TW201222821A - Thin film transistor and method for fabricating the same - Google Patents

Thin film transistor and method for fabricating the same Download PDF

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TW201222821A
TW201222821A TW99140006A TW99140006A TW201222821A TW 201222821 A TW201222821 A TW 201222821A TW 99140006 A TW99140006 A TW 99140006A TW 99140006 A TW99140006 A TW 99140006A TW 201222821 A TW201222821 A TW 201222821A
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layer
conductive layer
patterned
oxide semiconductor
covered
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TW99140006A
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Chinese (zh)
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TWI416736B (en
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Yih-Chyun Kao
Hui-Chun Chen
Chun-Nan Lin
Shu-Feng Wu
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Au Optronics Corp
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  • Thin Film Transistor (AREA)

Abstract

A method for fabricating a thin film transistor is provided, including following steps. Form a gate on a substrate. Form a gate insulating layer, a semiconductor oxide material layer and a conductive layer on the substrate in sequence. Form a patterned photoresist layer on the conductive layer. The patterned photoresist layer includes two first parts, and a second part connecting between the first parts. Thickness of each first part is greater than that of the second part. Remove the conductive layer and the semiconductor oxide material layer that are not covered by the patterned photoresist layer by using the patterned photoresist layer as a mask, so that a semiconductor oxide channel layer and a patterned conductive layer between the semiconductor oxide channel layer and the patterned photoresist layer are formed. Remove a portion of the patterned photoresist layer so as to lower the thickness of the first parts until the second part. Remove the patterned conductive layer not covered by the remaining first parts by using the remaining first parts as a mask, so as to form a source and a drain on the semiconductor oxide channel layer.

Description

201222821201222821

ιυυ^υ02 36141twf.doc/I 六、發明說明: 【發明所屬之技術領域】 本發明是有關於一種薄膜電晶體及其製造方法,且特 別是有關於一種能夠避免氧化物半導體通道層受到損傷的 薄膜電晶體及其製造方法。 【先前技術】 隨著顯示科技的日益進步,人們藉著顯示器的輔助可 使生活更加便利,為求顯示器輕、薄之特性,促使平面顯 示器(flat panel display,FPD)成為目前的主流。常見的平面 顯示器包括液晶顯示器(liquid crystal display, LCD)、電聚 顯示器(plasma display)、電激發光顯示器 (electroluminescent display)等。以目前最為普及的液晶顯 示器為例,其主要是由薄膜電晶體陣列基板、彩色濾光基 板以及夾於二者之間的液晶層所構成。特別是,在顯示器 中被大量使用到的薄膜電晶體,其結構設計或是材料的選 擇更是會直接影響到產品的性能。 在習知的薄膜電晶體陣列基板上,多採用非晶矽 (amorphous smcon,a_Si)薄膜電晶體或低溫多晶矽薄膜電 晶體作為各個子晝素的切換元件。近年來,已有研究指出 氧化物半導體(oxide semicon(juct〇r)薄膜電晶體相較於非 晶石夕薄膜電晶體’具有較高的載子移動率(carrier mobility);而氧化物半導體薄膜電晶體相較於低溫多晶矽 薄膜電晶體,則具有較佳的臨界電壓(thresh〇ld v〇ltage,vth)Υυυυ^υ02 36141twf.doc/I VI. Description of the Invention: [Technical Field] The present invention relates to a thin film transistor and a method of manufacturing the same, and more particularly to a method capable of preventing damage of an oxide semiconductor channel layer Thin film transistor and method of manufacturing the same. [Prior Art] With the advancement of display technology, people can make life more convenient by the aid of the display. In order to make the display light and thin, the flat panel display (FPD) has become the mainstream. Common flat displays include liquid crystal displays (LCDs), plasma displays, and electroluminescent displays. Taking the most popular liquid crystal display as an example, it is mainly composed of a thin film transistor array substrate, a color filter substrate, and a liquid crystal layer sandwiched therebetween. In particular, thin-film transistors that are widely used in displays have a structural design or material selection that directly affects the performance of the product. On a conventional thin film transistor array substrate, an amorphous smcon (a-Si) thin film transistor or a low temperature polycrystalline germanium thin film transistor is often used as a switching element of each sub-tenoxine. In recent years, it has been pointed out that an oxide semiconductor (oxide semicon (juct〇r) thin film transistor has higher carrier mobility than an amorphous thin crystal transistor]; and an oxide semiconductor thin film The transistor has a better threshold voltage (thresh〇ld v〇ltage, vth) than the low temperature polycrystalline germanium film transistor.

201222821 Λ〇ιυυ^υ02 36141twf.d〇cA =:之=導體薄_體有潛力成為下- -般會❹城作為射找化 之源極與汲__劑。然而,_對於氧化晶體 膜電晶體之氧化物半導體通道層_ 體薄 ,_體薄膜電晶體之源極與没極的 ==靠r影響到氧化物半導細電晶體的: 【發明内容】 本發明提供-種薄膜電晶體的製造, 用光,製程,並避免氧化物半導體通道層受二減使 導體提供—種薄膜電晶體,其具有突出之氧化物半 氧化物半導體材料層以及導電^。於^朗絕緣層、 ::圖案化光阻層包括二個第二部以;以案ΐ 案化光阻層為罩幕,料未厚度。以圖 與氧化物半導體材料層 蓋之導電層 位於氧化物半導趙通道層與道層以及 圖案化光阻層二; 圖莱料層’狀氧化財_通道層上201222821 Λ〇ιυυ^υ02 36141twf.d〇cA =: = conductor thin _ body has the potential to become the next - the general will be the source of the search and the 汲 __ agent. However, the oxide semiconductor channel layer of the oxidized crystal film transistor is thin, and the source and the immersion of the _ bulk thin film transistor affect the oxide semiconducting fine crystal by the r: The invention provides a method for manufacturing a thin film transistor, using light, a process, and avoiding the oxide semiconductor channel layer being subjected to a subtraction to provide a thin film transistor having a prominent oxide semiconductor material layer and a conductive film. . In the insulating layer, the :: patterned photoresist layer comprises two second portions; the photoresist layer is used as a mask, and the material is not thick. The conductive layer covered with the oxide semiconductor material layer is located on the oxide semiconductor channel layer and the track layer and the patterned photoresist layer 2;

201222821 AU1009002 36141twf.doc/I 形成源極與汲極。 在本發明之-實施例中,上述之圖案化光阻層係藉由 階調式(Gray-Tone Mask,GTM)製程或半調式(Half_T曰 Mask,HTM)製程所形成。 De 在本發明之-實施例中,上述移除未被圖案化光 覆蓋之導電層與氧化物半㈣㈣層的方法包括下列+ 驟。進行第-濕式触刻製程,以移除未被圖案化光阻芦^ 蓋之導電層。進行第二濕式_製程,以移除未被圖^化 光阻層覆蓋之氧化物半導體材料層,其中第—濕式敍^製 程所使用之與第二濕式_製⑽使用福 同。 J卜 u明之—實施财,上述移除未被圖案化光 覆盖之導電層與氧化物半導體材料層的方法包括進行 蚀刻製程’以移除未被圖案化光阻層覆蓋之導電層以及 ===::其中導電層與氧化物半導雜材料層採 層的=:::例中’上述移除部分之圖案化光- 在本發明之-實施财,上述形成雜與汲極的方法 ^以未被移除之第—部為罩幕,進行濕式侧以移除未 被第一部覆蓋之圖案化導電層。 在本㈣之-實施财,麵錢極姐極之後,薄 膜電晶體的製造方法更包括移除第一部。 本發明另提出-種_電晶體的製造方法,其包括^ γ驟。於基板上形成酿。於基板上依序形成閘絕緣層 201222821201222821 AU1009002 36141twf.doc/I Forms the source and the drain. In an embodiment of the invention, the patterned photoresist layer is formed by a Gray-Tone Mask (GTM) process or a Half_T曰 Mask (HTM) process. De In the embodiment of the invention, the above method of removing the conductive layer and the oxide half (four) (four) layer not covered by the patterned light comprises the following + steps. A first-wet etch process is performed to remove the conductive layer that is not covered by the patterned photoresist. A second wet process is performed to remove the oxide semiconductor material layer not covered by the photoresist layer, wherein the first wet process is used in conjunction with the second wet process (10). The method for removing the conductive layer and the oxide semiconductor material layer not covered by the patterned light includes performing an etching process to remove the conductive layer not covered by the patterned photoresist layer and == =:: wherein the conductive layer and the oxide semi-conductive material layer are layered =::: in the above-mentioned "removed portion of the patterned light - in the present invention - the implementation of the above method of forming the impurity and the bungee ^ The wet side is performed with the first portion not removed as a mask to remove the patterned conductive layer not covered by the first portion. In the implementation of this (four) - the implementation of the financial, after the face of the extremes, the manufacturing method of the thin film transistor further includes the removal of the first part. The invention further proposes a method for producing a transistor, which comprises a gamma step. The brew is formed on the substrate. Forming a gate insulating layer on the substrate in sequence 201222821

AU1UWU02 36141twf.doc/I 氧化物半導體材料層以及導電層。於導電層上形成圖案化 光阻層’圖案化光阻層包括二個第一部、連接於第一邻 間的第二部以及二個與各第一部連接之第三部。各第: ^厚度大於第二部之厚度,且第二部之厚度實質上等於各 ^二部之厚度。間案化恤層為罩幕,移除未被圖案化 ^層覆蓋之導電層與氧化物半導體材料層,以形成氧化 物半導體通道層以及位於氧化物半導體 =1的圖案化導電層,其_所導致的】= 導料道層之㈣處,且底她於第三部下 化光阻層,以減少第-部的厚度直到 η!τ: !未被移除之第-部為罩幕,移 氧化物半導趙通;二案化導電層, 階調調::形土述之圖案化光阻層係藉由 覆蓋例中,上述移除未被圖案化光阻層 驟。進行半導體材料層的方法包括下列步 導電層丨製程’以移除未被圖案化光阻層覆蓋之 蓋之氧化物半導體材料^叫除未被_化光阻層覆 在本發明之—實施例中,上述之 以及頂導電層,轉除未 電層^括底導電層 钱刻製程,以移進行第一濕式 行乾式飯刻势程,二先阻層覆蓋之頂導電層。進 场除未被圖案化光阻層覆蓋之底導電AU1UWU02 36141twf.doc/I Oxide semiconductor material layer and conductive layer. Forming a patterned photoresist layer on the conductive layer The patterned photoresist layer includes two first portions, a second portion connected to the first adjacent portion, and two third portions connected to the respective first portions. Each of the: ^ thickness is greater than the thickness of the second portion, and the thickness of the second portion is substantially equal to the thickness of each of the two portions. The intervening lining layer is a mask, and the conductive layer and the oxide semiconductor material layer not covered by the patterned layer are removed to form an oxide semiconductor channel layer and a patterned conductive layer located in the oxide semiconductor=1. The resulting == at the (4) of the guide layer, and at the bottom she lowers the photoresist layer in the third part to reduce the thickness of the first part until η!τ: ! The first part that is not removed is the mask. Oxide semiconducting Zhaotong; two cases of conductive layer, tone modulation:: the patterned soiled photoresist layer by the cover case, the above removal of the unpatterned photoresist layer. The method of conducting a layer of a semiconductor material includes the following step of conducting a conductive layer to remove an oxide semiconductor material that is not covered by the patterned photoresist layer, and is not covered by the photoresist layer. The above-mentioned and the top conductive layer are removed from the uncharged layer and the bottom conductive layer is processed to move the first wet-type dry rice-cutting potential, and the first conductive layer is covered by the first resist layer. The entrance is conductive except for the bottom that is not covered by the patterned photoresist layer

