mass or more, more preferably 25% by mass or more, and more preferably 60% by mass or less, and more preferably 50% by mass or more. In the following, it is preferably contained in an amount of 40% by mass or less.

洗淨劑組合物B較佳為含有5質量%以上之非離子界面活性劑,更佳為含有9質量%以上,進而佳為含有15質量%以上,並且較佳為含有50質量%以下,更佳為含有40質量%以下,進而佳為含有30質量%以下。 The detergent composition B preferably contains 5% by mass or more of a nonionic surfactant, more preferably 9% by mass or more, further preferably 15% by mass or more, and more preferably 50% by mass or less. It is preferably contained in an amount of 40% by mass or less, and more preferably 30% by mass or less.

洗淨劑組合物B較佳為含有0.5質量%以上之陽離子界面活性劑,更佳為含有3質量%以上,並且較佳為含有10質量%以下,更佳為含有5質量%以下。 The detergent composition B preferably contains 0.5% by mass or more of a cationic surfactant, more preferably 3% by mass or more, and preferably 10% by mass or less, more preferably 5% by mass or less.

洗淨劑組合物B較佳為含有4.5質量%以上之兩性界面活性劑,更佳為含有6質量%以上,進而佳為含有10%以上,並且較佳為含有30質量%以下,更佳為含有25質量%以下,進而佳為含有20質量%以下。 The detergent composition B preferably contains 4.5% by mass or more of the amphoteric surfactant, more preferably 6% by mass or more, further preferably 10% or more, and more preferably 30% by mass or less, more preferably It is contained in an amount of 25% by mass or less, and more preferably 20% by mass or less.

洗淨劑組合物B較佳為含有非離子性界面活性劑,更佳為含有非離子界面活性劑及兩性界面活性劑。 The detergent composition B preferably contains a nonionic surfactant, more preferably a nonionic surfactant and an amphoteric surfactant.

就黏度、除菌性、洗淨性及低溫保存穩定性之觀點而言,洗淨劑組合物B較佳為含有烷基葡糖苷。作為烷基葡糖苷,就同樣之觀點而言,更佳為下述通式(1)所表示之化合物。 The detergent composition B preferably contains an alkyl glucoside from the viewpoints of viscosity, sterilizing property, detergency, and low-temperature storage stability. From the same viewpoint, the alkyl glucoside is more preferably a compound represented by the following formula (1).

R11-(OR12)xGy (1) R 11 -(OR 12 ) x G y (1)

[式中,R11為碳數為8以上、較佳為10以上且16以下、較佳為14以下之直鏈烷基。R12為碳數2以上且4以下之伸烷基,較佳為伸乙基或伸丙基,更佳為伸乙基。G為源自還原糖之殘基。x表示平均值為0以上且6以下之數。y表示平均值為1以上且10以下、較佳為5以下、更佳為2以下之數] [wherein R 11 is a linear alkyl group having a carbon number of 8 or more, preferably 10 or more and 16 or less, preferably 14 or less. R 12 is an alkylene group having 2 or more and 4 or less carbon atoms, preferably an extended ethyl group or a stretched propyl group, more preferably an extended ethyl group. G is a residue derived from a reducing sugar. x represents an average value of 0 or more and 6 or less. y represents an average value of 1 or more and 10 or less, preferably 5 or less, more preferably 2 or less]

於通式(1)之化合物中,G為源自還原糖之殘基。G之原料之還原糖亦可為醛糖與酮糖之任一種。又,G之原料之還原糖可列舉:碳數3之丙糖、碳數4之丁糖、碳數5之戊糖、碳數6之己糖。醛糖具體可列舉:洋芹糖、阿拉伯糖、半乳糖、葡萄糖、來蘇糖、甘露糖、瓊脂 糖、醛糖、艾杜糖、塔羅糖、木糖。又,酮糖具體可列舉果糖。就黏度、除菌性、洗淨性及低溫保存穩定性之觀點而言,本發明之G之原料之還原糖較佳為碳數5之醛糖即戊醛糖或碳數6之醛糖即己醛糖,更佳為葡萄糖。 In the compound of the formula (1), G is a residue derived from a reducing sugar. The reducing sugar of the raw material of G may also be any of aldose and ketose. Further, examples of the reducing sugar of the raw material of G include a carbon number 3 propylene sugar, a carbon number 4 buty sugar, a carbon number 5 pentose sugar, and a carbon number 6 hexose sugar. Specific examples of aldose include parsley, arabinose, galactose, glucose, lyxose, mannose, and agar. Sugar, aldose, idose, tarotose, xylose. Further, specific examples of the ketose include fructose. The reducing sugar of the raw material of G of the present invention is preferably an aldose having a carbon number of 5, that is, an aldopentose or an aldose having a carbon number of 6, in view of viscosity, sterilizing property, detergency, and low-temperature storage stability. Aldohexose, more preferably glucose.

通式(1)之化合物可藉由使用酸觸媒使上述還原糖與R11-(OR12)x-OH進行縮醛化反應或縮酮化反應而容易地合成。又,於縮醛化反應之情形時,可為半縮醛結構,亦可為通常之縮醛結構。 The compound of the formula (1) can be easily synthesized by subjecting the above reducing sugar to acetalization or ketalization reaction with R 11 -(OR 12 ) x -OH using an acid catalyst. Further, in the case of the acetalization reaction, it may be a hemiacetal structure or a usual acetal structure.

關於洗淨劑組合物B中之烷基葡糖苷之含量,就黏度、除菌性、洗淨性及低溫保存穩定性之觀點而言,較佳為5質量%以上,更佳為7質量%以上,進而佳為9質量%以上,並且就黏度及調配性之觀點而言,較佳為22.5質量%以下,更佳為21.5質量%以下,進而佳為20質量%以下,進而更佳為17質量%以下。 The content of the alkyl glucoside in the detergent composition B is preferably 5% by mass or more, and more preferably 7% by mass, from the viewpoints of viscosity, sterilizing property, detergency, and low-temperature storage stability. The above is more preferably 9% by mass or more, and is preferably 22.5 mass% or less, more preferably 21.5 mass% or less, further preferably 20 mass% or less, and still more preferably 17 from the viewpoint of viscosity and blendability. Below mass%.

就黏度、除菌性、洗淨性及低溫保存穩定性之觀點而言,洗淨劑組合物B較佳為含有氧化胺。就黏度、除菌性及低溫保存穩定性之觀點而言,氧化胺具有碳數較佳為8以上、更佳為10以上、進而佳為11以上、並且較佳為14以下、更佳為13以下之烴基。更佳為氧化胺具有1個碳數較佳為8以上、更佳為10以上、進而佳為11以上、並且較佳為14以下、更佳為13以下之烴基與2個碳數為1以上且3以下之烴基。碳數8以上且14以下之烴基較佳為烷基或烯基,更佳為烷基。碳數1以上且3以下之烴基較佳為烷基或烯基,更佳為烷基。 The detergent composition B preferably contains an amine oxide from the viewpoints of viscosity, sterilizing property, detergency, and low-temperature storage stability. The amine oxide has a carbon number of preferably 8 or more, more preferably 10 or more, further preferably 11 or more, and preferably 14 or less, more preferably 13 in terms of viscosity, sterilization property, and low-temperature storage stability. The following hydrocarbon groups. More preferably, the amine oxide has one carbon number of preferably 8 or more, more preferably 10 or more, further preferably 11 or more, and preferably 14 or less, more preferably 13 or less, and 2 or more carbon atoms are 1 or more. And a hydrocarbon group of 3 or less. The hydrocarbon group having 8 or more and 14 or less carbon atoms is preferably an alkyl group or an alkenyl group, more preferably an alkyl group. The hydrocarbon group having 1 or more and 3 or less carbon atoms is preferably an alkyl group or an alkenyl group, more preferably an alkyl group.

具體而言,作為較佳之氧化胺,可列舉下述通式(2)之化合物。 Specifically, as a preferred amine oxide, a compound of the following formula (2) can be mentioned.

[式中,R21為碳數8以上、較佳為10以上、更佳為11以上、並且14以下、較佳為13以下之直鏈烷基或直鏈烯基,R23、R24為碳數1以上且3以下之烷基或羥基烷基。R22為碳數1以上且5以下、較佳為2或3之伸烷基。A為選自由酯基、醯胺基、及醚基所組成之群中之基,n為0或1,較佳為0] In the formula, R 21 is a linear alkyl group or a linear alkenyl group having a carbon number of 8 or more, preferably 10 or more, more preferably 11 or more, and 14 or less, preferably 13 or less, and R 23 and R 24 are An alkyl group or a hydroxyalkyl group having 1 or more and 3 or less carbon atoms. R 22 is an alkylene group having 1 or more and 5 or less, preferably 2 or 3. A is a group selected from the group consisting of an ester group, a guanamine group, and an ether group, and n is 0 or 1, preferably 0]

氧化胺較佳為具有碳數8以上、較佳為10以上、更佳為11以上、並且14以下、較佳為13以下之烷基的烷基二甲基氧化胺。 The amine oxide is preferably an alkyl dimethyl amine oxide having an alkyl group having 8 or more carbon atoms, preferably 10 or more, more preferably 11 or more, and 14 or less, preferably 13 or less.

關於洗淨劑組合物B中之氧化胺之含量,就黏度及除菌性之觀點而言,較佳為4.5質量%以上,更佳為5.5質量%以上,進而佳為7質量%以上,進而更佳為10質量%以上,並且就黏度、調配性及低溫保存穩定性之觀點而言,較佳為22質量%以下,更佳為21質量%以下,進而佳為17質量%以下。 The content of the amine oxide in the detergent composition B is preferably 4.5% by mass or more, more preferably 5.5% by mass or more, and still more preferably 7% by mass or more, from the viewpoint of viscosity and sterilizing property. It is more preferably 10% by mass or more, and is preferably 22% by mass or less, more preferably 21% by mass or less, and still more preferably 17% by mass or less from the viewpoint of viscosity, blending property, and low-temperature storage stability.

