TW200916953A - Coloring curable composition - Google Patents

Abstract

The present invention provides a coloring, curable composition comprising (A) a colorant and (B) a polymerizable compound, wherein the colorant comprises a pigment represented by formula (I): (wherein, k represents an integer of 0 or 1; M represents a metal or a metal oxide; A<SP>1</SP> to A<SP>14</SP> each independently represent a hydrogen atom, a halogen atom or other substituents).

Description

200916953 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a colored curable composition. [Prior Art] The colored curable composition is used for producing a color former used in a display device such as a liquid crystal display panel or an electrophotographic X-ray display panel. The colored curable composition is known to use a pigment or a dye as its colorant. One of the 'color-hardening compositions using pigments, which generally has light resistance and thermal properties. However, due to the particles of the pigment, the light transmittance of the filter or the color device is reduced, or the contrast is lowered. (Refer to Patent Document 1). Further, the color-curable composition using a dye has a characteristic that the contrast of the color filter is high because there is no political emission by the pigment particles. However, it has the disadvantage of low light resistance or low heat resistance. (Refer to Patent Document 2, Section 3, Figure 4 for improving the light resistance and heat resistance of the color-hardening composition of the dye, and recording each 4 ^ ^ Λ ^ In the case of a green colored curable composition, there are proposed (4) (ph) (phtha 1 QGyan 1 ne) dyes having a specific structure and an improved method of a bite-azo dye having a specific structure ( Refer to Patent Document 4). Patent Document 1: JP-A-2000-352610, page 2, right shed, lines 24 to 30. Patent Document 2, JP-A-2004-157455, page 3, line 42 To the fourth page, the eighth line. The present invention is disclosed in Japanese Laid-Open Patent Publication No. 2004-246105, the second, the third, the third, the third, the third, the third. SUMMARY OF THE INVENTION However, the inventors of the present invention have found that even in the invention described in Patent Document 4, there is still room for further improvement in heat resistance and solvent resistance of the obtained color filter. Excellent heat resistance and solvent resistance The color hardening composition of the color filter is found by the present inventors, and it has been found that a colored hardening composition containing another g phthalocyanine dye different from the well-known phthalocyanine dye as a coloring agent can be solved. The present invention has been made in view of the above problems. In other words, the present invention provides the inventions of the following items [1] to [1]. [1] A color-hardening composition containing (...a coloring agent and (B) a polymerizable compound, It is characterized in that the (A) colorant contains the pigment represented by the formula (1):

[In the formula (1), k represents an integer of 〇 or 1, and μ represents a metal or a metal oxide, and Α to Α 16 each independently represents a hydrogen atom, a halogen atom, or is selected from the formulas (2) to (5). Substituents in the substituent group; however, from Αι to Aie, 320502 7 200916953 has 1 to 8 lines representing a group selected from the group of substituents represented by formulas (2) to (5); Γ 〇1_/= VC00Rl1)ei (2)

-G2-/==^V{C〇〇(CH2CH2〇)fRl2)E

V (COO(CH2CH2CH2〇)hR13)ii (3) (4)

Kg2 ,==^rLi —Θ4

(5) In the formulae (2) to (5), G1 to G4 each independently represent an oxygen atom, a furnace or a -N(R14)- group; and R14 represents a hydrogen atom or a linear or branched chain carbon number. a saturated aliphatic hydrocarbon group of 6 to 6; R11 to R13 each independently represent a hydrogen atom, an aryl group having 6 to 2 G carbon atoms which may have a substituent, or a saturated fat having a linear or branched chain number of 8 a hydrocarbon group; the enemy mountains J to J3 each independently represent a halogen atom, a linear or branched chain having a saturated aliphatic hydrocarbon group having 1 to 4 carbon atoms, or a carbon alkoxy group; The carbon atoms of the atomic, linear or branched chain are 丄 to 4 and an aliphatic hydrocarbon group, or an alkoxy group having a carbon number of 1 to 4; el, gl and il each independently represent an integer of 1 to 5; E2 and χ 2 each independently represent an integer from 〇5; u, the sum of 61 and 62, the sum of gl and g2, and 丨1 and i2d are integers of 5 or less; 夂ι2 sum f and h each Independently represents an integer from 1 to 6; J represents an integer of 1 or 2. The color-hardening composition as described in the item [1], wherein the substituent of the formula (I) is substituted with a substituent group selected from the group consisting of the formulae (2) to (5). The rest of the substituents are all fluorine atoms. [3] The color hardening composition according to [1] or [2], wherein G1 in the formula (2) is an oxygen atom. [4] The color hardening composition as described in any one of [1] to [3] wherein the (A) colorant is further selected from the group consisting of barbituric acid gas dyes, oxime = ketones (four) (four) At least one dye selected from the group consisting of a nitrogen "material, a money (4) dye, and a cyanine dye. [5] A color-hardening composition as described in [4], wherein the acid-type azo dye system is (7) The dye shown:

0 /R33 Η·2 -Ν 0’ , R34 R®1 -

Τ1=5 R3^ [In the formula (7), T and τ2 are each independently π each independently represent hydrogen/subunit; atom or sulfur atom aliphatic hydrocarbon group, the base substitution is wide; - to 10 bis and hydrazine, Substituted by an alkoxy group having a carbon number of 1 to 8, after the number of aliphatic hydrocarbon groups, the carbon number is 丨 to, ', to the fullness of the :: ! to 1 和 and the aliphatic hydrocarbon group, the oxy substituted carbon Number. 7 to 20 aromatic base, cut to 20 aryl, charcoal: A inverse number is 2 to 1 〇 护 甘. ... 42 each independently represents a saturated atomic hydrocarbon group of chlorine to 1G, _ _ prime atom, a saturated aliphatic hydrocarbon group having a carbon number of 10, and a carbon number substituted by a Shanghai halogen atom is 1. a:,, a methoxy group of 1 to 8, a group; 320502 9 200916953 acid group, amine group Base, 4N-substituted amine gamma]. Here, σ is a dye of the formula (8) as shown in the item [4], and the ketone azo dye is a dye represented by the formula (8):

Rf R21 0==\ί__/~Ν=Ν~Ζ (8)

R23 OH * [in the formula (8), Ζ indicates that it has! Or 2 selected from the group consisting of (4), amine-% acid groups, amine gamma groups, and hydrazine-substituted amines, the base group of the fluorenyl fluorenyl group or having 1 or 3 selected from the group consisting of a carboxyl group and an amine formamidine. a naphthyl group of a group of genus, alkaloid, an amine gamma, and a ruthenium-substituted amine gal group; a R represents a hydrogen atom, a linear or branched chain or a ring a saturated aliphatic hydrocarbon group having a carbon number of up to 1 Torr, a carboxyl group, or a trifluoromethyl group; "R22 represents a hydrogen atom, a cyano group, an amine carbaryl group, an anthracene group, an amine group, an amine group, an amine group, a sulfonic acid group and any one of an ammonium salt, a lithium salt, a sodium salt or a potassium salt of each of the above substituents; and R represents a hydrogen atom, a linear or branched chain having a carbon number which may be substituted from 丨 to 1 〇 Or a cyclic saturated aliphatic hydrocarbon group, a substituted aryl group having 6 to 30 carbon atoms, a substituted aralkyl group having 7 to 2 carbon atoms, and an alicyclic hydrocarbon group having 3 to 20 carbon atoms. a part of a carbon substituted by a hetero atom, an amine fluorenyl group, a fluorene-substituted amine carbhydryl group, a substituted aliphatic oxycarbonyl group having 2 to 20 carbon atoms, a carbon number which may be substituted For 7 to 3 〇 An oxymethyl group, a substituted carbon number of 2 to 20, a substituted aliphatic acid group having a carbon number of 1 to 30, or a substituted number of 320502 10 200916953 6 to 30 arylsulfonyl group; and formula (8) can form a polymer of a dimer or more at any position] [7] The color hardening property as described in any one of [1] to [6] A composition comprising (C) a binder resin, wherein the color hardening composition according to any one of the items [8] is a pattern, which is characterized in that: [如] is used. Formed by [7] (Photolithographic method) or inkjet method.

And according to the light lithography method [9] a [10] - a liquid crystal display device, the color filter. [Embodiment] (Formation for carrying out the invention) The composition contains the dye represented by the formula (1). The color hardenability of the present invention is (A) a colorant.

Each of the formulae (2) to (5) represents a metal or a metal oxygen, each independently representing a hydrogen atom, a substituent dentate atom in the unsubstituted group, or a selected one. However, among A1 to A16, there are 320502 11 200916953 1 to 8 are substituents selected from the group of substituents represented by formulas (2) to (5).

-G (3) W V -π 00(CH2CH20)fR12)g1 -G4

-G3H^^(3C〇〇(CH2CH2CH2〇)hR13)i 92 (5) In the formulae (2) to (5), G1 to G4 each independently represent an oxygen atom, a sulfur j or a -N(R14)- group; ^ K 4 A hydrogen atom or a linear or branched chain carbon number 6 saturated aliphatic hydrocarbon group; R to R each independently represent an aryl group having a hydrogen number of 6 to 20, or a straight bond A carbonic acid having a linear or branched chain of 1 to 8 saturated aliphatic hydrocarbon groups; the horses 1 J to J3 each independently represent a dentate atom, a complex complex of i to 4 and an aliphatic group. Nicotinyl = branched alkoxy, 4 L of 1 to 4 represents an i atom, a linear or branched (four) saturated aliphatic hydrocarbon group, or a carbon number of 2 to 4 1 to 4 el, gl, and U each independently represent 1 to $=•' e2, g2, and ι2 each independently represent the sum of w and e2 and sum of sum, u, and 12 ; Μ f and h each independently represent an integer from 1 to 6; the following integer; j indicates an integer of 1 or 2. The metal shown in Μ can be exemplified by words such as 辞, 鎸, Shi Xi m short, wrong, copper, nickel, Xu kick, wrong, pin, among which zinc, _, #, 320502 200916953 is preferred. Examples of the metal oxide shown by ruthenium include vanadium oxide, titanium oxide, and the like. The metal-free in 1 refers to a combination of an ammonia atom on two nitrogen atoms which are originally combined with a metal or a metal oxide as a ligand. Examples of the dentate atom of c* can be exemplified by an example of a bromine atom. Examples of the fluorene-based di-diaryl group include a phenyl group, a transphenyl group (for example, a phenyl group), a tris-μ phenyl group (for example, a 4-tris(phenyl)phenyl group, a basic group, and an ethyl group, Can be cited... Third butyl and the like. Soil, earth, n-butyl, isobutyl, t-butyl, and a straight-chain or branched chain having a carbon number of 1 to 8 in the R. Methyl, ethene n-butyl, isobutyl, pot-butlyn n-propyl, isopropyl, linear or branched chain SI-based straight-chain branched pentyl, and straight-bonded or branched-bonded The octyl group and the like === 2 groups, and the isopropyl group 3, n-butyl group and isobutyl group are preferred. i-Poly-di-indigenous Pi Pi==::, for example, a fluorine atom, a gas atom, and a formazan atom are preferable. The linear or branched bond of the 匕J1 to J3, which may be, for example, a saturated n-butyl group, an isobutyl group, a third earth, a n-propyl group or a different group. The carbon number in propyl, 320502 13 200916953 J to J3 is! Examples of the gas-burning group to 4 include a group, an ethoxy group, a n-propoxy group, an isopropoxy group, a n-butoxy group, a third butoxy group and the like. a milk base, to alkoxy group of 4, which is a compound of the above-mentioned L, a linear or branched chain carbon number, a saturated aliphatic hydrocarbon group, and a carbon number of J1 to J3. the same. In the formula (2), G1 represents an oxygen atom, a sulfur atom or a _N(Rl4)- group, and among them, an oxygen atom or a sulfur atom is preferred, and an oxygen atom is more preferred. El is an integer of 1 to 5, wherein an integer of from 3 to 3 is preferable, and an integer of 1 or 2 is more preferably. E2 is an integer from 〇 to 4, and an integer of 〇 to 2 is preferable, and an integer of 0 or 1 is more preferable. Examples of the substituent which is not represented by the formula (2) include a group represented by the formulae (2-丨) to (2-26), and the like, wherein the formula (2-1) to (2-7), (2-9) ) to (2-11), (2-13) to (2-18), (2-20) to (2-22), (2-24), and (2_25) are preferred, especially It is more preferable to use the groups represented by the formulae (2-1) to (2-7), (2-9) to (2_n), (2_13) to (2_15), (2-17) and (2-21) . 320502 14 200916953

15 320502 200916953

(2-13)

(2-14)

COCHo H3CH2C (2-15) — s.

COCH2CH(CH3)CH3 (2-16)

Coch2ch2ch3 och3 (2-17)

COCH(CH3)CH2CH3 (2-18)

(2-19) COCHgCHa (2-21)

Cl -NH

0 COCH2CH3 (2-20)

(2-22)

(2-25) COCHo II 3 0 (2-23)

COCH(CH2CH3)CH2CH2CH3 (2*26)

COCH3 (2-24) In the case of oxygen, G2 represents an oxygen atom, a sulfur atom or a -N(R14)- group, and the present invention is preferably a sulfur atom or a sulfur atom. Especially an integer of 6, wherein an integer from 1 to 3 is more preferably an integer of 1 or 2. ~ Pregnancy 乂 to represent an integer from 1 to 5, 苴, where an integer from 1 to 3 is more preferably than 320502 16 200916953, especially an integer of 1 or 2. In order to represent an integer from 〇 to 4, it is more preferably an integer of 0 or 1. The integer of 0 to 2 is a substituent represented by the preferred formula (3), and can be exemplified by the beauty, #士如(3-1) to (3-19), the temple of the temple, (3-1) To (3-3),. , '不13-in. rq 10λ ... (3,6), (3-8), (3-10), earth), (3-14), (3'15) and (3-Π) The basis of the formula is 仏, L is based on the formula (3 - Π to (3-3), (3-6), (3-10), (3-12) and (3-14) good.