201222821 Αυιυυ^υ〇2 36141twf.d〇c/I 層。進行第二濕式個製程,以移除未被圖案化光 蓋之氡化物半導體材料層。 在本發明之-實施例中’上述移除部分之圖案化光阻 層的方法包括灰化製程。 在本發明之-實施例中,上述形成源極與及極的方法 包括以未被移除之第-部為轉,進行乾式_以移除位 於底切上方且未被第一部覆蓋之圖案化導電層。 在本發明之-實施例中,在形成源極與汲極之後 膜電晶體的製造方法更包括移除第一部。 本發明又提出一種薄膜電晶體的製造方法,其包括 ,步驟。於基板上形成_。於基板上依序形成閘絕 氧化物半導體材料層、底導電層以及頂導電層。於 層上形成圖案化光阻層,圖案化光阻層包括二個第 連接於第-部之間的第二部以及二個與各第—部連 2 °各,部之厚度大於第二部之厚度, 又實質上等於各第三部之厚度。以圖案化細層為罩幕, 移除未被酸化光阻層覆蓋之頂導電層與底導電層 :分之圖案化光阻層,以減少第—部的厚度直到第二部與 第三部被瓣。以未被移除之第—部為罩幕,移除未被第 -部覆蓋之頂導電層以及部分氧化物半導體材料層,以於 底導電層與_緣層之間形成氧化物铸㈣道層,盆中 因側⑽導朗底切發生在氧化物半導體通道層之伯: 處。以未赫n部為罩幕,移除未被第—部覆蓋之 底導電層以及位於底切上方之底導電層,以於氧化 體通道層上形成源極與汲極。 201222821201222821 Αυιυυ^υ〇2 36141twf.d〇c/I layer. A second wet process is performed to remove the germanide semiconductor material layer that is not patterned. In the embodiment of the present invention, the method of removing a portion of the patterned photoresist layer described above includes an ashing process. In an embodiment of the invention, the method of forming the source and the pole includes performing a dry mode with the first portion that is not removed, to remove the pattern that is above the undercut and is not covered by the first portion. Conductive layer. In an embodiment of the invention, the method of fabricating the film transistor after forming the source and the drain further comprises removing the first portion. The invention further provides a method of fabricating a thin film transistor comprising the steps. Forming _ on the substrate. A gate insulating oxide semiconductor material layer, a bottom conductive layer, and a top conductive layer are sequentially formed on the substrate. Forming a patterned photoresist layer on the layer, the patterned photoresist layer comprises two second portions connected between the first portions and two portions connected to each of the first portions, the thickness of the portions being greater than the second portion The thickness is substantially equal to the thickness of each third portion. The patterned thin layer is used as a mask to remove the top conductive layer and the bottom conductive layer not covered by the acidified photoresist layer: the patterned photoresist layer is divided to reduce the thickness of the first portion until the second portion and the third portion Beveled. The first conductive layer and the partial oxide semiconductor material layer not covered by the first portion are removed by the first portion which is not removed, so as to form an oxide casting (four) between the bottom conductive layer and the _ edge layer. In the layer, the side (10) conduction undercut in the basin occurs at the top of the oxide semiconductor channel layer. The bottom conductive layer is not covered by the first portion and the bottom conductive layer is disposed above the undercut to form a source and a drain on the oxide channel layer. 201222821

AU1009002 36141twf.doc/I 階調式形t述之圖案化光阻層係藉由 在本剌之-實施财,上述移除未被圖案化光阻声 導電層與底導電層的方法包括下形驟 : 程’以移除未被圖案化光阻層覆蓋之頂導電芦: g乾式_製程,以移除未被圖案化光阻層覆蓋之底導AU1009002 36141twf.doc/I The patterned photoresist layer is described in the present invention. The method for removing the unpatterned photoresist acoustic conductive layer and the bottom conductive layer includes the following steps. : Process 'to remove the top conductive reed that is not covered by the patterned photoresist layer: g dry _ process to remove the bottom trace not covered by the patterned photoresist layer

在本發明之-實關巾,上述以未郷除之第 未被第—部覆蓋之頂導電層以及部分氧化物半 導體材制之方法包括進行濕式_製程,以移除 一部覆蓋之頂導電層以及部分氧化物半導體材料層。 在本發明之—實施财,上述以未被移除之^ 一部為 罩幕,移除未被第-部覆蓋之底導電層以及位於底切上方 之底導電層之方法包括崎乾式蝴餘以移除未被第 一部覆蓋之底導電層以及位於底切上方之底導電層。 在本發明之一實施例中,上述移除部分之^ 層的方法包括灰化製程。 元1 在本發明之一實施例中,在形成源極與汲極之後,薄 膜電晶體的製造方法更包括移除第一部。 本發明又提出-種薄膜電晶體,其包括閑極、問絕緣 層、氧化物半導體通道層、源極以及汲極。閘絕緣層位於 閘極上。氧化物半導體通道層位於閘絕緣層上。源極以及 汲極位於氧化物半導體通道層上。氧化物半導體通道層之 底邛穴出源極以及沒極其中之一之底部之水平距離約為 0.1 μιη 至 1 μπι。 201222821In the present invention, the method of manufacturing the top conductive layer and the partial oxide semiconductor material which are not removed by the first portion includes a wet process to remove a top of the cover. a conductive layer and a portion of an oxide semiconductor material layer. In the present invention, the method of removing the bottom conductive layer not covered by the first portion and the bottom conductive layer above the undercut includes the unsettled one. To remove the bottom conductive layer not covered by the first portion and the bottom conductive layer above the undercut. In an embodiment of the invention, the method of removing a portion of the layer includes an ashing process. In an embodiment of the invention, after forming the source and the drain, the method of fabricating the thin film transistor further comprises removing the first portion. The invention further proposes a thin film transistor comprising a dummy, an insulating layer, an oxide semiconductor channel layer, a source and a drain. The gate insulation is on the gate. The oxide semiconductor channel layer is on the gate insulating layer. The source and the drain are on the oxide semiconductor channel layer. The horizontal distance between the bottom of the oxide semiconductor channel layer and the bottom of one of the poles is about 0.1 μm to 1 μm. 201222821

V2 36141twf.doc/I 在本發明之一實施例中,上述之源極包括第一導電層 以及第二導電層。第一導電層位於氧化物半導體通道層 上。第二導電層位於第一導電層上,其中第一導電層之底 部突出第二導電層之底部之水平距離約為〇1 μιη至15 μιη ° 在本發明之一實施例中,上述之源極更包括第三導電 層’其位於第二導電層上。 在本發明之一實施例中,上述之第一導電層、第二導 電層以及第三導電層之材料分別為選自由銅(Cu)、鉬 (Mo)、鈦(Ti)、鋁(A1)、鎢(w)、銀(Ag)、金(Au)及其合金 所組成之族群中的至少一者。 基於上述,本發明之薄膜電晶體及其製造方法透過具 有至少兩種不同厚度之圖案化光阻層來分別形成薄膜電晶 體之氧化物半導體通道層、源極與汲極,因此可有助於減 少製程步驟與成本。此外,本發明之薄膜電晶體及其製造 方法可以避免氧化物半導體通道層的結構產生破壞缺陷, 並能夠改善因侧蝕所導致的底切現象。 —為讓本發明之上述特徵和優點能更明顯易懂,下文特 舉實施例,並配合所附圖式作詳細說明如下。 【實施方式】 第一實施例 圖1A至圖1D是依照本發明之第一實施例之一種薄 膜電晶體的製造流程示意圖。請參照圖1A,提供基板刚, 並於基板100上形成間極102。基板1〇〇例如是玻璃基板 201222821V2 36141twf.doc/I In one embodiment of the invention, the source includes a first conductive layer and a second conductive layer. The first conductive layer is on the oxide semiconductor channel layer. The second conductive layer is located on the first conductive layer, wherein the bottom of the first conductive layer protrudes from the bottom of the second conductive layer by a horizontal distance of about μ1 μηη to 15 μηη °. In one embodiment of the present invention, the source is There is further included a third conductive layer 'which is located on the second conductive layer. In an embodiment of the invention, the materials of the first conductive layer, the second conductive layer and the third conductive layer are respectively selected from the group consisting of copper (Cu), molybdenum (Mo), titanium (Ti), and aluminum (A1). At least one of a group consisting of tungsten (w), silver (Ag), gold (Au), and alloys thereof. Based on the above, the thin film transistor of the present invention and the method of fabricating the same, by forming a patterned photoresist layer having at least two different thicknesses, respectively forming an oxide semiconductor channel layer, a source and a drain of the thin film transistor, thereby contributing to Reduce process steps and costs. Further, the thin film transistor of the present invention and the method of manufacturing the same can prevent the structure of the oxide semiconductor channel layer from being damaged, and can improve the undercut caused by the side etching. The above-described features and advantages of the present invention will become more apparent from the following description. [Embodiment] FIG. 1A to FIG. 1D are schematic views showing a manufacturing process of a thin film transistor according to a first embodiment of the present invention. Referring to FIG. 1A, a substrate is provided and a drain 102 is formed on the substrate 100. The substrate 1 is, for example, a glass substrate 201222821