洗淨劑組合物B較佳為含有氧化胺與烷基葡糖苷。於該情形時,關於氧化胺與烷基葡糖苷之質量比,就黏度、除菌性、洗淨性及低溫保存穩定性之觀點而言,以洗淨劑組合物B中之氧化胺/烷基葡糖苷計,較佳為0.20以上,更佳為0.25以上,進而佳為0.35以上,進而更佳為0.65以上,並且較佳為8以下,更佳為5以下,進而佳為3以下,進而更佳為2以下。 The detergent composition B preferably contains an amine oxide and an alkyl glucoside. In this case, regarding the mass ratio of the amine oxide to the alkyl glucoside, the amine oxide/alkane in the detergent composition B is from the viewpoints of viscosity, sterilizing property, detergency, and low-temperature storage stability. The glucoside is preferably 0.20 or more, more preferably 0.25 or more, still more preferably 0.35 or more, still more preferably 0.65 or more, and still more preferably 8 or less, still more preferably 5 or less, still more preferably 3 or less, and further preferably More preferably 2 or less.

就除菌性之觀點而言,洗淨劑組合物B較佳為含有鋅或鋅鹽。鋅較佳為以鋅離子之形式含有。作為鋅鹽,可列舉:硫酸鋅、硝酸鋅、氯化鋅、過氯酸鋅、葡萄糖酸鋅、酒石酸鋅、溴化鋅、氯化鋅銨、硫酸鋅鋁、硫酸鋅鉀、碘化鋅等。就抗菌性之觀點而言,較佳為選自由硫酸鋅、硝酸鋅、葡萄糖酸鋅、酒石酸鋅、氯化鋅及過氯酸鋅所組成之群中之1種以上之化合物。又,就通用性之觀點而言,較佳為硫酸鋅。關於洗淨劑組合物B中之鋅或鋅鹽之含量,以鋅或鋅鹽之鋅離子 換算計,就除菌性之觀點而言,較佳為0.02質量%以上,更佳為0.04質量%以上,進而佳為0.06質量%以上,進而更佳為0.08質量%以上,並且就低溫保存穩定性之觀點而言,較佳為0.7質量%以下,更佳為0.6質量%以下,進而佳為0.4質量%以下,進而較佳為0.2質量%以下,進而更佳為0.15質量%以下。 The detergent composition B preferably contains a zinc or zinc salt from the viewpoint of sterilization. Zinc is preferably contained in the form of zinc ions. Examples of the zinc salt include zinc sulfate, zinc nitrate, zinc chloride, zinc perchlorate, zinc gluconate, zinc tartrate, zinc bromide, zinc ammonium chloride, zinc aluminum sulfate, zinc sulfate, zinc iodide, and the like. . From the viewpoint of antibacterial properties, one or more compounds selected from the group consisting of zinc sulfate, zinc nitrate, zinc gluconate, zinc tartrate, zinc chloride, and zinc perchlorate are preferred. Further, from the viewpoint of versatility, zinc sulfate is preferred. Regarding the content of zinc or zinc salt in the detergent composition B, zinc ion of zinc or zinc salt The conversion meter is preferably 0.02% by mass or more, more preferably 0.04% by mass or more, still more preferably 0.06% by mass or more, still more preferably 0.08% by mass or more, from the viewpoint of the sterilizing property, and is stable at a low temperature. From the viewpoint of the properties, it is preferably 0.7% by mass or less, more preferably 0.6% by mass or less, further preferably 0.4% by mass or less, further preferably 0.2% by mass or less, and still more preferably 0.15% by mass or less.

關於洗淨劑組合物B中之烷基葡糖苷、氧化胺及鋅或鋅鹽之合計含量,就洗淨性及黏度之觀點而言,較佳為18質量%以上,更佳為22質量%以上,進而佳為25質量%以上,並且就黏度、低溫保存穩定性及經濟性之觀點而言,較佳為40質量%以下,更佳為35質量%以下,進而佳為30質量%以下。 The total content of the alkyl glucoside, the amine oxide, and the zinc or zinc salt in the detergent composition B is preferably 18% by mass or more, and more preferably 22% by mass, from the viewpoints of detergency and viscosity. In the above, it is preferably at least 25% by mass, and is preferably 40% by mass or less, more preferably 35% by mass or less, and still more preferably 30% by mass or less from the viewpoint of viscosity, low-temperature storage stability, and economy.

於洗淨劑組合物B中,就除菌性之觀點而言,烷基葡糖苷、氧化胺及鋅或鋅鹽之合計含量於水以外之成分中較佳為85質量%以上,更佳為90質量%以上,進而佳為93質量%以上。 In the detergent composition B, the total content of the alkyl glucoside, the amine oxide, and the zinc or zinc salt is preferably 85% by mass or more, more preferably from the viewpoint of the sterilizing property. 90% by mass or more, and more preferably 93% by mass or more.

關於洗淨劑組合物B之25℃下之pH值,就使用時之安全性之觀點而言,較佳為5.5以上,更佳為5.8以上,進而佳為6.0以上,並且較佳為8.5以下,更佳為7.5以下,進而佳為7.0以下。 The pH of the detergent composition B at 25 ° C is preferably 5.5 or more, more preferably 5.8 or more, still more preferably 6.0 or more, and preferably 8.5 or less from the viewpoint of safety at the time of use. More preferably, it is 7.5 or less, and further preferably 7.0 or less.

關於洗淨劑組合物B之20℃下之黏度,就使用時之處理性之觀點而言,較佳為80mPa.s以上,更佳為100mPa.s以上,進而佳為150mPa.s以上,進而更佳為220mPa.s以上,並且較佳為1000mPa.s以下,更佳為700mPa.s以下,進而佳為600mPa.s以下,進而更佳為500mPa.s以下。黏度係藉由B型黏度計使用轉子No.2,於60rpm、1分鐘、20℃之條件下測得者。 The viscosity at 20 ° C of the detergent composition B is preferably 80 mPa from the viewpoint of rationality at the time of use. Above s, more preferably 100mPa. Above s, and then preferably 150mPa. More than s, and more preferably 220mPa. Above s, and preferably 1000 mPa. Below s, more preferably 700mPa. s below, and then preferably 600mPa. s below, and more preferably 500mPa. s below. The viscosity was measured by a B-type viscometer using a rotor No. 2 at 60 rpm, 1 minute, and 20 °C.

洗淨劑組合物B作為一例,係如下洗淨劑組合物:其含有:5質量%以上、較佳為7質量%以上、更佳為9質量%以上、並且22.5質量%以下、較佳為21.5質量%以下、更佳為20質量%以下、進而佳為17質量%以下之烷基葡糖苷, 4.5質量%以上、較佳為5.5質量%以上,更佳為7質量%以上、進而佳為10質量%以上、並且22質量%以下、較佳為21質量%以下、更佳為17質量%以下之氧化胺,以鋅離子換算計而為0.02質量%以上、較佳為0.04質量%以上、更佳為0.06質量%以上、進而佳為0.08質量%以上、並且0.7質量%以下、較佳為0.6質量%以下、更佳為0.4質量%以下、進而佳為0.2質量%以下、進而更佳為0.15質量%以下之鋅或鋅鹽,及水,且陰離子界面活性劑之含量於洗淨劑組合物B中為3質量%以下,較佳為2質量%以下,更佳為1質量%以下,進而佳為不含陰離子界面活性劑,即,洗淨劑組合物B中之陰離子界面活性劑之含量為0質量%。 The detergent composition B is, as an example, a detergent composition containing 5% by mass or more, preferably 7% by mass or more, more preferably 9% by mass or more, and 22.5 % by mass or less, and more preferably 21.5 mass% or less, more preferably 20 mass% or less, further preferably 17 mass% or less of alkyl glucoside, 4.5% by mass or more, preferably 5.5% by mass or more, more preferably 7% by mass or more, further preferably 10% by mass or more, and 22% by mass or less, preferably 21% by mass or less, and more preferably 17% by mass or less. The amine oxide is 0.02% by mass or more, preferably 0.04% by mass or more, more preferably 0.06% by mass or more, further preferably 0.08% by mass or more, and 0.7% by mass or less, preferably 0.6 in terms of zinc ion. 5% by mass or less, more preferably 0.4% by mass or less, further preferably 0.2% by mass or less, still more preferably 0.15% by mass or less of zinc or zinc salt, and water, and an anionic surfactant is contained in the detergent composition. B is 3% by mass or less, preferably 2% by mass or less, more preferably 1% by mass or less, and further preferably contains no anionic surfactant, that is, an anionic surfactant in the detergent composition B. It is 0% by mass.

該洗淨劑組合物之20℃下之pH值較佳為5以上,更佳為6以上,並且較佳為9以下,更佳為8以下。 The pH of the detergent composition at 20 ° C is preferably 5 or more, more preferably 6 or more, and is preferably 9 or less, more preferably 8 or less.

步驟5中之食品加工設備或調理器具之洗淨方法可於與步驟1同樣之條件下進行。 The method of washing the food processing equipment or the conditioning apparatus in the step 5 can be carried out under the same conditions as in the step 1.

藉由本發明,提供一種食品加工設備或調理器具之衛生管理方法,其包括:製程C,其進行下述步驟1、步驟2及步驟3;及製程D,其進行步驟4,且於製程C之步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下,進行製程D之最初之步驟4。於該方法中,可任意地應用較佳之成分、較佳之含量等上文已說明之事項。 According to the present invention, there is provided a food processing apparatus or a sanitary management method for a conditioning apparatus, comprising: a process C, which performs the following steps 1, 2 and 3; and a process D, which performs the step 4, and in the process C After the step 3, the first step 4 of the process D is carried out in a state in which one or more compounds selected from the group consisting of polylysine and protamine are brought into contact. In the method, preferred components, preferred contents, and the like described above can be arbitrarily applied.

[製程C] [Process C]

步驟1:洗淨食品加工設備或調理器具之步驟 Step 1: Steps to wash the food processing equipment or conditioning equipment

步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟 Step 2: After step 1, the step of contacting composition A containing one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus

步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群 中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟 Step 3: After step 2, a group selected from the group consisting of polylysine and protamine The state in which one or more of the compounds are in contact with the above-mentioned food processing equipment or conditioning apparatus for 4 hours or more

[製程D] [Process D]

步驟4:使用上述食品加工設備或調理器具之步驟 Step 4: Steps of using the food processing equipment or conditioning apparatus described above

於該方法中,可於製程C之步驟1中,使用下述洗淨劑組合物B洗淨食品加工設備或調理器具。 In this method, the food processing equipment or conditioning apparatus can be washed using the following detergent composition B in step 1 of Process C.

