TW201119978A - Hydrogen fluoride-HFC-254eb azeotrope and its uses - Google Patents
Hydrogen fluoride-HFC-254eb azeotrope and its uses Download PDFInfo
- Publication number
- TW201119978A TW201119978A TW099135476A TW99135476A TW201119978A TW 201119978 A TW201119978 A TW 201119978A TW 099135476 A TW099135476 A TW 099135476A TW 99135476 A TW99135476 A TW 99135476A TW 201119978 A TW201119978 A TW 201119978A
- Authority
- TW
- Taiwan
- Prior art keywords
- composition
- tetrafluoropropane
- azeotrope
- hydrogen fluoride
- pentafluoropropane
- Prior art date
Links
- 239000001257 hydrogen Substances 0.000 title claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 16
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 193
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 104
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims abstract description 103
- INEMUVRCEAELBK-UHFFFAOYSA-N 1,1,1,2-tetrafluoropropane Chemical compound CC(F)C(F)(F)F INEMUVRCEAELBK-UHFFFAOYSA-N 0.000 claims abstract description 56
- 238000004821 distillation Methods 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 47
- ZDCWZRQSHBQRGN-UHFFFAOYSA-N 1,1,1,2,3-pentafluoropropane Chemical compound FCC(F)C(F)(F)F ZDCWZRQSHBQRGN-UHFFFAOYSA-N 0.000 claims abstract description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000001294 propane Substances 0.000 claims description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052707 ruthenium Inorganic materials 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- -1 propylene compound Chemical class 0.000 claims description 4
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 claims description 3
- ISQINHMJILFLAQ-UHFFFAOYSA-N argon hydrofluoride Chemical compound F.[Ar] ISQINHMJILFLAQ-UHFFFAOYSA-N 0.000 claims description 2
- VLHYAWNCTMZTSC-UHFFFAOYSA-N 1,1,3,3,3-pentafluoropropan-1-ol Chemical compound OC(F)(F)CC(F)(F)F VLHYAWNCTMZTSC-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- GVGCUCJTUSOZKP-UHFFFAOYSA-N nitrogen trifluoride Chemical compound FN(F)F GVGCUCJTUSOZKP-UHFFFAOYSA-N 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 16
- 239000000463 material Substances 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 21
- 238000010025 steaming Methods 0.000 description 20
- 238000009835 boiling Methods 0.000 description 18
- 239000000047 product Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 238000005984 hydrogenation reaction Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 4
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000003507 refrigerant Substances 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- WFHFXEYKXJKYMG-UHFFFAOYSA-N 1,1,2-trichloro-1,3,3,3-tetrafluoropropane Chemical compound FC(F)(F)C(Cl)C(F)(Cl)Cl WFHFXEYKXJKYMG-UHFFFAOYSA-N 0.000 description 3
- DMUPYMORYHFFCT-UHFFFAOYSA-N 1,2,3,3,3-pentafluoroprop-1-ene Chemical compound FC=C(F)C(F)(F)F DMUPYMORYHFFCT-UHFFFAOYSA-N 0.000 description 3
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000010533 azeotropic distillation Methods 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052762 osmium Inorganic materials 0.000 description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005796 dehydrofluorination reaction Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- WQAWXRFLNDAOON-UHFFFAOYSA-N 1,1,1,3,3-pentafluoropropan-2-one Chemical compound FC(F)C(=O)C(F)(F)F WQAWXRFLNDAOON-UHFFFAOYSA-N 0.000 description 1
- CSUFEOXMCRPQBB-UHFFFAOYSA-N 1,1,2,2-tetrafluoropropan-1-ol Chemical compound CC(F)(F)C(O)(F)F CSUFEOXMCRPQBB-UHFFFAOYSA-N 0.000 description 1