AU1009002 36141twf.doc/I 之硬質基板(rigid substrate)’或是如塑膠基板之可撓式基板 (flexible substrate)等。閘極1〇2例如是單層或多層堆疊之 導電材料,如選自由銅(Cu)、鉬(M〇)、鈦(Ti)、鋁(A1)、鎢 (W)、銀(Ag)、金(Au)及其合金所組成之族群中的至少一 者,且閘極102的形成方法可透過微影及蝕刻製程來圖案 化導電材料而製作。此外,閘極102的製作還可以與掃描 線(未纟會示)或共通線(未繪示)的製作整合。 接著,於基板10〇上依序形成閘絕緣層104、氧化物 半導體材料層106以及導電層1〇8。閘絕緣層1〇4覆蓋閘 極102。閘絕緣層1〇4可為單層結構或多層堆疊的複合結 構,且其材質例如是氮化矽、氧化矽或氮氧化矽等介電材 料。氧化物半導體材料層106覆蓋閘絕緣層1〇4。氧化物 半導體材料層106的材質例如是銦鎵鋅氧化物 (Indirnn-Gallium-Zinc Oxide,IGZO)、銦鋅氧化物 (Indium-Zinc Oxide,IZO)、鎵鋅氧化物(GalHum_Zinc ⑽如, GZO)、氧化铭鋅(Aiuminum_zinc 〇xide,AZ〇)、鋅錫氧化 •物(Zinc>Tin 〇xide,ZTO)或銦錫氧化物(Indium-Tin 〇xide, ITO)等。導電層i〇8覆蓋氧化物半導體材料層i〇6。導電 層108可為單層結構或多層堆疊的複合結構,且其材質例 如是銅(Οι)、鉬(Mo)或其合金等金屬材料。導電層' 1〇8之 材質可與閘極102之材質相同或不同。 日 之後,於導電層108上形成圖案化光阻層11〇。圖案 化光阻層110包括二個第一部11〇a以及第二部li〇b,其 中第二部110b連接於二第一部110a之間,且各第一部 之厚度大於第二部11〇b之厚度。圖案化光阻層 201222821 AU1009002 36141twf.doc/I 之第二部110b例如是位於後續預定形成通道區之上方。 一實施例中,圖案化光阻層11〇係藉由階調式製程或 式製程所形成。舉例而言’本實施例可先於導電層⑽丄 全面形成-層恤材料(未繪示),接著使用階調 ,光罩來圖案化光阻材料,以形成上述之圖案化光阻層 110。軸本實施例是赠調式或伟式 = 明’但本發明不限於此。 勺列木况 凊參照圖1B ’以圖案化光阻層11G為罩幕 ^案化光阻層11G覆蓋之導電層⑽與氧化物體^ 料層106,以形成氧化物半導體通道層以及位於2 光阻層U。之間的圖案化導 :二Of==實施例中,移除未被圖案化光 方法可透過紐行第-料勤m程, 刻製程,以移除未被圖案化光阻層110覆蓋之虫 =:。6。第一濕糊製程所使 :J導 濕式勒刻製程所使用之钱刻劑不 Ί一 刻選擇比。具體而言,第一 刀I有不同的蝕 的銅酸作輕·來移除導fH 邮2 氧化物半導_層106具有二::擇導比電(I 電層1〇_解物_ m擇比(導 半導體材料層_。第二濕糊製 12 201222821AU1009002 36141twf.doc/I's rigid substrate' or a flexible substrate such as a plastic substrate. The gate 1〇2 is, for example, a single-layer or multi-layer stacked conductive material, such as selected from the group consisting of copper (Cu), molybdenum (M〇), titanium (Ti), aluminum (A1), tungsten (W), silver (Ag), At least one of the group consisting of gold (Au) and its alloy, and the method of forming the gate 102 can be fabricated by patterning a conductive material through a photolithography and etching process. In addition, the fabrication of the gate 102 can also be integrated with the fabrication of scan lines (not shown) or common lines (not shown). Next, a gate insulating layer 104, an oxide semiconductor material layer 106, and a conductive layer 1〇8 are sequentially formed on the substrate 10A. The gate insulating layer 1〇4 covers the gate 102. The gate insulating layer 1〇4 may be a single-layer structure or a multi-layer stacked composite structure, and the material thereof is, for example, a dielectric material such as tantalum nitride, hafnium oxide or tantalum oxynitride. The oxide semiconductor material layer 106 covers the gate insulating layer 1〇4. The material of the oxide semiconductor material layer 106 is, for example, Indium-Gallium-Zinc Oxide (IGZO), Indium-Zinc Oxide (IZO), Gallium Zinc Oxide (GalHum_Zinc (10), for example, GZO). Oxidized zinc (Aiuminum_zinc 〇xide, AZ〇), zinc tin oxide (Zinc>Tin 〇xide, ZTO) or indium tin oxide (Indium-Tin 〇xide, ITO). The conductive layer i 8 covers the oxide semiconductor material layer i 〇 6 . The conductive layer 108 may be a single layer structure or a multilayer stacked composite structure, and is made of a metal material such as copper (m), molybdenum (Mo) or an alloy thereof. The material of the conductive layer '1〇8' may be the same as or different from the material of the gate 102. After the day, a patterned photoresist layer 11 is formed on the conductive layer 108. The patterned photoresist layer 110 includes two first portions 11〇a and a second portion li〇b, wherein the second portion 110b is connected between the two first portions 110a, and the thickness of each first portion is greater than the second portion 11 The thickness of 〇b. The patterned photoresist layer 201222821 AU1009002 36141twf.doc/I of the second portion 110b is, for example, located above the subsequent predetermined formation channel region. In one embodiment, the patterned photoresist layer 11 is formed by a step process or a process. For example, the present embodiment may be formed entirely on the conductive layer (10) to form a layer of material (not shown), and then the photoresist is patterned using a tone mask to form the patterned photoresist layer 110 described above. . The present embodiment is a gift or a genre = ming', but the invention is not limited thereto. Referring to FIG. 1B', the patterned photoresist layer 11G is used as a mask to cover the conductive layer (10) and the oxide body layer 106 covered by the photoresist layer 11G to form an oxide semiconductor channel layer and is located at 2 light. Resistance layer U. The patterning between the two: Inf== in the embodiment, the method of removing the unpatterned light is transparent, and the engraving process is performed to remove the unmasked photoresist layer 110. Insect =:. 6. The first wet paste process makes it possible to use the money engraving agent used in the wet etching process without selecting the ratio. Specifically, the first knife I has a different etched copper acid as a light · to remove the lead fH 2 oxide semi-conductive layer _ 106 has two:: selective conductivity (I electrical layer 1 〇 _ solution _ m selection ratio (conductive semiconductor material layer _. second wet paste 12 201222821

AU1009002 36141twf.doc/I 於氧化物半導體材料層1〇6與導電層1〇8具有报高的蝕刻 選擇比(氧化物半導體材料層106/導電層1⑽),因而不易触 刻導電層108,而使製程能夠獲得良好的控制。 、此外,在另一實施例中,可透過濕式蝕刻製程來移除 未被圖案化光阻層110覆蓋之導電層1〇8與氧化物半導體 =料層106。也就是說,導電層108與氧化物半導體材料 曰106是採用相同的鞋刻劑來移除,钱刻劑對於導⑽ 與氧化物半導體材料層106具有相近的钱刻率,而钮曰刻劑 與濃度大於1 wt%之含_液_混合物, 即磷酸、硝酸與醋酸的混合物)。因此, 電層⑽與氧化物半導體材料層廳。π f移除導 請參照圖1C,移除部公夕園安乂p 第-部nn紅也 圖案化光阻層110,以減少 f 4 110a的厚度直到第二部u 案化導電層108,之一部份的 移f而暴露出圖 =的方式’使圖= = ^ -X的為止。ί於第二i 會有未被完全移之後,仍 蕭上。除之第—部11Ga’殘留在圖案化導電^ 請參照圖1D,在完全移除 後,以未被移除之第一立Λ、又乂'、之第二部110b之 覆蓋之圖案化導電層&為罩幕,移除未被第-部 電層1〇8 ’以於氧化物半導體通道層AU1009002 36141twf.doc/I has a high etching selectivity (oxide semiconductor material layer 106 / conductive layer 1 (10)) in the oxide semiconductor material layer 1 〇 6 and the conductive layer 1 , 8 , so that the conductive layer 108 is not easily etched, and The process can be well controlled. In addition, in another embodiment, the conductive layer 1 8 and the oxide semiconductor layer 106 not covered by the patterned photoresist layer 110 may be removed by a wet etching process. That is to say, the conductive layer 108 and the oxide semiconductor material 曰106 are removed by the same shoe polish, and the money engraving agent has a similar engraving rate for the conductive layer (10) and the oxide semiconductor material layer 106, and the button engraving agent With a concentration of more than 1 wt% of the mixture containing _ liquid, that is, a mixture of phosphoric acid, nitric acid and acetic acid). Therefore, the electric layer (10) and the oxide semiconductor material layer chamber. π f removal guide Referring to FIG. 1C, the removal portion of the 夕 第 第 第 nn nn 也 也 也 也 也 也 也 也 也 也 也 也 也 也 也 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案 图案One part of the shift f exposes the way of the graph = 'make the graph == ^ -X. ί After the second i will not be completely moved, it will still be stunned. In addition, the first portion 11Ga' remains in the patterned conductive layer. Referring to FIG. 1D, after completely removing, the patterned conductive layer covered by the first portion, the second portion 110b, which is not removed, is removed. Layer & is the mask, removed from the first part of the electrical layer 1 〇 8 ' to the oxide semiconductor channel layer

201222821 AU100 卯02 36141twid0c/I 106’上形成源極112盥 是分別形成在氧化物半導體=::112與汲極114例如 施例中,移除未被第—Λ ": θ __上。在一實 而形成源極m料極覆紅圖案化導電層庸 程,並採用對於圖案的方法可以採用濕式韻刻製 層具有高敍刻選擇比(nn氧化物半導體通道層 通道層__劑,rHO=108v氧化物半導體 與沒極114之後,概第2的級°在形成源極 ^ # B ^ φ,. >、 邛U〇a',以完成本實施例之薄 氣體來進,其中可利用氧氣電⑽乍為反應201222821 AU100 卯02 36141twid0c/I 106' is formed on the source 112 盥 is formed in the oxide semiconductor =:: 112 and the drain 114, respectively, for example, the removal is not the first - Λ ": θ __. In the case of forming a source m-material red-plated patterned conductive layer, and adopting a method for patterning, the wet-type rhyme-forming layer can have a high sculpt selection ratio (nn oxide semiconductor channel layer channel layer __ After the rHO=108v oxide semiconductor and the dipole 114, the second stage is forming the source ^B^φ, . >, 邛U〇a' to complete the thin gas of the embodiment. , which can use oxygen (10) as a reaction

SiΪΊ製程。當然,源極112與祕114的製作 還可以與-貝料線(未繪示)的製作整合。 第·一貫施例SiΪΊ process. Of course, the fabrication of source 112 and secret 114 can also be integrated with the production of a bead line (not shown). First consistent example

帝曰f2A至圖2E是依照本發明之第二實施例之一種薄膜 ^曰體的製造流程示意圖。須注意的是,在圖2A至圖2E ’和圖1A至圖ID相_構件則使用相_標號並省略 其說明。 請參照圖2A,提供基板100,並於基板1〇〇上形成閘 極102。接著,於基板100上依序形成閘絕緣層104、氧化 物半導體材料層1〇6以及導電層1〇8。之後,於導電層1〇8 上形成圖案化光阻層210。圖案化光阻層210包括二個第 21〇a、第二部21〇b以及第三部210c,其中第二部210b 連接於第一部21〇a之間,第三部210c則分別與各第一部帝曰f2A to Fig. 2E are schematic views showing a manufacturing process of a film body according to a second embodiment of the present invention. It is to be noted that the phase_reference numerals are used in Figs. 2A to 2E' and Fig. 1A to ID phase_members, and the description thereof is omitted. Referring to Figure 2A, a substrate 100 is provided and a gate 102 is formed on the substrate 1A. Next, a gate insulating layer 104, an oxide semiconductor material layer 1〇6, and a conductive layer 1〇8 are sequentially formed on the substrate 100. Thereafter, a patterned photoresist layer 210 is formed on the conductive layer 1A8. The patterned photoresist layer 210 includes two 21st corners 21a, a second portion 21b, and a third portion 210c, wherein the second portion 210b is connected between the first portions 21a, and the third portion 210c is respectively First