洗淨劑組合物B:陰離子界面活性劑之含量為3質量%以下之洗淨劑組合物;或陰離子界面活性劑之含量為3質量%以下,且包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物 Detergent composition B: a detergent composition having a content of an anionic surfactant of 3% by mass or less; or a content of an anionic surfactant of 3% by mass or less, and comprising a surfactant interface selected from a nonionic surfactant Detergent composition of one or more surfactants in the group consisting of an active agent and an amphoteric surfactant

又,於該方法中,可於製程D中,於步驟4後進行下述步驟5。步驟5:使用洗淨劑組合物洗淨步驟4中所使用之食品加工設備或調理器具之步驟 Further, in this method, in the process D, the following step 5 is performed after the step 4. Step 5: Steps of washing the food processing equipment or conditioning apparatus used in step 4 using the detergent composition

於步驟5中,可使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 In step 5, the food processing device or conditioning device can be washed using the above detergent composition B.

又,於該方法中,可於步驟1及步驟5之兩者中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 Further, in this method, the food processing equipment or the conditioning apparatus can be washed using the above detergent composition B in both of the steps 1 and 5.

又,藉由本發明,提供一種食品加工設備或調理器具之衛生管理方法,其重複進行如下製程:製程C,其進行下述步驟1、步驟2及步驟3;及製程D,其進行步驟4。於該方法中,可任意地應用較佳之成分、較佳之含量等上文已說明之事項。 Further, according to the present invention, there is provided a food processing apparatus or a sanitary management method for a conditioning apparatus which is repeatedly subjected to the following process: Process C, which performs the following Step 1, Step 2 and Step 3; and Process D, which proceeds to Step 4. In the method, preferred components, preferred contents, and the like described above can be arbitrarily applied.

[製程C] [Process C]

步驟1:洗淨食品加工設備或調理器具之步驟 Step 1: Steps to wash the food processing equipment or conditioning equipment

步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟 Step 2: After step 1, the step of contacting composition A containing one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus

步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟 Step 3: After step 2, the step of contacting one or more compounds selected from the group consisting of poly-lysine and protamine with the above-mentioned food processing equipment or conditioning apparatus for 4 hours or more

[製程D] [Process D]

步驟4:於步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下,使用上述食品加工設備或調理器具之步驟 Step 4: After the step 3, in the state of being contacted with one or more compounds selected from the group consisting of polylysine and protamine, the steps of using the above food processing equipment or conditioning apparatus

洗淨劑組合物B:陰離子界面活性劑之含量為3質量%以下之洗淨劑組合物;或陰離子界面活性劑之含量為3質量%以下,且包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物 Detergent composition B: a detergent composition having a content of an anionic surfactant of 3% by mass or less; or a content of an anionic surfactant of 3% by mass or less, and comprising a surfactant interface selected from a nonionic surfactant Detergent composition of one or more surfactants in the group consisting of an active agent and an amphoteric surfactant

於該方法中,較佳為於製程C之步驟1中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。於該方法中,更佳為於製程D後之製程C之步驟1中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 In this method, it is preferred to wash the food processing equipment or the conditioning apparatus using the above detergent composition B in the first step of the process C. In this method, it is more preferred to wash the food processing equipment or the conditioning apparatus using the above detergent composition B in the first step of the process C after the process D.

該方法可進而於製程D中於步驟4之後包括下述步驟5。 The method may further comprise the following step 5 after the step 4 in the process D.

步驟5:使用洗淨劑組合物洗淨步驟4中所使用之食品加工設備或調理器具之步驟 Step 5: Steps of washing the food processing equipment or conditioning apparatus used in step 4 using the detergent composition

於包括步驟5之情形時,就洗淨劑使用時之簡便性及菌之增殖抑制性之觀點而言,更佳為於製程D之步驟5及製程D後之製程C之步驟1的至少一個、較佳為兩個步驟中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 In the case of the step 5, at least one of the step 1 of the process D and the process 1 of the process C after the process D is more preferable in terms of the simplicity of use of the detergent and the inhibition of the growth of the bacteria. Preferably, in two steps, the food processing device or the conditioning device is washed using the above detergent composition B.

又,藉由本發明,提供一種食品加工設備或調理器具之衛生管理方法,其重複進行如下製程:製程C,其進行下述步驟1、步驟2及步驟3;及製程D,其進行複數次步驟4,且於複數次之步驟4之間進行步驟5。於該方法中,可任意地應用較佳之成分、較佳之含量等上 文已說明之事項。 Further, according to the present invention, there is provided a food processing apparatus or a sanitary management method for a conditioning apparatus, which is repeatedly subjected to the following process: Process C, which performs the following Step 1, Step 2 and Step 3; and Process D, which performs a plurality of steps 4, and step 5 is performed between steps 4 of the plurality of times. In the method, the preferred component, the preferred content, and the like can be arbitrarily applied. The matter already stated in the text.

[製程C] [Process C]

步驟1:使用洗淨劑組合物,洗淨使用後之食品加工設備或調理器具之步驟 Step 1: Steps for washing the used food processing equipment or conditioning equipment using the detergent composition

步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟 Step 2: After step 1, the step of contacting composition A containing one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus

步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟 Step 3: After step 2, the step of contacting one or more compounds selected from the group consisting of poly-lysine and protamine with the above-mentioned food processing equipment or conditioning apparatus for 4 hours or more

[製程D] [Process D]

步驟4:於步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下,使用上述食品加工設備或調理器具之步驟 Step 4: After the step 3, in the state of being contacted with one or more compounds selected from the group consisting of polylysine and protamine, the steps of using the above food processing equipment or conditioning apparatus

步驟5:使用洗淨劑組合物洗淨上述食品加工設備或調理器具之步驟 Step 5: Steps of washing the above food processing equipment or conditioning apparatus using the detergent composition

洗淨劑組合物B:陰離子界面活性劑之含量為3質量%以下之洗淨劑組合物;或陰離子界面活性劑之含量為3質量%以下,且包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物 Detergent composition B: a detergent composition having a content of an anionic surfactant of 3% by mass or less; or a content of an anionic surfactant of 3% by mass or less, and comprising a surfactant interface selected from a nonionic surfactant Detergent composition of one or more surfactants in the group consisting of an active agent and an amphoteric surfactant

於該方法中,較佳為於製程D之步驟5中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 In this method, preferably, in step 5 of Process D, the food processing equipment or conditioning apparatus is washed using the above detergent composition B.

又,於該方法中,更佳為於製程C之步驟1中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 Further, in the method, it is more preferable to wash the food processing equipment or the conditioning apparatus using the above detergent composition B in the first step of the process C.

又,於該方法中,就洗淨劑使用時之簡便性及菌之增殖抑制性之觀點而言,更佳為於製程D後之製程C之步驟1中,使用上述洗淨劑 組合物B洗淨食品加工設備或調理器具。 Further, in the method, it is more preferable to use the above-mentioned detergent in the step 1 of the process C after the process D, from the viewpoint of the simplicity of use of the detergent and the inhibition of proliferation of the bacteria. Composition B cleans food processing equipment or conditioning equipment.

又,於該方法中,就洗淨劑使用時之簡便性及菌之增殖抑制性之觀點而言,更佳為於製程D之步驟5、及製程D後之製程C之步驟1的至少一個、較佳為兩個步驟中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 Further, in the method, at least one of the step 1 of the process D and the process 1 of the process C after the process D is more preferable from the viewpoint of the simplicity of use of the detergent and the inhibition of the growth of the bacteria. Preferably, in two steps, the food processing device or the conditioning device is washed using the above detergent composition B.

又,於該方法中,較佳為於複數次之步驟4之中,於最後之步驟4與其前一個步驟4之間進行步驟5。 Further, in the method, step 5 is preferably carried out in step 4 of the plurality of times, between the last step 4 and the previous step 4.

關於上述實施形態,本發明揭示以下之食品加工設備或調理器具之衛生管理方法。以下之食品加工設備或調理器具之衛生管理方法中,可任意地併入較佳之成分、較佳之含量等上文已說明之事項。 Regarding the above embodiment, the present invention discloses the following sanitary management method of a food processing facility or a conditioning appliance. In the following sanitary management methods for food processing equipment or conditioning equipment, the preferred ingredients, preferred contents, and the like described above may be arbitrarily incorporated.

<項1> <item 1>

一種食品加工設備或調理器具之衛生管理方法,其包括如下製程:製程C,其進行下述步驟1、步驟2及步驟3;及製程D,其進行1次以上之下述步驟4,且於製程C之步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下,進行製程D之最初之步驟4。 A hygiene management method for a food processing device or a conditioning device, comprising the following process: Process C, which performs the following steps 1, 2, and 3; and Process D, which is performed one or more times as follows: After the step 3 of the process C, the first step 4 of the process D is carried out in a state in which one or more compounds selected from the group consisting of polylysine and protamine are brought into contact.

[製程C] [Process C]

步驟1:洗淨食品加工設備或調理器具之步驟 Step 1: Steps to wash the food processing equipment or conditioning equipment

步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟 Step 2: After step 1, the step of contacting composition A containing one or more compounds selected from the group consisting of polylysine and protamine with the above-mentioned food processing equipment or conditioning apparatus

步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟 Step 3: After step 2, the step of contacting one or more compounds selected from the group consisting of poly-lysine and protamine with the above-mentioned food processing equipment or conditioning apparatus for 4 hours or more

[製程D] [Process D]

步驟4:使用上述食品加工設備或調理器具之步驟 Step 4: Steps of using the food processing equipment or conditioning apparatus described above

<項2> <item 2>

如上述<項1>記載之衛生管理方法,其中製程D進而包括下述步驟5,步驟5:於步驟4後,使用洗淨劑組合物洗淨食品加工設備或調理器具之步驟。 The sanitary management method according to the above <1>, wherein the process D further comprises the following step 5, step 5: after the step 4, the step of washing the food processing device or the conditioning device with the detergent composition.

