TW201138854A - Composition - Google Patents
Composition Download PDFInfo
- Publication number
- TW201138854A TW201138854A TW100107218A TW100107218A TW201138854A TW 201138854 A TW201138854 A TW 201138854A TW 100107218 A TW100107218 A TW 100107218A TW 100107218 A TW100107218 A TW 100107218A TW 201138854 A TW201138854 A TW 201138854A
- Authority
- TW
- Taiwan
- Prior art keywords
- dye
- composition
- blue
- monomer
- acid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 24
- 229920000642 polymer Polymers 0.000 claims abstract description 23
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 14
- 210000004209 hair Anatomy 0.000 claims abstract description 11
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 6
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 6
- 150000002367 halogens Chemical class 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims abstract description 5
- 150000001336 alkenes Chemical group 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 4
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 3
- 150000001412 amines Chemical class 0.000 claims abstract 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine group Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 28
- -1 tris-dioxazine Chemical compound 0.000 claims description 6
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 5
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 4
- 125000006295 amino methylene group Chemical group [H]N(*)C([H])([H])* 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 claims description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 2
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 claims description 2
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 229950008882 polysorbate Drugs 0.000 claims 2
- 229920000136 polysorbate Polymers 0.000 claims 2
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 230000037308 hair color Effects 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 abstract 2
- 239000000975 dye Substances 0.000 description 47
- 239000002253 acid Substances 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- 210000002268 wool Anatomy 0.000 description 7
- 239000002453 shampoo Substances 0.000 description 6
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 231100000640 hair analysis Toxicity 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 235000021419 vinegar Nutrition 0.000 description 3