201222821 Auiuuyu02 36141twf.d〇c/I 210a連接而位於第一部21〇a之外側。各第一部21〇a之厚 度例如是大於第二部21〇b及各第三部210c之厚度,且第 二部210b之厚度實質上等於各第三部21〇c之厚度。具體 而言,圖案化光阻層210之第二部210b例如是位於後續預 定形成通道區之上方,而各第三部2l〇c例如是位於後續預 定形成源極與汲極之兩相對外侧的上方。在一實施例中, 圖案化光阻層210係藉由階調式製程或半調式製程所 成。 請參照圖2B,以圖案化光阻層21〇為罩幕,移除未 被圖案化光阻層21〇覆蓋之導電層1〇8,以於氧化物半導 體材料層106與圖案化光阻層21〇之間形成圖案化導電層 108·。在一實施例中,移除未被圖案化光阻層21〇覆蓋^ =電層1G8❸方法包括進行乾式㈣丨製程,其例如使用α ” BCI3作為反應氣體來蝕刻暴露出的導電層⑴8,且此反 ,氣體對於導電層⑽與氧化物半導體材料層1()6且有很 而的姓刻選擇比(導電層·氧化物半導體材料層1〇6)。 睛參照圖2C,以圖案化光阻層21〇為罩幕,移除未被 =化光阻層21〇覆蓋之氧化物半導體材料層讓,以形 通道層2G6。在—實施例中,移除未被覆 之,化物+導體材料層1〇6的方法包括進行濕式侧製 半導體==草酸作劑來移除暴露出的氧化物 除暴半酬製程來移 在濕式靖程中可作為硬罩幕 15201222821 Auiuuyu02 36141twf.d〇c/I 210a is connected to the outside of the first part 21〇a. The thickness of each of the first portions 21〇a is, for example, greater than the thickness of the second portion 21〇b and each of the third portions 210c, and the thickness of the second portion 210b is substantially equal to the thickness of each of the third portions 21〇c. Specifically, the second portion 210b of the patterned photoresist layer 210 is, for example, located above a predetermined predetermined channel region, and each of the third portions 21c is, for example, located opposite the two opposite sides of the source and the drain. Above. In one embodiment, the patterned photoresist layer 210 is formed by a tonal process or a half-tone process. Referring to FIG. 2B, the patterned photoresist layer 21 is used as a mask to remove the conductive layer 1〇8 not covered by the patterned photoresist layer 21 to form the oxide semiconductor material layer 106 and the patterned photoresist layer. A patterned conductive layer 108· is formed between 21 turns. In an embodiment, the removing is not covered by the patterned photoresist layer 21 ^ 电 电 电 = 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 包括 , , , , , , , , , , = = = = = = = = = = = = = = = = = = = = On the contrary, the gas has a very high selectivity ratio (conductive layer·oxide semiconductor material layer 1〇6) to the conductive layer (10) and the oxide semiconductor material layer 1() 6. The pattern is lighted with reference to FIG. 2C. The resist layer 21 is a mask, and the oxide semiconductor material layer not covered by the photoresist layer 21 is removed to form a channel layer 2G6. In the embodiment, the uncovered, compound + conductor material is removed. The method of layer 1〇6 includes performing a wet side semiconductor==oxalic acid agent to remove the exposed oxides, and removing the half-receiving process to move in the wet atmosphere as a hard mask 15

201222821 au l uuy υ02 36141twf.doc/I 108'下方的氧化物半導體通道層206會因側餘而導致其侧 壁處發生底切(undercut)216,且底切216例如是發生在位 於相對外側之第三部210c的下方。在此實施例中,因侧姓 所導致的底切216會使得圖案化導電層自氧化物半導 體通道層206之側壁突出。 請參照圖2D,移除部分之圖案化光阻層21〇,以減少 第-部210a的厚度直到第二部2娜與第三部職被移 除:在一實施例中,移除部分之圖案化光阻層21〇的方法 可採用灰化製程,其例如是錢氧氣電漿之乾式侧的方 式,使圖案化光阻層210的整體厚度降低。由於第二部21% 與第三部詹的厚度㈣,因此在完全移除第二部210b 3三部2H)c之後,仍會有未被完全移除 $留在圖案化導電層⑽,上。此時,剩餘之第一部施, 分圖案化導電層‘是位二皮暴露出的部 電# 108·,以於“仏未被第2術覆蓋之圖案化導 在-實:體=:=21的2 反應氣趙化^與…作為 與汲極214之後,可以^,導電I °在形成源極212 實施例之薄膜電晶步移除第一部2l〇a,,以完成本 是採用乾式去去:第-,^ 漿作為反應氣體來進行灰其中可氧氣電 201222821201222821 au l uuy υ 02 36141twf.doc / I 108' under the oxide semiconductor channel layer 206 will cause an undercut 216 at the sidewall thereof due to the side, and the undercut 216 occurs, for example, on the opposite side. Below the third portion 210c. In this embodiment, the undercut 216 due to the side surname causes the patterned conductive layer to protrude from the sidewalls of the oxide semiconductor channel layer 206. Referring to FIG. 2D, a portion of the patterned photoresist layer 21A is removed to reduce the thickness of the first portion 210a until the second portion 2a and the third portion are removed: in an embodiment, the portion is removed. The method of patterning the photoresist layer 21A may employ an ashing process, such as the dry side of the money oxygen plasma, to reduce the overall thickness of the patterned photoresist layer 210. Due to the thickness of the second portion 21% and the third portion (four), after the second portion 210b 3 three portions 2H)c are completely removed, there is still not completely removed $ remaining on the patterned conductive layer (10), . At this time, the remaining first portion, the sub-patterned conductive layer 'is the portion of the second skin exposed to the light, so that "the pattern is not covered by the second technique - in the body: body =: =21 of 2 reaction gas Zhao ^ and ... as with the drain 214, can be ^, conductive I ° in the formation of the source 212 embodiment of the film electro-technical step to remove the first part 2l〇a, to complete this Use dry type to go: -, ^ pulp as reaction gas to carry out ash, which can be oxygen 201222821

Auiuuyu02 36141twf.doc/I 在此說明的是,如圖2D及圖2E所示,第一部210a' 除了暴露出通道區上的部分圖案化導電層1〇8,外,還暴露 出位於底切216上方之圖案化導電層1〇8’的突出部。因 此,在移除暴露的圖案化導電層1〇8,之後,可以去除底切 216上方之圖案化導電層1〇8’的突出部,使得所形成之源Auiuuyu02 36141twf.doc/I It is explained that, as shown in FIG. 2D and FIG. 2E, the first portion 210a' is exposed to the undercut in addition to exposing a portion of the patterned conductive layer 1〇8 on the channel region. A protrusion of the patterned conductive layer 1〇8' above 216. Therefore, after the exposed patterned conductive layer 1?8 is removed, the protrusion of the patterned conductive layer 1?8' over the undercut 216 can be removed, so that the source is formed

極212與汲極214不會自氧化物半導體通道層2〇6之側壁 突出。在一實施例中,氧化物半導體通道層2〇6例如是突 出源極212與汲極214,而形成兩段式的側壁輪廓。氧化 物半導體通道層206之底部突出源極212與汲極214其中 之一之底部之水平距離D1約為〇.1 μηι至ι.〇μιη。八 此外,由於位於底切216上方之圖案化導電層1〇8,突 出部是利用圖案化光阻層210之剩餘的第一部21〇&,作為 罩幕而移除,因此在形成圖案化光阻層21〇時,還可以根 據氧化物半導體通道層206之底切216的程度來 ^ 兩相對外側之第三部21〇c的佈局,以使得位於底^加 上方之圖案化導電層可以被暴露出來㈣利於 移除,如圖2D所示。 说後續之 第三實施例 圖3A至圖3F是依照本發明之第三實施例之 膜 電晶體的製造流程示意圖。須注意的是,在圖Μ至圖π :’和圖2A至圖2E相同的構件則使用相同的標號並省略 其說明。在第三實補之_電_的製造方法 與 ^列所述之方法類似、然而兩者之間的差異技= 導電層的配置結構以及形成圖案化導電層之疋似 17The pole 212 and the drain 214 do not protrude from the side walls of the oxide semiconductor channel layer 2〇6. In one embodiment, the oxide semiconductor channel layer 2〇6, for example, protrudes from the source 212 and the drain 214 to form a two-stage sidewall profile. The bottom surface of the oxide semiconductor channel layer 206 protrudes from the source 212 and the bottom of one of the drains 214 by a horizontal distance D1 of about 1.1 μηι to ι.〇μιη. In addition, due to the patterned conductive layer 1〇8 located above the undercut 216, the protrusion is removed by using the remaining first portion 21〇& of the patterned photoresist layer 210, thus forming a pattern When the photoresist layer 21 is turned on, the layout of the third portion 21c can be further compared according to the degree of the undercut 216 of the oxide semiconductor channel layer 206, so that the patterned conductive layer is located above the bottom layer. Can be exposed (d) to facilitate removal, as shown in Figure 2D. Third Embodiment to Be Followed Figs. 3A to 3F are views showing a manufacturing process of a film transistor in accordance with a third embodiment of the present invention. It is to be noted that the same reference numerals are used for the same members as those of Figs. 2A to 2E, and the description thereof will be omitted. The manufacturing method of the third real complement is similar to the method described in the column, but the difference between the two is as follows: the configuration of the conductive layer and the formation of the patterned conductive layer.