<項3> <item 3>

如上述<項2>記載之衛生管理方法,其中製程D之步驟5之洗淨劑組合物為下述洗淨劑組合物B,洗淨劑組合物B:陰離子界面活性劑之含量為3質量%以下之洗淨劑組合物;或包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物;或陰離子界面活性劑之含量為3質量%以下,且包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物。 The hygienic management method according to the above item 2, wherein the detergent composition of the step 5 of the process D is the following detergent composition B, and the detergent composition B: the anionic surfactant is 3 mass. a detergent composition of less than %; or a detergent composition comprising one or more surfactants selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant; or an anion A detergent composition containing at least one surfactant selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant, is contained in an amount of 3% by mass or less.

<項4> <item 4>

如上述<項1>至<項3>中任一項記載之衛生管理方法,其中重複進行製程C與製程D,或重複進行製程C、與進行複數次步驟4且於複數次之步驟4之間進行步驟5之製程D。 The sanitary management method according to any one of the above items 1 to 3, wherein the process C and the process D are repeated, or the process C is repeated, and the plurality of steps 4 and 4 are repeated. Process D of step 5 is performed.

<項5> <item 5>

如上述<項4>記載之衛生管理方法,其中於製程D後之製程C之步驟1中,使用下述洗淨劑組合物B洗淨食品加工設備或調理器具,洗淨劑組合物B:陰離子界面活性劑之含量為10質量%以下之洗淨劑組合物;或包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物;或陰離子界面活性劑之含量為10質量%以下,且包含選自由非離 子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物。 The sanitary management method according to the above [Item 4], wherein in the step 1 of the process C after the process D, the food processing device or the conditioning device is washed using the following detergent composition B, the detergent composition B: a detergent composition having an anionic surfactant content of 10% by mass or less; or a surfactant selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant The detergent composition; or the anionic surfactant is contained in an amount of 10% by mass or less, and is selected from the group consisting of A detergent composition of one or more surfactants selected from the group consisting of a sub-surfactant, a cationic surfactant, and an amphoteric surfactant.

<項6> <Item 6>

如上述<項5>記載之衛生管理方法,其中於製程D之步驟5及製程D後之製程C之步驟1的至少一個、較佳為兩個步驟中,使用上述洗淨劑組合物B洗淨食品加工設備或調理器具。 The sanitary management method according to the above item 5, wherein in the at least one, preferably two, steps 1 of the process D of the process D and the process C after the process D, the detergent composition B is washed. Net food processing equipment or conditioning equipment.

<項7> <item 7>

如上述<項1>至<項6>中任一項記載之食品加工設備或調理器具之衛生管理方法,其中步驟1為藉由含有界面活性劑之洗淨劑組合物洗淨食品加工設備或調理器具之步驟。 The method for sanitary management of a food processing device or a conditioning device according to any one of the above items, wherein the step 1 is to wash the food processing device by a detergent composition containing a surfactant or The steps of conditioning the appliance.

<項8> <item 8>

如上述<項1>至<項7>中任一項記載之衛生管理方法,其中於步驟1中,食品加工設備或調理器具之洗淨為浸漬洗淨,或使用選自由海綿、毛刷及硬毛刷所組成之群中之洗淨用具的擦洗之洗淨。 The sanitary management method according to any one of the above items, wherein in the step 1, the food processing device or the conditioning device is washed by dipping, or is selected from the group consisting of a sponge and a brush. Wash the scrubbing utensils in the group consisting of hard bristle brushes.

<項9> <item 9>

如上述<項1>至<項8>中任一項記載之衛生管理方法,其中於步驟3中,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與食品加工設備或調理器具接觸的狀態保持之時間較佳為5小時以上,更佳為6小時以上,進而佳為7小時以上,進而較佳為8小時以上,進而更佳為9小時以上,進一步佳為10小時以上,進一步較佳為11小時以上,進一步更佳為12小時以上,進一步更佳為16小時以上,並且較佳為5天以下,更佳為3天以下,進而佳為2天以下,進而較佳為24小時以下,進而更佳為20小時以下,進一步佳為10小時以下,進一步更佳為5小時以下。 The sanitary management method according to any one of the above items, wherein in the step 3, one or more compounds selected from the group consisting of polylysine and protamine are The state in which the state in which the food processing equipment or the conditioning device is in contact is preferably 5 hours or longer, more preferably 6 hours or longer, further preferably 7 hours or longer, more preferably 8 hours or longer, still more preferably 9 hours or longer, further Preferably, it is 10 hours or more, further preferably 11 hours or more, further preferably 12 hours or more, further preferably 16 hours or more, and preferably 5 days or less, more preferably 3 days or less, and further preferably 2 days. Hereinafter, it is preferably 24 hours or shorter, more preferably 20 hours or shorter, further preferably 10 hours or shorter, and still more preferably 5 hours or shorter.

<項10> <item 10>

如上述<項1>至<項9>中任一項記載之衛生管理方法,其中 於步驟3中,保持化合物接觸之狀態之溫度較佳為5℃以上,更佳為10℃以上,並且較佳為50℃以下,更佳為40℃以下,進而佳為30℃以下。 The sanitary management method according to any one of the above items 1 to <9>, wherein In the step 3, the temperature at which the compound is kept in contact is preferably 5 ° C or more, more preferably 10 ° C or more, and is preferably 50 ° C or less, more preferably 40 ° C or less, and still more preferably 30 ° C or less.

<項11> <item 11>

如上述<項1>至<項10>中任一項記載之衛生管理方法,其中於製程C之步驟3後,不洗淨組合物A而進行製程D之最初之步驟4。 The sanitary management method according to any one of the above items, wherein, after the step 3 of the process C, the first step 4 of the process D is carried out without washing the composition A.

<項12> <item 12>

如上述<項1>至<項11>中任一項記載之衛生管理方法,其中聚離胺酸之分子量較佳為3,000以上,更佳為4,000以上,並且較佳為10,000以下,更佳為8,000以下,進而佳為6,000以下,進而更佳為5,000以下。 The hygienic management method according to any one of the above items, wherein the molecular weight of the polylysine is preferably 3,000 or more, more preferably 4,000 or more, and still more preferably 10,000 or less, more preferably It is 8,000 or less, more preferably 6,000 or less, and still more preferably 5,000 or less.

<項13> <item 13>

如上述<項1>至<項12>中任一項記載之衛生管理方法,其中魚精蛋白較佳為自鮭魚、鯡魚、虹鱒、鮪魚或烏魚之魚精獲得之魚精蛋白,更佳為自鮭魚之魚精獲得之魚精蛋白。 The hygienic management method according to any one of the above items, wherein the protamine is preferably protamine obtained from fish, carp, rainbow trout, squid or mullet. Jia is a protamine obtained from the fish of the carp.

<項14> <item 14>

如上述<項1>至<項13>中任一項記載之衛生管理方法,其中魚精蛋白為魚精蛋白鹽酸鹽。 The hygienic management method according to any one of the above items, wherein the protamine is protamine hydrochloride.

<項15> <Item 15>

如上述<項1>至<項14>中任一項記載之衛生管理方法,其中選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的含量於組合物A中較佳為0.05質量%以上,更佳為0.1質量%以上,並且較佳為1質量%以下,更佳為0.7質量%以下。 The hygienic management method according to any one of the above items, wherein the content of one or more compounds selected from the group consisting of polylysine and protamine is in the composition A. It is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and is preferably 1% by mass or less, and more preferably 0.7% by mass or less.

<項16> <Item 16>

如上述<項1>至<項15>中任一項記載之衛生管理方法,其中組合物A含有聚離胺酸及魚精蛋白。 The hygienic management method according to any one of the above items, wherein the composition A contains polylysine and protamine.

<項17> <item 17>

如上述<項16>記載之衛生管理方法,其中組合物A中之(聚離胺酸之質量)/(魚精蛋白之質量)之比較佳為0.1以上,更佳為0.15以上,進而佳為0.2以上,進而更佳為0.5以上,並且較佳為10以下,更佳為5以下,進而佳為2以下。 The hygienic management method according to the above [Item 16], wherein the ratio of (the mass of the polyaminic acid) / (the mass of the protamine) in the composition A is preferably 0.1 or more, more preferably 0.15 or more, and further preferably 0.2 or more, more preferably 0.5 or more, and still more preferably 10 or less, still more preferably 5 or less, and still more preferably 2 or less.

<項18> <Item 18>

如上述<項1>至<項17>中任一項記載之衛生管理方法,其中於步驟2中,組合物A對食品加工設備或調理器具之接觸量較佳為0.002g/cm2以上,更佳為0.003g/cm2以上,進而佳為0.004g/cm2以上,進而更佳為0.005g/cm2以上,並且較佳為0.04g/cm2以下,更佳為0.030g/cm2以下,進而佳為0.025g/cm2以下,進而更佳為0.02g/cm2以下。 The sanitary management method according to any one of the above items, wherein the amount of contact of the composition A with the food processing device or the conditioning device is preferably 0.002 g/cm 2 or more in the step 2, More preferably, it is 0.003 g/cm 2 or more, further preferably 0.004 g/cm 2 or more, further preferably 0.005 g/cm 2 or more, and more preferably 0.04 g/cm 2 or less, still more preferably 0.030 g/cm 2 . Hereinafter, it is preferably 0.025 g/cm 2 or less, and more preferably 0.02 g/cm 2 or less.

<項19> <Item 19>

如上述<項1>至<項18>中任一項記載之衛生管理方法,其中於步驟2中,選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物對食品加工設備或調理器具的接觸量較佳為4×10-6g/cm2以上,更佳為6×10-6g/cm2以上,進而佳為8×10-6g/cm2以上,進而更佳為1×10-5g/cm2以上,進一步佳為3×10-5g/cm2以下,並且較佳為8×10-5g/cm2以下,更佳為6×10-5g/cm2以下,進而佳為5×10-5g/cm2以下,進一步佳為4×10-5g/cm2以下。 The sanitary management method according to any one of the above-mentioned item, wherein, in the step 2, one or more compounds selected from the group consisting of polylysine and protamine are used for foods. The contact amount of the processing equipment or the conditioning apparatus is preferably 4 × 10 -6 g / cm 2 or more, more preferably 6 × 10 -6 g / cm 2 or more, and further preferably 8 × 10 -6 g / cm 2 or more. More preferably, it is 1 × 10 -5 g / cm 2 or more, further preferably 3 × 10 -5 g / cm 2 or less, and preferably 8 × 10 -5 g / cm 2 or less, more preferably 6 × 10 -5 g/cm 2 or less, further preferably 5 × 10 -5 g / cm 2 or less, further preferably 4 × 10 -5 g / cm 2 or less.