- XUDJOVURIXHNRW-UHFFFAOYSA-N 1-amino-4-anilinoanthracene-9,10-dione Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=CC=C1NC1=CC=CC=C1 XUDJOVURIXHNRW-UHFFFAOYSA-N 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- FQLZTPSAVDHUKS-UHFFFAOYSA-N 6-amino-2-(2,4-dimethylphenyl)benzo[de]isoquinoline-1,3-dione Chemical compound CC1=CC(C)=CC=C1N(C1=O)C(=O)C2=C3C1=CC=CC3=C(N)C=C2 FQLZTPSAVDHUKS-UHFFFAOYSA-N 0.000 description 2
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- LGNOFMLHGRSNNC-UHFFFAOYSA-N helium;prop-1-ene Chemical compound [He].CC=C LGNOFMLHGRSNNC-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- RRETZLLHOMHNNB-UHFFFAOYSA-M sodium;1-amino-9,10-dioxo-4-(2,4,6-trimethylanilino)anthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=CC(C)=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O RRETZLLHOMHNNB-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- SVGUNYFQHHUNDJ-UHFFFAOYSA-N (6-fluoro-1-benzothiophen-2-yl)boronic acid Chemical compound C1=C(F)C=C2SC(B(O)O)=CC2=C1 SVGUNYFQHHUNDJ-UHFFFAOYSA-N 0.000 description 1
- BTEIWWXAPYLKDK-UHFFFAOYSA-N 1,1-diphenyldecylbenzene Chemical compound CCCCCCCCCC(c1ccccc1)(c1ccccc1)c1ccccc1 BTEIWWXAPYLKDK-UHFFFAOYSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 1
- KZYAYVSWIPZDKL-UHFFFAOYSA-N 1,4-diamino-2,3-dichloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=C(Cl)C(Cl)=C2N KZYAYVSWIPZDKL-UHFFFAOYSA-N 0.000 description 1
- SDICTISQCKLMEB-UHFFFAOYSA-N 1,4-diamino-5-nitroanthracene-9,10-dione Chemical compound O=C1C=2C(N)=CC=C(N)C=2C(=O)C2=C1C=CC=C2[N+]([O-])=O SDICTISQCKLMEB-UHFFFAOYSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- SPDRRRCQUXHHLH-UHFFFAOYSA-N 1-amino-2-bromo-4-(4-methylanilino)anthracene-9,10-dione Chemical compound C1=CC(C)=CC=C1NC1=CC(Br)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O SPDRRRCQUXHHLH-UHFFFAOYSA-N 0.000 description 1
- MSSQDESMUMSQEN-UHFFFAOYSA-N 1-amino-2-bromo-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC(Br)=C2N MSSQDESMUMSQEN-UHFFFAOYSA-N 0.000 description 1
- ICVRBKCRXNVOJC-UHFFFAOYSA-N 1-amino-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2NC ICVRBKCRXNVOJC-UHFFFAOYSA-N 0.000 description 1
- RQLMZSLFKGNXTO-UHFFFAOYSA-N 1-amino-4-hydroxy-2-(6-hydroxyhexoxy)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC(OCCCCCCO)=C2N RQLMZSLFKGNXTO-UHFFFAOYSA-N 0.000 description 1
- CRMKCODPIHHCGA-UHFFFAOYSA-N 1-amino-4-hydroxy-2-[2-(2-methoxyethoxy)ethoxy]anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(N)C(OCCOCCOC)=CC(O)=C3C(=O)C2=C1 CRMKCODPIHHCGA-UHFFFAOYSA-N 0.000 description 1