201222821 AU1009002 36141twf.doc/I 請參照圖3A,提供基板loo,並於基板1〇〇上形 極102。接著,於基板1〇〇上依序形成閘絕緣層1〇4、氧化 物半導體材料層106以及導電層3〇8。在一實施例中 電層308包括底導電層以及頂導電層,且底導電層以及頂 導電層例如是具有不同的蝕刻選擇性。詳言之,導電層3〇8 的形成方法例如是於氧化物半導體材料層1%上依序曰形 第-導電層3_、第二導電層娜以及第三導電層細c, 其中第-導電層3G8a例如是作為底導電層,而其上之第二 導電層3·與第三導電層3〇8c例如是作為頂導電層。^ -導電層3G8a、第二導電層·b、第三導電層·之材 料分別可選自由銅(〇〇、钥_)、鈦⑼、雖、鶴㈤、 銀(Ag)、金(Au)及其合金所組成之族群中的至少一者。舉 例而言,第-導電層308a的材質例如是欽,第二導電層 3_的材質例如是紹,第三導電層3账的材質例如是麵, 而形成多層堆疊的複合金屬結構。 之後於導電層3〇8上形成圖案化光阻層训。圖案 阻層210包括二個第一部21〇a、第二部21〇b以及第 21〇c ’其中第二部21%連接於第一部別&之間,第 f 210c則刀別與各第一部21加連接而位於第一 部 210a : 一部2l0a之厚度例如是大於第二部210b及 各第二部210c之Μ ;#,b结_ 。 各第三部2收之厚^。第二卩雇之厚度實質上等於 Γ關案化*阻層210為罩幕,移除未被 八 9 1〇覆蓋之頂導電層(即第三導電層308c與201222821 AU1009002 36141twf.doc/I Referring to FIG. 3A, a substrate loo is provided, and the substrate 102 is formed on the substrate 1A. Next, a gate insulating layer 1?4, an oxide semiconductor material layer 106, and a conductive layer 3?8 are sequentially formed on the substrate 1?. In one embodiment, the electrical layer 308 includes a bottom conductive layer and a top conductive layer, and the bottom conductive layer and the top conductive layer have, for example, different etch selectivity. In detail, the method for forming the conductive layer 3〇8 is, for example, sequentially forming a first conductive layer 3_, a second conductive layer, and a third conductive layer fine c on the oxide semiconductor material layer 1%, wherein the first conductive portion The layer 3G8a is, for example, a bottom conductive layer, and the second conductive layer 3· and the third conductive layer 3〇8c thereon are, for example, a top conductive layer. ^ - Conductive layer 3G8a, second conductive layer b, third conductive layer · materials can be selected from copper (〇〇, key _), titanium (9), though, crane (five), silver (Ag), gold (Au) At least one of the groups consisting of its alloys. For example, the material of the first conductive layer 308a is, for example, the material of the second conductive layer 3_, for example, the material of the third conductive layer 3 is, for example, a surface, and a composite metal structure of a plurality of layers is formed. A patterned photoresist layer is then formed on the conductive layer 3〇8. The pattern resist layer 210 includes two first portions 21〇a, a second portion 21〇b, and a 21st 'c′ where the second portion 21% is connected between the first portion and the second portion, and the f 210c is Each of the first portions 21 is connected to be located at the first portion 210a: the thickness of the portion 210a is, for example, greater than the thickness of the second portion 210b and each of the second portions 210c; #,b结_. Each third part 2 is thicker. The thickness of the second employment is substantially equal to the thickness of the barrier layer. The barrier layer 210 is a mask to remove the top conductive layer that is not covered by the octagonal layer (ie, the third conductive layer 308c and

201222821 auiuuvu02 36141twf.doc/I 第二導電層308b)’以於第一導電層遍a與 210之間形成圖案化第三導電層3〇8c,與圖案化第阻層 3_,。在-實施例中,移除暴露出的第三導電層1電: 第二導電層遞的方法包括進行第—濕式侧製程,=、 :是藉由鋁酸(亦即磷酸、硝酸與醋酸的混合物)作為蝕 請參關3C ’以圖案化光阻層謂為罩幕 圖案化光阻層㈣覆蓋之底導電層(即第—導電層3=被 以於氧化物半導體材料層1〇6與圖案化第二導電 層3°8a,,因而形成如“ 層308之疊層。在一實施例中,移除暴露出的第2 3〇8a的方法包括進行乾式钱刻製程, ^電, BC13作為反應氣體。 使肖〇2與 請參照圖3D,以圖案化光阻層21()為罩幕 被圖案化光阻層21〇覆蓋之氧化物半 ,多除未 形,_體通道層306。在一實施:二:去: 覆蓋之氧化物半導體材料層1〇6的方法包:破 餘刻製程’ ^例如是藉由草酸作為_劑。 —濕式 Φ^Μ似地」由於· f向性之濕式似彳製程來移除暴靈 ’化物半導體材料層106,且圖案化導電層308,在、 iffί程中可作為硬罩幕,因此由側蝕所導致的底ΐ 广生在氧化物半導體通道層3〇6之側壁處,且底 316例如是位於相對外側之第三部2i〇c的下方。- 電層,例如會自氧化物半導體通道層_201222821 auiuuvu02 36141twf.doc/I The second conductive layer 308b)' forms a patterned third conductive layer 3?8c and a patterned resistive layer 3_ between the first conductive layer a and 210. In an embodiment, the exposed third conductive layer 1 is removed: the second conductive layer transfer method includes performing a first wet side process, =, : by alumina acid (ie, phosphoric acid, nitric acid, and acetic acid) As a etch, please refer to 3C' to pattern the photoresist layer as a mask patterned photoresist layer (4) to cover the bottom conductive layer (ie, the first conductive layer 3 = is used for the oxide semiconductor material layer 1 〇 6 Forming a second conductive layer 3°8a, thus forming a stack such as “layer 308. In one embodiment, the method of removing the exposed second 3〇8a includes performing a dry etching process, ^, BC13 is used as the reaction gas. 〇 〇 2 and please refer to FIG. 3D, the patterned photoresist layer 21 () is used as a mask to be patterned by the photoresist layer 21 〇 covered oxide half, more than unshaped, _ body channel layer 306. In one implementation: two: go: cover the oxide semiconductor material layer 1 〇 6 method package: break through the process ' ^ for example, by oxalic acid as a _ agent. - wet Φ ^ Μ 地 」 由于 由于 由于 由于f directional wet-like process to remove the turbulent 'semiconductor material layer 106, and patterned conductive layer 308, in the iff As a hard mask, the bottom ridge caused by the side etching is widely grown at the side wall of the oxide semiconductor channel layer 3〇6, and the bottom 316 is, for example, located below the third portion 2i〇c of the opposite outer side. , for example, from the oxide semiconductor channel layer _

201222821 aujuuvu02 36141twf.doc/I 請參照圖3Ε,移除部分之圖案化光阻層21〇,以減少 第一部210a的厚度直到第二部2·與第三部2l〇c被移 除,而暴露出圖案化第三導電層3〇8c,之部份上表面。此 時’未被兀全移除之第-部21〇a’會殘留在圖案化導電層 308’上’而暴露出位於後續預定形成通道區上方之部分圖 案化導電層308’以及位於底切316上方之圖案化導電層 308'的突出部。在—實施例中,移除部分之圖案化光阻^ 210的方法可採用灰化製程,其例如是使用氧氣電漿之乾 式侧的方式’使圖案化光阻層21G的整體厚度降低。 明參照圖3F,以未被移除之第一部210a,為罩幕,移 除位於底切316上方且未被第一部驗,覆蓋之圖案化導 電層細,’以於氧化物半導體通道層306上形成源極312 與没極314。在一實施例中,形成源極312與没極314的 方法包括進行乾式_製程,其例如使用a#Bcl3作為 反應氣體來移除暴露的圖案化導電層3〇8%此外,在形成 源,312姐極314之後,可以進一步移除第一部21〇&,, 以完成本實施例之薄膜電晶體的製作。 在本實施例中,藉由使第三部210c下方之部分圖S ❿ 化導電層則,暴露出來’因此在進行乾式侧製程之後, 位於底切316上方之圖案化導電層3〇8•的突出部即可被去 除,且氧化物半導體通道層3〇6例如是突出源極犯與汲 ,314。此外’圖案化光阻層21〇的佈局同樣地也可以根 據氧化物半導體通道層3〇6之底切M6的程度來設計位於 兩相對外側之第三部21〇c的範圍。 值得-提的是,由於圖案化第一導電層施,、圖案 20 201222821201222821 aujuuvu02 36141twf.doc/I Referring to FIG. 3A, a portion of the patterned photoresist layer 21A is removed to reduce the thickness of the first portion 210a until the second portion 2· and the third portion 2c〇c are removed. A portion of the upper surface of the patterned third conductive layer 3〇8c is exposed. At this time, the first portion 21〇a' which is not completely removed may remain on the patterned conductive layer 308' and expose a portion of the patterned conductive layer 308' located above the subsequent predetermined formation channel region and at the undercut. A protrusion of patterned conductive layer 308' above 316. In an embodiment, the method of removing portions of the patterned photoresist 210 may employ an ashing process that reduces the overall thickness of the patterned photoresist layer 21G by, for example, using the dry side of the oxygen plasma. Referring to FIG. 3F, the first portion 210a that has not been removed is used as a mask to remove the patterned conductive layer that is above the undercut 316 and is not covered by the first portion, and is used for the oxide semiconductor channel. Source 312 and dipole 314 are formed on layer 306. In one embodiment, the method of forming the source 312 and the gate 314 includes performing a dry process, which uses, for example, a#Bcl3 as a reactive gas to remove the exposed patterned conductive layer 3〇8%, in addition to the source, After the 312 sister pole 314, the first portion 21〇&, can be further removed to complete the fabrication of the thin film transistor of the present embodiment. In the present embodiment, the conductive layer is exposed by the portion S below the third portion 210c, so that after the dry side process, the patterned conductive layer 3 above the undercut 316 is removed. The protrusions can be removed, and the oxide semiconductor channel layer 3〇6 is, for example, a source of protrusions, 314. Further, the layout of the patterned photoresist layer 21A can also be designed in the range of the third portion 21c of the opposite outer sides in accordance with the degree of undercut M6 of the oxide semiconductor channel layer 3?6. It is worth mentioning that, due to the patterning of the first conductive layer, the pattern 20 201222821