<項20> <item 20>

如上述<項3>至<項19>中任一項記載之衛生管理方法,其中洗淨劑組合物B中之陰離子界面活性劑之含量較佳為5質量%以下,更佳為3質量%以下,較佳為2質量%以下,更佳為1質量%以下,進而佳為0.5質量%以下,進而更佳為0質量%。 The hygienic management method according to any one of the above items, wherein the content of the anionic surfactant in the detergent composition B is preferably 5% by mass or less, more preferably 3% by mass. Hereinafter, it is preferably 2% by mass or less, more preferably 1% by mass or less, further preferably 0.5% by mass or less, and still more preferably 0% by mass.

<項21> <Item 21>

如上述<項3>至<項20>中任一項記載之衛生管理方法,其中洗淨劑組合物B含有非離子界面活性劑,較佳為含有非離子界面活性劑及兩性界面活性劑。 The sanitary management method according to any one of the above items, wherein the detergent composition B contains a nonionic surfactant, preferably a nonionic surfactant and an amphoteric surfactant.

<項22> <Item 22>

如上述<項3>至<項21>中任一項記載之衛生管理方法,其中上述洗淨劑組合物B含有烷基葡糖苷。 The sanitary management method according to any one of the above items, wherein the detergent composition B contains an alkyl glucoside.

<項23> <item 23>

如上述<項3>至<項22>中任一項記載之衛生管理方法,其中上述洗淨劑組合物B含有下述通式(1)所表示之化合物,R11-(OR12)xGy (1) The sanitary management method according to any one of the above items, wherein the detergent composition B contains a compound represented by the following formula (1), R 11 -(OR 12 ) x G y (1)

[式中,R11為直鏈之碳數8以上、較佳為10以上且16以下、較佳為14以下之烷基,R12為碳數2以上且4以下之伸烷基,較佳為伸乙基或伸丙基,更佳為伸乙基,G表示源自還原糖之殘基,x表示平均值為0以上且6以下之數,y表示平均值為1以上且10以下、較佳為5以下、更佳為2以下之數]。 In the formula, R 11 is a linear carbon number of 8 or more, preferably 10 or more and 16 or less, preferably 14 or less alkyl groups, and R 12 is an alkylene group having 2 or more and 4 or less carbon atoms, preferably Ethyl or propyl, more preferably ethyl, G represents a residue derived from a reducing sugar, x represents an average value of 0 or more and 6 or less, and y represents an average value of 1 or more and 10 or less. It is preferably 5 or less, more preferably 2 or less.

<項24> <item 24>

如上述<項23>記載之衛生管理方法,其中源自還原糖之殘基G較佳為戊醛糖或己醛糖,更佳為葡萄糖。 The hygienic management method according to the above [Item 23], wherein the residue G derived from the reducing sugar is preferably an aldopentose or an aldohexose, more preferably glucose.

<項25> <Item 25>

如上述<項22>至<項24>中任一項記載之衛生管理方法,其中洗淨劑組合物B中之烷基葡糖苷之含量較佳為5質量%以上,更佳為7質量%以上,進而佳為9質量%以上,並且較佳為22.5質量%以下,更佳為21.5質量%以下,進而佳為20質量%以下,進而更佳為17質量%以下。 The hygienic management method according to any one of the above items, wherein the content of the alkyl glucoside in the detergent composition B is preferably 5% by mass or more, more preferably 7% by mass. The amount is more preferably 9% by mass or more, more preferably 22.5 mass% or less, still more preferably 21.5 mass% or less, further preferably 20 mass% or less, and still more preferably 17 mass% or less.

<項26> <Item 26>

如上述<項3>至<項25>中任一項記載之衛生管理方法,其中 上述洗淨劑組合物B含有氧化胺。 The sanitary management method according to any one of the above-mentioned item 3, wherein, The above detergent composition B contains an amine oxide.

<項27> <item 27>

如上述<項3>至<項26>中任一項記載之衛生管理方法,其中上述洗淨劑組合物B含有具有碳數較佳為8以上、更佳為10以上、進而佳為11以上、並且較佳為14以下、更佳為13以下之烴基之氧化胺。 The sanitary management method according to any one of the above-mentioned items, wherein the detergent composition B has a carbon number of preferably 8 or more, more preferably 10 or more, and still more preferably 11 or more. Further, it is preferably an amine oxide of a hydrocarbon group of 14 or less, more preferably 13 or less.

<項28> <Item 28>

如上述<項26>或<項27>記載之衛生管理方法,其中洗淨劑組合物B中之氧化胺之含量較佳為4.5質量%以上,更佳為5.5質量%以上,進而佳為7質量%以上,進而更佳為10質量%以上,並且較佳為22質量%以下,更佳為21質量%以下,進而佳為17質量%以下。 The hygienic management method according to the above <26> or <27>, wherein the content of the amine oxide in the detergent composition B is preferably 4.5% by mass or more, more preferably 5.5% by mass or more, and further preferably 7 The mass% or more is more preferably 10% by mass or more, and is preferably 22% by mass or less, more preferably 21% by mass or less, and still more preferably 17% by mass or less.

<項29> <Item 29>

如上述<項3>至<項28>中任一項記載之衛生管理方法,其中洗淨劑組合物B含有氧化胺及烷基葡糖苷。 The sanitary management method according to any one of the above items, wherein the detergent composition B contains an amine oxide and an alkyl glucoside.

<項30> <item 30>

如上述<項29>記載之衛生管理方法,其中洗淨劑組合物B中之氧化胺與烷基葡糖苷之質量比以氧化胺/烷基葡糖苷計,較佳為0.20以上,更佳為0.25以上,進而佳為0.35以上,進而更佳為0.65以上,並且較佳為8以下,更佳為5以下,進而佳為3以下,進而更佳為2以下。 The hygienic management method according to the above <29>, wherein the mass ratio of the amine oxide to the alkyl glucoside in the detergent composition B is preferably 0.20 or more, more preferably 0.20 or more, based on the amine oxide/alkyl glucoside. 0.25 or more, more preferably 0.35 or more, still more preferably 0.65 or more, and still more preferably 8 or less, still more preferably 5 or less, still more preferably 3 or less, still more preferably 2 or less.

<項31> <item 31>

如上述<項3>至<項30>中任一項記載之衛生管理方法,其中上述洗淨劑組合物B含有鋅或鋅鹽。 The sanitary management method according to any one of the above items, wherein the detergent composition B contains zinc or a zinc salt.

<項32> <item 32>

如上述<項31>記載之衛生管理方法,其中洗淨劑組合物B中之鋅或鋅鹽之含量以鋅離子換算計,較佳為0.02質量%以上,更佳為0.04質量%以上,進而佳為0.06質量%以上,進而更佳為0.08質量%以上,並且較佳為0.7質量%以下,更佳為0.6質量%以下,進而佳為0.4 質量%以下,進而較佳為0.2質量%以下,進而更佳為0.15質量%以下。 In the sanitary management method according to the above-mentioned item, the content of the zinc or the zinc salt in the detergent composition B is preferably 0.02% by mass or more, more preferably 0.04% by mass or more, in terms of zinc ion. It is preferably 0.06% by mass or more, more preferably 0.08% by mass or more, and is preferably 0.7% by mass or less, more preferably 0.6% by mass or less, and further preferably 0.4% by mass or less. The mass% or less is further preferably 0.2% by mass or less, and more preferably 0.15% by mass or less.

<項33> <Item 33>

如上述<項1>至<項32>中任一項記載之衛生管理方法,其中於製程C之步驟2中,將噴霧或塗佈組合物A而使其與食品加工設備或調理器具接觸。 The sanitary management method according to any one of the above items, wherein in the step 2 of the process C, the composition A is sprayed or coated to be brought into contact with a food processing device or a conditioning device.

<項34> <item 34>

如上述<項1>至<項32>中任一項記載之衛生管理方法,其中對象物為食用肉切片機、製麵機、油炸鍋或電飯煲或者砧板、廚刀或瀝水籃,較佳為設置於食品加工設備上之網帶輸送機或帶式輸送機或砧板或瀝水籃。 The sanitary management method according to any one of the above items, wherein the object is a meat slicer, a noodle maker, a deep fryer or a rice cooker or a chopping board, a kitchen knife or a drain basket, preferably. A mesh belt conveyor or belt conveyor or cutting board or drain basket for food processing equipment.

實施例 Example

以下之實施例對本發明之實施進行說明。實施例係對本發明之例示進行說明者,並非用以限定本發明。 The following examples illustrate the practice of the invention. The examples are intended to be illustrative of the invention and are not intended to limit the invention.

<試驗用污染試片之製作> <Production of test contamination test piece>

以如下順序製作以下之實施例、比較例中所使用之污染試片。 The contaminated test pieces used in the following examples and comparative examples were produced in the following order.

(1)雞肉污垢之製作 (1) Making of chicken dirt

對市售雞肉肉末100g利用高壓釜於121℃下進行20分鐘滅菌處理。將進行了滅菌處理之雞肉90g及滅菌水90g放入至攪拌器中攪拌3分鐘而製成漿料狀。 100 g of commercially available chicken minced meat was sterilized by autoclaving at 121 ° C for 20 minutes. 90 g of the sterilized chicken and 90 g of sterilized water were placed in a stirrer and stirred for 3 minutes to prepare a slurry.

(2)樣本菌液污垢之製備 (2) Preparation of sample bacterial liquid soil

將經調整為OD(Optical Density,光密度)=0.001之綠膿桿菌(Pseudomonas aeruginosa ATCC15692)之菌液0.1mL、上述雞肉污垢2.0mL、及滅菌水7.9mL混合。 0.1 mL of the bacterial solution of Pseudomonas aeruginosa ATCC 15692 adjusted to OD (Optical Density, optical density) = 0.001, 2.0 mL of the chicken flesh and 7.9 mL of sterilized water were mixed.

