TW200907138A - Straight-type finish for synthetic fibers, processing method for false twisted textured yarns using same, and false twisted textured yarns - Google Patents

Abstract

A straight-type finish, which has improved storage characteristics and is capable of preventing synthetic fibers from becoming electrically charged and uneven dyeing from being generated, contains a smoothing agent and a functional improvement agent at specified ratios. A metal organic sulfonate of a specified type is contained at least as a part of the functional improvement agent at a specified mass % of the total.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a straight-type type treating agent for synthetic fibers, a method for treating synthetic fiber false twisted yarns using the same, and a synthetic fiber false twisted textured yarn. In the manufacture or processing of synthetic fibers, it is known that, for example, in the false twist processing of synthetic fibers, the synthetic fibers are easily electrostatically charged due to the friction of the synthetic fibers or the friction between the synthetic fibers and the guides. The occurrence of clustering failure, m-force change, broken wire, etc. caused by such static electricity occurs, and dyeing unevenness occurs at the time of dyeing due to such addition. In order to prevent such a disadvantage from occurring, a treatment agent for imparting smoothness or antistatic property to synthetic fibers is used in the production or processing of synthetic fibers. The present invention relates to a direct-use type treating agent for synthetic fibers in such a treating agent: a method for treating a synthetic fiber false twisted textured yarn using the same, and a synthetic fiber false twisted textured yarn obtained by the treating. x [Knowledge Technology] It is known that it is a treatment for imparting smoothness or antistatic property to synthetic fibers. It is known that 1) contains a straight number/~18 which is an alicyclic polycarboxylic acid and a carbon number Branched alcohol or alicyclic alcohol with a carbon number of 3~1G:: The purpose of the end-chain rate is above the alicyclic poly (4) =, (for example, refer to the special offer 1); 2) contains the fat a hydrocarbon monomer monomer;; ♦ a molecular weight of 20,000 to 1 million copolymers (for example, see 2 = 2); 3) contains _ oil, history (staudlnger) viscosity, : (two: 1 million ~ 70 ° 10,000 oil-soluble polymer and surfactant (for example, refer to Patent Document 3); 4) Containing a 1,2-epoxyalkane or a disc with a carbon number of 6 to 24 97112518 200907138 The compound of the (4) compound = the amount of the filament of the compound = 2 (refer to the patent document 4); 5) the vinegar compound containing the above, and the carbon number of the 2nd = and the high-grade alcohol 25 Ά 〇)) The turbidity of 5% or more of the turbidity is 401 or more and emulsifier of 8 〇C or less (see, for example, Patent Document 5). However, these conventional treatment agents have limitations due to their actual storage safety, and in particular, θ, electricity, and as a result, there is a problem that the synthesis fabric can sufficiently prevent the uneven dyeing of the synthetic fiber ribbon. (Patent Document 1) (Patent Document 2) (Patent Document 3) (Patent Document 4) (Patent Document 5) (Patent Document 5) [Patent Document 5] [Patent Document 5] Japanese Patent Laid-Open No. Hei No. Hei No. Hei 2-68367 Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. 5-9. Different from '#1 牮 牮 Γ Γ \ \ 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存 保存由此 由此 由此 由此 由此 由此 由此 由此 由此 由此 由此 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本It is a smoothing agent and functional composition of the two 97112518 200907138, and the function is one of the following: the part is particularly suitable for containing a specific ratio in a predetermined ratio. The invention is based on the invention: the invention relates to a synthetic fiber directly: it comprises a smoothing agent and a function-imparting agent, and the second is a whole (four) 9.5% by mass of smoothing agent and the overall 匕% The function of the agent, and the function of the agent. 5 to 15% by mass of the following J; the second part is composed of a metal compound of an organic sulfonic acid which is monolithic or not; [Chemical 1] R1 - S〇3