- WSPPHHAIMCTKNN-UHFFFAOYSA-N 1-amino-4-hydroxy-2-methoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(O)=C3C(=O)C2=C1 WSPPHHAIMCTKNN-UHFFFAOYSA-N 0.000 description 1
- MHXFWEJMQVIWDH-UHFFFAOYSA-N 1-amino-4-hydroxy-2-phenoxyanthracene-9,10-dione Chemical compound C1=C(O)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 MHXFWEJMQVIWDH-UHFFFAOYSA-N 0.000 description 1
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 description 1
- PPGISMVFVBBTGY-UHFFFAOYSA-N 1-amino-8-anilino-4,5-dihydroxyanthracene-9,10-dione Chemical compound C=12C(=O)C=3C(N)=CC=C(O)C=3C(=O)C2=C(O)C=CC=1NC1=CC=CC=C1 PPGISMVFVBBTGY-UHFFFAOYSA-N 0.000 description 1
- IHWDSEPNZDYMNF-UHFFFAOYSA-N 1H-indol-2-amine Chemical group C1=CC=C2NC(N)=CC2=C1 IHWDSEPNZDYMNF-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- WZNMYVXPXBZDJK-UHFFFAOYSA-N 2-(decylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCNCCOC(=O)C(C)=C WZNMYVXPXBZDJK-UHFFFAOYSA-N 0.000 description 1
- AACHVWXCVWWMSI-UHFFFAOYSA-N 3-hydroxypropyl(trimethyl)azanium Chemical compound C[N+](C)(C)CCCO AACHVWXCVWWMSI-UHFFFAOYSA-N 0.000 description 1
- ZCMWRFQVYXHUQN-UHFFFAOYSA-N 4,11-diamino-1-imino-2-(3-methoxypropyl)naphtho[2,3-f]isoindole-3,5,10-trione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=C(C(N(CCCOC)C1=N)=O)C1=C2N ZCMWRFQVYXHUQN-UHFFFAOYSA-N 0.000 description 1
- DJWUYSRYGUVNBA-UHFFFAOYSA-N 4,5,6-triphenyldioxazine Chemical compound N=1OOC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)C=1C1=CC=CC=C1 DJWUYSRYGUVNBA-UHFFFAOYSA-N 0.000 description 1
- ALXCWDABTQQKAH-UHFFFAOYSA-N 4-(1-amino-4-hydroxy-9,10-dioxoanthracen-2-yl)oxy-n-(3-ethoxypropyl)benzenesulfonamide Chemical compound C1=CC(S(=O)(=O)NCCCOCC)=CC=C1OC1=CC(O)=C(C(=O)C=2C(=CC=CC=2)C2=O)C2=C1N ALXCWDABTQQKAH-UHFFFAOYSA-N 0.000 description 1
- FHYNZKLNCPUNEU-UHFFFAOYSA-N 4-[(3,4-dihydroxyphenyl)methyl]-3-[(4-hydroxyphenyl)methyl]oxolan-2-one Chemical compound C1=CC(O)=CC=C1CC1C(=O)OCC1CC1=CC=C(O)C(O)=C1 FHYNZKLNCPUNEU-UHFFFAOYSA-N 0.000 description 1
- ALJHHTHBYJROOG-UHFFFAOYSA-N 7-(dimethylamino)phenothiazin-3-one Chemical compound C1=CC(=O)C=C2SC3=CC(N(C)C)=CC=C3N=C21 ALJHHTHBYJROOG-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- YCSMVPSDJIOXGN-UHFFFAOYSA-N CCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCC[Na] YCSMVPSDJIOXGN-UHFFFAOYSA-N 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 206010019049 Hair texture abnormal Diseases 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- XREZMAAQVYVESP-UHFFFAOYSA-N acetyloxymethyl 2-[n-[2-(acetyloxymethoxy)-2-oxoethyl]-2-[2-[2-[bis[2-(acetyloxymethoxy)-2-oxoethyl]amino]-4-fluorophenoxy]ethoxy]-5-fluoroanilino]acetate Chemical compound CC(=O)OCOC(=O)CN(CC(=O)OCOC(C)=O)C1=CC(F)=CC=C1OCCOC1=CC=C(F)C=C1N(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O XREZMAAQVYVESP-UHFFFAOYSA-N 0.000 description 1