320502 200916953

(3-10)

(3-12)

In the formula (4), G3 represents an oxygen atom, a sulfur atom or a -N(R14)- group, and among them, an oxygen atom or a sulfur atom is preferred, and an oxygen atom is more preferred. h represents an integer of 1 to 6, wherein an integer of 1 to 3 is preferable, and an integer of 1 or 2 is more preferably. i 1 represents an integer of 1 to 5, and preferably an integer of 1 to 3 is preferable, and an integer of 1 or 2 is more preferably. 18 320502 200916953 i2 represents an integer from 0 to 4, wherein an integer from 〇 to 2 is preferred, and an integer of 0 or 1 is more preferred. The substituent represented by the formula (4) may, for example, be a group represented by the formula (4_υ to (4-19), wherein the formulae (4-1) to (4-4), (4-7), (4-8) The bases shown by (4-10), (4-13), (4-14) and (4-16) are preferred, especially to (4-3), (4-7), ( The bases shown in 4-10) and (4-14) are more preferred.

H3COH2CH2CH2COC

(4-1) h3co

COCH2CH2CH2OCH3 (4-2)

H3CH2CO

0 COCH2CH2CH2OCH2CH3 (4-3) q

P〇ch2ch2ch2och3 (4-4) coch2ch2ch2och3 0

H3CH2C fCO(CH2CH2CH&amp;0)2CH3 (4-5)

COCH2CH2CH2OCH3 (4-6)

CO(CH2CH2CHzO)4CH3 (4-7) one 〇COCH2CH2CH2OCH3 (4-8)

Cl 19 320502 200916953

H3CH2CH2C〇H2CH2CH c〇H; Ο

〇CH3 (4-11) Ο

OCH2CH3 (4-12)

COCH2CH2CH2〇CH3 O (4-14)

COCH2CH2CH2OCH3 (4-15) - NH

COCH2CH2CH2OCH2CH3 (4-16)

C0CH2CH2CH20CH2CH3 (4-18) In the formula (5), G4 represents an oxygen atom, a ruthenium 2 is a ruthenium atom, or a J(R")- group, and a ruthenium atom or a sulfur atom is preferred. In the formula (5), j represents a formula of 1 or 2 as a further enthalpy. The formula ^ is a positive number, wherein 1 is a substituent which is not a '(5), and for example, the formula (5- The base of the formula, etc., is preferably (b), and the base of (5'8) to (5) is better. )(51G),(5-(1),(Μ 320502 20 200916953

(5-1) OCH2CH2CH3 (5_2) (5-3) CH2CH(CH3)CH3 (5-4) H3C(H3C)HCH2C4 •0

(5-5) C! -o

(5-7) a

OCHzCHzCHzCHa (5-9)

(5-6) (5-8) (5-10) OCH2CHzCH2CH3 CH2CH(CH3)CH3 -CH2CH(CH3)CH3 (5-11)

CH2CH(CH3)CH3 (5,12)

CH2CH2CH3 (5-15) —NH CH -N (5-13) CH2CH(CH3)CH3 (5-14) 〇ch2ch2ch3 (5-16)

OCH, (5.17) 丫h2ch3 CH2CH(CH3)CH3 (5-18) The dye of the formula (1) is exemplified by the dyes of the formula J (1-1) to (1-33). Formula (1-1) to (1-5), (1 ^ to (l-llhd-n), 0-14), (1-16), (Bu 18), (1-19), (] 99 , b, 22) to (Bu 24), (Bu 27) 320502 21 200916953 to (1-31) and (1-33) are preferred, especially in formula (1-1) to (1- 3)&gt; (1-7) ' (1-8) ' (1-10) ' (1-13)&gt; (1-14) ' (1-18) ' (1-22), (1- The pigments shown in 24), (1-28) and (1-29) are more preferred.

H3CH2CH2COOC

22 320502 200916953

HgCOOC

Cooch3

23 320502 200916953

H3CH2CH2COOC OCH3 H3CO POOCH2CH2CH3 , \

H3co. H3CH2CH2COOC COOCH2CH2ci?3C〇 COOCH2CH2CH3

24 320502 200916953

25 320502 200916953

H3COH2CH2COOC

Cooch2ch2och3 \ ch3 h3coh2ch2cooc H3C0H2CH2C00C

\〇 Vy^COOCH2CH2OCH3 λ ^^.COOCHzCHgOCHg (1-13) h3coh2ch2cooc cooch2ch2och3 cooch2ch2och3

C〇och2ch2och3 F (1-14)

N w N H3COHzCH2COOC

Cooch2ch2och3 OCHa

H3COH2CH2COOC

Och3 26 320502 200916953

\

(1-18) 27 320502 200916953

COOCH2CH2OCH2CH3 η

Cooch2ch2och2ch3 28 320502 200916953

COOCH2CH2CH2OCH2CH3 COOCH2CH2CH2OCH3 H3C0H2CH2CH2CC)0C*· H3COH2CHzCH2COOC. h3coh2ch2ch2cooc

H3coh2ch2ch2cooc h3coh2ch2ch2cooc. h3coh2ch2ch2cooc H3COH2CH2CH2COOCx h3coh2ch2ch2cooc \^cooch2ch2ch2och3 COOCH2CH2CH2OCH3 COOCH2CHzCH2OCH3 (1-23) ,COOCH2CH2CH2OCHa COOCH2CH2CH2OCH3 COOCHzCH2CH2OCH3 cooch2ch2ch2och3

Cooch2ch2ch2och2ch3 29 320502 200916953

H3CH2CH2COH2CH2CH2COOC.

Och2ch3

COOCH2CH2CH2OCH2CH3 30 320502 200916953 h3c(h3c>hch2c

^S^CH2CH(CH3)CH3

(1-29)

31 320502 200916953 CH2CH(CH3)CH3 h3c(h3c)hch2c h3c(h3c)hch2c^^^ \ j= F, from H3C(H3C)HCH2C f

, NwN, N, , Ni,

S ' F F CH2CH(CH3)CH3 (1-31) CH2CH(CH3)CH3 CHzCH(CH3)CH3

CH2CH(CH3)CH3

H3ch2ch2c

/==\ ^ch2ch2ch3

Ch2ch2ch3 h3ch2ch2c , NH HN ^\^CH2CH2CH3

Ch2ch2ch3 (b) ch2ch2ch3 ch2ch2ch3 ch2ch2ch3 FF, / In the color-curable composition of the present invention, the dye of the formula (1) contains 32 320502 200916953, the amount of solid matter of the colored curable composition is expressed by mass percentage It is preferably 15 to 65 mass%, preferably 2 to 60% by mass, most preferably 25 to 60% by mass. When the content of the dye is in the above range, a sufficient color concentration can be obtained when the color filter is used, and a polymerizable compound having a necessary amount can be contained in the composition, so that the solvent resistance tends to be improved, which is preferable. The "solid matter" in the brother's book refers to the total amount of the components obtained by removing the solvent contained in the colored curable composition. ' The color-hardening composition of the present invention may further comprise a pigment selected from the group consisting of a buckwheat exhaust material, a side-by-side nitrogen dye, and a saliva/(1) colorant. At least one dye in the group is used as a seed. Female compound, but the wood bamboo 1猓 is not limited,

: Barbituric acid azo dyes represented by the following formula (7) are =, P.

(7) In the formula (7), each of T1 and T2 independently represents a hydrogen atom, an atom or a sulfogen, and an aliphatic hydrocarbon group, and the number of carbon atoms substituted by a hydroxyl group is 1 to 10 · a hydrocarbon group a saturated aliphatic ester of the filaments of the genus of the genus of the genus, and a saturated aliphatic hydrocarbon group of 1 to 8 and a number of 1 to 10: a saturated aliphatic hydrocarbon group of 1 to 10, a carbon number, and an alkane An aryl group having an alkyl group of 7 to 20, or an aryl group having a carbon number of 2 to 20 to 20, an alkyl group of 10; 320502 33 200916953 independently representing a hydrogen atom, a saturated fat of 1 to 20 A hydrocarbon group, a (four) sub, a saturated aliphatic hydrocarbon group having a carbon number of i 10, and a carbon number! To 8 bis, the carbon number is 1 to an acid group, an amine phase group or an N-substituted amine group. The μ group, the several groups, the continuation Τ1 and the Τ2 each independently represent a hydrogen atom or a sulfur, but the same is preferred. a ', sub, may be the same or the number of carbons in p to R34 is i 5 1n linear, branched or ring === group, and the carbon number of the saturated aliphatic hydrocarbon group may be 1 to 1 Better. The carbon number is... And fat, such as methyl, ethyl, n-propyl, denier, and the system, butyl, second, earth, n-butyl, isobutyl, first

Cyclohexyldiyl is ethylhexyl, etc.), cyclopentyl: and the carbon number is 1 to 0P. To 8 (wherein the base is as defined above, an oxy group, or an alkoxyl group having a carbon number of 1 to 8 (wherein, preferably sartozoene to 4 is preferred). The above substituted ',,, The sulfur which is preferably 4 is exemplified by a transethyl group (for example, 2 to ethoxylated ketone, 2 to ethoxyethyl hydrazine), ethyl hydrazine, and ethoxyethyl ( For example, two or two = for example, 3, propyl, etc.) and the like. The earth κ〒 stone has an anomaly of 6 to 2, and may have a saturated aliphatic hydrocarbon group, a group, and may have no substituent or the like. _ of the aryl group: package: take =:: base 6 to 1. It is better. Specific examples of the aryl group include, for example, 'base two: phenyl group 320502 34 200916953 3曱^, 4-methylphenyl group, 2-methoxyphenyl group, 3-methoxyphenyl group: : substituted or unsubstituted, such as methyl lactyl phenyl, 2-sulfonic acid phenyl, 3-sulfonyl phenyl, sulfonic acid sulfhydryl, ethoxylated phenyl (for example, 4-((3)OGDPh) The phenyl group, etc., the alkyl moiety of the aralkyl group having 7 to 2 carbon atoms in the R to R may be any of a ^, a branched chain or a ring. The number is preferably 7 to 1 (), and the specific example of the alkyl group having 7 to f of the carbon number is benzyl, phenethyl or the like. The number of turns in the range is from 2 to 10, and may have no substituents, such as a residue of a sulfonate, a hydrocarbon group such as a fatty group, or an alkoxy group. The carbon number of the carbon substituent of the aryl group is 2 to 10 is preferred. The specific shots of the brewing base are as follows: W-based m-based, methoxy-methyl-branthyl (p-methoxybenzamide, etc.), etc. The number of slaves from ί?34 to R is The saturated aliphatic hydrocarbon group of 1 to 1 is the same as the shape of R31, which may be linear or branched. The number Φ in the shape or the ring is preferably 2 to 8, particularly preferably 3 to 6. The specific examples of the saturated aliphatic hydrocarbon group of _ are as in the case of 1^ and {^ : the saturation of the example to R42 The aliphatic hydrocarbon group may be preferably ===, and a specific example of the ruthenium substituted by the _ atom may, for example, be a trifluoromethyl group. For comparison: Λ7: exhaustive oxy-oxyl group, the number of dishes... Specific examples thereof include a methoxy group, an ethoxy group, a ri::propoxy group, a n-butoxy group, an isobutoxy group, a second butoxy group, a di-butoxy group, etc. ^ 320502 35 200916953 An example of the N-substituted amine stone yellow base in R35 to R42 is a N-monosubstituted amine sulfonyl group, which is represented by the formula -S〇2匪R43. R43 represents a saturated carbon number of u 10 Aliphatic nicotine (including a saturated aliphatic hydrocarbon group having a carbon number of 1 to 10 and an alkoxy group having a carbon number of i to 8), an aryl group having a carbon number of 6 to 20, and a carbon number of 2 = base, or a ruthenium with a carbon number of 2 to 10. The eight/medium carbon is a saturated aliphatic nicotine group of U10, which can be either a straight bond, a second listener or a %. The carbon number of the aliphatic hydrocarbon group is calculated by the number of carbon atoms of the substituent. Preferably, it is 6 to 1 Torr. It is a specific example of a saturated aliphatic hydrocarbon group having an anisotropy of 1 to 10, ethyl, n-propyl, isopropyl, n-butyl, isobutyl Base, its expectant, ticlo-butyl, methyl butyl (for example, 11,3,3-tetramethylbutane = bis = (eg ... hexyl, alpha dimethyl hexyl, etc.), bis' 歹 ' 2 ethyl a hexyl group, a cyclopentyl group, a cyclohexyl group, a methylcyclohexyl group (4, for example, a 21-cyclohexyl group, etc.), a cyclohexyl group, etc., wherein the saturated aliphatic hydrocarbon group having an inverse number of 1 to 10 is as the former = yl group Specific examples of the decyloxy group to be 8 (preferably having 1 to 4 carbon atoms) such as a substituted saturated aliphatic hydrocarbon group may, for example, be a propyl propyl group (for example, 3-(isopropoxy)propyl group, etc.) Wait. The aryl group having a carbon number of 6 to 2 in R43 may not have a saturated aliphatic hydrocarbon group 哎 Α簟 ' ' to include a # substituent. The carbon number of the aryl group is preferably 6 to 7 (), and is exemplified by a phenyl 1 phenyl group such as a nonyl group such as a nonyl group (for example, 4). -Trifluoromethylphenyl, etc., substituted or unsubstituted, 320502 36 200916953 phenyl, etc. The carbon number in R43 is 7 to 2 Å, and the alkyl portion of the aralkyl group may be linear or branched. The number of carbon atoms of the aralkyl group is generally from 7 to 20, and preferably from 7 to 1 Torr. Specific examples of the aralkyl group include a benzyl group and a phenylpropyl group (e.g., a methyl group to a benzene group). a phenylalkyl group such as a propyl group or the like, a phenylbutyl group (for example, 3-amino-1-phenylbutyl group, etc.), etc. The number of slaves in R is 2 to 1 fluorenyl group, and may have no substituent. Further, a substituent such as a saturated aliphatic hydrocarbon group or an alkoxy group is bonded. The carbon number of the fluorenyl group is preferably 6 to 1 G by weight based on the carbon number of the substituent. Specific examples of the acid group include, for example, Ethyl thiol, benzoyl, ortho-tolylmethyl, m- benzhydryl, p-tolylhydryl, decyl benzhydryl (eg p-nonylphenyl) Nb. Examples thereof include a group represented by the following formulas (9) to (丨5). When the molecule contains 2 (d) N-substituted amine decanoic acid groups, the N-substituted amine sulfonyl group may be the same or different. Construction. 320502 37 200916953 Η -S02N (9)