R2 — S〇

Μ1, RR. Alkene number 1 to 36 alkyl group, carbon number 2 to 24 alkenyl group, phenyl group, a phenyl group having a carbon number of 36, a naphthyl group, having a carbon number a calcined naphthyl group or a u-bis(alkyloxycarbonyl)-1-ethane group having a carbon group of 4 to 24; Μ: a metal having a divalent atomic value. Further, the present invention relates to a method for treating a synthetic fiber false twisted textured yarn, which is characterized in that the above-mentioned synthetic fiber of the present invention is used in a direct use type! For the synthetic fiber false twisted silk after the processing, it is attached in a manner of 1 to $% by mass. Further, the present invention relates to the use of the synthetic fiber false twist of the present invention. 97112518 8 200907138

Synthesis of the wire processing method _ false 捻 plus H: a direct-use type treatment agent for the synthetic fiber of the invention (referred to as the treatment agent of the present invention) by the smoothing agent and the machine furnace The treatment agent consisting of a solvent and a hydrazine is used as a function-imparting agent. The 77-series metallolithic acid metal compound represented by Formula 1. The organic sulfonic acid metal compound may be the same beauty at the same time, and the iT gate * may be the same as the r. As such a beauty, it is not: ethyl, propyl, butyl, pentyl, hexyl, heptyl, /, fluorenyl, undecyl, undecyl, tridecyl, tetradecyl , fifteen carbon, hexadeca, heptadecyl, octadecyl, ninth carbon, twenty carbon, twenty-two, twenty-two, twenty-three, twenty Tetracarbyl, heptacosyl, heptacarbyl, heptacosyl, dit8 octadecyl, octadecyl, tridecyl, triacontyl, decyl , tris-trimethyl, tri-tetramethyl, 35-carbon, tris/, succinyl, 2-mercapto-pentyl, 2-ethyl-hexyl, 2-propyl-heptyl, 2 ^-Butyl-octyl, 2-pentyl-indenyl, 2-hexyl-indenyl, 2-hexyl-undecyl, 2-octyl-dodecyl, 2-indolyl-tride Carbon group, 2_mercapto-14 nucleus, 2-undecyl-pentadecyl group, 2-dodecyl group to hexadecyl group, etc., having a carbon number of 1 to 36; 2) ethylene Base, propenyl, butenyl, pentenyl, hexenyl, heptenyl, octenyl, nonenyl, decenyl, decyl, decyl, dodecyl, ten Tri-breaking alkenyl, tetradecyl, fifteen-stone anti-smelt, hexadecene, hepta-carban, 9c-octadecenyl, octadecenyl, 9c, 12c-ten Octadenadienyl, 9c, 12c, 15c-octadecadiyl, 9c-eicosyl, 5, 8, 11, 14-eicosatetraenyl, 13c_ 97112518 9 200907138 Alkenyl, 13t-tetracosylalkenyl, behenyl, alkenyl, tetracosyl, and the like are 2 to 24 alkenyl groups; 3) phenyl; 4) nonylphenyl, ethyl Phenyl, propylphenyl, butylphenyl, hexylphenyl, octylphenyl, nonylphenyl, nonylphenyl, anthracenylphenyl, dodecylphenyl, tetradecyl Phenyl, pentadecenylphenyl, hexadecenylphenyl, heptadecylphenyl, octadecylphenyl, nonadesylphenyl, eicosylphenyl, twenty-one carbon Phenyl, behenylphenyl, docosaphenyl, tetracosylphenyl, pentadecylphenyl, hexadecylphenyl, heptacosylphenyl , octadecylphenyl, 29-carbonylphenyl, tridecylphenyl, tridecylphenyl, thirty Carbophenyl, tris-triphenyl, trimethyltetraphenyl, triphenylcarbylphenyl, trihexylphenyl, 2-mercapto-pentylphenyl, 2-B -hexylphenyl, 2-propyl-heptylphenyl, 2-butyl-octylphenyl, 2-pentyl-nonylphenyl, 2-hexyl-nonylphenyl, 2-heptyl- Undecylphenyl, 2-octyl-dodecylphenyl, 2-mercapto-tridecylphenyl, 2-mercapto-tetradecylphenyl, 2-J carbon- An alkylphenyl group having a carbon number of 1 to 36, such as a pentadecylphenyl group, a 2-dodecyl-hexadecylphenyl group; 5) a naphthyl group; 6) a methylnaphthyl group, Naphthyl, propylnaphthyl, butylnaphthyl, hexylnaphthyl, octylnaphthyl, nonylnaphthyl, decylnaphthyl, undecylnaphthyl, dodecylnaphthyl, tetradecyl Naphthyl, pentadecylnaphthyl, hexadecaonaphthyl, heptadecylnaphthyl, octadecylnaphthyl, pentadecenylnaphthyl, icosylnaphthyl, fluorene Naphthyl, dodecylnaphthyl, docosylnaphthyl, tetracosylnaphthyl, twenty-pentadenaphthyl, hexadecacarbonaphthyl, heptacosylnaphthalene Base, two