- LIKZXCROQGHXTI-UHFFFAOYSA-M acid blue 25 Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1=CC=CC=C1 LIKZXCROQGHXTI-UHFFFAOYSA-M 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- RZUBARUFLYGOGC-MTHOTQAESA-L acid fuchsin Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=C(N)C(C)=CC(C(=C\2C=C(C(=[NH2+])C=C/2)S([O-])(=O)=O)\C=2C=C(C(N)=CC=2)S([O-])(=O)=O)=C1 RZUBARUFLYGOGC-MTHOTQAESA-L 0.000 description 1
- 229940099540 acid violet 43 Drugs 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N aconitic acid Chemical compound OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- KSKRLEFNLNIYRS-UHFFFAOYSA-N azanium 2,3-di(nonyl)benzenesulfonate Chemical compound C(CCCCCCCC)C=1C(=C(C=CC1)S(=O)(=O)[O-])CCCCCCCCC.[NH4+] KSKRLEFNLNIYRS-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000012709 brilliant black BN Nutrition 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- BBWPEJUNPNPWJI-UHFFFAOYSA-L disodium 3-[(4-aminophenyl)diazenyl]-4,5-dihydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].NC1=CC=C(C=C1)N=NC=1C(=CC2=CC(=CC(=C2C=1O)O)S(=O)(=O)[O-])S(=O)(=O)[O-] BBWPEJUNPNPWJI-UHFFFAOYSA-L 0.000 description 1
- VGCGYVHOTSGFBE-UHFFFAOYSA-L disodium 4-amino-3-[(4-aminophenyl)diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(cc1)N=Nc1c(N)c2c(O)c(N=Nc3ccccc3)c(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O VGCGYVHOTSGFBE-UHFFFAOYSA-L 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- ARZVLGVDYAMAFX-UHFFFAOYSA-L disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc2cc(cc(O)c2c1N=Nc1ccc(cc1S([O-])(=O)=O)[N+]([O-])=O)S([O-])(=O)=O ARZVLGVDYAMAFX-UHFFFAOYSA-L 0.000 description 1
- XHWOCFKPINOVST-UHFFFAOYSA-L disodium 6-amino-5-[(4-amino-2-sulfonatophenyl)diazenyl]-4-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2c(N)ccc3cc(cc(O)c23)S([O-])(=O)=O)c(c1)S([O-])(=O)=O XHWOCFKPINOVST-UHFFFAOYSA-L 0.000 description 1
- RHCZISCTNGVWCV-UHFFFAOYSA-L disodium;1-amino-4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O RHCZISCTNGVWCV-UHFFFAOYSA-L 0.000 description 1
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 1