(3)試片之製作 (3) Production of test strips

於實際之廚房現場,由1年以上之用於將魚剖開清理之聚乙烯製 砧板來製作複數片具有5cm×5cm之底面的長方體形狀之試片。 At the actual kitchen site, it is made of polyethylene for more than one year to cut the fish. The chopping board was used to produce a plurality of test pieces having a rectangular parallelepiped shape having a bottom surface of 5 cm × 5 cm.

(4)試片之重設 (4) Reset of the test piece

為了去除源自現場之污垢或菌,進行試片之重設。將試片於有效氯濃度為2質量%之次氯酸鈉水溶液中浸漬18小時,利用自來水充分地清洗。其後,藉由lumitester-DP-20(Kikkoman Biochemifa股份有限公司製造)進行污染物質(ATP(Adenosine Triphosphate,三磷酸腺苷))量之測定,確認到相對發光量(RLU(Relative Light Unit,相對發光單位))之值未達20。進而,利用乙醇進行清洗並加以乾燥。 In order to remove dirt or bacteria from the site, the test piece is reset. The test piece was immersed in an aqueous sodium hypochlorite solution having an effective chlorine concentration of 2% by mass for 18 hours, and sufficiently washed with tap water. Then, the amount of the pollutant (ATP (Adenosine Triphosphate)) was measured by lumitester-DP-20 (manufactured by Kikkoman Biochemifa Co., Ltd.), and the relative luminescence amount (RLU (Relative Light Unit)) was confirmed. ) The value is less than 20. Further, it was washed with ethanol and dried.

(5)菌之接種及繁殖 (5) Inoculation and reproduction of bacteria

於乾燥之試片之一面上將上述樣本菌液污垢0.3mL均勻地塗開。 The above sample bacterial soil fouling 0.3 mL was uniformly spread on one side of the dried test piece.

於聚丙烯製密封容器(Tight Box No.3,Chopla工業股份有限公司製造)之內部,鋪墊含浸有0.2質量%氯化苄烷銨水溶液20g之紙巾,使塗佈有樣本菌液污垢之面朝上而將試片靜置於其上,蓋上容器之蓋,於30℃下保存20小時。將其作為被污染之試片。再者,氯化苄烷銨係用於排除水等中所含之環境菌之影響。 In a sealed container made of polypropylene (Tight Box No. 3, manufactured by Chopra Industries Co., Ltd.), a paper towel impregnated with a 0.2% by mass aqueous solution of benzalkonium chloride (20 g) was placed on the surface to coat the surface of the sample. The test piece was placed on top of it, covered with a lid of the container, and stored at 30 ° C for 20 hours. Use it as a contaminated test piece. Further, benzalkonium chloride is used to exclude the influence of environmental bacteria contained in water or the like.

實施例1-1 Example 1-1

依序進行下述步驟1、步驟2及步驟3(以上為製程C)及步驟4(製程D)。於步驟4後,藉由下述方法測定試片之菌數(cfu/mL),以將底設為10之對數而記載於表1中。表中,初始菌數為步驟4中所使用之樣本菌液污垢中之菌數,處理後之菌數為上述擴增處理後,利用標準瓊脂培養基培養擦拭液之稀釋液後之菌數(下同)。處理後之菌數之測定方法將於步驟4中進行詳細說明。 The following steps 1, 2, and 3 (above, process C) and step 4 (process D) are performed in sequence. After the step 4, the number of bacteria (cfu/mL) of the test piece was measured by the following method, and the bottom was set to the logarithm of 10 and is shown in Table 1. In the table, the initial number of bacteria is the number of bacteria in the sample bacterial liquid soil used in the step 4, and the number of bacteria after the treatment is the number of bacteria after the above-mentioned amplification treatment, and the dilution of the wiping liquid is cultured in a standard agar medium (below) with). The method for measuring the number of bacteria after the treatment will be described in detail in step 4.

[製程C] [Process C] <步驟1> <Step 1>

使用下述洗淨劑1於下述洗淨條件1下洗淨被污染之試片。 The contaminated test piece was washed under the following washing condition 1 using the following detergent 1.

*洗淨劑1 *Detergent 1

※1 LAS:月桂基苯磺酸鈉 *1 LAS: sodium laurylbenzene sulfonate

※2 ES:具有碳數12~15之烷基,且伸乙氧基之平均加成莫耳數為2.0之聚氧乙烯烷基醚硫酸鈉 *2 ES: polyoxyethylene alkyl ether sulfate with an alkyl group having 12 to 15 carbon atoms and an average addition molar ratio of 2.0 to the ethoxy group

※3 AO:N-月桂基-N,N-二甲基氧化胺 *3 AO: N-Lauryl-N,N-dimethylamine oxide

※4 AHSB:N-月桂基-N,N-二甲基-N-(2-羥基-3-磺丙基)甜菜鹼 *4 AHSB: N-Lauryl-N,N-dimethyl-N-(2-hydroxy-3-sulfopropyl)betaine

※5 AG:具有碳數12之烷基及源自葡萄糖之基、且糖縮合度為1.3之烷基葡糖苷 *5 AG: an alkyl glucoside having an alkyl group having 12 carbon atoms and a glucose-derived group and having a sugar condensation degree of 1.3

洗淨條件1: Washing conditions 1:

使利用自來水將洗淨劑稀釋為30倍(體積比)而成之稀釋洗淨液2.5mL含浸於海綿片中,將對象物洗淨30秒鐘,洗淨後,利用500mL之自來水清洗對象物。再者,海綿片(28.75mm×37.5mm×35mm)係將市售之海綿(115mm×75mm×35mm之可撓性吸收體,商品名:Kikulon,經銷商:Kikulon股份有限公司)進行8等分(將長邊4等分,將短邊2等分)而製作。 2.5 mL of the diluted washing solution obtained by diluting the detergent to 30 times (volume ratio) with tap water was immersed in the sponge sheet, and the object was washed for 30 seconds. After washing, the object was washed with 500 mL of tap water. . Further, the sponge sheet (28.75 mm × 37.5 mm × 35 mm) was subjected to 8 equal parts of a commercially available sponge (115 mm × 75 mm × 35 mm flexible absorber, trade name: Kikulon, dealer: Kikulon Co., Ltd.) (The long side is divided into 4 equal parts, and the short side is divided into 2 equal parts).

<步驟2> <Step 2>

於步驟1後,將0.3mL之下述殺菌劑組合物1塗佈於試片上。 After the step 1, 0.3 mL of the following bactericidal composition 1 described above was applied to the test piece.

*殺菌劑組合物1 * bactericide composition 1

魚精蛋白(※6) 0.1質量% Protamine (*6) 0.1% by mass

※6 ε-聚離胺酸,食品添加物,JNC股份有限公司製造,重量平均分子量4,700 *6 ε-polyaminic acid, food additive, manufactured by JNC Co., Ltd., weight average molecular weight 4,700

※7源自鮭魚之魚精蛋白,魚精蛋白鹽酸鹽,加工食品,Maruha nichiro食品股份有限公司製造 *7 From the squid fish protamine, protamine hydrochloride, processed food, manufactured by Maruha nichiro Food Co., Ltd.

<步驟3> <Step 3>

於步驟2後,將試片於開放系統中於20℃下靜置18小時。 After step 2, the test piece was allowed to stand in an open system at 20 ° C for 18 hours.

[製程D] [Process D] <步驟4> <Step 4>

於步驟3後,將上述樣本菌液污垢0.3mL於試片上塗開。於聚丙烯製密封容器(Tight Box No.3,Chopla股份有限公司製造)中,鋪墊含浸有0.2質量%氯化苄烷銨水溶液20g之紙巾,使塗佈有樣本菌液污垢之底面朝上而將試片靜置於其上,蓋上容器之蓋,於37℃下保存8小時。於步驟4中將樣本菌液污垢塗佈於試片上係假定因器具之使用而污垢接觸之狀態者。又,於密閉系統中進行保存係假定於操作期間中,使用狀態長時間持續,菌最初接觸後,接觸之狀態於長時間、濕潤狀態下持續者。再者,氯化苄烷銨係用於排除水等中所含之環境菌之影響者。 After the step 3, 0.3 mL of the sample bacterial liquid stain was spread on the test piece. In a sealed container made of polypropylene (Tight Box No. 3, manufactured by Chopra Co., Ltd.), a paper towel impregnated with 20% by mass of a 0.2% by mass aqueous solution of benzalkonium chloride was placed, and the bottom surface coated with the sample bacteria liquid was faced upward. The test piece was placed on it, covered with a lid of the container, and stored at 37 ° C for 8 hours. The application of the sample bacterial liquid soil to the test piece in the step 4 is assumed to be in a state in which the dirt is in contact due to the use of the device. Further, the preservation in the closed system is assumed to be continued during the operation period, and the state of use continues for a long time, and the state of the contact is continued for a long time and in a wet state after the initial contact of the bacteria. Further, benzalkonium chloride is used to exclude the influence of environmental bacteria contained in water or the like.

<菌數之測定方法> <Method for measuring the number of bacteria>

藉由簡易擦拭套組(日水製藥股份有限公司製造)擦拭於步驟4中保存後之試片之表面,立即提取擦拭液200μL,為了實現藥劑鈍化而於LP稀釋液(DAIGO製造)1.8mL中進行混合稀釋,獲得擦拭液之10倍稀釋液。將該稀釋液200μL於生理鹽水1.8mL中進行混合稀釋,獲得100倍稀釋液,藉由同樣之操作,獲得擦拭液之1000倍稀釋液及10000 倍稀釋液。將各稀釋液100μL塗佈於標準瓊脂培養基上,於37℃下培養20小時後測量菌落數,求出菌數cfu/mL。 The surface of the test piece stored in the step 4 was wiped off by a simple wiping kit (manufactured by Risho Pharmaceutical Co., Ltd.), and 200 μL of the wiping liquid was immediately extracted, and 1.8 ml of the LP diluent (manufactured by DAIGO) was obtained in order to achieve drug passivation. Mix and dilute to obtain a 10-fold dilution of the wipe. 200 μL of the diluted solution was mixed and diluted in 1.8 mL of physiological saline to obtain a 100-fold dilution, and a 1000-fold dilution of the wiping liquid and 10000 were obtained by the same operation. Double dilution. 100 μL of each diluted solution was applied to a standard agar medium, and cultured at 37° C. for 20 hours, and the number of colonies was measured to determine the number of bacteria cfu/mL.