Octacarbonaphthyl, 29-nonylnaphthyl, tridecylnaphthyl, 31-carbon 97112518 10 200907138 phenylmethyl, docosaphthyl, icosylnaphthyl, thirty Tetracarbonaphthyl, tripenthonocarbonaphthyl, trihexadecenonaphthyl, 2-indolyl-pentylnaphthyl, 2-ethyl-hexylnaphthyl, 2-propyl-heptylnaphthyl , 2-butyl-octylnaphthyl, 2-pentyl-indenylnaphthyl, 2-hexyl-indenylnaphthyl, 2-heptyl-undecylnaphthyl, 2-octyl-dodeca Naphthyl, 2-mercapto-tridecylnaphthyl, 2-mercapto-tetradecylnaphthyl, 2-undecyl-pentadecylnaphthyl, 2-dodecyl-ten An alkylnaphthyl group having a carbon number of alkyl groups such as a hexacarbenyl group; or 7) 1,2-bis(butyloxycarbonyl)ethane, 1'2-bis(octyloxy) a carbonyl group, a ethane group, a bis(undecyloxycarbonyl)-1-ethane group, etc., having a carbon number of 4 to 24, and an alkyl group ) 1- 1-B-based. Wherein, 2 and 2 are preferably an alkyl group having 6 to 22 carbon atoms, an alkylphenyl group having an alkyl group having 8 to 18 carbon atoms or an alkylnaphthalene having an alkyl group having 8 to 18 carbon atoms. base. Further, in the organic sulfonic acid metal compound represented by Formula 1, one of the ruthenium compounds is a metal having a valence of a divalent atom. w cites 镁, magnesium, calcium, strontium, strontium:

f, iron, wrong, drill, recorded, copper, zinc, etc., of which dance or magnesium is preferred. The organolithic acid metal compound shown in the present invention can be used alone or in combination of two or more kinds of organic acid-acid metal compounds, and can be used for example, for example, in the patent publication No. 2000-2041 93, etc. The corpse is synthesized by the method of 77 °. ^ 66 m At the weight of the organic sulfonic acid metal compound with ^#J ', the sigma-forming fiber bundles are bundled into a set of ancient 毺 π lack a research Xuan Yabei auxiliaries, used to make the 1 scared A compounding agent for homogenizing organic shale acid metal compound and Pingxing ten alpha agent 9 Chuan 2518 11 200907138 and the like. Examples of such a function-imparting agent include: 丨) polyoxyalkylene alkyl ether, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene oxide polyoxyalkylene monovalent sesame oil, polyoxygen oxide Alkylalkylamine ether sorbitan monolaurate, sorbitan trioleate, glycerol monolauryl ester, dilauryl dilaurate, partial esterification of 3 to 6-membered alcohol with fatty acid An oxide or a fully esterified product of a 3 to 6-membered alcohol of an alkylene oxide and an esterified product of a 3 to 6-membered alcohol and a hydroxy fatty acid. Non-ionic surfactants of the polyoxyalkylene polyol fatty acid ester type; 2) anionic surfactants such as organic fatty acid salts and organic phosphates; 3) lauryl tridecyl ammonium ethoxysulfate Or a cationic surfactant; and 4) an amphoteric surfactant such as octyl dimethyl hydroxyacetate; wherein a nonionic surfactant is preferred. In the treatment agent of the present invention, a known one can be used as the smoothing agent. As the smoothing agent, there are mentioned: 1) lauryl oleate, stearyl oleate, oleyl oleate, octyl oleate, tridecyl oleate, decyl oleate, butyl oil Sour vinegar, 2-ethylhexyl oleate, octyl stearate, oleyl stearate, butyl palmitate, oleyl palmitate, oleyl laurate, oil-based iso-hardy Acid ester, oleyl octanoate, ethylene glycol = dilaurate, propylene glycol = distea vinegar, hexanediol = dilaurate, glycerol = tris(12-hydroxystearic acid vinegar), glycerol = Trioleate, glycerol = chlorpyrifos = distearate, trisyl mercapto = tripalmitate, sorbitan = tetraoleate, pentaerythritol = tetralaurate, succinic acid Stearyl ester, distearyl glutarate, dicetyl adipate, di(tartate) pimelate, suberic acid (2097112518 12 200907138 diester), sebacic acid An aliphatic ester compound such as distearyl ester or distearyl sebacate; 2) various mineral oils having various viscosities; 3) linear polydimethyl siloxane having various viscosities or clustering the linear Dimethyl hydrazine The alkane is ethyl, phenyl, fluorinated propyl, aminopropyl, ruthenyl, polyoxylated ethyl ethoxylated propyl, hydrazine-methoxypolyethoxy/polypropoxypropyl, etc. Modified linear polyorganosiloxane