AU1009002 36141twf.doc/IAU1009002 36141twf.doc/I

化第二導電層3〇8b,以及圖案化第三導電層3〇8c,例如是具 有不同的蝕刻選擇性,因此在進行乾式蝕刻製程來移除未 被第一部210a’覆蓋之圖案化導電層308,時,圖案化第二導 電層308a1、圖案化第二導電層308b,以及圖案化第三導電 層308c'被移除的程度也會有所差異。此外,在一實施例 中,圖案化第一導電層308a,與圖案化第二導電層3〇8b,所 構成的堆疊結構例如是具有實質上連續的侧壁,其可以為 垂直側壁或傾斜侧壁(tapered sidewall)。因此,氧化物半導 體通道層306以及源極312與汲極314會在兩相對外側處 形成二段式的側壁輪廓,且源極312與汲極314會在通道 區處形成兩段式的側壁輪靡。 舉例而言’如圖3F之區域A的局部放大示意圖所示, 氧化物半導體通道層之底部突出源極312與沒極314 其中之一之底部(亦即圖案化第一導電層3〇8a,之底 水 平距離D2約為0.1 μιη至i μπι,且圖案化第一導電層施, 之底部突出随化第二導電層姻b,之底部之水平距離D3 約為Ohm至L5Hm。另一方面,如圖3ρ之區域b的局 部放大示意圖所示’在通道區中,圖案化第—導電層撕 出圖案化第二導電層着之底部之水平距離Μ 約為 0.1 μπι 至 1.5 μηι。 賦_製郷絲化物半導體 且未被第一部21Ga’覆蓋之圖案化導電層逝。如此一 t 肖除氧化㈣導體通道層寫巾關騎導致的底切 現冢· 21The second conductive layer 3〇8b, and the patterned third conductive layer 3〇8c, for example, have different etch selectivity, so a dry etching process is performed to remove the patterned conductive layer not covered by the first portion 210a' The degree of layer 308, when the patterned second conductive layer 308a1, the patterned second conductive layer 308b, and the patterned third conductive layer 308c' are removed may also vary. In addition, in an embodiment, the first conductive layer 308a is patterned, and the second conductive layer 3〇8b is patterned, for example, the stacked structure has substantially continuous sidewalls, which may be vertical sidewalls or inclined sides. Tapered sidewall. Therefore, the oxide semiconductor channel layer 306 and the source 312 and the drain 314 form a two-stage sidewall profile at opposite outer sides, and the source 312 and the drain 314 form a two-stage sidewall wheel at the channel region. extravagant. For example, as shown in a partially enlarged schematic view of region A of FIG. 3F, the bottom of the oxide semiconductor channel layer protrudes from the bottom of one of the source 312 and the gate 314 (ie, the patterned first conductive layer 3〇8a, The bottom horizontal distance D2 is about 0.1 μm to i μπι, and the patterned first conductive layer is applied, and the bottom portion of the second conductive layer b is protruded, and the horizontal distance D3 of the bottom is about Ohm to L5Hm. As shown in the partially enlarged schematic view of the region b of Fig. 3p, in the channel region, the horizontal distance Μ of the bottom of the patterned second conductive layer from the patterned first conductive layer is about 0.1 μπι to 1.5 μηι. The patterned conductive layer is not covered by the first portion 21Ga', and the undercut is caused by the (4) conductor channel layer.

201222821 AU1009002 36141twf.doc/I 第四實施例 圖4A至圖4C是依照本發明之第四實施例之一種主動 元件陣列基板的製造流程示意圖。須注意的是,圖4A至 圖4C所示之製造流程是接續圖3C後的步驟,且在圖4a 至圖4C t ’和圖3A至圖3F相同的構件則使用相同的標 號並省略其說明。在第四實施例之薄膜電晶體的製造方法 與第三實施例所述之方法類似,然而兩者之間的差異主要 疋在於:形成圖案化導電層及形成氧化物半導體通道層之 籲 方式。 凊參照圖4A,在形成圖案化導電層3〇8,之疊層後, 移除部分之圖案化光阻層210,以減少第一部21〇a的厚度 直到第二部210b與第三部210c被移除。此時,未被完全 移除之第一部210a,會殘留在圖案化導電層3〇8,上,而暴露 出位於後續預定形成通道區上方之部分圖案化導電層308, 以及位於底切316上方之圖案化導電層3〇8,的突出部。在 一實施例中’移除部分之圖案化光阻層21〇的方法可採用 灰化製程’其例如是使用氧氣電漿之乾式蝕刻的方式使 φ 圖案化光阻層210的整體厚度降低。 請參照圖4B,以未被移除之第一部210a'為罩幕,移 除未被第一部21〇a,覆蓋之頂導電層(亦即圖案化第三導電 層308c’與圖案化第二導電層308b,)以及部分氧化物半導體 材料層106,而底導電層(亦即圖案化第一導電層308a>f列 如是不會被移除。因此’在圖案化第一導電層3〇8a,與第一 部21〇a’之間形成圖案化第三導電層4〇8c、圖案化第二導 22 201222821201222821 AU1009002 36141twf.doc/I Fourth Embodiment FIG. 4A to FIG. 4C are schematic diagrams showing a manufacturing process of an active device array substrate according to a fourth embodiment of the present invention. It should be noted that the manufacturing flow shown in FIG. 4A to FIG. 4C is the step subsequent to FIG. 3C, and the same components as those in FIGS. 4a to 4C' and FIGS. 3A to 3F are denoted by the same reference numerals and the description thereof will be omitted. . The method of manufacturing the thin film transistor of the fourth embodiment is similar to that of the third embodiment, but the difference between the two mainly lies in the manner of forming the patterned conductive layer and forming the oxide semiconductor channel layer. Referring to FIG. 4A, after forming the patterned conductive layer 3〇8, a portion of the patterned photoresist layer 210 is removed to reduce the thickness of the first portion 21〇a until the second portion 210b and the third portion. 210c was removed. At this time, the first portion 210a which is not completely removed may remain on the patterned conductive layer 3〇8, exposing a portion of the patterned conductive layer 308 located above the subsequent predetermined formation channel region, and located at the undercut 316. A protruding portion of the patterned conductive layer 3〇8 above. In one embodiment, the method of removing a portion of the patterned photoresist layer 21A may employ an ashing process which reduces the overall thickness of the φ patterned photoresist layer 210 by, for example, dry etching using oxygen plasma. Referring to FIG. 4B, the first portion 210a' that has not been removed is used as a mask to remove the top conductive layer (ie, the patterned third conductive layer 308c' and the patterned layer that is not covered by the first portion 21A. The second conductive layer 308b, and a portion of the oxide semiconductor material layer 106, and the bottom conductive layer (ie, the patterned first conductive layer 308a>f column is not removed. Therefore, the first conductive layer 3 is patterned. 〇8a, forming a patterned third conductive layer 4〇8c and a patterned second guide 22 between the first portion 21〇a′ 201222821

AU1009002 36141twf.d〇c/I 電層佩,且在圖案化第 之間形成氧化物半導體诵、^ ==閘錢層104 未被覆蓋之圖宏Π 道層 在一實施例中,移除 、案化第二導電層3〇8c,、圖案化第二導電屏 戈巍鄉广力氧化物半導崎料層106的方法包括進行i =人itf,且例如是藉由紹酸(亦即傭、硝酸與醋酸的、 1 合物=為_劑4此㈣劑對圖案化第-導3 308a之材質的钱刻率低。 曰 化第類由於採料向性之濕式侧製程來形成圖案 二導電層姻e、圖案化第二導電層· 條’且此濕式靖程不易移除圖 =層308a,,因此在氧化物半導體通道層獅之侧壁處會 务生因側倾導致的底切416。換言之,圖案化第一導& ^ 3〇8a,例如是自圖案化第三導電層她、圖案化第二導 電曰408b以及氧化物半導體通道層4〇6之側壁突出。 請參照圖4C ’以未被移除之第一部21〇a•為罩幕,移 除未破第-部210a’覆蓋之圖案化第一導電層3_,以及位 416上方之圖案化第一導電層術,以形成圖案化 第一導電層408a。圖案化第一導電層4〇8a、圖案化第二導 ^層4嶋以及圖案化第三導電層4敝例如是構成圖案化 導電層408之疊層,以於氧化物半導體通道層4〇6上分別 作為源極412與汲極414。在一實施例中,上述移除未被 第。卩210a覆蓋之圖案化第一導電層308a'以及位於底切 416上方之圖案化第一導電層3〇8a,的方法包括進行乾式钱 刻製程,其例如使用CL與BCI3作為反應氣體來移除暴露 的圖案化第一導電層308a1。此外,在形成源極412與汲極 23AU1009002 36141twf.d〇c/I electro-layered, and an oxide semiconductor is formed between the patterned portions, and the gate layer 104 is uncovered. In one embodiment, the layer is removed, The method of patterning the second conductive layer 3〇8c, patterning the second conductive screen Geyangxiang Guangli oxide semi-conducting layer 106 comprises performing i=person itf, and for example by using acid (also known as commission) , nitric acid and acetic acid, 1 compound = _ agent 4 This (four) agent has a low engraving rate for the material of the patterned first guide 308a. The smelting type is formed by the wet-side process of the tangential material. The second conductive layer is patterned, and the second conductive layer is stripped, and the wet pattern is not easy to remove the layer 308a, so that the bottom of the oxide semiconductor channel layer lion is caused by the roll. Cut 416. In other words, the patterned first conductive & ^ 3 〇 8a, for example, is self-patterned third conductive layer her, patterned second conductive 曰 408b and sidewalls of the oxide semiconductor channel layer 4 〇 6 protrude. 4C' is a masked first portion 21〇a• removed, and the patterned first conductive layer covered by the unbroken first portion 210a' is removed. 3_, and a patterned first conductive layer over the bit 416 to form a patterned first conductive layer 408a. Patterning the first conductive layer 4〇8a, patterning the second conductive layer 4嶋, and patterning the third conductive layer The layer 4 敝 is, for example, a laminate constituting the patterned conductive layer 408 to serve as the source 412 and the drain 414 on the oxide semiconductor channel layer 4 〇 6 respectively. In an embodiment, the above removal is not performed. The method of patterning the first conductive layer 308a' covered by 210a and the patterned first conductive layer 3?8a over the undercut 416 includes performing a dry etching process that removes exposure using, for example, CL and BCI3 as reactive gases. Patterning the first conductive layer 308a1. Further, forming the source 412 and the drain 23

201222821 AU1009002 36141twf.doc/I 414之後’可以進一步移除第一部210a',即完成本實施例 之薄膜電晶體的製作。 承上述’圖案化第三導電層408c與圖案化第二導電 層408b所構成的堆疊結構例如是具有實質上連續的側 壁,其可以為垂直側壁或傾斜側壁。此外,氧化物半導體 通道層406以及源極412與沒極414例如是會在兩相對外 側處形成二段式的側壁輪廓’且源極412與沒極414例如 是會在通道區處形成兩段式的側壁輪廓。類似圖3f之區 域A的局部放大示意圖,本實施例之氧化物半導體通道層 406之底部突出源極412與汲極414其中之一之底部(亦^ — 圖案化第一導電層408a之底部)之水平距離約為〇1 μηι至 1 μπι,且圖案化第一導電層408a之底部突出圖案化第二 導電層408b之底部之水平距離約為01 μπι至i 5μιη。 在本實施例中,先利用濕式蝕刻製程來同時移除未 第一部2·覆蓋之圖案化第三導電層3〇8c,、圖案化^ 導電層308b,以及部分氧化物半導體材料層1〇6,而留下圖 ^第-導電層308a,;之後才藉由乾式敍刻製程來移除未 破第一部210a,覆蓋之圖案化第一導電層3〇8a,。如此一 φ 來,即可消除由等向性濕式蝕刻製程對氧化物半導體通道 層406所造成的底切現象。 特別說明的是,在第三及第四實施例中,是以形成第 —導電層308a作為底導電層、形成第二導電 ^導電層她作為頂導電層之三層堆疊的電複層合結構= ^進行說明,但本發明並不限於此。當然,在其他實施例 ,底導電層例如是由多層金屬層所組成,且頂導電層也 24 201222821201222821 AU1009002 36141twf.doc/I 414 After the first portion 210a' can be further removed, the fabrication of the thin film transistor of the present embodiment is completed. The stacked structure formed by the above-described patterned third conductive layer 408c and patterned second conductive layer 408b has, for example, a substantially continuous side wall which may be a vertical side wall or a slant side wall. In addition, the oxide semiconductor channel layer 406 and the source 412 and the gate 414 may, for example, form a two-stage sidewall profile at two opposite outer sides and the source 412 and the gate 414 may form two segments at the channel region, for example. Side wall profile. A portion of the oxide semiconductor channel layer 406 of the present embodiment protrudes from the bottom of one of the source 412 and the drain 414 (also - the bottom of the patterned first conductive layer 408a). The horizontal distance is about μ1 μηι to 1 μπι, and the bottom of the patterned first conductive layer 408a protrudes from the bottom of the patterned second conductive layer 408b by a horizontal distance of about 01 μm to i5 μm. In this embodiment, the wet etching process is first used to simultaneously remove the patterned third conductive layer 3 8c, which is not covered by the first portion 2, the patterned conductive layer 308b, and the partial oxide semiconductor material layer 1 〇6, leaving the first conductive layer 308a, and then the unbroken first portion 210a is removed by the dry etch process to cover the patterned first conductive layer 3〇8a. With such a φ, the undercut caused by the isotropic wet etching process to the oxide semiconductor channel layer 406 can be eliminated. Specifically, in the third and fourth embodiments, the electrical-composite laminated structure in which the first conductive layer 308a is formed as the bottom conductive layer and the second conductive conductive layer is formed as the top conductive layer = ^ is explained, but the invention is not limited thereto. Of course, in other embodiments, the bottom conductive layer is composed of, for example, a plurality of metal layers, and the top conductive layer is also 24 201222821