Η S02N (10) γ^Ο Η -S02N, (11)

Η -S02N

(12) H3C

Η -so2n (14)

Η -S02Ns (13) so2n (15) υΟν The aforementioned barbituric acid azo dye may, for example, be a compound represented by the formula (7-1) to (7-7), wherein the formula (7-1), Compounds represented by 7-3), (7-4), (7-5) and (7-7) are preferred. 38 320502 200916953

(7-1) (7-2) (7-3) (7-4) 39 320502

V 200916953

\ Ρ Ν —_ /SOgNH 〇=Κ )—Ν=Ν Ν~{〇 Ν )=0 (7-6) Ί _ 7S〇2NH Ν

==ν

Q ΗΝο^

ο ΝyS〇2NH 0={ ^~NaM Ν

Ο Ο.

==ν

VnSot) .(7-7) 0 is not specific to the ketone azo dye, and is represented by the following formula (8);:: not limited, a well-known combination can be used.

Rf R21

0==\ /—N=N-Z (8)

R23 OH

[In the formula (8), z represents a phenyl group having (4) at least one selected from the group consisting of a carboxyl group, an aminecarbamyl group, a rhein group, and an N-substituted amine sulfonyl group, or 1 to 3 groups of a group selected from the group consisting of a carboxyl group, an amine carbenyl group, a sulfonyl group and an N-substituted amine; at least one group selected from the group consisting of ε yellow groups; 320502 40 200916953 R21 represents a hydrogen atom a saturated aliphatic hydrocarbon group having a carbon number of 1 to 1 Torr or a trifluoromethyl group; ^ R22 represents a hydrogen atom, a cyano group, an amine carbaryl group, an N-substituted amine methacrylate, an acid group, and the above Each of the substituted base salt, (four), and sodium salt; R23 represents a hydrogen atom, a linear or branched or cyclic saturated aliphatic hydrocarbon group having a carbon number of from 丨 to 1〇, a carbon atom of a substituted carbon = 30, a substituted aryl group having a carbon number of 7 to 2 (), a carbon atom of 3 to 2 Å, and a carbon atom via a hetero atom = , Aminomethyl sulfhydryl, N-substituted amine carbhydryl, a substituted number of moles of alkoxy groups, and the number of carbons that can be substituted for: = The number of carbons that can be substituted is 2 to 2 〇 base, The inverse number was taken as ^ the Ge aliphatic Jiaji, 30 b, or may be of aryl sulfonic acyl group; and trans alkylene von Mo, formula (8) may be formed at a desired position thereof _]. In the multi-polymer (8) above, the phenyl group and the naphthyl group represented by Z are represented by N---SOzI^R24)!^5. Substituent

R and R25 each independently represent a hydrogen atom, a carbon number A, and an aliphatic nicotine group (the carbon number is ...0 and the = carbon number of the crucible is from 丨 to 8) The hydrocarbon group includes a ruthenium to alkane fluorenyl group substituted, the base, the carbon number is 7 to 2 〇$^, the inverse number is 6 to 20, and the saturated group having a number of 1 to 1 G can be a linear chain. The number of carbon atoms of the saturated aliphatic hydrocarbon group is preferably from 6 to 10, in the form of a bond or a fraction of 41 320502 200916953 . The carbon number represented by R is 1 to 1 Torr and the aliphatic hydrocarbon group, and examples thereof include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl sulfonium isobutyl group, and second butyl group. , a third butyl group, a methyl butyl group (for example, 1,1,3,3-tetramethylbutyl group, etc.), a methylhexyl group (for example, a decyl group, a 1,5-dimethyl 1 group, etc.), a hexyl group (for example, 2-ethylhexyl group, etc.), a cyclopentyl group, a cyclohexyl group, a methylcyclohexyl group (for example, a 2-fluorenylcyclohexyl group), a cyclohexyl group, and the like, wherein A group, m3-tetramethylbutyl group, i,5-didecylhexyl group, 2-ethylhexyl group or the like is preferred. The saturated aliphatic hydrocarbon group having a carbon number of from 5% to R25, as defined by R24 and R25, may be substituted with an alkoxy group having a carbon number of from 丨 to 8 (preferably having a carbon number of from 4 to 4) as described above. The carbon (four)! Specific examples of the alkoxy group substitution to 8 and the aliphatic ketone group include a propoxy propyl group (for example, 3-(isopropyl group) or the like. The carbon number of the group is represented by R and R25. The aryl group having a carbon number of 6 to 20 may have a saturated aliphatic hydrocarbon group or a (tetra) or other substituent. The carbon number of the above aryl group is preferably 20 to 20, and preferably 6 to 10, and 111. V ΤΊΧ. . i + w Specific examples of the aryl group include a phenyl group, a hydroxyphenyl group (for example, a hydroxyphenyl group), a difluoromethylphenyl group (for example, a 4-trifluorodecylphenyl group), and the like. Substituted or unsubstituted phenyl and the like. The alkyl moiety of the aralkyl group represented by K and R may be a linear or branched chain. The carbon number of the aralkyl group is usually 7 to 2 Å, and preferably 7 to 1 Å. Specific examples of the aryl group include benzyl group, phenylpropyl group (for example, 320502 42 200916953 1-methyl-3-phenylpropyl group, etc.), phenylbutyl group (for example, 3-aminophenyl group). Butyl, etc. are used as typical phenylalkyl groups. The mercapto group represented by R24 and R25 may have no substituent, and may have a substituent such as a saturated aliphatic hydrocarbon group or an alkoxy group. The carbon number of the wake-up base is generally 2 to 1 Torr, and preferably 6 to 1 Torr, based on the carbon number including the substituent. Specific examples of the brewing base include, for example, an ethenyl group, a benzoyl group, a methoxybenzylidene group (e.g., p-methoxybenzylidene group). Soil R21 represents any one of a hydrogen atom, a saturated aliphatic hydrocarbon group, a carboxyl group and a trifluoromethyl group. The saturated aliphatic hydrocarbon group represented by R21 may be linear, branched or cyclic. The carbon number of the saturated silk (tetra) group does not include the carbon of the substituent. R: 2 is preferably 2 to 8, more preferably 3 to 6. Specific examples of the "saturated month" include, for example, a methyl group, an ethyl group, a n-propyl group, an isopropyl group or the like. Any one of a butyl group, a tributyl butyl group, a cyclopentyl group, a ring &gt; 22 amine, a cyano group, an amine mercapto group or an N-substituted amine carbaryl potassium salt. The ammonium salt of the substituent, the N-substituted amine methyl sulfide represented by the salt and the sodium salt R22 | a ^ represents the τ ^ group, which can be represented by the formula -C0N(R26)R"; 0: in the 'R 6 And R27 each independently represent a hydrogen atom, a carbon number of 1 to several hydrocarbon groups, a terminal carbon number A 7 saturated aliphatic hydrocarbon group substituted with an alkoxy group having 1 to 8 carbon atoms, and a carbon number of 6 to 2 Å. An aryl group, an inverse number two to two, an aryl group, or a carbon number of 2 to 1 )). Saturated fat _ group, aryl group, aryl group and brewing group 320502 43 200916953     As in the previous example, the methyl group such as a specific group of a benzoin atom: a dibasic group (such as a benzoyl group, etc.) may be further enumerated, for example, a carbon number of the benzamidine chain may be substituted. a linear or branched saturated aliphatic nicotine group of 1 to 1 G, a carbon number which may be substituted by a calorie substitution of 7 to 2 G, and a carbon number of 3: an anthracene hydrocarbon group: Part of the carbon atom is substituted by a hetero atom to form a tight second: an amine of the I group, a W group, a decyloxy group, an aryloxy group, a 23 fluorenyl group, an aliphatic sulfonyl group, or an arylsulfonyl group. An example of a fresh aliphatic hydrocarbon group which is not included in R. It is the same as the saturated aliphatic hydrocarbon group of the above 。r. The aryl group is generally 6 to 30, and more preferably 6 to 1 = preferably '6 to 16. The specific of the aryl group. Examples include: base, :-nitrophenyl, 2, phenyl, such as benzyl, 2,4-methylphenyl, 2-methylphenyl, 4-methoxyphenyl, 2- a methoxycarbonyl group + a dichhyl phenyl group, etc. a carbon having a carbon number of 3 to 20 as a part of an alicyclic hydrocarbon group: a group substituted by a hetero atom, optionally saturated or unsaturated , = 3 to 2 碳 is preferable, especially 5 to 15 is more preferable. The specific example of the hybrid base can be exemplified by (4), !, 2, 4-trisyl,嗟: base, benzopyrene, sputum, sulphonyl, benzopyrene, thiophenazolyl, etc., and may also have a substituent. R is not a Fangyuan base, It is a linear or branched chain, and the carbon number is preferably from 7 to 10. Specific examples of the aromatic group include, for example, a benzyl group, a phenylpropyl group 320502 44 200916953 group (for example, 1-mercapto-3-3-benzene) Phenyl propyl, etc., phenyl butyl (eg 3-amino-1-phenyl butyl) And the like is a typical phenylalkyl group. p 2 3 _ is not an N-substituted amine fluorenyl group, which is the same as the substituted amine oxime group shown by the above R22. 烷基 1 is not an alkyloxycarbonyl group It may or may not have a substituent or may be a %. The total carbon number of the alkyloxycarbonyl group is generally 2 to 2, and it is preferably 2 to 6, preferably 2 to 1 Å. Specific examples of the alkyloxy group include, for example, a methoxymethyl group, an ethoxylated group, and a butoxy group. The aryloxy group of the stone mountain may or may not have a substitution. a base of 7 to 30, wherein 7 to 20 are preferred 'especially 7 to 2 bases (4) may be (10) such as phenoxy oxime 2 3 _ fishing b Γ 酿 ,, may be aliphatic The base or aryl group may also be a pot of carbon, and may have a substituent. Generally better. Talk about /, 2 to U is preferred, especially 2 to 10 ~ the specific examples of the brewing base can be listed as the base, diced 醯 醯 牛 牛 牛, 醯 醯, 醯 醯 丁 丁 丁 丁 、 醯 醯 醯 醯 醯 醯 醯 醯 醯Base, diterpene, etc. A 1-mercaptoacetinyl group, a benzotriene R23 new-former', a::: is -:::w, or a ring gamma, butyl = base === base, specific examples such as methyl ethoxylate Ethyl sulfonyl thiol and the like. Earth /, mercapto, methoxyethanesulfonyl and 320502 45 200916953 ψ R23 arylsulfonyl group may have a substituent, generally having a total carbon number of 6 to 30, of which 6 to ? . , η main (9) is preferred, especially 6 to 丨 8 is more preferable. Specific examples of the aryl sulfonyl group may be, for example, a poor one, such as a sulfonium group and a toluenesulfonyl group. The above-mentioned ketone azo dye may be, for example, the following compound, and a compound represented by the formula (8-1) to (8-9) is preferred. ’,

(8-1) (8-2) (8-3) (8-4)

(8-5) 320502 46 200916953

NQ COOH

(8-10)

(8-11) The pyridine &amp; /, which is represented by the formula (8), is a polypolymer or more. The &lt;anthraquinone dye may be in the form of a polymer represented by the polymer system of the formula (8) at any position thereof, and the specific sentence may have two or more formulas (8) in the molecule, such as the following compounds. S2〇^ 47

For example, C. C can be cited as a compound, for example, C. 可. Acid Yellow 56, CI Solvent Yellow 82, or the following compounds, etc. The 17' C·L Solvent Lamp 320502 48 (20) 200916953 can be used as disclosed in the K.K.