- VVIVVAIHOWVTHB-UHFFFAOYSA-L disodium;3-[[4-amino-9,10-dioxo-3-[2-sulfonato-4-(2,4,4-trimethylpentan-2-yl)phenoxy]anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC1=CC(OC=2C(=CC(=CC=2)C(C)(C)CC(C)(C)C)S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O VVIVVAIHOWVTHB-UHFFFAOYSA-L 0.000 description 1
- WSALIDVQXCHFEG-UHFFFAOYSA-L disodium;4,8-diamino-1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulfonate Chemical compound [Na+].[Na+].O=C1C2=C(N)C=C(S([O-])(=O)=O)C(O)=C2C(=O)C2=C1C(O)=C(S([O-])(=O)=O)C=C2N WSALIDVQXCHFEG-UHFFFAOYSA-L 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 150000004141 diterpene derivatives Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- HYLDLLCHFLSKAG-UHFFFAOYSA-M lissamine flavine FF Chemical compound [Na+].C1=CC(C)=CC=C1N(C1=O)C(=O)C2=C3C1=CC=CC3=C(N)C(S([O-])(=O)=O)=C2 HYLDLLCHFLSKAG-UHFFFAOYSA-M 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- BXIGAWRFDMDLTL-UHFFFAOYSA-N n-(4-amino-3-methoxy-9,10-dioxoanthracen-1-yl)-4-methylbenzenesulfonamide Chemical compound C=12C(=O)C3=CC=CC=C3C(=O)C2=C(N)C(OC)=CC=1NS(=O)(=O)C1=CC=C(C)C=C1 BXIGAWRFDMDLTL-UHFFFAOYSA-N 0.000 description 1
- BOUCRWJEKAGKKG-UHFFFAOYSA-N n-[3-(diethylaminomethyl)-4-hydroxyphenyl]acetamide Chemical compound CCN(CC)CC1=CC(NC(C)=O)=CC=C1O BOUCRWJEKAGKKG-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- KUGJMOBKICDOTA-UHFFFAOYSA-N sodium 3-[(4-acetamidophenyl)diazenyl]-4,5-dihydroxynaphthalene-2,7-disulfonic acid Chemical compound CC(=O)NC1=CC=C(C=C1)N=NC2=C(C3=C(C=C(C=C3C=C2S(=O)(=O)O)S(=O)(=O)O)O)O.[Na+] KUGJMOBKICDOTA-UHFFFAOYSA-N 0.000 description 1
- MHHGZCMFNNAVCQ-UHFFFAOYSA-M sodium;1-amino-4-[3-(2-hydroxyethylsulfamoyl)-4,5-dimethylanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].OCCNS(=O)(=O)C1=C(C)C(C)=CC(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)=C1 MHHGZCMFNNAVCQ-UHFFFAOYSA-M 0.000 description 1
- QVCCZAZTGUCIHD-UHFFFAOYSA-M sodium;2-[(4-amino-3-bromo-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(Br)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O QVCCZAZTGUCIHD-UHFFFAOYSA-M 0.000 description 1
- BADRBIXUSUCBEG-UHFFFAOYSA-M sodium;2-[(4-amino-3-methyl-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(C)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O BADRBIXUSUCBEG-UHFFFAOYSA-M 0.000 description 1
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 description 1
- XRDGMZURKJHKPO-UHFFFAOYSA-M sodium;dodecyl sulfate;sulfuric acid Chemical compound [Na+].OS([O-])(=O)=O.CCCCCCCCCCCCOS(O)(=O)=O XRDGMZURKJHKPO-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 description 1