實施例1-2 Example 1-2

使用洗淨劑2作為實施例1-1之步驟1之洗淨劑組合物,除此以外,以與實施例1-1同樣之方式進行操作。 The same procedure as in Example 1-1 was carried out except that the detergent 2 was used as the detergent composition of the first step of Example 1-1.

*洗淨劑2 *Detergent 2

※8 AO:N-月桂基-N,N-二甲基氧化胺 ※8 AO: N-Lauryl-N,N-dimethylamine oxide

※9 AHSB:N-月桂基-N,N-二甲基-N-(2-羥基-3-磺丙基)甜菜鹼 ※9 AHSB: N-Lauryl-N,N-dimethyl-N-(2-hydroxy-3-sulfopropyl)betaine

※10 AG:具有碳數12之烷基及源自葡萄糖之基、且糖縮合度為1.3之烷基葡糖苷 *10 AG: an alkyl glucoside having an alkyl group having 12 carbon atoms and a glucose-derived group and having a sugar condensation degree of 1.3

比較例1-1 Comparative Example 1-1

將實施例1-1之步驟2設為下述步驟2',又,於該步驟2'後,利用500mL之自來水清洗試片,除此以外,以與實施例1同樣之方式進行操作。將結果示於表1。 Step 2 of Example 1-1 was used as the following step 2', and after the step 2', the test piece was washed with 500 mL of tap water, and the operation was carried out in the same manner as in Example 1. The results are shown in Table 1.

<步驟2'> <Step 2'>

於有效氯濃度為200ppm之次氯酸鈉水溶液300mL中,將1個於步驟1中經洗淨之試片浸漬30分鐘。 One 300 piece of the test piece washed in the step 1 was immersed in 300 mL of an aqueous solution of sodium hypochlorite having an effective chlorine concentration of 200 ppm for 30 minutes.

比較例1-2 Comparative Example 1-2

省略實施例1-1之步驟1,除此以外,以與實施例1-1同樣之方式 進行操作。將結果示於表1。 The procedure of Example 1 was omitted except that Step 1 of Example 1-1 was omitted. Take action. The results are shown in Table 1.

實施例2-1 Example 2-1

於實施例1-1中,將步驟3之靜置時間設為4小時,除此以外,以與實施例1-1同樣之方式進行操作。又,關於樣本菌污垢,於向試片之菌之接種或步驟4中使用菌數為表2之初始菌數者。將結果示於表2。 In the same manner as in Example 1-1, except that the standing time of the step 3 was set to 4 hours in the example 1-1. Further, regarding the sample bacteria stain, the number of bacteria used in the inoculation of the test piece or the number of bacteria in the step 4 is the initial number of bacteria in Table 2. The results are shown in Table 2.

實施例2-2 Example 2-2

以與實施例1-1同樣之方式進行操作。其中,關於樣本菌污垢,於向試片之菌之接種或步驟4中使用菌數為表2之初始菌數者。將結果示於表2。 The operation was carried out in the same manner as in Example 1-1. Among them, regarding the sample bacteria, the number of bacteria used in the inoculation of the test piece or the number of bacteria in the step 4 is the initial number of bacteria in Table 2. The results are shown in Table 2.

實施例3-1 Example 3-1

於實施例1-1中,將步驟3之靜置時間變更為4小時,將步驟4中所塗佈之樣本菌污垢中之雞肉污垢變更為0.2mL,將滅菌水變更為9.7mL,且將塗佈後之保存設為於37℃下5小時,除此以外,以與實施例1-1同樣之方式進行操作。又,關於步驟4中所使用之樣本菌污垢,剛塗佈後之菌數為表3之初始菌數。將結果示於表3。 In Example 1-1, the standing time of the step 3 was changed to 4 hours, the chicken dirt in the sample bacteria stain applied in the step 4 was changed to 0.2 mL, and the sterilized water was changed to 9.7 mL, and The operation after the application was carried out in the same manner as in Example 1-1, except that the storage was carried out at 37 ° C for 5 hours. Further, regarding the sample bacteria stain used in the step 4, the number of bacteria immediately after the application was the initial number of bacteria in Table 3. The results are shown in Table 3.

實施例3-2 Example 3-2

於實施例3-1中,將步驟3之靜置時間設為6小時,除此以外,以與實施例3-1同樣之方式進行操作。又,關於步驟4中所使用之樣本菌污垢,剛塗佈後之菌數為表3之初始菌數。將結果示於表3。 In the same manner as in Example 3-1, except that the standing time of the step 3 was set to 6 hours in the example 3-1. Further, regarding the sample bacteria stain used in the step 4, the number of bacteria immediately after the application was the initial number of bacteria in Table 3. The results are shown in Table 3.

實施例3-3 Example 3-3

於實施例3-1中,將步驟3之靜置時間設為23小時,除此以外,以與實施例3-1同樣之方式進行操作。其中,關於步驟4中所使用之樣本菌污垢,剛塗佈後之菌數為表3之初始菌數。將結果示於表3。 In the same manner as in Example 3-1, except that the standing time of the step 3 was changed to 23 hours in the example 3-1. Among them, regarding the sample bacteria stain used in the step 4, the number of bacteria immediately after the application was the initial number of bacteria in Table 3. The results are shown in Table 3.

比較例3-1 Comparative Example 3-1

於實施例3-1中,將步驟3之靜置時間設為1小時,除此以外,以與實施例3-1同樣之方式進行操作。又,關於步驟4中所使用之樣本菌污垢,剛塗佈後之菌數為表3之初始菌數。將結果示於表3。 In the same manner as in Example 3-1, except that the standing time of the step 3 was set to 1 hour in the example 3-1. Further, regarding the sample bacteria stain used in the step 4, the number of bacteria immediately after the application was the initial number of bacteria in Table 3. The results are shown in Table 3.

比較例3-2 Comparative Example 3-2

於實施例3-1中,將步驟3之靜置時間設為2小時,除此以外,以與實施例3-1同樣之方式進行操作。又,關於步驟4中所使用之樣本菌污垢,剛塗佈後之菌數為表3之初始菌數。將結果示於表3。 In the same manner as in Example 3-1, except that the standing time of the step 3 was set to 2 hours in the example 3-1. Further, regarding the sample bacteria stain used in the step 4, the number of bacteria immediately after the application was the initial number of bacteria in Table 3. The results are shown in Table 3.

實施例4-1 Example 4-1

於實施例3-1中,將步驟2之殺菌劑組合物替換為殺菌劑組合物2,除此以外,以與實施例3-1同樣之方式進行操作。又,關於步驟4中所使用之樣本菌污垢,剛塗佈後之菌數為表4之初始菌數。將結果示於表4。 In the same manner as in Example 3-1, except that the bactericidal composition of the step 2 was replaced with the bactericidal composition 2 in Example 3-1. Further, regarding the sample bacteria stain used in the step 4, the number of bacteria immediately after application was the initial number of bacteria in Table 4. The results are shown in Table 4.

實施例5-1 Example 5-1

於實施例5-1中,關於向試片之菌之接種或步驟4中所使用之樣本 菌污垢,剛塗佈後之菌數為表5之初始菌數。 In Example 5-1, the inoculation to the bacteria of the test piece or the sample used in the step 4 The bacteria scale, the number of bacteria immediately after coating was the initial number of bacteria in Table 5.

[第1製程C] [Process 1 C]

以與實施例1-2同樣之方式進行步驟1、步驟2及步驟3。 Step 1, Step 2, and Step 3 were carried out in the same manner as in Example 1-2.

[第1製程D] [1st process D]

以與實施例1-2同樣之方式同樣地進行步驟4。其中,將步驟4之保存時間設為2小時(步驟4-2)。 Step 4 was carried out in the same manner as in Example 1-2. Here, the storage time of step 4 is set to 2 hours (step 4-2).

進而,於該步驟4-2後,使用洗淨劑2於洗淨條件1下進行洗淨(步驟5)。 Further, after the step 4-2, the detergent 2 is used for washing under the washing condition 1 (step 5).

於步驟5後,再次進行步驟4-2。 After step 5, step 4-2 is performed again.

[第2製程C] [2nd process C]

於第1製程D後,以與實施例1-2同樣之方式進行步驟1及步驟2。 After the first process D, steps 1 and 2 were carried out in the same manner as in the example 1-2.

於聚丙烯製密封容器(Tight Box No.3,Chopla工業股份有限公司製造)中,鋪墊含浸有0.2質量%氯化苄烷銨水溶液20g之紙巾。使塗佈有樣本菌液污垢之面朝上,而將步驟2後之試片靜置於其上。蓋上容器之蓋,於37℃下保存18小時(步驟3)。為了擴增效果而進行確認,該步驟3係於菌容易增加之密閉系統中進行。 In a sealed container made of polypropylene (Tight Box No. 3, manufactured by Chopra Industries Co., Ltd.), a paper towel impregnated with a 0.2% by mass aqueous solution of benzalkonium chloride 20 g was placed. The surface coated with the sample bacterial liquid was faced upward, and the test piece after step 2 was allowed to stand thereon. The lid of the container was capped and stored at 37 ° C for 18 hours (step 3). This is confirmed for the amplification effect, and this step 3 is carried out in a closed system in which the bacteria are easily increased.

[第2製程D] [2nd process D]

於第2製程C後,進行步驟4-2,藉由與實施例1-1同樣之方法測定試片之菌數(cfu)。將結果示於表5。 After the second process C, the step 4-2 was carried out, and the number of bacteria (cfu) of the test piece was measured by the same method as that of Example 1-1. The results are shown in Table 5.

實施例5-2 Example 5-2

使用洗淨劑1代替洗淨劑2,除此以外,以與實施例5-1同樣之方式進行操作。將結果示於表5。 The operation was carried out in the same manner as in Example 5-1 except that the detergent 1 was used instead of the detergent 2. The results are shown in Table 5.