(twenty one)

(twenty two)

(19) COOCjHg

The material is not particularly limited, and it is possible to use a known compound, No. 339, No. 339, No. 5-39269, and a special ketone dye from Japan. 8 171201 et al., quinine 54, ::1,: yellow c.1. Solvent yellow 33'C.1. Disperse yellow ring steam 64, or the following compounds, etc.

The phthalocyanine dyes described in Japanese Patent Publication No. 2005-297406, and the like. Specifically, for example, the following compounds and the like can be mentioned.

The pigment is used as the (A) colorant. The pigment may be exemplified by a color index (The s〇ciety 〇f Dyers grab (C〇laUriSi: s publication), which is classified as a pigment (Pigment), and the composition may be, for example, (Μ.颜料黄卜3, 12, 13, 14, 15/16, 17, 20, 24, 31, 53, 83, 86, 93, 94, 109, 11〇, in, 125, 128, 137, 138, 139, 147, 148, 150 , 153, 154, 166, 173, 194, 214 and other yellow pigments, CI•Pigment Green 7, etc. Green c”. Pigment yellow 138, 139, 15〇,” Pigment Green 7, 3 6 is preferred. Examples of the pigment which can be obtained by dispersing a pigment in a state in which the pigment is dispersed in a solution, if necessary, may be exemplified by a cationic system, an anionic system, and a polyester system. A surfactant such as a polyamine or the like may be used or used in combination of two or more. 320502 50 200916953 Examples of the surfactant include polyoxyethylene ethyl ethers and polyoxyalkylenes. Phenyl ethers, polyethylene glycol diacetates, sorbitol wild fatty acid vinegars, fatty acid modified polyacetates, tertiary amine modified polyamines In addition to the above, the product name is kp (product of Sakamoto Shin-Etsu Chemical Industry Co., Ltd.), p〇ly fl〇w (曰本共荣化子) Division products), EF Top (Tohkem Products products),

Megaface (product of Dainippon Ink Chemical Industry Co., Ltd.), FiuQMd (product of Sumitomo 3M Co., Ltd.), Asahi Guard, Ryuichi 1〇n (product of Asahi Glass Co., Ltd.), Solsperse (product of Zeneka), efka (efka chemical product), PB821 (product of Japan Ajinomoto Co., Ltd.), etc. When the dispersant is used, it is used in an amount of from 0.1 to 100% by mass, based on the mass% of the pigment, preferably from 5 to 50% by mass, more preferably from 5 to 50% by mass. When the amount of the dispersant used is in the above range, it is preferred to have a tendency to obtain a homogenous dispersion. In the coloring agent (I) used in the color hardening composition of the present invention, the solid content of the colored curable composition is at a mass ratio of from 30 to 65 mass%, wherein More preferably, 6 % by mass is more preferably 35 to 55% by mass. When the content of the (A) coloring agent is in the above range, a sufficient color concentration for filtration can be obtained, and since the composition can contain a compound having a required amount or more, a pattern having sufficient mechanical strength can be formed, and a preferred factory is: The (8) polymerizable compound used in the present invention may be a monomer which can be hardened by enthalpy or enthalpy, and may be a known substance. T and use the special. 320502 51 200916953 Specific examples of the monomer include, for example, pentaerythritol tetrapropyl acrylate, quaternary tetraol tetradecyl acrylate, dipentaerythritol penta methacrylate, dipentaerythritol hexamethacrylate, and a carboxyl group. Pentaerythritol pentaacrylate derivative, ethylene oxide triglyceride, ethylene oxide trihydrocarbyl propane triacrylate, and propylene oxide triglyceride. Examples of the oligomer include epoxy acrylate, urethane acrylate, and polyester acrylate. For example, the "Status and Prospects of UV and EB Hardening Technology" (CMC) can be used. Publication) The oligomers and the like described on pages 18 to 20. (B) The content of the polymerizable compound is preferably from 5 to 50% by mass, more preferably from 10 to 40% by mass, more preferably from 12 to 10% by mass based on the color of the curable composition. %% by mass is the best, when the content of the compound is in the above range, the hardening can be sufficiently caused; the ratio of the money before and after development, (4) the purely good tilt (4) is the preferred product = in the present specification "Solid matter" means a coloring hardening component at room temperature: a liquid amount and an added r as needed. The secondary chromophoric composition may still contain (c) the binder of the tree, which is derived from (4):: above. Here, '(meth)acrylic acid means acrylic acid and the above is derived from (methyl) The inclusion of the constituents of the propylene fosphate: In all the constituent units of the 黏 黏 树 树 树 树 , 3 35 35 35 35 35 35 35 35 35 35 35 35 35 35 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影 显影In the case where the solubility is good, and there is no tendency to retain the residue after development, it is preferable to use, for example, an aromatic oral substance other than the constituent unit of the (meth)acrylic acid. , unsaturated carboxylic acid _, unsaturated (tetra) amine keji g and a few acid propylene vinegar, a few acid vinyl vinegar, and scaly, cyanide = olefinic compounds, unsaturated amides, Unsaturated oximines / R16

HO

(32) t-thin, polymer molecules have a single (four) county at the end of the ruthenium or a single monomer with a monomethyl group; x, for example, the unit shown in the formula (32) and the unit shown in the formula (33), and the like.

(33) In the mountains [in the formulas (32) and (33), '^ and ^ each independently represent a hydrogen atom or a saturated aliphatic nicotine group having an inverse number of 1 to 6]. R16 and R17 may, for example, be a hydrogen atom, a methyl group, an ethyl group, a n-propyl group, an isopropyl group, an n-butyl group, a second butyl group, a tert-butyl group, a n-pentyl group or a methyl group; , 3-mercaptobutyl, i-ethylpropyl, 2-ethylpropyl, n-hexyl, methylpentyl '2-methylpentyl, 3-methylpentyl, 4-methylpentyl , 1-ethylbutyl, 2-ethylbutyl, 3-ethylbutyl, etc., wherein, hydrogen atom, sulfhydryl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, second butyl group The base and the tributyl group are preferred, and a hydrogen atom, a mercapto group or an ethyl group is more preferred. 320502 53 200916953 The specific example of the (c) binder resin is preferably, for example, methacrylic acid/benzyl methacrylate copolymer, methacrylic acid/methyl methacrylate/styrene copolymer, methacrylic acid. /Methyl methacrylate / isodecyl methacrylate copolymer, methacrylic acid / styrene / benzyl methacrylate / N-phenyl maleimide copolymer, methyl acrylate / (33) The constituents shown (in the formula (33), R16 represents an f group, and R&quot; represents a gas atom methyl maleimide/benzyl methacrylate copolymer, methacrylic acid / formula (33) ) The constituents shown (in the formula (33), Rle represents a meglumines, and the ruthenium atom VN-cyclohexylmaleimide/methyl acrylate benzene

a component represented by the formula (10) (wherein W represents a methyl group, R17 represents a hydrogen atom), a benzoyl acrylate copolymer, and a formula ( 32) The constituent components shown (in the formula (32), rI6 represents a hydrogen atom) / methyl benzoic acid benzamidine copolymer, = K represents a methyl group, and the brother 7 represents a hydrogen atom) / Ethylene/dicyclopentyl methacrylate copolymer and the like.