- GMMAPXRGRVJYJY-UHFFFAOYSA-J tetrasodium 4-acetamido-5-hydroxy-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].OC1=C2C(NC(=O)C)=CC=C(S([O-])(=O)=O)C2=CC(S([O-])(=O)=O)=C1N=NC(C1=CC(=CC=C11)S([O-])(=O)=O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 GMMAPXRGRVJYJY-UHFFFAOYSA-J 0.000 description 1
- CTIIFDITHFRQBX-UHFFFAOYSA-J tetrasodium 7-anilino-4-hydroxy-3-[[6-sulfonato-4-[[6-sulfonato-4-[(3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Oc1c(N=Nc2ccc(N=Nc3ccc(N=Nc4cccc(c4)S([O-])(=O)=O)c4cc(ccc34)S([O-])(=O)=O)c3cc(ccc23)S([O-])(=O)=O)c(cc2cc(Nc3ccccc3)ccc12)S([O-])(=O)=O CTIIFDITHFRQBX-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/91—Graft copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
201138854 六、發明說明： 【發明所屬之技術領域】 本發明係關於聚合物染料及其在乾燥頭髮中之使用方 法。 【先前技術】 儘管具有先前技術，仍需要改良之頭髮乾燥組合物。 【發明内容】 因此，且在第一態樣中，提供包含聚合物染料之頭髮護 理組合物，該聚合物染料可藉由聚合以下物質獲得： (a)第一染料單體，其具有式I之結構：
Y—染料
式I 其中 Y選自-CONH-或-C02CH2CH(0H)CH2-NH-，且1^ 選自 Η、烧基、芳基、节基、鹵素、醋、醯胺及CN， 式II及
式III (b)第二單體，其具有選自式II及式III之結構：
X—nr2r3 154382.doc 201138854 ' 其中χ係將胺共價連接至該單體之烯烴部分之有機橋接基 團，較佳地，X係-C02(CH2)n-，其中n=l至6 ; 其中Rs選自：Η、烷基、芳基、苄基、鹵素、酯、醯胺及 CN，較佳地，115係(：113或Η ;且 其中R2、R3及R4獨立地選自Η或烷基，較佳地，R2、尺3及 ’ R4中之至少兩者係烷基》 較佳地，Y係-CH2CH(OH)CH2-NH。較佳地，R,選自Η或 CH3。較佳地，η=2。較佳之烷基係C1至C6具支鏈、直鏈 或環狀，最佳CH3或C2Hs。R2及&可結合形成5或6員環。 【實施方式】 較佳地，染料係有機染料。 較佳地’染料選自以下發色團種類··蒽醌、偶氮、鳴 嗪、吖嗪、三苯二噁嗪、三苯基曱烷、咕噸及酞菁，更佳 偶氮、蒽醌及吖嗪發色團種類，最佳偶氮及蒽醌，最佳 地，染料係蒽醌。 較佳地’染料於pH 8下帶負電或不帶電。更佳地，染料 於pH 8下不帶電。 . 較佳地，單體（a)可藉由使烯烴與選自以下種類之染料反 應獲得··具有與染料之芳香族基團共價鍵結之NH2基團之 酸性、鹼性、分散或溶劑染料。染料索引（c〇1〇r Ιη£^χ) (Society of Dyers and Colourists及 American Association of
Textile Chemists and Colorists)中列舉該等染料之實例。 較佳地，反應選自： 154382.doc 201138854
染料—nh2 + 及
r\
含有用於該等反應之-NH2基團的較佳染料選自：酸性紫 1 ;酸性紫3 ;酸性紫6 ;酸性紫u ;酸性紫13 ;酸性紫 ⑷酸性紫19;酸性紫20;酸性紫36;酸性紫36:1;酸性 紫41 ;酸性紫42 ;酸性紫43 ;酸性紫5〇;酸性紫51 ;酸性 紫63;酸性紫48;酸性藍25;酸性藍4〇;酸性藍4〇:ι;酸 性藍41 ;酸性藍45 ;酸性藍47 ;酸性藍49 ;酸性藍η ;酸 性藍53 ;酸性藍56 ;酸性藍61 ;酸性藍61:1 ;酸性藍& ; 酸性藍69 ;酸性藍78 ;酸性藍;酸性藍％ ;酸性藍 96，酸性藍丨08 ;酸性藍丨丨丨：酸性藍2丨5 ;酸性藍23〇 ;酸 性藍277 ;酸性藍344 ;酸性藍117 ;酸性藍124 ;酸性藍 129，酸性藍129·· 1 ;酸性藍138 ;酸性藍145 ;直接紫99 ; 直接紫5 ;直接紫72 ;直接紫16 ;直接紫78 ;直接紫77 ; 直接紫83 ;食品黑2 ;直接藍33 ;直接藍41 ;直接藍22 ; 直接藍71 ;直接藍72 ;直接藍74 ;直接藍75 ;直接藍82 ; 直接藍96;直接藍11〇;直接藍m ;直接藍12〇;直接藍 120:1 ’直接藍121 ;直接藍122 ;直接藍123 ;直接藍 124 ;直接藍126 ;直接藍127 ;直接藍128 ;直接藍129 ; 直接藍130;直接藍132;直接藍133;直接藍135;直接藍 154382.doc -6- 201138854 138 ;直接藍140 ;直接藍145 ;直接藍148 ;直接藍149 ; 直接藍159 ;直接藍162 ;直接藍163 ;食品黑2 ;食品黑 1 ’其中醯胺基團由NHZ替代；分散藍1;分散藍5;分散藍 . 