having various viscosities; q polyfluorene monool, polydecanediol, polytriol, etc. having a polyoxyalkylene group; 5) benzyl stearate , an aromatic ester combination of benzyl laurate, diisostearate, trioctyl benzene tricarboxylate, etc.: and 6) a 3-membered aliphatic alcohol from 4 to 26 Addition of a (poly)ether compound having a carbon number of 2 to 4 to a (poly)ether compound having a carbon number of 4, an aliphatic carboxylic acid compound having a carbon number of 4, and an aromatic alcohol addition carbon of a 3 atomic acid a (poly)ether compound obtained from a (poly)ether compound of a 2 to 4 alkylene oxide and a carbonic acid carboxylic acid, and a carbon number of 2 to 4 by an aliphatic alcohol having a carbon number of (6) A (poly)-bonded compound of a (poly)-bonded eight-membered metal oxide and a (poly)(tetra) compound obtained from an aromatic carboxylic acid. Among them, 'as a smoothing agent, an aliphatic vinegar compound, a mineral oil, and a linear polyorganismite are preferred, and it is preferred that the aliphatic group is obtained from an aliphatic i-membered aliphatic mono-(four) having a carbon number of 17 to 10 (10). The compound, the fat obtained from the month I aliphatic polyol and the aliphatic single (four) 17~6(), the complete compound, the aliphatic portion obtained from the aliphatic polyol and the aliphatic single (four), the aliphatic portion of the 1HG The carbon number of the compound, etc. = ester compound, 3 (TC viscosity A 2xl ()-6 9ylfr4 2 / fat private anvil is 10~2xl〇V/s mineral oil; 30 degree is 1X10 6~2xl0 -V/s linear polydimethyl sylvestre. Flat 97115518 13 200907138 The slip agent can be used alone or in combination of two or more. The treatment of the present invention is 剑 ώ w μ & % _ 矛之之之# k The smoothing agent and the organic rhodamine metal compound containing the compound 1 constitute a whole 7G to 99 5 ^, the smoothing agent - preferably 70 to 90% by mass, containing

. The function of the metal compound is 10%, preferably 10% to 30% by mass, and the compound J is a compound of the total mass of the TM5. When it is attached to the synthetic fiber, it can be combined with the present invention. ,:: humic agent, anti-clearing, but the amount is as much as possible ^ (two: the method for treating the synthetic fiber false twisted silk of the present invention is described. The invention of the invention ... synthetic fiber false twist processing:: For the adhesion of ^, the force is 0. 1~5 mass% of the way to the dimension ===: ' is relative to the latter synthetic fiber Γ = 5 mass%, preferably 〇. 5~3 mass% The workshop uses the 軏 oil supply method, the use of a metering pump, the oil method, or the spray method, and the like. (10) Guidance - Oil method H is used to feed the oil and attach it to the treatment agent of the present invention. Wedge in the treatment method of the invention, the system is not limited to the conditions of the processing of the false twisting process, and there is a section of the type of the more than the section / the end ^ contact type and non-contact type, , one & can be put into any of the 97112518 14 200907138 lines in any combination, and the use of contact heaters The surface temperature is usually carried out at 70:24, preferably _22 (rc), and in the case of using a non-contact heater, the surface temperature is usually 1 〇〇 to 6 〇 (rc, preferably 150). It is carried out at ~500 ° C, and in any case, the processing speed is usually 10 (M500 m / min, preferably 2 〇〇 ~ 12 〇〇 m / min, so it can be carried out under any of these conditions However, the processing of the processing method of the present invention is preferably carried out at a processing speed of 200 to 1200 m/min using a contact heater having a surface temperature of 100 to 22 Torr. Finally, the synthetic fiber false twist processing yarn of the present invention is Hereinafter, the false twisted textured yarn of the present invention will be described. The false twisted textured yarn of the present invention is obtained by the above-described treatment method of the present invention. 