For the piece: (6) The acid value of the (6) bonded resin is preferably 30 to 150. Among them, 35 to 135 is the decodu 1DU. When the acid value is in the above range, the m is 4G magic 2G. optimal. The unexposed portion becomes easily dissolved, and, =, the shirt liquid = the solubility is improved, and the pattern of the exposed portion remains after the image is formed: 2, preferably. Here, the acid value is a value measured based on the amount of potassium oxide (mg) according to the neutralization = sheep (4), and is obtained by titrating a hydrogen solution required for the ruthenium polymer. The use of the potassium hydroxide water (C) binder resin is preferably in the form of a mass percentage, preferably 8 to 35 mass%, based on the total amount of the solid solution of the coloring hardenable composition of 320502 54 200916953. Especially = to 4 〇; « is preferable, wherein the content of the binder resin is preferably in the range of the above-mentioned range to the range of berber to berry. When (the degree of enthalpy and residual film rate tends to increase, it is the second genus, and the composition of the composition shown in the formula (10) is (6) viscous, what is the composition of the constitutive component / constitutive component: (32), Rl6 represents a copolymer composed of a methyl group and a hydrogen atom A =:: vinegar, and the polymerization of the two components can be obtained by polymerizing methacryl oxime and methacrylic acid. The two-component polymer is obtained by reacting with a formula (34) represented by the formula (34) and R represents a hydrogen atom. (34) 〇, consisting of a constituent represented by a component derived from methyl acetoacetate/formula (3)) (in the formula (33), f represents a methyl group, and Rl7 represents a chlorine atom" Street = self-methacrylic acid A constitutive component of benzyl ester/a copolymer derived from a constituent component of dicyclopentanyl methacrylate, which can be obtained by using methyl propyl acrylate propylene acrylate and methacrylic methacrylate The copolymer of acrylic acid and methyl propyl acetoacetate is prepared by reacting. (C) The polystyrene-equivalent weight average molecular weight of the binder resin is preferably 5,000 to 100, ,, wherein , from 6, 〇〇〇 to 8 〇, 〇〇〇 is preferred, especially 7,000 to 60, 〇〇〇 is better. When the molecular weight is in the above range, the hardness of the coating film can be improved, and the residual film rate is also high. The unexposed portion is preferably good for the developer solution 320502 55 200916953, and has a tendency to enhance the resolution, and is preferred. The color hardening composition of the present invention may further contain (...a photopolymerization initiator. Examples of the agent include a triterpenoid compound, an acetophenone-based compound, and a bi-diimidazole ( A biimidazole compound, an active radical generator, an acid generator, etc. Examples of the above-mentioned three-tillage compound include, for example, 2,4-bis(trichloromethane) 6-(4-methoxyphenyl)- 1,3,5-triterpene, 2,4-bis(trichloromethyl)_6_(4-methoxynaphthyl)-1,3,5-three tillage, 2,4-double (trichloropurinyl) )_6_(4_methoxystyryl)-1,3,5-three tillage, 2,4-bis(trichloromethyl)-6-[2_(5-methyl-anthran-2-yl)vinyl -1,3,5-trianthrene, 2,4-bis(trichloroindenyl)-6-[2-(furan-2-yl)vinyl]-1,3, 5-triphthyl, 2, 4-bis(trichloromethyl)-6-[2-(4-diethylamino-2-methylphenyl)vinyl j — l 3, 5_trioxane, 2, 4-bis(trichloro) Methyl)-6-[2-(3,4-dimethoxyphenyl)vinyl]-1' 3,5-trin, 2,4-bis(trichloroindenyl)-6-flower base ^, 3, 5-trisphine, etc., of which 2,4-bis(trichloroindenyl)-6-(4-methoxyphenyl)q,3,b three tillage, 2,4-double (three Chloromethyl)-6-(4-decyloxynaphthyl) 4, 3, 5_three tillage, 2, 4-bis(trichloroindenyl)-6-(4-methoxy stupid vinyl) 5 Tri- or tri-, 4-, 4-bis(trichloromethyl)-6-direction Japanese sunflower-丨, 3, 5_三哄 is preferred, especially 2, 4-bis(trichloroindenyl)-6- to holly-base, 3, 5_ three tillage is better. Examples of the acetophenone-based compound include, for example, diethoxyacetophenone, 2-methyl-2-(N-morpholinyl)-bu(4-methylthienyl)propanone, 2_ Hydroxy-2-mercapto-1-phenylpropanone, benzyldidecyl ketal, 2-hydroxy-2-methyl-1-[4-(2-hydroxyethoxy)phenyl]propene - ketone, hydroxycyclohexyl phenyl ketone, 2-benzyl-2- oxalyl morpholinyl) phenyl] 320502 56 200916953 butan-1-one, 2-(4-methylbenzyl )-2-dimethylamino-morpholinyl)phenyl]butan-1-one, 2-hydroxy-2-methyl-indole-[4_(1_mercaptovinyl)phenylpropan-1-one Convergence of a polymer, etc., wherein 2-methyl-2_(N_morpholinyl)-bu (4-methylthienyl)propan-one, 2-phenylindenyl-2-diamine —morpholinyl)phenyl]butan-one, 2-(4-methylbenzyl)_2-dimethylamino-1-[4-(indolyl-morpholinyl)phenyl]butyl-! Ketones are preferred, especially 2-benzoic acid-2-diamino-1_[4-(N-morpholinyl)phenyl]butyl-indole-ketone, 2-(4-methylbenzoic acid) ) -2-dimethylamino -1- [4 - (N_ morpholinyl) phenyl] butoxy - BU-one is more preferred. ', 月 ij说马" An example of a sigma rice salivary compound, such as 2,2 '-bis(2-chlorophenyl)-4, 4,5,5'-tetraphenyldiimidazole, 2 , 2'_bis(2__gasphenyl)-4,4',5,5'-tetrakis(4-ethoxycarbonylphenyl)biimidazole, 2,2,_bis(&quot;2-chlorobenzene Base)-4,4',5,5'-tetrakis(4-bromophenyl)biimidazole, 2, 2, bis(2-hydroxyphenyl)-4,4',5,5'-tetra 2,4-Dichlorophenyl.)biimidazole, 2,2,_bis(2/smoke)-4,4,5,5-tetraphenyl-linked two-π m saliva, 2,2,_ Bis(2 4-dichlorophenyl)-4,4',5,5'-tetraphenyldiimidazole, 2,2,_bis(2-chlorophenyl)-4, 4',5, 5 '-tetrakis-(methoxy-phenyl)biimidazole, 2, 2, bis(2,3-dichlorophenyl)-4,4',5,5,-tetraphenyl-diimidazole, 2,2,_bis(2' 6-dichlorophenyl)-4, 4',5, 5'-tetraphenyldiimidazole, 2, 2, bis(2-nitrophenyl)-4 , 4''5,5'-tetraphenyldiimidazole, 2,2,_bis(2-nonylphenyl)-4,4,5,5'-tetraphenyldiimidazole, etc., among them, 2,2,-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl Imidazole, 2,2,-bis(2,3-monochlorophenyl)-4,4,5,5-tetraphenyldiimidazole is preferred. Active radical generators produce active free radicals by light irradiation. Examples of the active radical generator of 320502 57 200916953 include a benzoin compound, a benzophenone compound, a thioxanthone compound, an oxime compound, and the like. Examples of the auxin-based compound include benzoin, benzoin, benzoin B, benzoin, benzoin, and the like. Examples of the benzophenone-based compound can be exemplified. Such as benzophenone, decyl benzoyl benzoate, 4-phenyl benzophenone, 4-phenylmercapto-4'-mercaptodiphenyl sulfide, 3, 3', 4 4'-tetrakis(t-butylperoxycarbonyl)dibenzophenone, 2,4,6-trimercaptobenzophenone, etc. Examples of the aforementioned thioxanthone-based compound may be, for example, 2-isopropyl. Anthrone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthene, 1-aluminum-4-propoxyβ, and the like. Examples of the lanthanide compound can be enumerated as 〇_醯The compound is a compound, and specific examples thereof include, for example, 1-(4-phenylthio-phenylpyridinium, ketone, 2-indolyl-indole-benzoate, and diphenylthiol. Monophenyl)-octyl-dione 2_肟V benzoic acid ester, 1-(4-phenylthio-phenyl)-oct-1-one oxime-indole-acetic acid hydrazine, 1-( 4-phenylthio-phenyl)-butyl-butanone oxime-acetate. Examples of the living radical generating agent other than those exemplified above include 2,4,6-methylbenzoinyl diphenylphosphine oxide, 1〇-butyl-2-chloroacridinium, 2-B. Keen 醌, diphenylethylene g g (benzil), 9, 1 〇 phenanthrenequinone, camphorquinone, methyl phenylglyoxylate, titanocene compound, and the like. Examples of the aforementioned acid generator include, for example, 4-hydroxyphenyl dimethyl p-toluenesulfonate, 4-phenyl phenyl hexafluorophthalate mirror, and p-toluene ruthenic acid 4- ethoxylate base. Methyl hydrazine hexafluoro(tetra) 4 _ ethoxy phenyl phenyl phenyl methacrylate 320502 58 200916953 Mirror, p-toluene chloroform triphenyl mirror, hexafluoro acid triphenyl vegetable, dandenyl lock, hexafluoride Recording of bismuth salts such as diphenyl hydrazine, or toluene continued to 'two 酉 酉 酉 category (5) tr〇benzy tosylate), benzoin toluene acid 酉 酉 category. Further, in the compound exemplified above as the active radical generator, a compound which produces an active radical and an acid, for example, a tri(tetra) photopolymerization initiator can also be used as an acid generator. The content of the photopolymerization initiator of the above (9) is preferably from 〇 1 to 25% by mass based on the total amount of the (8) polymerizable compound and (c) the binder resin, and particularly preferably ! 1 to 25% by mass; It is preferred to be 2% by mass. When the content of the (8) photopolymerization initiator is in the above range, the exposure time is shortened due to high sensitivity, and the productivity is improved. On the other hand, the pattern of the line and space (hue and space) is resolved due to the high sensitivity. The minimum line amplitude has a tendency that the wired amplitude does not become too thick, so it is better. In the color hardening composition of the present invention, (8) photopolymerization initiation aid (8) photopolymerization initiation aid may be further contained, and it may be used in combination with (8) photopolymerization initiator. The (8) photopolymerization initiation aid is a compound which promotes polymerization of the photopolymerizable compound when the polymerization reaction is initiated by (9) a photopolymerization initiator. Examples of the photopolymerization initiation aid include an amine compound, a methoxy oxime compound, and a thioxanthone compound. Examples of the amine compound include triethanolamine and ketoethanol. Female diisopropanolamine, methyl 4-dimethylaminobenzoate, 4-dimethylaminobenzamide, isoamyl 4-methylaminobenzoate, 2-dimethylaminobenzoate 320502 59 200916953 乙, 4-Dimethylaminobenzoic acid 2-ethyl, 7, 4, 4, dimethylamino) diphenylmethyl, 4 , 4, bis (diethylamino) benzophenone, 4, 4' bis (ethyl decylamino) benzophenone, etc., wherein 4, 4'-bis (diethylamino) The benzophenone is preferred. Examples of the alkoxy fluorene compound include, for example, 9,1 methoxymethoxy oxime, 2-ethyl hydrazine, 2-ethyl-9, 10-dimethoxy Ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones, ketones —Diethyl thiophene, 2,4-dichloro: ton 1 -chloro-4-propoxy sinone, etc. (E) Photopolymerization The initiator may be used singly or in combination of two or more. (E) The photopolymerization initiation aid may be used by a commercially available person, and the commercially available (e) photopolymerization initiation aid may be exemplified by a trade name of ΕΑΒ_ρ (Budong Valley). Chemical Industry Company's product '4, 4'. bis (diethylamino) diphenyl (5) and other organic amine compounds, etc. (9) Photopolymerization initiator / (8) Photopolymerization initiator in the color hardening composition of the present invention The combination may, for example, be 2,4_bis(trimethylmethyl)-6-to geranyl-1,3,5-trituric/4,4,-bis(diethylamino)benzophenone. Diethoxyacetophenone/4,4,-bis(diethylamino)benzophenone, 2-methyl-2-(N-morpholinyl)-bu (4-methylthienyl) Propionyl ketone / 4, 4, a double (diethylamino) diphenyl fluorenone, 2-hydroxy-2-methyl-; [-phenyl propyl- ketone / 4, 4, _ double (two Amino)benzophenone, benzyldimethylketal/4,4,_bis(diethylamino)benzophenone, 2-hydroxy-2-methyl-hydroxyethoxy)benzene Propionan-1-one/4,4'-bis(diethylamino)benzophenone, hydroxycyclohexyl 320502 60 200916953 phenyl ketone / 4, 4 '-bis(diethylamino)benzophenone, 2-hydroxy-2-mercapto-1-[4-(1-indolylvinyl)phenyl]propan--one ketone. 4,4'-bis(diethylamino)bis+benzophenone, 2-phenylhydrazino-2-dimethylamino-1-[4-(indolyl-morpholinyl)phenyl]butene-1- Ketone/4,4'-bis(diethylamino)benzophenone, 2-benzyl-2-dimethylamino-1-[4-(indolyl-morpholinyl)phenyl]butane-1 -keto/4,4'-bis(diethylamino)benzophenone, 2-(4-methylbenzyl)-2-didecylamino-1-[4-(N-morpholinyl) Phenyl]butan-1-one/4,4'-bis(diethylamino)dibenzophenone, etc. 