- BIPNYHXPHOUMCL-UHFFFAOYSA-N 1,1,2-trichloro-1,2,3,3,3-pentafluoropropane Chemical compound FC(F)(F)C(F)(Cl)C(F)(Cl)Cl BIPNYHXPHOUMCL-UHFFFAOYSA-N 0.000 description 1
- UYVWNPAMKCDKRB-UHFFFAOYSA-N 1,2,4,5-tetraoxane Chemical compound C1OOCOO1 UYVWNPAMKCDKRB-UHFFFAOYSA-N 0.000 description 1
- JRHNUZCXXOTJCA-UHFFFAOYSA-N 1-fluoropropane Chemical compound CCCF JRHNUZCXXOTJCA-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 208000033962 Fontaine progeroid syndrome Diseases 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical class [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- BULLHNJGPPOUOX-UHFFFAOYSA-N chloroacetone Chemical compound CC(=O)CCl BULLHNJGPPOUOX-UHFFFAOYSA-N 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/191—Hydrogen fluoride
- C01B7/195—Separation; Purification
- C01B7/196—Separation; Purification by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
- C07C17/386—Separation; Purification; Stabilisation; Use of additives by distillation with auxiliary compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25634009P | 2009-10-30 | 2009-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201119978A true TW201119978A (en) | 2011-06-16 |
Family
ID=43447920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW099135476A TW201119978A (en) | 2009-10-30 | 2010-10-18 | Hydrogen fluoride-HFC-254eb azeotrope and its uses |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US8486293B2 (enExample) |
| EP (1) | EP2493836B1 (enExample) |
| JP (1) | JP5706909B2 (enExample) |
| KR (1) | KR20120099703A (enExample) |
| CN (1) | CN102666453B (enExample) |
| BR (1) | BR112012009821A2 (enExample) |
| CA (1) | CA2778250A1 (enExample) |
| ES (1) | ES2545740T3 (enExample) |
| HU (1) | HUP1200449A2 (enExample) |
| IN (1) | IN2012DN03132A (enExample) |
| MX (1) | MX2012004921A (enExample) |
| RU (1) | RU2012122225A (enExample) |
| TW (1) | TW201119978A (enExample) |
| WO (1) | WO2011053449A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5393454B2 (ja) * | 2006-06-27 | 2014-01-22 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | １，２，３，３，３−ペンタフルオロプロペンの製造方法 |
| US8513474B2 (en) | 2010-06-24 | 2013-08-20 | Honeywell International Inc. | Process for the manufacture of fluorinated olefins |
| BR112014021670B1 (pt) * | 2012-03-02 | 2020-09-29 | Arkema Inc | Métodos para a remoção de contaminante de uma hidroclorofluorolefina por destilação extrativa, trans-1,1,1-trifluoro-3-cloro-2-propeno (1233zd(e)) purificado e processo de destilação |
| CA3040740A1 (en) * | 2016-12-21 | 2018-06-28 | Arkema Inc. | Processes and systems for recovering r1233zd in purified form |
| JP6485493B2 (ja) * | 2017-06-16 | 2019-03-20 | ダイキン工業株式会社 | ペンタフルオロプロパンと水とを含む共沸又は共沸様組成物、並びにペンタフルオロプロパンの製造方法 |
| CN110945099B (zh) | 2017-07-27 | 2024-07-05 | 科慕埃弗西有限公司 | 包含氟化氢和氟碳化合物的共沸组合物 |
| CN111094503B (zh) * | 2017-09-11 | 2022-04-01 | 科慕埃弗西有限公司 | 包含氟化氢和含氟烃的共沸组合物 |
| JP7670992B2 (ja) * | 2020-03-19 | 2025-05-01 | セントラル硝子株式会社 | （ハイドロ）ハロカーボンの製造方法 |
| EP4235702A4 (en) * | 2020-10-22 | 2024-07-24 | Agc Inc. | ELECTRICAL EQUIPMENT |
| CN116802170A (zh) * | 2021-01-29 | 2023-09-22 | Ａｇｃ株式会社 | 3-氯-1,1,2,2-四氟丙烷的制造方法和1-氯-2,3,3-三氟丙烯的制造方法 |
| CN113624570B (zh) * | 2021-08-06 | 2023-04-28 | 清华大学 | 汽液相平衡装置及氟代烃中的hf的分析方法 |
| CN114350321B (zh) * | 2021-12-03 | 2024-02-09 | 湖北瑞能华辉能源管理有限公司 | 一种节能环保型热泵工质及其应用 |
| JP2025536644A (ja) | 2022-11-18 | 2025-11-07 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | ３－クロロ－３，３－ジフルオロ－１－プロペン、３，３，３－トリフルオロプロペン、及びフッ化水素の共沸性混合物 |