1) Polyesters such as polyethylene terephthalate, polytrimethylene terephthalate, poly(p-phenylene terephthalate), poly(terephthalic acid tetraethyl ester), etc. Synthetic fiber; 2) Polyamide-based synthetic fiber such as nylon 6, nylon 66, etc. , modified polyacrylonitrile (m〇dacrylic) and other polyacrylic fiber = fiber; 4) polyethylene, polybutene and other polyolefin-based synthetic fibers; 5) polyaminocarboxylic acid I-based synthetic fiber; and 6) poly A lactic acid-based synthetic fiber or the like; wherein the effect of the present invention can be highly exhibited when it is applied to a synthetic fiber, a polyamide-based synthetic fiber or a polylactic acid-containing synthetic fiber. (Effect of the Invention) The treatment agent of the present invention is excellent in storage stability itself, and in particular, by adhering thereto, the synthetic fiber can be sufficiently prevented from being electrostatically charged, and as a result, the fabric made of such synthetic fiber can be sufficiently prevented from being equal to dyeing. Uneven dyeing. [Embodiment] The following three embodiments are described in order to make the configuration and effects of the present invention more specific, but the present invention is not limited to the embodiments = in the following examples and comparative examples, It means quality, quality %. 77 Series Table No (Example) Test Category 1 (Synthesis σ of the organic sulfonic acid metal compound represented by the chemical sulfonate metal compound (S-丨)) is provided with a thermometer, a stirrer, and a reflux cooler. In a four-necked flask with a bottom drain valve, 248 parts (20 moles) of propyl sulfonic acid and 1 000 parts of water were added, and the mixture was heated to 70 to 90 ° C while stirring, and dissolved. Then, the solution was stirred. On the other hand, add 74 parts of calcium (1. 〇mol) to the time of 丨〇 to 9 〇 to 9 〇. After the hydrazine, the mixture was stirred at the same temperature for 1 hour to carry out a neutralization reaction. The stirring was stopped, and the mixture was allowed to stand at the same temperature for 30 minutes, and the lower portion containing the calcium propylsulfonate was sedimented and separated. Add 500 parts of water to the part containing calcium propyl sulfonate, heat to 7 0 0 0 C, stir-fry for 1 hour, stop mixing, and let stand for 3 hours at the same temperature to make part of the lower layer And the upper aqueous solution is drained from the upper part and then washed with water. After the same water washing treatment was repeated once more, it was dehydrated and dried to obtain 257 parts of calcium propylsulfonate (0.9 mol). This was designated as an organic sulfonic acid metal compound (8_丨). - Synthesis of organic sulfonic acid metal compounds (S-2) to (s_35) and (τ-丨) to (τ-3) The organic sulfonate shown in Table 1 was synthesized in the same manner as the organic acid metal compound (S-1). Acid metal compounds (S-2) to (S-35) and (T-ι) to (T-3). 97112518 16 200907138 (Table 1) Organic acid metal compound type R1 R2 种类 Species type S-1 Propyl propyl magnesium S-2 hexyl hexyl magnesium S-3 壬 癸 钙 calcium S-4 Η - carbon Η Η carbon Calcium-based S-5 Tetracafluoropentadecyl-based calcium S-6 Eighteen carbon-based Twenty-two carbon-based calcium S-7 Twenty-eight carbon-based octadecyl sulfonium S-8 Thirty carbon-based thirty Tricarbyl hydrazine S-9 Trihexadecyl hexadecacarbyl magnesium S-10 Hexenyl hexenyl sulphide S-11 decyl alkenyl sulphate S-12 Fourteen 蝉 蝉 蝉 十六 十六 十六Dilute Calcium S-13 Octadecyl Hexadecyl Iron S-14 13c-Tetradenyl Alkenyl 13t-Tetradenyl Alkenyl Calcium S-15 Phenylphenyl Drill S-16 Propyl Phenylpropylphenyl copper S-17 octylphenyloctylphenyl calcium S-18 nonylphenyl nonylphenyl calcium S-19 eleven phenyl octadecyl phenyl calcium S-20 Tetradecylhexadecylphenylmagnesium S-21 octadecylphenyldodecylphenylmagnesium S-22 octadecylphenyl octadecylphenyl magnesium S-23 Carbophenyl phenyl tricarbyl phenyl magnesium S-24 trihexyl phenyl hexadecane Phenyl S-25 naphthylnaphthyl calcium S-26 propyl naphthylpropyl naphthyl magnesium S-27 hexyl decyl isopropyl naphthyl magnesium S-28 octyl naphthyl fluorenyl naphthyl