'where' is 2-phenylindenyl-2-dimethylamino-1-[4-( Ν-morpholinyl) phenyl]butan-1-one/4,4'-bis(diethylamino)benzophenone, 2,4-bis(trichloroindenyl)-6-mallowyl-1 , 3, 5-three tillage / 4, 4,-bis(diethylamino) dioxin, 2-(4-methylbenzyl)-2-dimethylamino-1-[4-( ^-morpholinyl)phenyl]butan-1-one/4,4'-bis(diethylamino)dibenzophenone is preferred. When the oxime (E) photopolymerization initiation aid is used, it is preferably used in an amount of from 1 to 1 part by mass per 1 part by mass of the (D) photopolymerization initiator, particularly preferably 0.01. It is more preferably 5 parts by mass. The color hardening composition of the present invention may further contain (F) a solvent. Examples of the (F) bathing agent include ethers, aromatic hydrocarbons, ketones, alcohols, esters, and guanamines. Examples of the ethers include tetrahydrofuran, tetrahydropyran, 1,4-dioxane, ethylene glycol monoterpene ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, and ethylene glycol. Monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethyl ether diethyl ether, diethylene glycol dipropyl ether, two Ethylene glycol dibutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether ethyl 320502 61 200916953 acid vinegar, methyl cellosolve acetate vinegar (methyI ceil〇s〇lve North also (4), = base cold fiber acetate, ethyl carbitol acetate, butyl carbitol acetate, glycol ether acetate, methoxybutyl acetate, methoxy acetate Examples of the aromatic hydrocarbons include benzene, fbenzene, xylene, 1,3,5-dimethylbenzene (mesitylene), and the like. Examples of the aromatic hydrocarbons include esters, anisole, phenethyl ether, and methylanisole. Examples of the ketones include acetone, 2-butanone, 2-heptanone, 3-heptanone, 4-heptanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexanone, and 4 Mercapto-2-pentanone, etc. Examples of the alcohols include, for example, methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, diacetone alcohol, glycerin, etc. Examples of the above-mentioned hydrazines include ethyl acetate. , n-butyl vinegar acetate, isobutyl ketone acetate, formic acid pentyl acetate, isoamyl acetate, butyl propionate, isopropyl acetonate, ethyl butyrate, butyric acid butyrate, vinegar, lactate , lactic acid ethyl acetate, methyl oxyacetate, oxyacetic acid ethyl vinegar, oxyacetic acid butyl vinegar, methoxy acetic acid methyl, methoxy acetic acid B: ?, ethoxy acetic acid methyl vinegar, Ethoxyacetate acetoacetate: methyl 3-oxypropionate, ethyl 3-oxypropionate, methyl methoxypropionate, ethyl 3-methoxypropionate, 3-ethoxylate Methyl 3-, 3-methoxypropanoate, methyl 2-hydroxypropionate, ethyl 2-oxypropionate, propyl 2-methoxypropionate, methyl 2-methoxypropionate , 2-ethyl methoxypropionate, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, 2-oxy-2-methyl Propyl acid propionate, 2-iodo-2-methylpropionic acid ethyl acetate, 2-methoxy Methyl 2-methylpropionate, 2-ethoxylate|ethyl methacrylate, 320502 62 200916953 methyl pyruvate, ethyl pyruvate, propyl propionate, methyl ethyl acetate, ethyl hydrazine &amp; Ethyl acetate, methyl 2-ketobutanoate (me thy 1 2 ~ 'oxobutanoate), ethyl 2-ketobutyrate, 3-methoxybutyrate t-acetate 3-methyl-3-oxime Butyl ketone, 7 - butyl vinegar, etc. - Examples of the above amides include N,N-dimethylformamide, N,I-mercaptoacetamide and the like. Examples of the other (F) solvent include, for example, N-methylpyrrolidine, disulfoxide, and the like. — A These (F) solvents may be used singly or in combination of two or more. Among the (F) solvents, a solvent containing propylene glycol monoterpene ether acetate, propylene glycol monomethyl ether, lactic acid ethyl acetonate or dipropylene g homopoly alcohol is preferably used. (F) The content of the solvent is preferably 70 to 90% by mass, and preferably 75 to 88% by mass, based on the mass of the curable composition, when the content of the solvent is in the above range. It is preferable that the in-plane uniformity at the time of coating is good, and that the color density at the time of forming the color filter is sufficient to exhibit good display characteristics. Further, (G) a surfactant may be contained. Examples of the (G) surfactant include, for example, a silica-based surfactant, a fluorine-based surfactant, and a fluorine atom-containing ketone-based surfactant. Examples of the above-mentioned anthrone-based surfactants include surfactants having a cerium oxide bond. Specifically, the product names are Toray ketone DC3PA, SH7PA, DC11PA, SH21PA, SH28PA, 29SHPA, SH30PA, polyether modified eucalyptus SH8400 (product of Toray ketone), KP32, KP322, KP323, KP324, KP326, KP340, KP341 (transfer 320502 63 200916953 products), TSF400, TSF4 (H, TSF410, TSF4300, TSF4440, TSF4445, TSF-4446, TSF4452, TSF4460 (products from GE Toshiba). Examples of the fluorine-based surfactant include a surfactant having a fluoroquinone chain, etc. Specific examples thereof include Fluorad FC430, FC431 (product of Sumitomo 3M Co., Ltd.), Megaface F142D, F171, F172, and F173. , F177, F183, F470, F475, R30 (products of Dainippon Ink Chemical Industry Co., Ltd.), Eft〇p EF301, EF303, EF351, EF352 (products of New Akita Chemical Co., Ltd.), Surflon S38 Bu 8382, 3 (:101, 8 ( : 105 (product of Asahi Glass Co., Ltd.), E5844C Daikin Institute of Precision Chemistry, BM-1000, BM-1100 (product of BM Chemie), etc. Examples of the surfactant include, for example, a surfactant having a siloxane coupling and a fluorocarbon chain. Specifically, for example, the product names are Megaface R08, BL20, F475, F477, and F443 (大曰本墨化学The above-mentioned surfactants may be used singly or in combination of two or more. The colored curable composition of the present invention may further contain an organic acid having a molecular weight of 1,000 or less. Examples of the organic acid include, for example, An organic acid disclosed in Japanese Laid-Open Patent Publication No. Hei No. 5-343631. Specific examples thereof include malonic acid, oxalic acid, a tartaric acid, glutaric acid, adipic acid, benzoic acid, citric acid, and iso-g-acid. For the big acid, citraconic acid, itaconic acid, mesaconic acid, fumaric acid, acrylic acid, methacrylic acid, among which malonic acid, oxalic acid, fumaric acid and citric acid are preferred. It is preferred to contain an organic acid having a molecular weight of 1,000 or less, which is preferable because it has a tendency to be more excellent. 64 320502 200916953 The color hardening composition of the present invention may further contain a filler: :: polymer compound other than resin, adhesive Promoters, antioxidants, and agents, anti-agglomerating agents, organic amine compounds, and (8) hardening additives. The monthly size f is filled with particles such as glass and oxygen. Examples of the polymer compound other than the (c) binder resin include an enol, a polyacrylic acid, a polyethylene glycol mono(tetra), a polyacrylic acid fluoroalkylsulfonium S, and the like. Examples of the above adhesion promoter include, for example, vinyltrimethoxy sulphur, vinyl triethoxy valence, vinyl ginseng (2-methoxyethoxy), and N-(2-aminoethyl) Base)_3—Aminopropylmethyldimethoxyxanthine, (tetra)-aminoethyl)|Silk-glycoloxy, 3-methylpropyltriethoxy-xanthine, 3-epoxypropyl Oxypropyltrimethoxy^^, 3-glycidoxymethyldimethoxymethane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxycarbazide, 3-gas Propylmethyldimethoxywei, 3'-chloropropyltrimethoxycarbazide, 3-methylpropionateoxypropyltrimethoxy(tetra), (tetra)propyltrimethoxydecane, and the like. Examples of the aforementioned antioxidants include, for example, 4,4,-thio-bis(6-t-butyl-3-methylphenol), triethylene glycol-bis[3_(3_t-butyl_5_) Methyl 4-(hydroxyphenyl)propionate], 1,6-hexanediol-bis-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], pentaerythritol _肆[3_(3,5_di-t-butyl-4-hydroxyphenyl)propionate], octadecyl_3_(3,5-di-t-butyl-4-ylhydroxyphenyl) Propionate, 1,3,5-trimethyl-2,4,6-gin (3,5-di-t-butyl-4-hydroxybenzyl)benzene, 2,6-di-third Butylmethyl g, 2, 6_ 320502 65 200916953 Dibutyl- 4-ethylate, 2,2-extension methyl bis(4-methyl-t-butylphenol), 4, 4'-sulfur Base-bis(3-methyl-6-tert-butylphenol), 4, 4^butylidene bis(3-indolyl-6-secondyl butyl), 1,1,3-parameter (2_ Methyl 4-(trans)-5-t-butylphenyl)butane, ^5-parade (4-hydroxyphenylhydrazino)benzene f and hydrazine [methyl-3-(3,5--- Second butyl _4, _ hydroxyphenyl propionate) decane and the like. Examples of the ultraviolet absorber include a benzotriazole system such as 2_(2-hydroxy-3-t-butyl-5-methylphenyl)-5-chlorobenzotriazole; 2-hydroxy-4- a benzophenone such as octyloxy or benzophenone; a benzoate such as 2,4-di-t-butylphenyl-3,5-di-t-butyl-4-hydroxybenzoate It is a triterpenoid such as 2-(4,6-phenyl-1,3,5-di-yt-2-yl)-5-hexoxyphenol. Examples of the aforementioned coagulant-preventing agent include sodium polyacrylate. By adding an organic amine compound, it is possible to prevent residue from being generated on the unexposed portion of the plate during development, and it is possible to impart a silly sound excellent in adhesion to the substrate.之 Examples of the aforementioned organic amine compound include, for example, n-propylamine, isopropylamine n-butylamine, isobutylamine, second butylamine, third butylamine, n-pentylamine dihexylamine=amine, n-octylamine, n-decylamine , monodecylamines such as n-decylamine, n-undecylamine, n-decene, alkylamine; cyclohexylamine, 2-methylcyclohexylamine, 3-methylmonocycloalkylamine; T丞衣己i A Ethylethylamine, =ethylamine, methyl-n-propylamine propylamine, -j-mu-j-third-di-n-butylamine, diisobutylamine, di-second butanamine,: n-pentylamine, one positive a dialkylamine such as an amine; 320502 66 200916953 a monoalkylmonocycloalkylamine such as methylcyclohexylamine or ethylcyclohexylamine; a dicycloalkylamine such as dicyclohexylamine; dimercaptoethylamine or fluorenyl Diethylamine, triethylamine, dimethyl-n-propylamine, diethyl-n-propylamine, decyl-di-n-propylamine, ethyldi-n-propylamine, tri-n-propylamine, triisopropylamine, tri-n-butylamine, triiso a trialkylamine such as butylamine, tri-t-butylamine, tri-t-butylamine, tri-n-pentylamine or tri-n-hexylamine; a dialkyl monocyclic ring such as dimethylcyclohexylamine or diethylcyclohexylamine; Alkylamines; methyl dicyclohexylamine, ethyl dicyclohexylamine, Monoalkyldicycloalkylamines such as cyclohexylamine; 2-aminoethanol, 3-amino-1-propanol, amidino-2-propanol, 4-amino-1-butanol, 5- Monoalkanolamines such as amino-p-pentanol and 6-amino-1-hexanol; monocycloalkanolamines such as 4-amino-1-cyclohexanol; diethanolamine, di-n-propanolamine, a dialkanolamine such as diisopropanolamine, di-n-butanolamine, diisobutanolamine, di-n-pentanolamine or di-n-hexanolamine; a dicycloalkanol such as bis(4-cyclohexanol)amine Amines; triolamines such as triethanolamine, tri-n-propanolamine, triisopropanolamine, tri-n-butanolamine, triisobutanolamine, tri-n-pentanolamine, tri-n-hexanolamine; 3-amine 1,2-propanediazine, 2-amino-1,3-propanediol, 4-amino-1,2-butanediol, 4-amino-1,3-butanediol, 3- Diammonium-1,2-propanediol, 3-diethylamino-1,2-propanediol, 2-diaminoamino-.1,3-propanediamine, 2-diethylamino-1, Amino diols such as 3-propanediol; amino-alkylcycloalkanes such as 4-amino-1,2-cyclohexanediol, 4-amino-1,3-cyclohexanediol; Amine group-containing cycloalkanone 67 320 such as cyclopentanone methanol or 4-aminocyclopentanone sterol 502 200916953 Methanol; acetocyclohexanone methanol, 4-aminocyclohexanone methanol, 4-dimethylaminocyclopentane methanol, 4-diethylaminocyclopentanol, 4-dimethylamine An amine group-containing ring-burning methanol such as cyclohexane sterol or 4-diethylaminocyclohexanol; /5-alanine, 2-aminobutyric acid, 3-aminobutyric acid, 4- Aminobutyric acid, 2-month-based isobutyric acid, 3-aminoisobutyric acid, 2-aminopentanoic acid, 5-aminopentanoic acid, 6-aminohexanoic acid, :!-aminocyclopropane Aminocarboxylic acids such as carboxylic acid, acetocyclohexanecarboxylic acid, 4-aminocyclohexanecarboxylic acid; aniline, o-methylaniline, m-nonylaniline, p-nonylaniline, p-B Aniline, p-n-propylaniline, p-isopropylaniline, p-n-butylaniline, p-t-butylaniline, 1-naphthylamine, 2-naphthylamine, n,N-didecylaniline , aromatic amines such as diethylaniline, p-nonyl-N'N-didecylphenylamine; o-aminobenzyl alcohol, m-aminobenzyl alcohol, p-aminobenzyl alcohol, p-dimethyl Aminobenzyl alcohols such as aminobenzyl alcohol and p-diethylaminobenzyl alcohol; o-aminophenol, m-aminophenol, p-amino group , p-dimethylaminophenol, p-monoethylamine, and the like; 'm-aminobenzoic acid, p-aminobenzoic acid, p-dimethylaminobenzoic acid, pair' An aminobenzoic acid such as diethylaminobenzoic acid or the like. The above (8) hardener refers to, for example, a compound which can be reacted with (6) a carboxyl group in a binder resin by heating and (C) a binder resin, and a compound which can be hardened by a single polymerization to form a coloring pattern. Wait. The compounding compound may, for example, be an epoxy compound or an oxocyclic ring compound (Qxetane), and among them, an oxetane compound is preferably used. Here, examples of the epoxy compound include, for example, double-spectrum A-based epoxy tree 320502 68 200916953 fat, hydrogenated bisphenol A-based epoxy resin, bisphenol^^ epoxy resin-acid varnish--(8) type tree ^Hydrogenation double: family epoxy gambling, alicyclic epoxy resin, other aromatic oxypropyl acetonide wax, epoxy propylamine resin, epoxy ^ or bismuth oxide resin brominated derivatives , ring '45⁄4 milk resin, other than the aliphatic, alicyclic or aromatic ring ^ 曰 ^ ^ 臭 臭 臭 衍生物 衍生物 derivative (co) epoxide, isoindole ( ==, Ding a (4) polymer, an epoxide, a triglycid, and an isocyanurate of a dilute (meth)propionate, and an oxetane compound. Dioxetane, -toluene dioxetane, adipic acid bismuth bis-p-butyric acid, dioxetane, cyclohexanate dioxetane, color hardening of the present invention When the composition contains an epoxy compound, an oxygen: a baking compound or the like as a curing agent, it may contain an epoxy group or an oxetane which can make an epoxy compound. The oxetane skeleton is subjected to ring-opening polymerization. Examples of the compound include a polybasic acid, a polybasic acid-reducing liver, an acid generator, and the like. Examples of the polycarboxylic acid include citric acid, 3, 4 _ Dimercaptoic acid, isodecanoic acid, p-citric acid, pyromellitic acid, trimellitic acid, hydrazine, m naphthalene tetradecanoic acid, 3, 3', 4, 4'-diphenyl fluorenone tetraquinone An aromatic polybasic acid such as acid; succinic acid, glutaric acid, adipic acid, hydrazine, 2, 3, 4-butane tetradecanoic acid, maleic acid, fumaric acid, itaconic acid and other aliphatic polybasic acids; Hydrogen donating acid, 3,4-mercaptotetrahydroauric acid, hexahydroisodecanoic acid, hexahydropyridinic acid, 1,2,4-cyclopentanetricarboxylic acid, l 2,4-cyclohexane Formic acid, cyclopentane 69 320502 200916953 tetracarboxylic acid, 1,2,4, 5-cyclohexanetetradecanoic acid and other alicyclic polybasic acids, etc. Examples of Tanabata yuan 酉 liver articles can be enumerated as domic anhydride, benzoic acid Aromatic polybasic acid such as formic anhydride, phthalic anhydride, 3, 3', 4, 4,-dibenzophenone tetraphthalic acid dianhydride; itaconic anhydride, succinic anhydride, citraconic anhydride, twelve carbon Alkenyl succinic anhydride An aliphatic polybasic acid anhydride such as tricarballylic anhydride, maleic anhydride, 1,2,3, 4 butanic acid dianhydride; /, hydrophthalic anhydride 3' 4-dimethyltetrahydrogen anhydride, ι 2 , 4-cyclopentane triterpenic anhydride 1 ' 2, 4 cyclohexane bismuth anhydride, cyclopentane tetracarboxylic acid dianhydride, 1,2'4,5-cyclohexane tetracarboxylic dianhydride, 5_ N-alkene 2,3-dicarboxylic anhydride