6 ;分散藍9 ;分散藍11 ;分散藍19 ;分散藍20 ;分散藍 28 ;分散藍40 ;分散藍56 ;分散藍60 ;分散藍81 ;分散藍 83 ;分散藍87 ;分散藍1〇4 ;分散藍118 ;分散紫1 ;分散 紫4、分散紫8 '分散紫17、分散紫26 ;分散紫28 ;溶劑紫 26 ;溶劑藍12 ;溶劑藍13 ;溶劑藍18 ;溶劑藍68 ;溶劑藍 76 ;分散紅4 ;分散紅11 ;分散紅15 ;分散紅3丨；分散紅 53’ 7J散紅55，分散紅60;分散紅63;分散紅86;分散紅 91 ;分散红92 ;分散黃9 ;分散黃11 ;酸性紅33 ;酸性紅 30 ;酸性紅34 ;酸性黃7 ;酸性黃9 ;酸性黃66 ;酸性綠 20 ;酸性綠33 ;酸性棕4 ;酸性棕9及酸性黑1 ^ 更佳染料選自含有直接附接至偶氮基團之苯基的單-偶 氮染料，其中苯基具有與其共價鍵結之Nh2基團。 較佳地’單體（a)佔聚合物之〇5 wt%至3〇 wt%、較佳5 wt%至 20 wt%。 較佳地’單體（b)佔聚合物之5 wt%至99.5 wt%。最佳 . 地，（b)係曱基丙烯酸二曱基胺基乙基酯。 較佳地，本發明之組合物包含較佳佔聚合物之5 至 挑之不帶電單體單^較佳地，單體單元選自丙稀 酸5旨及苯乙稀。較佳地，其係以1〇哪至3〇加％存在。 較佳地，本發明之組合物係沖洗組合物。更佳地，組合 物係洗髮精、調理劑或染髮劑組合物。若組合物係洗髮 154382.doc ^ 201138854 精，則其較佳包含5%至50%清潔表 A 系表面活性劑。較佳地，清 潔表面活性劑包含陰離子型及兩性表面活性劑。若组人物 =調理組合物’則其較佳包含調理活性物質，例如脂肪 醇、月旨肪酸、脂肪醯胺及脂肪醋、聚石夕氧、陽離子表面活 性劑等。 較佳地，本發明組合物之？11為3至9、較佳4至8。 可使用聚合物染料之組合來獲得具有有限數目之染料之 用途的多色彩⑽ette)。較佳地，三絡酸鹽系統由三、種聚 合物染料之混合物組成。較佳地’三鉻酸鹽系統含有藍色 或黑色聚合物染料、紅色聚合物染料及黃色聚合物染料之 組合。 在第二態樣中，本發明提供藉由對頭髮施用任一前述技 術方案之頭髮組合物來染髮之方法。 實例 實例1:染料單體之合成 反應不意圖 0
0 nh2 〇 〇φφ + =Λτ^ ο νη2 1，4-二胺基蒽酿（DAQ)係自Aldrich(90%工業級）構得且以 供應原樣使用。 染料單體係藉由在碳酸氫鈉存在下使DAQ(1,4-二胺基蒽 醌）與Ac(丙稀醯氣）反應製得。將150 ml無水THF、1 g 154382.doc 201138854 DAQ及0 · 6 g碳酸氫納之混合物裝入配備有冷凝器、滴液漏 斗及磁力授拌棒之250 ml三頸圓底燒瓶中。隨後將燒瓶維 持於R.T.下’同時自滴液漏斗添加溶解於5 ml無水TfjF中 之0.38 g Ac並保持3h。將反應混合物於25°C下再搜掉 2Oh。過渡反應混合物以去除在20h後反應過程期間出現之 不溶固體，藉由使用旋轉蒸發減壓儀乾燥澄清溶液，隨後 獲得紫色粉末並用水洗滌三次，將粉末於真空及6〇。(：下完 全乾燥24h。使用NMR確認DAQ-AC之結構，且顯示，該 反應完成大於88%。因此，大於88°/。之惹醌含有一個 NHCOCH=CH2基團。 實例2含有染料之聚合物之合成
將3 g甲基丙烯酸二甲基胺基乙基酯（DMAEMA)、〇.〇3 g DAQ-Ac及0· 06 g AIBN存於10 ml曱苯中之溶液裝入具有冷 凝器及磁力授掉棒之乾無Ν'2氣吹掃的兩頸管中。密封管並 將其置於65 °C下之調節恒溫器中達24小時。在反應後，將 溶液在5倍過量之石油醚中沉殿三次，之後在真空及4〇。〇 下乾燥24h。經由控制染料單體及功能單體之基本用途調 154382.doc 201138854 節共聚物之組成。在實驗中，所添加染料單體之量分別係 1 0 wt %。 實例3含有染料之聚合物之合成 使用酸性藍14及亞甲基紫RAX實施與實例1及2類似之反 應，從而產生以下染料聚合物。
實例3染料聚合物之UV-VIS 在去礦質水中以1 g/L染料聚合物記錄實例2之染料聚合 物的UV-Vis譜。結果展示於下表中。對於C11而言，添加1 g/L直鏈苯項酸烧基醋表面活性劑。 -10- 154382.doc 201138854 編號 染料單體 400 nm 至 700 nm範圍内之 Irnax 吸光度(1cm)， Imax » 1 g/L 5 存於水中 C7 0 546 1.10 C11 0 HN人〆 0 ΗΝΧ) 534 1.37 C15 ㈣ 557 4.37* *於50%稀釋度下量測 實例3沈積至羊毛 於293K下將經漂白編織羊毛樣品在去礦質水中攪拌30分 鐘，分別向其中添加20 ppm C7、C11、C15及40 ppm C19。羊毛與液劑之重量比係1:30。移出羊毛樣品並在空 氣中乾燥，隨後使用反射計（不包括UV)量測顏色並表示為 CIE L*a*b*值。結果展示於下表中：- L* a* b* 對照 86.5 0.1 17.2 C7 78.9 6.5 8.6 C11 81.8 2.9 11.4 C15 69.6 13.8 0.9 154382.doc 201138854 所有染料聚合物均對羊毛進行染色，如與4 在水令攪拌之對照的變化所示。 … 實例4沈積至人類頭髮 於293K下將人類頭髮樣品在去礦質水中搜掉3〇分鐘，向 其令添加20 ppm C7、C】】、Cj5e頭髮與液劑之重量比係 ::3〇。使用灰棕色及金色頭髮樣品。移出頭髮樣品並在空 氣中乾燥’隨後使用反射計（不包括uv)量測顏色並表示為 CIE L a b*值。結果展示於下表中且係3次重複之平均 值：-
I54382.doc •12- 201138854 • 0 0 0¾ o nh2 5 5 5 0 HN人〆 cx^SOaNa O NHPh 5 5 ^0-γ〇Η Ο ΗΝ> Ο〇φ 0 ηη2 5 ch3 H2C—— C C02CH2CH2NH(CH3)2 95 95 95 75 95 ch3 Η2〇=:0 co2ch2ch2oh 75 CH3 h2c=c 1 θ co2ch2ch2n(ch3)3 20 苯乙烯 20 染料單體係藉由使相應染料之nh2基團與丙烯醯氣或