/\kj i wy\j〇2 36141 twf.doc/I ’所屬技術領域中具 變化及應用,故於此 例如是由單層或多層的金屬層所組成 有通常知識者當可依前述實施例知其 不再贅述。 而且,須注意的是’以上所述之薄膜電晶體的製造方 法主要是絲詳細說卿成氧化物半導體通道層、源極與 没極之流程,峨熟習此項技術者能夠據以實施,但並# 用以蚊本侧之範圍。至於_電晶韻其他構件或佈/\kj i wy\j〇2 36141 twf.doc/I 'There is a variation and application in the technical field, so for example, it is composed of a single layer or a plurality of metal layers, and the general knowledge can be used according to the foregoing embodiment. I know that I will not repeat them. Moreover, it should be noted that the manufacturing method of the above-mentioned thin film transistor is mainly a detailed description of the process of forming an oxide semiconductor channel layer, a source and a immersive step, which can be implemented by those skilled in the art, but And # Use the scope of the mosquito side. As for _ electro-crystal rhyme other components or cloth

局’均可依所屬技術領域巾具有通常知識者所知的技術適 當調整’而不限於上述實施例所述。 综上所述,本發明之薄膜電晶體及其製造方法至少具 有下列優點: 1·上述實施例之薄膜電晶體及其製造方法藉由具有 多個厚度之圖案化光阻層來形成氧化物半導體通道層以及 源極與汲極,因而利用此減光罩製程可有助於減少士程步 驟與成本。 2. 上述實施例之薄膜電晶體及其製造方法可以避免 氧化物半導體通道層受損,並改善因側蝕所導致的底切現 象’因而使製程能夠獲得良好的控制。 3. 上述實施例之薄膜電晶體及其製造方法能夠與現 有的製程整合’並且廣泛應用在形成多種不同佈局之薄膜 電晶體。 ' 雖然本發明已以實施例揭露如上,然其並非用以限定 本發明’任何所屬技術領域中具有通常知識者,在不脫離 本發明之精神和範圍内,當可作些許之更動與潤飾,故本 25The bureau can be appropriately adjusted according to the technology of the art to which the person skilled in the art knows, and is not limited to the above embodiment. In summary, the thin film transistor of the present invention and the method of fabricating the same have at least the following advantages: 1. The thin film transistor of the above embodiment and the method of fabricating the same, the oxide semiconductor is formed by a patterned photoresist layer having a plurality of thicknesses The channel layer as well as the source and drain are used, so using this mask process can help reduce the steps and costs. 2. The thin film transistor of the above embodiment and the method of manufacturing the same can prevent the oxide semiconductor channel layer from being damaged and improve the undercut phenomenon caused by the side etching, thereby enabling the process to be well controlled. 3. The thin film transistor of the above embodiment and its method of fabrication can be integrated with existing processes' and are widely used in the formation of thin film transistors of a variety of different layouts. Although the present invention has been disclosed in the above embodiments, it is not intended to limit the invention to those skilled in the art, and may be modified and modified without departing from the spirit and scope of the invention. Therefore, this 25

201222821 AU1009002 36141 twf.doc/I 發明之保護範圍當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 圖1A至圖1D是依照本發明之第一實施例之一種薄 膜電晶體的製造流程示意圖。 圖2A至圖2E是依照本發明之第二實施例之一種薄膜 電晶體的製造流程示意圖。 圖3A至圖3F是依照本發明之第三實施例之一種薄膜 電晶體的製造流程示意圖。 圖4A至圖4C是依照本發明之第四實施例之一種主動 元件陣列基板的製造流程示意圖。 【主要元件符號說明】 100 :基板 102 :閘極 104 :閘絕緣層 106 :氧化物半導體材料層 106'、206、306、406 :氧化物半導體通道層 108、308 :導電層 108’、308’、408 :圖案化導電層 110、210 :圖案化光阻層 110a、110a'、210a、210a,:第一部 110b、210b :第二部 112、212、312、412 :源極 201222821201222821 AU1009002 36141 twf.doc/I The scope of protection of the invention is subject to the definition of the scope of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS Figs. 1A to 1D are views showing a manufacturing process of a thin film transistor according to a first embodiment of the present invention. 2A to 2E are schematic views showing a manufacturing process of a thin film transistor according to a second embodiment of the present invention. 3A to 3F are views showing a manufacturing process of a thin film transistor according to a third embodiment of the present invention. 4A to 4C are schematic views showing a manufacturing process of an active device array substrate in accordance with a fourth embodiment of the present invention. [Main component symbol description] 100: Substrate 102: Gate 104: Gate insulating layer 106: Oxide semiconductor material layers 106', 206, 306, 406: Oxide semiconductor channel layers 108, 308: Conductive layers 108', 308' 408: patterned conductive layers 110, 210: patterned photoresist layers 110a, 110a', 210a, 210a, first portions 110b, 210b: second portions 112, 212, 312, 412: source 201222821

AU1U09002 36141twf.doc/I 114、214、314、414 :汲極 210c :第三部 216、316、416 :底切 308a :第一導電層 308a'、408a:圖案化第一導電層 308b :第二導電層 308b'、408b:圖案化第二導電層 308c :第三導電層 308c’、408c:圖案化第三導電層 A、B :區域 D卜D2、D3、D4 :水平距離AU1U09002 36141twf.doc/I 114, 214, 314, 414: drain 210c: third portion 216, 316, 416: undercut 308a: first conductive layer 308a', 408a: patterned first conductive layer 308b: second Conductive layer 308b', 408b: patterned second conductive layer 308c: third conductive layer 308c', 408c: patterned third conductive layer A, B: region D Bu D2, D3, D4: horizontal distance

2727

Claims (1)