(norbornene 2, 3-dicarboxylic anhydride, also known as HIMIC

Anhydride) An alicyclic polybasic acid such as nadiic acid anhydride (nadie fused to him), ethylene glycol trimellitic acid g anhydride, glycerol trimellitic acid § anhydride, and the like. Months can be used as an epoxy resin hardener and sold on the market. Examples of the &amp;oxy resin hardener include AMKA Hardener HH and faint 700 (all of which are manufactured by Shin-Nippon Chemical Co., Ltd.). The hardeners may be used singly or in combination of two or more. ^Using the colored hardening composition of the present invention to form a colorless device, the color hardening composition of the substrate is slaughtered. The second layer:: upper layer (::; = ^ removes volatile components such as an agent to form a color 320502 70 200916953 f, and exposed to the colored layer by a light mask, and developed, if necessary, heated by the light lithography; or using an inkjet skirt to color the hardening composition; k, on the substrate or another An inkjet method in which a volatile component such as a solvent is removed from a resin layer to form a coloring layer, and is cured by at least one of heating or exposure. The color filter 2 obtained above contains a pattern. A liquid crystal display device can be obtained by using the above-mentioned coloring effect. By using the colored curable composition of the present invention, it is possible to produce a color filter which is excellent in heat resistance and graininess and which does not have reduced light resistance and contrast. The present invention is described in detail by the following examples, but the present invention is not limited to the scope of the examples. The color hardening composition of the present month is (A) The formula (1) used for the colorant is not the same. For the production method of the green compound, JP-A-63-306566, JP-A-63-141982, JP-A-No. 474, JP-A No. 2-282386, JP-A-4-39361, Japan, Kaiping 5-- It is produced by the method described in the publication No. 222302, Japanese Patent Application Laid-Open No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei. The compound of the formula (1-1) was synthesized in a four-necked four-necked flask, and 9.29 g (2 mmol) of 3,6-difluoro 4' 5-bis(p-nonyloxy) was placed. a benzyloxy) ugly nitrile, 〇. 59g (6_u of 320502 71 200916953 anhydrous chlorinated ketone, and 2 〇 ml of benzonitrile, reacted at 1751 for 12 hours. After the reaction is terminated, the reaction mixture is put into In the sterol, the solid matter to be produced was first washed with methanol and then with water, and dried under reduced pressure to give a green compound (yield: π. 1%). The obtained green compound was dissolved in ethyl lactate, and the visible light absorption spectrum was measured, and the maximum absorption wavelength was 654. Onm, Mohr absorption The coefficient (ε) is 1·〇26xl〇5. Synthesis Example 2 <Synthesis of Colorant (Α-2)> Synthesis of a phthalocyanine compound represented by Formula (1-14) In a 100 ml four-necked flask, 7.83 is placed. g (20_ol) of 3,4,6-trifluoro-5-(2-mercapto-6-fluorenylethoxycarbonylphenoxy)phthalonitrile, 〇. 94 g (6 mmol) of tri-glycine, And 25 ml of benzoquinone was reacted for 4 hours at 175. After the reaction was terminated, the insoluble matter was filtered, and the solvent was distilled off and washed twice with 200 ml of sterol at 60. The green compound of the objective compound (yield 54.2%) was obtained. The obtained green compound was dissolved in ethyl lactate and the visible light absorption spectrum was measured. The maximum absorption wavelength was 714. 〇nm, and the molar absorption coefficient (ε) was 1·055×l05. 'Synthesis Example 3 <Synthesis of Colorant (A-3)> Synthesis of Barbituric Acid Azo Dyes represented by Formula (7-4) 300 g of water was added at 30 δ (61 〇υ 式 (35) After the 2, 2, monobenzidine disulfonic acid (containing 30% water) is shown, it is adjusted to pH 7 to 8 using an aqueous solution of 3〇% hydrogen oxygen 320502 72 200916953 under ice cooling. It was carried out under ice-cooling. 12.6 g (183 mmol) of sodium nitrite was added and stirred for 30 minutes. After adding 38. lg of 35% hydrochloric acid to a small amount of brown to make it a brown solution, it was mixed for 2 hours. 61 mmol) of the decylamine sulphuric acid was dissolved in 57.4 g of water to prepare an aqueous solution, and the aqueous solution was added to the reaction solution to "distract" to obtain a suspension containing diazolium salt.

After adding 372 g of water to N'N-monomethylbarbituric acid of formula (36) of ig.6 g (i46 mm〇i), it was adjusted to pH 8 with ice-cold 30% aqueous sodium hydroxide solution. 9.

~ The following knowledge is carried out under ice cold. After the above-mentioned barbituric acid alkaline water was stirred and turned into a colorless liquid at night, the aqueous solution of cerium 3 (10) was adjusted to pH 8 to 9' while a suspension containing a heavy nitrogen rust salt was added dropwise by a pump. Addition: After completion, stirring was further carried out for 3 hours to obtain a yellow suspension. The azo compound represented by the formula (37) was obtained by subjecting the color solid obtained after the completion of the mixture to 6 (rc, to afford (2), yield: 34%).

(37) 320502 73 200916953=In the flask with cooling tube and (4) device, add azo compound of ((4)-), chloroform of 5〇g, and ',,-f base ketone amine' The temperature below 2Gt, with her: ί ^ : Asia ^ 醯 chlorine 6g (5) coffee. 1). After the completion of the dropwise addition, the temperature was raised to 50 ° C, and the reaction was carried out for 5 hours. (4) Cooling to 2 G ° C. The cooled reaction solution was maintained at a temperature of 2 (rc or less) while stirring, while adding 3 g (曰20 mmc) of the 3-aminophenylbutane and 1 () g (1 () 3 mmGi). After the mixture 1 of triethylamine was stirred at the same temperature for 5 hours, it was reacted. Subsequently, the obtained reaction mixture was evaporated to remove the solvent using a rotary emulsifier, and a small amount of methanol was added thereto to vigorously stir. The mixture was added to a mixture of 29 g of acetic acid and ion-exchanged water under stirring to precipitate crystals. The precipitated crystals were collected by filtration, washed thoroughly with ion-exchanged water, and dried under reduced pressure at 6 Torr to give 6 g (yield: yield: 78%) of the azo compound of the formula (7-4).

With respect to the azo compound obtained in the present synthesis, LC-MS analysis was carried out under the following conditions. Device: Agi lent 1100 (Agi lent Technology company wears σ) Detector · UV detector: 254nm 320502 74 200916953 Separation tube: Sumipax 0DS (product of Sumitomo Chemical Co., Ltd.) Eluent solvent: in water-acetonitrile mixed solvent The solvent obtained by adding 0.1% trifluoromethyl acetic acid is the content of each azo compound, which is calculated from the peak and the area. The result is that the azo compound represented by the formula (7-4) is a compound having a molecular weight of 940, and its area percentage value with respect to the total peak area is 98%. Synthesis Example 4 <Synthesis of Colorant (A-4)> Synthesis of Pyridone Azo Dyes of Formula (16) Addition of 3000 g of water to l〇〇g (203 mmol) of the formula (35) After 2'-benzidine disulfonic acid (containing 30% water), it was adjusted to pH 7 to 8 using a 30% aqueous sodium hydroxide solution under ice cooling. The following operations are performed under ice cooling. 56 g (812 mmol) of sodium wallite was added and stirred for 30 minutes. 15 g of 35% hydrochloric acid was added in small portions, and after making it into a brown solution, it was stirred for 2 hours. 38 g (406 mmol) of decylamine sulfuric acid was dissolved in 38 〇g of water to prepare an aqueous solution, and this aqueous solution was added to the reaction solution, and the mixture was mixed to obtain a suspension containing a diazonium salt. After adding 100 g of water to 76 g (426 mmol) of the ethyl-3-cyano-4-indolyl-6-pyridylpyridin-2-one represented by the formula (38), 30% of the solution was used under ice cooling. The aqueous sodium hydroxide solution was adjusted to pH 8 to 9.

The following operations are carried out under ice cooling. After stirring the above basic aqueous solution of pyridone to make it a colorless solution, adjust the solution to 3 to 8 with 3〇% sodium hydroxide water 320502 75 200916953, and pour the suspension containing the heavy nitrogen rust salt with a pump. Turbidity. After the dropwise addition (4) was stirred for another 3 hours, a yellow suspension was obtained. The resulting yellow solid was filtered and dried under reduced pressure of &lt;RTI ID=0.0&gt;&gt;

(39) In the flask equipped with the cooling tube and the sifting device, the azo compound represented by the above formula (39), 5 gram of chloroform, and 2.4 g (33 mm 〇l) of N, are placed. N-dimercaptocaramine was maintained at a temperature below 2 ° C while stirring, while 7 g (59 mmol) of sulfite gas was added dropwise. After the completion of the dropwise addition, the temperature was raised to 50 ° C, the reaction was maintained at this temperature for 5 hours, and then the cold portion was brought to 20 C. The cooled reaction solution was maintained at 2 Torr with stirring. A mixture of 4 g (30 mmol) of 1,5-didecylhexylamine and 12 g (119 mmol) of triethylamine was added dropwise at the same temperature. The reaction was then stirred at this temperature overnight. Then, the obtained reaction mixture was subjected to a steam eliminator to remove the solvent, and then a small amount of sterol was added and stirred vigorously. The mixture was added to a mixture containing 29 g of acetic acid and 300 g of ion-exchanged water under stirring to precipitate crystals. The precipitated crystal was collected by filtration, washed thoroughly with ion-exchanged water, and dried under reduced pressure at 60 ° C to obtain 6 g (6 mm ,l, yield: 8 〇 0 / 〇) of the azo represented by the formula (16). Compound. 320502 76 200916953

The azo compound obtained in the present example was subjected to structural analysis in the same manner as above, and the azo compound represented by the formula (16) was measured as an area percentage value of the compound having a molecular weight of 944 with respect to the total peak area. 58.3%. 1%。 The area ratio of the total peak area is 30. 1%. Synthesis Example 5 <Synthesis of Resin (C-1)> In a flask of 1 L capacity equipped with a stirrer, a thermometer, a reflux cooling tube, a dropping funnel and a gas introduction tube, 333 g of propylene glycol monoterpene ether acetate was introduced. Then, nitrogen gas was introduced into the flask through a gas introduction tube, and the atmosphere in the flask was replaced with nitrogen. Then, after the solution in the flask was heated to 100 ° C, dicyclopentyl methacrylate from 320502 77 200916953 22 \〇g (〇.10 mol) was added dropwise to the flask using a dropping funnel over 2 hours. (FA-513M; Hitachi \匕成工业股份有限公司), 7〇.5g (0.40 mol) of benzyl benzoate 43· 〇g (〇. 5 mol) of methacrylic acid, 3. 6 bogey A mixture of azobisisobutyronitrile and 164 g of propylene glycol monomethyl ether acetate was added, and after stirring, stirring was continued for 5 hours at TC. After the stirring was terminated, air was introduced through a gas introduction tube. In the flask, after the atmosphere in the bottle was made into air, methacrylic acid was added to the flask (relative to the methacrylic acid used in the reaction and 5 mol% in terms of mole percentage)] Glycidyl acrylate, ruthenium 9 g of dimethylaminomethyl age, and 145 g of hydrogen were brewed, and the reaction was continued for 6 hours at U (rc) to obtain a resin ((&gt;1). The solution (solid content: (10) 5 mass%, acid value: 80 mgKOH/g). Here, the acid value means neutralizing the polymer lg having an acid group such as a carboxylic acid. The measured value of the amount of potassium hydroxide (mg) required is generally determined by titration with an aqueous solution of potassium hydroxide having a known concentration. The obtained polystyrene-equivalent weight average molecular weight of the resin (C-1) is 9,000 〇. The polystyrene-equivalent weight average molecular weight of the above (C-1) binder resin was measured by the GPC method under the following conditions. Apparatus: HLC-8120 GPC (product of Tosoh Corporation) Column: TSK-Gel G2000HXL Column Temperature: 40 ° C Solvent: tetrahydrofuran flow rate: 1. Omi/miin 320502 78 200916953 〇.001 to 0.01 mass

Injectable amount of solids in the test liquid: 5 0 # 1 Detector: RI, F-4, F-1, abbreviated as standard material for calibration: TSK standard polystyrene A-2500, A-500 (east The product used in the present embodiment is as follows. In the following, (A-1) coloring agent: the coloring matter (A-2) obtained by Synthesis Example 1 : the coloring matter obtained in Synthesis Example 2 ( A-3) Colorant: Pigment (A-4) obtained by Synthesis Example 3 Colorant: Pigment (A-5) obtained by Synthesis Example 4 Colorant: Compound represented by the formula (29) (Cyanine dye, NK- 3212: Linyuan Biochemical Research Institute), ''

(29) (A-6) Colorant: Compound represented by formula (41) (FB-22: phthalocyanine dye from Yamada Chemical Co., Ltd.)

(A-7) Colorant: Compound represented by formula (42) (FB-24: phthalocyanine dye of Yamada Chemical Industry Co., Ltd.) 79 320502 200916953