(若適當）反應來合成 實例6 :染色性能 154382.doc •13· 201138854 在去礦質水中製備1 wt%染料聚合物溶液。將3 χ 10 cm編 織羊毛樣品（綿羊）置於染料聚合物溶液並攪拌20秒，移出 並乾燥。藉由以下評定羊毛顏色：使用反射儀量測樣品之 反射率並將顏色表示為CIE L*a*b*值及相對於未染色對照 之AE值。隨後在流淌水之龍頭下將樣品在水中沖洗30 秒，乾燥並重新量測顏色。隨後在洗髮精中洗滌樣品，沖 洗，乾燥並重新量測。結果顯示如下： ΔΕ P1 P2 P3 P4 P5 P6 初始 38 41 51 23 24 23 水沖洗 35 29 51 23 22 21 經洗髮精洗滌 33 - 49 20 17 18 所用洗髮精具有以下配方：20 wt%月桂基醚硫酸鈉； 5.3 wt%椰油醢胺基丙基甜菜驗；6.5 wt% Mirasheen A-220(購自Rhodia)，其係二硬脂酸二醇酯、月桂醇聚氧乙烯 醚硫酸銨、月桂基硫酸銨、椰油醯胺MEA、二曱苯磺酸銨 之混合物；其他微小物質（remainder minors)及水。 實例7 以下組合物係藉由標準製程製得。 洗髮精 組份 添加〇/〇 % 月桂醇聚氧乙烯醚硫酸鈉 70 17.14 椰油醯胺基丙基甜菜鹼 30 5.33 卡波姆(Carbomer) 100 0.4 154382.doc -14· 201138854 二硬脂酸二醇酯 35 4.0 二曱矽醇乳液 50 4.0 瓜耳羥丙基三甲基氣化銨 100 0.2 香水 100% 0.8 DMDM乙内醯脲及胺基曱酸3-碘-2 丙炔基丁基酯 50% 0.2 氣化納 100% 黏稠 染料聚合物 100% 0.5 水 補足至100 調理劑 成份 Wt% 水 至100 乳酸 0.38 對羥基苯甲酸甲酯 0.2 硬脂醇 5 山茶基氯化三敍 0.87 LexamineS-13 (100%TAS) 1.25 聚矽氧乳液 2.5 香水 0.5 染料聚合物 2 該染料聚合物係3種染料聚合物之1:1:1混合物（均基於 95wt%甲基丙烯酸二曱基胺基乙基酯）且具有5 wt%染料單 體⑷。 聚合物A:染料單體係藉由使丙烯醯氯與分散紅55反應 154382.doc •15· 201138854 來製得。 聚合物B :染料單體係藉由使丙烯醯氣與分散黃11反應 來製得。 聚合物C :染料單體係藉由使丙烯醯氣與分散藍56反應 來製得。
利用藉由使分散染料與 μ 反應製得之染料單體產 生類似調配物。 154382.doc -16-
Claims (1)
- 201138854 七、申請專利範圍： 1· -種頭髮組合物，&包含聚合物染肖，該聚合物染料可 藉由聚合以下物質獲得： (a)第一染料單體，其具有式j之結構：Y—染料 式I 其中 Y選自-CONH-或-C02CH2CH(0H)CH2-NH-，且尺丨選 自Η、烷基、芳基、苄基、鹵素、酯、醢胺及cN， (b)第二單體，其具有選自式II及式III之結構：式II及X—NR2R3 式III 其中X係將胺共價連接至該單體之烯烴部分之有機橋接 基團，較佳地，X係_C02(CH2)n·，其中n=l至6 ; 其中R5選自：Η、烷基、芳基、苄基、鹵素、酯、醯胺 及CN，較佳地，R5係CH3或Η ;且 其中R_2、Κ·3及Κ·4獨立地選自Η或烧基，較佳地’ R2、R3 154382.doc 201138854 及R4中之至少兩者係烷基。 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 如請求項1之組合物’其中該染料係有機染料。 如請求項2之組合物，其中該染料選自以下發色團種 類.蒽醌、偶氮、噁嗪、吖嗪、三笨二噁嗪、三苯基甲 烷、咕噸及酞菁，更佳偶氮、蒽醌及吖嗪發色團種類， 最佳偶氮及蒽酿，最佳地’該染料係蒽酿。 如前述請求項中任一項之組合物，其中該染料帶負電或 不帶電。 月J述凊求項中任一項之組合物，其中該染料不帶電。 月J述凊求項中任一項之組合物，其中單體⑷佔該聚洽 物之 0.5 wt0/〇至 3〇 wt%、較佳 5 wt%至 2〇 wt%。 士刖述哨求項中任一項之組合物，其中單體⑻佔該聚洽 物之 5 wt%至 99.5 wt%。 如前述請求項中任一項之組合物，其中該聚合物亦包含 ，佔該聚合物5 wt%至94 5 wt%之不帶電單體單元。 士前述π求項中任一項之組合物，其係沖洗組合物。 :前述請求項中任一項之組合物，其具有⑴、她 至8之pH » 如前述請求項中任一項之組合物來 一種藉由對頭髮施用 染髮之方法。 154382.doc 201138854 四、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明··Y—染料五、本案若有化學式時，請揭示最能顯示發明特徵的化學式： X—nr2r3 154382.doc
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| US4051138A (en) * | 1975-12-08 | 1977-09-27 | Dynapol | Water-soluble amine-linked polymeric colorants |
| DE3921498A1 (de) * | 1988-09-28 | 1990-03-29 | Bayer Ag | Polymer-gebundene-farbstoffe, verfahren zu deren herstellung und verwendung |
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