實施例5-3 Example 5-3

關於步驟1,使用洗淨劑1代替洗淨劑2,除此以外,以與實施例5-1同樣之方式進行操作。將結果示於表5。 In the same manner as in Example 5-1, except that the detergent 1 was used instead of the detergent 2 in the first step. The results are shown in Table 5.

實施例5-4 Example 5-4

關於步驟1,使用洗淨劑1代替洗淨劑2,且使用殺菌劑組合物2代替殺菌劑組合物1,除此以外,以與實施例5-1同樣之方式進行操作。將結果示於表5。 In the same manner as in Example 5-1, except that the detergent 1 was used instead of the detergent 2 and the bactericidal composition 2 was used instead of the bactericidal composition 1 in the first step. The results are shown in Table 5.

實施例5-5 Example 5-5

關於步驟1,使用洗淨劑1代替洗淨劑2,且將步驟3之靜置時間設為4小時,除此以外,以與實施例5-1同樣之方式進行操作。將結果示於表5。 In the same manner as in Example 5-1, except that the detergent 1 was used instead of the detergent 2 in the step 1, and the standing time of the step 3 was set to 4 hours. The results are shown in Table 5.

實施例5-6 Example 5-6

關於步驟1,使用洗淨劑1代替洗淨劑2,將步驟3之靜置時間設為12小時,除此以外,以與實施例5-1同樣之方式進行操作。將結果示於表5。 In the same manner as in Example 5-1, except that the detergent 1 was used instead of the detergent 2, and the rest time of the step 3 was set to 12 hours. The results are shown in Table 5.

實施例5-7 Example 5-7

關於步驟1,使用洗淨劑1代替洗淨劑2,且於與實施例1-1之製程C之步驟3相同之條件的開放系統中進行第2製程C之步驟3,除此以外,以與實施例5-1同樣之方式進行操作。將結果示於表5。 With respect to the step 1, the detergent 1 is used instead of the detergent 2, and in the open system of the same conditions as in the step 3 of the process C of the embodiment 1-1, the step 3 of the second process C is performed, and The operation was carried out in the same manner as in Example 5-1. The results are shown in Table 5.

比較例5-1 Comparative Example 5-1

於實施例5-2中,省略第1、第2製程C中之步驟2,除此以外,以與實施例5-2同樣之方式進行操作。將結果示於表5。 In the same manner as in the example 5-2, except that the step 2 in the first and second processes C was omitted in the embodiment 5-2. The results are shown in Table 5.

實施例5-1及實施例5-2與比較例5-1相比可知,於混入菌數之情形時抑制菌之增加程度。尤其可知,於第1製程D之步驟5與第2製程C之步驟1中使用洗淨劑2之實施例5-1中,儘管於菌數容易增加之密閉系統中進行第2製程C之步驟3,但第2製程D之步驟4後之菌數相較於初始菌數而減少,菌之增殖抑制效果明顯優異。 In Comparative Example 5-1 and Example 5-2, as compared with Comparative Example 5-1, it was found that the degree of increase in the number of bacteria was inhibited when the number of bacteria was mixed. In particular, in Example 5-1 in which the detergent 2 was used in the first step D of the first process D and the second process C, the second process C was carried out in a closed system in which the number of bacteria was easily increased. 3. However, the number of bacteria after step 4 of the second process D is reduced as compared with the initial number of bacteria, and the growth inhibition effect of the bacteria is remarkably excellent.

又,亦可知,於第1製程C之步驟5中使用洗淨劑2之實施例5-3~5-7中,第2製程D之步驟4後之菌數相較於初始菌數而減少,菌之增殖抑制效果明顯優異。 Further, in Examples 5-3 to 5-7 in which the detergent 2 was used in the step 5 of the first process C, the number of bacteria after the step 4 of the second process D was decreased as compared with the initial number of bacteria. The growth inhibition effect of the bacteria is remarkably excellent.

Claims (17)

一種食品加工設備或調理器具之衛生管理方法,其包括如下製程:製程C,其進行下述步驟1、步驟2及步驟3;及製程D,其進行1次以上之下述步驟4;且於製程C之步驟3後,於選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物接觸的狀態下,進行製程D之最初之步驟4,[製程C]步驟1:洗淨食品加工設備或調理器具之步驟步驟2:於步驟1後,使含有選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物的組合物A與上述食品加工設備或調理器具接觸之步驟步驟3:於步驟2後,將選自由聚離胺酸及魚精蛋白所組成之群中之1種以上之化合物與上述食品加工設備或調理器具接觸的狀態保持4小時以上之步驟[製程D]步驟4:使用上述食品加工設備或調理器具之步驟。 A hygiene management method for a food processing device or a conditioning device, comprising the following process: Process C, which performs the following steps 1, Step 2 and Step 3; and Process D, which is performed one or more times as follows: After step 3 of the process C, the first step 4 of the process D is carried out in a state of being contacted with one or more compounds selected from the group consisting of polylysine and protamine, [Process C] Step 1: Step 2 of washing the food processing equipment or conditioning apparatus: After the step 1, the composition A containing one or more compounds selected from the group consisting of polylysine and protamine and the above food processing equipment Or the step of contacting the conditioning device, step 3: after step 2, maintaining a state in which one or more compounds selected from the group consisting of polylysine and protamine are in contact with the food processing device or the conditioning device for 4 hours. The above steps [Process D] Step 4: The steps of using the above food processing equipment or conditioning apparatus. 如請求項1之衛生管理方法,其中製程D進而包括下述步驟5,步驟5:於步驟4後,使用洗淨劑組合物洗淨食品加工設備或調理器具之步驟。 The sanitary management method of claim 1, wherein the process D further comprises the following step 5, step 5: after the step 4, the step of washing the food processing device or the conditioning device with the detergent composition. 如請求項2之衛生管理方法,其中製程D之步驟5之洗淨劑組合物為下述洗淨劑組合物B,洗淨劑組合物B:包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑 的洗淨劑組合物。 The method of hygiene management according to claim 2, wherein the detergent composition of the step 5 of the process D is the following detergent composition B, and the detergent composition B: comprises a surfactant interface selected from the group consisting of a nonionic surfactant and a cation. One or more surfactants in the group consisting of a surfactant and an amphoteric surfactant Detergent composition. 如請求項3之衛生管理方法,其中實質上不含洗淨劑組合物B之陰離子界面活性劑。 A sanitization management method according to claim 3, wherein the anionic surfactant of the detergent composition B is substantially absent. 如請求項3之衛生管理方法,其中洗淨劑組合物B之陰離子界面活性劑之含量為3質量%以下。 The hygiene management method according to claim 3, wherein the content of the anionic surfactant of the detergent composition B is 3% by mass or less. 如請求項1至5中任一項之衛生管理方法,其中重複進行製程C與製程D。 The hygiene management method according to any one of claims 1 to 5, wherein the process C and the process D are repeated. 如請求項6之衛生管理方法,其中於製程D後之製程C之步驟1中,使用下述洗淨劑組合物B洗淨食品加工設備或調理器具,洗淨劑組合物B:包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物。 The hygienic management method of claim 6, wherein in the step 1 of the process C after the process D, the food processing device or the conditioning device is washed using the detergent composition B described below, the detergent composition B: comprising selected from the group consisting of A detergent composition of one or more surfactants selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant. 如請求項6或7之衛生管理方法,其中於製程D之步驟5及製程D後之製程C之步驟1的至少一個步驟中,使用下述洗淨劑組合物B洗淨食品加工設備或調理器具,洗淨劑組合物B:包含選自由非離子界面活性劑、陽離子界面活性劑及兩性界面活性劑所組成之群中之1種以上之界面活性劑的洗淨劑組合物。 The hygienic management method of claim 6 or 7, wherein in at least one of the step 1 of the process D and the process C of the process C after the process D, the following detergent composition B is used to wash the food processing equipment or conditioning Apparatus, detergent composition B: a detergent composition comprising at least one surfactant selected from the group consisting of a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant. 如請求項8之衛生管理方法,其中實質上不含洗淨劑組合物B之陰離子界面活性劑之含量。 A sanitization management method according to claim 8, wherein the content of the anionic surfactant of the detergent composition B is substantially not contained. 如請求項8之衛生管理方法,其中洗淨劑組合物B之陰離子界面活性劑之含量為3質量%以下。 The hygienic management method of claim 8, wherein the content of the anionic surfactant of the detergent composition B is 3% by mass or less. 如請求項1至10中任一項之衛生管理方法,其中於製程C之步驟3後,不洗淨組合物A而進行製程D之最初之步驟4。 The sanitary management method according to any one of claims 1 to 10, wherein after the step 3 of the process C, the first step 4 of the process D is carried out without washing the composition A. 如請求項1至11中任一項之衛生管理方法,其中組合物A含有聚離胺酸及魚精蛋白。 The hygiene management method according to any one of claims 1 to 11, wherein the composition A contains polylysine and protamine. 如請求項3至12中任一項之衛生管理方法,其中上述洗淨劑組合物B含有非離子界面活性劑。 The sanitary management method according to any one of claims 3 to 12, wherein the detergent composition B contains a nonionic surfactant. 如請求項3至13中任一項之衛生管理方法,其中上述洗淨劑組合物B含有烷基葡糖苷。 The sanitary management method according to any one of claims 3 to 13, wherein the detergent composition B contains an alkyl glucoside. 如請求項3至14中任一項之衛生管理方法,其中上述洗淨劑組合物B含有氧化胺。 The sanitary management method according to any one of claims 3 to 14, wherein the detergent composition B contains an amine oxide. 如請求項3至15中任一項之衛生管理方法,其中上述洗淨劑組合物B含有鋅或鋅鹽。 The sanitary management method according to any one of claims 3 to 15, wherein the detergent composition B contains zinc or a zinc salt. 如請求項1至16中任一項之衛生管理方法,其中於製程C之步驟2中,噴霧或塗佈組合物A而使其與食品加工設備或調理器具接觸。 A sanitization management method according to any one of claims 1 to 16, wherein in the step 2 of the process C, the composition A is sprayed or coated to be brought into contact with the food processing equipment or the conditioning apparatus.
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