GCHaCFaCFaCFaCFgH (42) HF2CF2CF2CF2CH2C〇/

, 〇CH2CF2CF2CF2CF2H (Bl) Photopolymerizable compound: DPHA (product of Nippon Kayaku Co., Ltd.) (B-2) Photopolymerizable compound: A-GLY_3E (product of Shin-Nakamura Chemical Industry Co., Ltd.) 'Ethylene oxide (3) Triglyceride (C-1) binder resin··Resin obtained in Synthesis Example 5 (c-丨) (solid content 38.5 berger% of 丙 酉 曱 曱 曱 曱 ) ) )) (D-1) Photopolymerization initiator: 2-monomethyl-2-ylamino-1-[4-(N-?-)-based base] butyl-1-(E-1) photopolymerization initiation aid: 4, 4,-bis(diethylamino)benzophenone (F-1) solvent: propylene glycol monoterpene _ (F 2) &gt; gluten. 3 - ethoxypropionic acid B g (G-1 Surfactant: Megaface F475 (product of Dainippon Ink Chemical Industry Co., Ltd.) (H-1) Hardener: Sumiepoxy ESCN-195XL-80 [o-nonanol novolak-type epoxy resin (product of Sumitomo Chemical Co., Ltd.)] Example 1 [Preparation of Colored Curable Composition 1] The following components were mixed to obtain a colored curable composition 1. (A-1) 7· 650 parts by mass (B-1) 4. 172 parts by mass (C-1) 8. 160 parts by mass (solid content converted value: 3.141 parts by mass) 80 320502 200916953 (Dl) 1.257 Quality (El) 0.236 parts by mass (Fl) 73.831 parts by mass (F-2) 4·150 parts by mass (Gl) 0. 004 parts by mass [formation of coating film] Next, the color obtained by the above-mentioned spin coating method is used. After the curable composition was applied onto glass (#1737: Corning glass), the volatile component was volatilized under the treatment for 3 minutes to form a colored curable composition film. After cooling, one line [wavelength: 365 nm] was irradiated onto the colored curable composition film to expose it. The light source of the i-line is illuminated by a parallel light beam using an ultra-high pressure mercury lamp. The amount of illumination light was 5 〇〇 mJ/cm 2 . Following, at 22 baht. The underarm was baked for 20 minutes to obtain a color-curable composition film having a film thickness of 2/m. [Evaluation 1] Evaluation of heat resistance The obtained color was measured for the color of the composition film (OSP-SP-200; manufactured by Olympus Co., Ltd.). Then, the obtained colored hardening composition is further heated in a furnace at a temperature of 23 (TC) for 120 minutes, and the color of the colored hardening composition film after heating is measured using the same one as described above. The result of finding the color difference (ΔEab*) after the addition is &amp; 6. The evaluation standard of the color difference is as follows: If the value of the color difference is almost invisible, the color filter is displayed as a color filter: △ Eab * If it exceeds 5 and is less than 5 (1), it can be seen that the hue is 320502 81 200916953 / still as a filter and the color is practically no problem; and △ (four) = above 10 is clear Look at the excellent phase change, as the grade of the filter problem. Qiao [Evaluation 2] Lightfastness evaluation is set on the color-curable composition film of the 4 color-blocking color film, the color optical lens L38, HqYA company products, can be cut off 38 {) Light below nm), and using a light resistance tester (SUNTEST CPS+: Toyo Seiki Co., Ltd.) to illuminate the light for 48 hours. : The chromaticity of the colored curable composition film after the irradiation is measured, and the color difference after the irradiation of the ruthenium is determined to be 〇. 6 The evaluation standard of the 〇 color difference is the same as the above, and when the (4) is 5 or less, the phase change is not observed. As a color filter, it shows good characteristics; when △Eab* exceeds 5 and changes in several hue, it can be seen as a color filter with no problem in practical use; AEab氺 is in ^ The above can be seen as a clear hue change, as a problem with the color filter system. _, inch · [Evaluation 3] Solvent resistance evaluation material = color hardening composition measured by the same color measuring instrument as above, followed by impregnation of the obtained color hardening composition film to maintain 23t :, - The chromaticity of the color-hardening composition film after the secondary stain is determined by the same method, and the result of the color difference between the palace and the main is i. The evaluation standard of the sigh color difference is almost not good when the 氺 touch is below 5, 320502 82 200916953 Aihua, as a color filter showing good characteristics. When the volume is below 10, it can be seen that several hues change. ::Two: More than 5 and in the practical problem-free level; AEab* If one, as a color change of the color, clear 4A & above, then you can see [Evaluation 4] Contrast Comment: The level of the problem. The contrast value of the resulting color-hardening composition film (CT-1 type, the pot 坂 Thunder eight π system is measured by comparison, the result is machine (four)) with a blank value The evaluation criteria for the contrast of the film of the sexual composition are as follows: If the contrast value is above the coffee, (4) the device shows good characteristics. Go to 斟/士, 1 马马色杂叮姜Γ + ratio exceeds (10) When the heart is below 8_, although I see a number of depolarizations, it is still used as a color filter in the practical problem of the temple level; if the contrast value is below the coffee, it can be seen (four); As a color filter, there is a problem level. Example 2 [Modulation of Colored Curable Composition 2] Except that it will be implemented In the same manner as in Example i, the coloring agent (the Α_η was changed to the coloring agent (Η) was mixed in the same manner as in Example i. The color of the waiter [formation and evaluation of the coating film] was the same as in Example 1. In the method, a color-hardening composition film having a film thickness was obtained, and as a result of evaluation, the color difference of the heat resistance evaluation was 4.8, the color difference of the light resistance evaluation was 3.5, the solvent resistance was evaluated 0.8, and the contrast value was 9057. Ba to Ma 320502 83 200916953 f Example 3 [Preparation of colored curable composition 3] The following components were mixed to obtain a colored curable composition 3. (A-1) 4. 590 parts by mass (A-3) 3. 060 parts by mass (β-ί) 4. 712 parts by mass: 3·141 parts by mass) (C-1) 8. 16 parts by mass (solid content converted value (D-1) 1.257 parts by mass (Ε-1) 〇 236 parts by mass (F-1) 73.831 parts by mass (F-2) 4. 150 parts by mass (G-1) 〇_ 〇〇 4 parts by mass [formation and evaluation of coating film] The same as in the first embodiment By the method, a film of a colored stone having a film thickness was obtained, and as a result of evaluation, the color difference of the heat resistance evaluation was 3 G2.6, and the color difference of the light resistance evaluation was 〇7. Color difference of solvent resistance evaluation 1. 8. The contrast value was 8971. * Example 4 [Modulation of colored curable composition 4] ” $ (A-3) of Example 3 was changed to (A-4) The mixture was mixed in the same manner as in Example 14 and the yoke yoke 1 to obtain a colored curable composition 4. [Formation and Evaluation of Coating Film] A film thickness of 2 / was obtained in the same manner as in Example 1. The color of the zm was hardened, and the film was evaluated. The color difference of the heat resistance evaluation was 84 320502 200916953 3. The color difference of the light resistance evaluation was 4. 3 'the contrast value was g232. Example 5 The chromatic aberration of the evaluation of the solvent resistance was [modulation of the colored curable composition 5], and the same procedure as in Example 1 was carried out except that (A-5) was changed to (A-5). The mixture was colored to obtain a curable composition 5. [Formation and Evaluation of Coating Film] A colored hardening composition having a film thickness of 2 #m was obtained in the same manner as in Example 1, and the color difference was evaluated as a result of evaluation. The color difference of the light resistance evaluation was 2.8, the color difference of the solvent resistance evaluation was 2·β, and the contrast value was 9151. Example 6 [Preparation of the colored curable composition 6] The following components were mixed to obtain a colored curable composition 6 . (8-1) 4.590 parts by mass (Α-3) 3. 060 parts by mass (Β-2) 4. 319 parts by mass (C-1) 7. 139 parts by mass (solid content converted value: 2.749 parts by mass) (D-1) 1.257 parts by mass (Ε-1) 0.236 parts by mass (F-1) 73. 831 parts by mass (F-2) 4. 150 parts by mass (G-1) 0.004 parts by mass (Η-1) 0 785 parts by mass 320502 85 200916953 [Formation and evaluation of coating film] According to the composition of the same chemical composition as in Example 1, an evaluation method was carried out to obtain a color hardness of 2.9, and the color difference of light resistance was evaluated. ^Results 'The heat resistance was evaluated with a color difference of 1.6 and a contrast value of 8652. The color difference of the evaluation of the solvent resistance of ',, and 2.4' was Comparative Example 1 [Modulation of the coloring hardenable composition 7] except that the method of Example 1 was used (A, the same method as the embodiment, and more (A-6) In the following, the coloring curable composition 7 was obtained according to the [formation and evaluation of the coating film]%. The evaluation of the coating was carried out according to the same formula composition film as in Example 1. (4) The color is hard ΟΛ 1 _ , . . . ^ Μ , 其 其 , 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热 耐热Comparative Example 2 [Preparation of Colored Curable Composition 8] The coloring was carried out in the same manner as in Example 1 except that (A-1) of Example 1 was changed to (A-7). Sturdy composition 8. [Formation and evaluation of coating film] A film having a film thickness of a color hardening composition was obtained in the same manner as in Example 1, and the result of evaluation was evaluated. 3, the color difference of the light resistance evaluation is 6.2, the color difference of the solvent resistance evaluation is 15.1, the contrast value is 8725. Example 3 320502 86 200916953 [Modulation of Colored Curable Composition 9] Except that the method of Example 3 (A- π proud ", according to the same method as in Example 1, 3 persons &quot; is θ (α ~ 6) The rest of the composition was obtained by the [formation and evaluation of the coating film] to obtain a colored curable composition 9. In the same manner as in Example 1, a film of a color hard film having a film thickness of ? was obtained, and the result was evaluated. Heat resistance evaluation = chromatic aberration of more nm evaluation is 7.5, solvent resistance evaluation ^ 3 〇. 6, contrast value is 812 〇. Color difference is [schematic description] No. [Main component symbol description] None. 320502 87

Claims (1)

200916953 X. Patent application scope: 1. A coloring hardening composition containing (1) a coloring agent and (8) a polymerizable compound, wherein (A) the coloring agent contains the coloring matter represented by the formula (1), A (1) In the formula (1), k represents an integer of ruthenium or osmium, M represents a metal or a metal oxide; 'substituents in the group; A1 to each independently represent a hydrogen atom, a _ atom, or a selected formula ( 2) a substituent in the substituent group shown in (5); wherein at least 1 to 8 in a1 to VIII are represented by a substituent selected from the formula (2) to (5), r - Θ ' /= V (COOR11) )e1 (2) ^=^(COO(CH2CH2CH2〇)hR,.1G· ;/^(C00(CH2CH20)fR^)gi Xj2qz (3) -G4 (5) In the oxygen atom formula (2) to (5), (^ to G4 each independently represent a sulfur atom or a -N(R14)- group; R&quot; represents a hydrogen atom, or a linear or branched chain to a saturated aliphatic group of 6 Hydrocarbyl group; inverse number 1 K11 to K13 each independently represent a hydrogen atom, a carbon number which may have a substituent of 6 S 2G, or a linear or branched chain number 320502 88 200916953 I- is 1 a saturated aliphatic hydrocarbon group of up to 8; each of J to J3 independently represents a halogen atom, a linear or branched chain having a saturated aliphatic hydrocarbon group having a carbon number of from 4 to 4, or an alkoxy group having a carbon number of from 1 to 4; L represents a halogen atom, a linear or branched chain, a saturated aliphatic hydrocarbon group having a carbon number of 4 to 4, or an alkoxy group of the carbon number of 1 to 4, el gl and 11 each independently representing an integer of 丨 to 5 E2, g2, and i2 each independently represent an integer of Q to 5 "only" the sum of 61 and e2, and the sum of §2, U and i2; an integer of 5 or less. f&amp;h each independently represents: T to An integer of 6; j represents an integer of 1 or 2.] 2. A color-hardening composition as described in the patent application scope, wherein the substitution shown by '3 C in the group 3. If the patent application scope is the fluorine atom. ^ 碉 The second color of the sclerosing composition of the second sulphur composition 4 () is the 'G1 oxygen atom. q goods / composition, item to item 3 of the color hardening dye, pyridin 1, (A) coloring agent complex containing barbituric acid azo wood, ° pyridine ji azo a nine-network dye and a phthalocyanine _=^^ 嗣 嗣 azo dye, such as 5. at least one dye in the patent application group. e, a nitrogen dye is a dye represented by the formula (7), 320502 89 * 1 200916953 *N=N- Rv!-7R35r42 R41 R33 A R32 d r37 UD^4n "h R R39 R4° u ^f (7) Yin, T! and each independently represent an oxygen atom or sulfur 4 'N^N &gt;-T2 (7) R3] to saturated aliphatic:: a hydrogen atom, a carbon number of 1 to 1 and an aliphatic hydrocarbon group, and the carbon number substituted by the secondary soil is "to 10" rhyme: to 〗. The carbon number in which the carbon number of the aliphatic group is oxy substituted is 丨", the thioalkyl group of 8 to 8 is substituted; the aryl group or the number of broken atoms is 2 hydrogen atoms, s atom = In addition to the aliphatic hydrocarbon group, the (tetra) atom substituted carbon: in the r; xn, the carbon number is ^ alkoxy ' '月女尹' 酉 &amp; base, or N-substituted amine sulfonyl]. A colored hardening composition according to item 4 of the patent application, wherein the &quot;bisacridone azo dye is a dye represented by the formula (8), Rf R21 R23 OH 0==\ /—·Ν=Ν-Ζ (8) [In the formula (8), Z represents 1 or 2 selected from a carboxyl group, an amine sulfhydryl group, a % acid group, an amine sulfonyl group and N a phenyl group substituted with at least one group of the aminesulfonyl group, or a naphthyl group having 1 or 3 groups selected from the group consisting of carboxyl groups, 320502 90 200916953; 珉R21 represents a hydrogen atom, a linear or branched chain or cyclic saturated aliphatic hydrocarbon group having 10 carbon atoms, a carboxyl group, or a trifluoromethyl group; Α ΓΛ 气 气 气 说 说 说 说 说 说 月 月 月 月 月 月 月 n n n n n Any of an amine, a sulfonic acid group, and an ammonium salt, a lithium salt, a sodium salt or a potassium salt of each of the above substituents; ', : a hydrogen atom, a carbon number which may be substituted, and a linear chain of 10 to 10 2 chain or cyclic saturated aliphatic hydrocarbon group, substituted aryl of charcoal ' to 30, substituted aralkylene having 7 to 2 carbon atoms, and slave number 3 to 20 The furnace is replaced by an atom, and part of the carbon is replaced by a heterogeneous soil, an amine methyl sulfhydryl group, an N-substituted amine carbhydryl group, a lipid (4) oxy group which can be passed through 2 to 20, and can be substituted. = 7 to a base oxy group (IV), a substituted carbon number of 2 20, a substituted aliphatic group having a carbon number of 丨 to %, or a substituted aryl group having 6 to 30 carbon atoms, , and the compound (8) can form a polycondensation of a dimer or more at any position: specifically: the color hardening property of any of the items 1 to 6 of the range, and the composition, wherein the complex (C) Adhesive resin. 8. - The pattern 'is characterized by the use of the patented scope of the item to::: the color-hardening composition, by photolithography or inkjet method; Patent No. 8 of the Model Fan Park 320502 91 200916953 t case. 10. A liquid crystal display device characterized by having a color filter of claim 9th. 92 320502 200916953 VII. Designated representative map: There is no schema in this case. (1) The representative representative of the case is: (). (2) A brief description of the symbol of the representative figure: 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 5 320502