201222821 Auiuuyu02 36141twf.doc/I 七、申請專利範圍: 1.一種薄膜電晶體的製造方法,包括: 於一基板上形成一閘極; 基板上依序形成—騎緣H化物半導體材 料層以及一導電層; T子ϋ材 於^電層上軸—_化雜層,該圖案化光限層 :一—部以及一連接於該些第-部之間的第二部,丄 该第一部之厚度大於該第二部之厚度; 各 化光_為畢幕,移ί未被該圖案化光随層 層無魏物半導體材制,以形成一氧化 化光阻層之間的一圖案化導電層; 荼 ^除部分之該圖案化紐層,以減少該些第―部的厚 度直到該第二部被移除;以及 以未被移除之該些第—部為罩幕,移除未被該些第一 盖之該圖案化導電層’以於該氧化物半導體通道層上 形成一源極與一没極。 、土 ϋ申清專利範圍第1項所述之薄膜電晶體的製造方 ,,其中該圖案化光阻層係藉由階調式(Gray_Tc)neMask, Μ)製程或半調式(Half_TQneMask,htm)製程所形成。 ^.如_凊專利範圍第1項所述之薄膜電晶體的製造方 1·^中移除未被該圖案化触層覆蓋之該導電層與該氧 化物半導體材料層的方法包括: js渔^订—第—濕式1 虫刻製程,以移除未被該圖案化光阻 層覆蓋之該導電層;以及 28 201222821 AU1009002 36141 twf.doc/I 芦霜—献綱製程,卿除未被該圖案化光阻 ;====’其:該第,_ 不同。 ’“,、式餘刻製程所使用之敍刻劑 法,㈣1項所述之薄膜電晶體的製造方 化物半導體材料層的方法包=阻層覆盖之該導電層與該氧 進仃-濕式姓刻製程,以 盖之該導電層以及該氧化物半導=圖;:先阻層覆 與,化物半導體材料層採用移二該導電層 法,其中移除部分之關魏光的製造方 6. 如申請專職_丨項所^之的方= 包括灰化製程。 法’其中形成該源極與該汲極的方法=電晶 體的製造方 以未被移除之該些第一部為罩 移除未被該些第-部覆蓋之該圖案^導^ 一濕式钱刻以 7. 如申請專·圍第1項所述之薄胺^ 法了=源極她錄之後,更包括移1=的第製T 8. -種薄膜電晶體的製造方法 ;于"亥』第-部。 於一基板上形成一閘極; . 於該基板上依序形成一閘絕緣層、— 料層以及一導電層; 氧化物半導體材 於該導電層上形成一圖案化 ,二第一部、-連接於該些第,案化光阻層 ’、各該第-部連接之第三部,各該第、第二部以及二 。之厚度大於該第 29 201222821 AU1009002 36141twf.doc/I 厚度’且該第二部之厚度實f上等於各該第三部之 且層為罩幕,移除未被該圖案化光阻層 於該氧化物半導體通道層ί該= 切發生^化物’其中_斤導致的底 該些第:部= 道層之側壁處,且該底切位於 度減第,厚 導::位於該底切上 物半導體通道層上形成—源極與::^電層,以於該氧化 9·如巾請專利翻第8項所述之_電 所形Ϊ中該圖案化光阻層係藉由階調式製“半調式ΪΞ 方法的製造 氧化物半導體材料層的方法包括.層覆盖之該導電層與該 蓋之in式=_,以贿未_㈣化光祖層覆 蓋之覆 如申請專利範圍第8項所述 ’其中該導電層包括-底導電層以及」 方法 30 201222821 AU1009002 36141twf.doc/I ===阻層覆蓋之該導電層與該氧化物半導 層覆刪程,以崎侧案化光阻 蓋之以移除未被該圖案化光阻層覆 ,行-第二濕式_製程,以移除未被該圖案 層覆蓋之該氧化物半導體材料層。 Ρ 方Α如::,範圍第8項所述之薄膜電晶體的製造 ^法,其中移除Μ之該圖案化触層的方法包括灰化製 13.如申料職_ 8摘述 方法,其中形成該源極與舰極的方法包括^體的I造 以未被移除之該些第一部為罩幕’進行一 =位於該底切上方且未被該些第—部覆蓋之該圖案= Η.如申請專·圍第8項所叙_電晶體 ^法’在形成該源極與概極之後,更包括移除該些第一 15.—種薄膜電晶體的製造方法,包括: 於一基板上形成一閘極; 於該基板上依序形成-閘絕緣層、一氧 料層、-底導電層以及-頂導電層; 干等體材 於該頂導電層上形成-圖案化光阻層,該圖案化 層包括二第-部、-連接於該些第—部之間的第二部以及 31 201222821 AU1009002 36141twf.doc/I 二與各該第一部連接之第三部, 第二部之厚度,且該第二部 部之厚度大於該 之厚度; 又質上等於各該第三部 以該圖案化光阻層為罩幕, 覆蓋之該頂導電層與該底導電層禾破該圖案化光阻層 移除部分之該圖案化光阻 度直到該第二部與該些第三部被移除减^些第-部的厚 以未被移除之該些第—部為罩 部覆蓋之該頂導電層以及部分該氧化物第- 層,其中因側触所導致氧化物半導體通道 層之侧壁m u在該氧化物半導體通道 以未被移除之該些第—Αβ炎 ======= 鲁 17·γ請專利範!|第15項所述之薄膜電晶體的製 4念道,、巾移除未被該_化光阻層覆蓋之該頂導電^斑 该底導電層的方法包括: 电增與 “進行-濕式姓刻製程,以移除未被該圖案化 盍之該頂導電層;以及 增復 蓋之ϊίίΐΐ侧心,絲未觀㈣化先阻層覆 32 201222821 AU1009002 36141twf.doc/I 18.如申請專利範圍第15項所述之 方法,其中以未被移除之該些第一部、電晶體的製造 些第—部覆蓋之該頂導電層以及部分哕羞’移除未被該 層之方法包括: '"氧化物半導體材料 進行一濕式蝕刻製程,以移除未被 _導電層以及部分該氧化物半導體材^第—部覆蓋之201222821 Auiuuyu02 36141twf.doc/I VII. Patent application scope: 1. A method for manufacturing a thin film transistor, comprising: forming a gate on a substrate; forming a layer on the substrate in sequence - riding a layer of H compound semiconductor material and a conductive a layer; a T sub-clay on the upper layer of the electro-layer - a hybrid layer, the patterned optical confinement layer: a portion and a second portion connected between the first portions, the first portion The thickness is greater than the thickness of the second portion; each of the luminescence _ is a screen, and the patterned light is not formed by the layered semiconductor-free material to form a patterned conductive layer between the oxidized photoresist layers. a layered portion of the patterned layer to reduce the thickness of the portions until the second portion is removed; and the portions that are not removed are masked and removed The patterned conductive layer of the first cover forms a source and a gate on the oxide semiconductor channel layer. The manufacturer of the thin film transistor according to the first aspect of the patent application, wherein the patterned photoresist layer is processed by a gray-scale (Gray_Tc)neMask, Μ) process or a half-tone (Half_TQneMask, htm) process. Formed. The method for removing the conductive layer and the oxide semiconductor material layer not covered by the patterned contact layer in the manufacturing method of the thin film transistor according to the first aspect of the invention includes: js fishing ^订-第湿1 insect engraving process to remove the conductive layer not covered by the patterned photoresist layer; and 28 201222821 AU1009002 36141 twf.doc/I frost frost - design process, Qing except The patterned photoresist; ====' it: the first, _ different. The method of manufacturing a compound semiconductor material layer of the thin film transistor described in the above-mentioned method, the conductive layer covered with the resist layer and the oxygen-in-wet type The last name is engraved to cover the conductive layer and the oxide semiconductor = map; the first resist layer is coated, and the semiconductor material layer is moved by the conductive layer method, wherein the part of the removal of Wei Guang is manufactured. The application for the full-time _ 所 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = The pattern that is not covered by the first part is a wet type of money. 7. If you apply for the thin amine method described in item 1, the source is recorded, and the shift is 1 = a method for manufacturing a T8-type thin film transistor; in the section of "Hai", forming a gate on a substrate; forming a gate insulating layer, a material layer, and the like on the substrate a conductive layer; an oxide semiconductor material forms a pattern on the conductive layer, and the first portion is connected to the a thinned photoresist layer, a third portion of each of the first-part connections, each of the second, second, and second thicknesses greater than the thickness of the 29th 201222821 AU1009002 36141twf.doc/I and the second portion The thickness of the third portion is equal to each of the third portions and the layer is a mask, and the removal is not caused by the patterned photoresist layer in the oxide semiconductor channel layer. The first part is at the side wall of the track layer, and the undercut is located at the degree of reduction, and the thick guide: is formed on the undercut semiconductor semiconductor channel layer to form a source and a :: an electrical layer for the oxidation 9· The method for fabricating an oxide semiconductor layer by a half-tone ΪΞ method includes a layer covering the conductive layer. The layer and the cover of the formula = _, covered with a bribe _ (four) photo-progenitor layer covered as described in the scope of claim 8 'where the conductive layer includes - bottom conductive layer and" method 30 201222821 AU1009002 36141twf.doc /I ===The conductive layer covered by the resist layer and the oxide semi-conductive layer are covered by the cut-off process, Cover the photoresist pattern to remove the patterned photoresist layer is not covered, the line - _ second wet process, not to remove the oxide layer covers the semiconductor material of the pattern layer. Ρ方Α::, The manufacturing method of the thin film transistor according to Item 8, wherein the method of removing the patterned contact layer of the crucible comprises ashing. 13. The method for forming the source and the ship includes: the first portion of the body that is not removed is a mask, and the first one is located above the undercut and is not covered by the first portion. Pattern = Η. As described in the application of the eighth paragraph _ transistor ^ method after the formation of the source and the extreme, including the removal of the first 15. -1 film transistor manufacturing methods, including Forming a gate on a substrate; forming a gate insulating layer, an oxygen layer, a bottom conductive layer, and a top conductive layer on the substrate; the dry body material forms a pattern on the top conductive layer a photoresist layer, the patterned layer comprising two first portions, a second portion connected between the first portions, and 31 201222821 AU1009002 36141twf.doc/I 2 and a third portion connected to each of the first portions a thickness of the second portion, wherein the thickness of the second portion is greater than the thickness; and qualitatively equal to each of the third portions being patterned The resist layer is a mask covering the top conductive layer and the bottom conductive layer to break the patterned photoresist of the patterned photoresist layer removing portion until the second portion and the third portions are removed The portions of the first portion that are not removed are the top conductive layer covered by the cover portion and a portion of the oxide first layer, wherein the sidewall of the oxide semiconductor channel layer is caused by the side contact Mu in the oxide semiconductor channel is not removed, the first - Αβ inflammation ======= Lu 17 · γ please patent! The method for manufacturing a thin film transistor according to claim 15, wherein the method for removing the top conductive layer of the top conductive layer that is not covered by the photoresist layer comprises: electrically increasing and "promoting-wet" The last name engraving process is to remove the top conductive layer that is not patterned, and the cover layer is ϊίίΐΐ, and the wire is not observed (4) the first resistance layer 32 201222821 AU1009002 36141twf.doc/I 18. Apply The method of claim 15, wherein the first portion, the top conductive layer covered by the first portion of the transistor, and the portion of the transistor are removed from the layer The method includes: '" an oxide semiconductor material performing a wet etching process to remove the un-conductive layer and a portion of the oxide semiconductor material 19·如申請專利範圍第15項所述之薄胆 ’其中以未被移除之該些第一部為軍幕電;= 電爾電⑽位於該細上 該底it乾式侧製程,以移除未被該些第—部覆蓋之 、電層以及位於該底切上方之該底導電層。 方决,〇甘如中請專利範圍第15項所述之薄膜電晶體的製造 程。、巾移除部分之該圖案化光阻層的方法包括灰化製 方法^如申請專利範圍第8項所述之薄膜電晶體的製造 部。在开)成該源極與該汲極之後,更包括移除該些第一 22. —種薄膜電晶體,包括: 〜閘極; 閘絕緣層,位於該閘極上; 氣化物半導體通道層,位於該閘絕緣層上;以及 其中極以及一汲極,位於該氧化物半導體通道層上, 其中S氣化物半導體通道層之底部突出該源極以及該沒極 〜之底部之水平距離約為0.1 μιη 至 1 μΐϋ。 33 201222821 auiuuvu02 36141twf.doc/I 23. 如專利申請範圍第22項所述之薄膜電晶體,其中 該源極包括: 一第一導電層,位於該氧化物半導體通道層上;以及 一第二導電層,位於該第一導電層上,其中該第一導 電層之底部突出該第二導電層之底部之水平距離約為0.1 μιη 至 1.5 μιη。 24. 如專利申請範圍第23項所述之薄膜電晶體,其中 該源極更包括一第三導電層,位於該第二導電層上。 25. 如專利申請範圍第24項所述之薄膜電晶體,其中 該第一導電層、該第二導電層以及該第三導電層之材料分 別為選自由銅、鉬、鈦、铭、鶴、銀、金及其合金所組成 之族群中的至少一者。 3419. The thin body described in claim 15 of the patent application, wherein the first part that has not been removed is the military power; the electric power (10) is located on the bottom of the dry side process to move Except for the electrical layer not covered by the first portions and the bottom conductive layer above the undercut. In the case of the decision, the processing of the thin film transistor described in the fifteenth patent section is requested. The method of removing the portion of the patterned photoresist layer by the towel comprises the method of ashing, such as the manufacturing of the thin film transistor described in claim 8. After the opening of the source and the drain, the method further includes removing the first 22-type thin film transistors, including: - a gate; a gate insulating layer on the gate; a vaporized semiconductor channel layer, Located on the gate insulating layer; and a pole and a drain on the oxide semiconductor channel layer, wherein a bottom of the S vapor-semiconductor channel layer protrudes from the source and a bottom horizontal distance of the bottom is about 0.1 Ιιη to 1 μΐϋ. A thin film transistor according to claim 22, wherein the source includes: a first conductive layer on the oxide semiconductor channel layer; and a second conductive layer And a layer on the first conductive layer, wherein a bottom of the first conductive layer protrudes from a bottom of the second conductive layer by a horizontal distance of about 0.1 μm to 1.5 μm. 24. The thin film transistor of claim 23, wherein the source further comprises a third conductive layer on the second conductive layer. The thin film transistor according to claim 24, wherein the materials of the first conductive layer, the second conductive layer and the third conductive layer are respectively selected from the group consisting of copper, molybdenum, titanium, Ming, and crane. At least one of the group consisting of silver, gold, and alloys thereof. 34
TW99140006A 2010-11-19 2010-11-19 Thin film transistor and method for fabricating the same TWI416736B (en)

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