magnesium S-29 Monocarbonaphthylnaphthylnaphthylcalcium S-30 Tetracafluoronaphthylpentadecylcarbonaphthylcalcium S-31 Octadecenylnaphthalenyloctadecylphenylcalcium S-32 Thirty carbon naphthalene Tridecylcarbenyl zinc S-33 trihexadenaphthalenyltrihexadecenylnaphthylmagnesium S-34 1,2-bis(octyloxycarbonyl)-1-ethaneyl 1,2 - bis(octyloxymethyl)-1-ethenyl S-35 1,2-bis(undecyloxycarbyl)-1-ethaneyl 1,2-bis(undecyl) Oxycarbyl)-1-ethaneyl T-1 eleven carbonyl^ carbon-based steel T-2 undecylphenyl hydrazine-carbylphenylnaphthalene T-3 undecylnaphthyl eleven carbon Potassium naphthyl potassium 97112518 17 200907138 In Table 1, 'R, R2, m: equivalent! R in the middle. Test Category 2 (Modulation of treatment agent) • Example 1 {Modulation of treatment agent (distress)} and metallization of organolithic acid synthesized in Test Category 1 Exactly... 7 ′ Dissolve while stirring at 60°. After reading, as a function other than the organic lysine compound, 13f =~12 carbon base t«poly (oxygen wuwn), the two sides of the mixture are mixed and dissolved, and the mixture is mixed for 1 hour. The stirring was stopped, and the mixture was cooled at a hanging temperature to prepare a treating agent (P-J). • Real, examples 2 to 35 and comparative examples 1〇{Processing agent (p_2)~(p-35) and CK-1)~(R-10) modulation} and the same modulation as f=KP-1) Ground Modulation Treatment Agent (P-2MP-35) Eight types of gas test; (wide 1). The contents of the treatment agents of the respective examples are shown in Tables 2 and 3. Test Category 3 (Evaluation of Storage Stability) The treatment agent of each of the prepared samples was transferred to a transparent beaker: after standing for 7 days at room temperature, the appearance was visually observed, and the following criteria were used. ,, ° is not shown in Table 2 and Table 3. A. Appearance is even and transparent. B: Uneven appearance, slightly white turbidity c: Severely cloudy or liquid phase separation. 97112518 18 200907138 (Table 2)

Classification of sorting agent type Smoothing agent function-imparting agent storage stability ratio (%) Organolithic acid metal compound organic acid gold 1 compound type ratio (%) Species ratio (%) Example 1 P-1 A-1 82 S-1 5 B-1 13 A 2 P-2 A-2 82 S-2 5 B-2 13 A 3 P-3 A-3 82 S-3 5 B-3 13 A 4 P-4 A- 1 82 S-4 5 B-1 13 A 5 P-5 A-2 82 S-5 5 B-2 13 A 6 P-6 A-3 82 S-6 5 B-3 13 A 7 P-7 A -4 84 S-7 0.5 B-1 13 A B-4 2.5 8 P-8 A-5 84 S-8 0.5 B-1 13 A B-5 2.5 9 P-9 A-6 94 S-9 0.5 B -2 3 A B-4 2.5 10 P-10 A-1 94 S-10 0.5 B-2 3 A B-5 2.5 11 P-11 A-2 72 S-11 13 B-2 14 A B-6 1 12 P-12 A-3 72 S-12 13 B-3 14 A B-4 1 13 P-13 A-4 72 S-13 13 B-1 14 A B-5 1 14 P-14 A-5 76 S-14 8 B-2 14 A B-4 2 15 P-15 A-6 76 S-15 8 B-3 13 A B-5 3 16 P-16 A-1 76 S-16 8 B-1 13 A B-6 3 17 P-17 A-1 79 S-17 8 B-1 13 A 18 P-18 A-2 82 S-18 5 B-1 13 A 19 P-19 A-2 82 S-19 5 B-2 13 A 20 P-20 A-1 82 S-20 5 B-3 13 A 21 P-21 A-2 79 S-21 8 B-1 13 A 22 P-22 A-3 94 S-22 2 B-2 3 A B-4 1 23 P-23 A-4 94 S-23 2 B-1 3 A B-5 1 24 P-24 A- 5 94 S-24 2 B-1 3 A B-6 1 25 P-25 A-6 88 S-25 5 B-1 5 A B-4 2 26 P-26 A-1 88 S-26 5 B- 1 5 A B-5 2 27 P-27 A-2 76 S-27 8 B-1 13 A B-6 3 28 P-28 A-1 82 S-28 5 B-1 13 A 29 P-29 A -1 82 S-29 5 B-2 13 A 30 P-30 A-2 82 S-30 5 B-2 13 A 31 P-31 A-2 82 S-31 5 B-3 13 A 32 P-32 A-3 82 S-32 5 B-2 13 A 33 P-33 A-3 82 S-33 5 B-3 13 A 34 P-34 A-4 82 S-34 5 B-1 13 A 35 P- 35 A-4 82 S-35 5 B-1 13 A 97112518 19 200907138

C Table 1 !) ______ SiS"? Agent------- Classification type of sorting agent πι______-Organic sulfonic acid metal compound Storage ratio of organic sulfonic acid metal compound stability ratio ^/0 y Type ratio (%) Species ratio (%) Comparative Example 1 2 3 4 R-1 R-2 R-3 R-4 Α-1 Α-1 Α-1 Α-1 —-—*— 80 80 80 99. 7 T-1 T -2 T-3 S-4 5 5 5 0. 01 B~1 B-4 B-5 B-4 15 15 15 0. 29 CCCB 5 6 R-5 R-6 Α-1 100 S-4 15 B -1 B-4 55 10 AB B-5 20 7 R-7 Α-1 30 S-4 20 B-1 B-4 20 10 C B-6 20 8 9 R-8 R-9 A-1 Α- 1 70 80 S-2 29 B-1 B-2 1 20 CC 10 R-10 Α-1 50 S-2 15 B-3 35 C In Tables 2 and 3, A-1: 30〇C has a viscosity of 3. 5xl (r5m2/s mineral oil A~2: isopropyl palmitate A-3: viscosity at 30 °C is 7. 