| JP2025536643A (ja) | 2022-11-18 | 2025-11-07 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | １，１，１，３－テトラフルオロプロパン、３，３，３－トリフルオロプロペン、及びフッ化水素を含む混合物並びにそれらの共沸混合物の分離のためのプロセス |
| FR3151590A1 (fr) | 2023-07-27 | 2025-01-31 | Dehon | Procede et installation pour la separation d’un melange comprenant au moins un fluide fluore et un ou plusieurs contaminants |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4944846A (en) | 1988-08-01 | 1990-07-31 | E. I. Dupont De Nemours And Company | Process for the separation of HF via Azeotropic distillation |
| US5396000A (en) | 1993-05-24 | 1995-03-07 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,1,1,2,3,-pentafluoropropane |
| EP0713485B1 (de) * | 1993-08-11 | 1998-04-15 | Bayer Ag | Thiocarbamoylverbindungen als mikrobizide |
| US5918481A (en) * | 1997-11-20 | 1999-07-06 | Alliedsignal Inc. | Process for separating hydrogen fluoride from fluorocarbons |
| US7897823B2 (en) * | 2004-10-29 | 2011-03-01 | E. I. Du Pont De Nemours And Company | Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes |
| US7476771B2 (en) | 2005-11-01 | 2009-01-13 | E.I. Du Pont De Nemours + Company | Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof |
| US7888539B2 (en) | 2007-02-23 | 2011-02-15 | E.I. Du Pont De Nemours And Company | Azeotrope compositions of octafluorocyclobutane and uses thereof |
| GB0801209D0 (en) | 2008-01-23 | 2008-02-27 | Ineos Fluor Holdings Ltd | Process |
| KR102035526B1 (ko) * | 2008-02-21 | 2019-10-24 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 3,3,3-트라이플루오로프로펜 및 플루오르화수소를 포함하는 공비 조성물 및 이의 분리방법 |
| EP2098499B2 (en) | 2008-03-06 | 2017-11-22 | Honeywell International Inc. | Azeotrope-like composition of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and hydrogen fluoride (HF) |
| US8845921B2 (en) | 2008-04-09 | 2014-09-30 | Honeywell International Inc. | Separation of close boiling compounds by addition of a third compound |
-
2010
- 2010-10-06 US US12/898,983 patent/US8486293B2/en active Active
- 2010-10-12 RU RU2012122225/04A patent/RU2012122225A/ru unknown
- 2010-10-12 WO PCT/US2010/052237 patent/WO2011053449A1/en not_active Ceased
- 2010-10-12 ES ES10768151.2T patent/ES2545740T3/es active Active
- 2010-10-12 MX MX2012004921A patent/MX2012004921A/es active IP Right Grant
- 2010-10-12 BR BR112012009821A patent/BR112012009821A2/pt not_active IP Right Cessation
- 2010-10-12 CA CA2778250A patent/CA2778250A1/en not_active Abandoned
- 2010-10-12 JP JP2012536843A patent/JP5706909B2/ja active Active
- 2010-10-12 KR KR1020127013791A patent/KR20120099703A/ko not_active Withdrawn
- 2010-10-12 EP EP10768151.2A patent/EP2493836B1/en active Active
- 2010-10-12 CN CN201080048381.0A patent/CN102666453B/zh active Active
- 2010-10-12 HU HU1200449A patent/HUP1200449A2/hu unknown
- 2010-10-18 TW TW099135476A patent/TW201119978A/zh unknown
-
2012
- 2012-04-11 IN IN3132DEN2012 patent/IN2012DN03132A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013509409A (ja) | 2013-03-14 |
| KR20120099703A (ko) | 2012-09-11 |
| RU2012122225A (ru) | 2013-12-10 |
| HUP1200449A2 (en) | 2012-11-28 |
| CN102666453A (zh) | 2012-09-12 |
| IN2012DN03132A (enExample) | 2015-09-18 |
| US20110101264A1 (en) | 2011-05-05 |
| EP2493836A1 (en) | 2012-09-05 |
| US8486293B2 (en) | 2013-07-16 |
| WO2011053449A1 (en) | 2011-05-05 |
| JP5706909B2 (ja) | 2015-04-22 |
| CN102666453B (zh) | 2015-11-25 |
| CA2778250A1 (en) | 2011-05-05 |
| EP2493836B1 (en) | 2015-07-08 |
| ES2545740T3 (es) | 2015-09-15 |
| MX2012004921A (es) | 2012-05-22 |
| BR112012009821A2 (pt) | 2016-10-18 |
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