〇xl (T5m2/s polydimethyl methoxy alkane A-4: Α-butyl-hydroxy poly(oxyethylene) (n=3) and dodecanoic acid ester compound A_5: benzyl laurate A-6. For butanol with ethylene oxide and propylene oxide 65/35 (mass ratio) ratio of random addition of a number average molecular weight of 1000 polyether monol dihydroxyl poly(oxyethylene) (n = 15) (non Sub-β-2 : For the extraction of 4 ears of ethylene oxide from t sesame oil (nonionic boundary 97112518 20 200907138 surfactant) B-3 : glycerol monolaurate (nonionic surfactant) B 4 . α-Lauryl _ω-hydroxydioxyethylene phosphate potassium salt (anionic surfactant) Β 5 · Lauryl dimethyl hydroxyethyl sulfate (cationic surfactant) Β 6 · Octyl 曱Aminoacetate (amphoteric surfactant) test classification 4 (manufacturing and processing of false twisted silk) (A) production and processing of poly(p-phenylene terephthalate) false twist processing wire will have an inherent viscosity of 0_64, oxidation Polyethylene terephthalate (Chip) having a titanium content of %2% is dried by a general method, and then spun by a U-machine uder), spun from the spun, cooled and solidified, and then traveled. The wire is adhered to the (10) aqueous solution of the synthetic fiber using a spinning oil agent (trade name DEU〇NF-168, manufactured by Takemoto Oil Co., Ltd.) using a metering pump, so that the amount of the spinning oil agent is Q, Concentrating with an introducer, in a manner that does not accompany mechanical extension, Velocity coiling, in the form of a continuous roll of silk cake, obtained a partial extension of 128 Danny's 3" 嶋t). Using the wire cake, a contact heating type false twisting machine (trade name leg 2 (4) manufactured by Teijin Seiki Co., Ltd., at a processing speed of _m/min, with a stretching ratio of 1.525, and a disc type external friction type (into) Side guide bow 丨 丨 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , 〇〇T / m conditions for false twist plus 1. In the (four) processing, relative to the winding to paper 97112518 21 200907138 false twist processing wire, the wedge oil supply by the roller oil method, so that the test classification 2 prepared by the treatment agent (P-1) The amount of adhesion described in Table 4 was obtained, and the polyethylene terephthalate false ruthenium processing yarn of Example 36 was obtained. Examples 37 to 72 and Comparative Examples U to 2 described in Table 4 were also obtained. Polyethylene terephthalate false twist processing yarn of bismuth. The contents of each example are shown in Table 4. (B) Manufacture and treatment of nylon 6,6 false 捻 processed silk will have relative viscosity of sulfuric acid (Cr) 2.4, titanium oxide After the nylon 6 and 6 pellets containing 1% of the pellet were dried in a usual manner, they were spun at 29 Torr using an extruder, and spun from the spun. After the cooling and solidification, the synthetic yarn is adhered to a 10% aqueous solution of a spinning oil (trade name DEU (10) F-168, manufactured by Takemoto Oil Co., Ltd.) using a metering pump, and the spinning oil is adhered to the traveling yarn. After the amount is 0.4%, it is bundled by an introducer, and is taken up at a speed of 4 mm/min without mechanical extension, and a part of the 70 Danny 24 tow is obtained in the form of a crepe roll cake. Silk. Using the wire cake, a contact heating type false twisting machine (S^, manufactured by Teijin Seiki Co., Ltd.) S1200) is used to divide the processing speed by the stretching ratio = 3 axis disc type external friction type ( Enter the side guide disc piece = guide disc hard polyurethane vinegar dish 4 pieces): twist side...w 2. 5m and surface temperature 23 (TC, untwisting side twister = helmet, 诵 ^ condition (4) Guarding. When the 捻 捻 捻 1 1 1 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻 捻Examples 74 to 109 and Comparative Examples 21 to 3 of the Examples TM Table are obtained. Nylon 97112518 22 200907138 6, 6 false Processing the silk. The contents of each example are shown in Table 5. (C) Polylactic acid artificial processing silk processing and processing will have an average molecular weight of 120,000, melt index (21 (TC) 25g / min, broken glass transfer point 60 ° C, specific gravity 1 · 26 of the lactic acid polymer pellets were spun at 210 C using an extruder, spun from the spun, and cooled and solidified, and then the spinning thread was applied to the traveling yarn by using a pilot pump to feed the synthetic fiber. The 10% aqueous liquid of the brand name DELIONF-168 manufactured by Takeshi Oil Co., Ltd. is attached, so that the adhesion amount of the spinning oil agent is 〇. 5% later, the bundle is bundled by the guide, so as not to accompany the mechanical extension. U 3800 m / min speed take-up, in the form of = kg rolled silk cake to obtain 100 Danny 36 tow extension wire. The resulting stretch cord strength = 4·6 g/dtx, and elongation = 3〇%. Using the wire cake, a contact heating type false twisting machine (trade name SDS1200 manufactured by Teijin Seiki Co., Ltd.) was used, and the processing speed was 5 〇〇m/min, and the stretching ratio = 1. μ, the 捻 method = 3 axis disc Type external friction type (1 piece into the side guide disc, out: 1 piece of guide disc 'hard urethane disc 4 pieces'), twisted side heater = 2.5m long and surface temperature 130〇c , Untwisting side heater = no, 2500T / m conditions, false twist processing. In the false twisting process, the wedge-shaped oil is applied by the roll-feeding method with respect to the false twisted yarn before being taken up to the paper tube, and the treatment agent (P-1) prepared by the classification 2 is shown in Table 6. In the adhesion, the polylactic acid false twist processing yarn of Example 110 was obtained. Similarly, the polylactic acid of Examples 111 to 146 and Comparative Examples 31 to 40, which are shown in Table 6, were obtained: processed silk. The contents of each example are shown in Table 6. Δ-type test classification 5 (Assessment of false-twisted silk, etc.) For the false-twist processing 97112518 23 200907138 of each of the samples manufactured and processed in the test class 4, and evaluating the antistatic properties and the silk, the adhesion of the treatment agent was measured as follows Amount of dyeability. The results are shown in Tables 4 to 6. • The amount of the treatment agent to be applied is measured by JIS-L1〇73 (synthetic fiber filament test method: n-hexane/ethanol (50/50 by volume), day-in, 々-from”, and , 槚)) This solvent is used as the extraction solvent, 'The false adhesion 拗 processed wire is used to measure the adhesion of the treatment agent. · The evaluation of antistatic property: = two I: false 捻 processed silk is arranged on the creel and hung on At this time, use the spring 曰"U ί ί 1()_m ' as the warp beam for the warp. 2==the potential measuring device measures the friction with the metal to produce A: the voltage is not full . ikv B ··with voltage 〇. lkV is above and not full. 5kv c: with voltage 〇.5kv or more and less than 1〇kv D: with voltage l.0kV or more and less than 2〇kv D: with voltage 2. OkV or more • t for this two m E 2 g. The evaluation of the dyeability of the processed silk yarn = the pair of warp beams taken for the evaluation of the above antistatic properties = ^ ^ E 2 捻 捻 processed silk paste • Dry, warp Prepare, pass the water jet loom (4) (reed). The obtained poly-p-formic acid B 8; = 捻 Γ Γ 打 打 打 纬 纬 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' Using disperse dyes (Japanese name ΚΑΥ 聚 E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E. Calculate the number of thick dyed parts on the surface of the flat fabric, and evaluate the results obtained by the naked eye to find the evaluation of each i-flat = 5 times, and evaluate it by line. 7 numbers, enter A in the following basis: The surface of the fabric is evenly B: the surface of the flat fabric is J. The state of the weaving grade is not dyed and the surface is flat and weave, but there is a C. The surface of the flat fabric is uniform and becomes a flat dyed π, And weaving 恝, but the surface of the 2~3 flat fabric becomes uneven, and the smear is smear, and there are 3~1〇, l:r flat: the surface of the flat is the flat weave state of the uneven sentence. , - The surface has a long and short dyed pattern on more than 10 faces. • Nylon 6' 6 The evaluation of the dyeability of the silk yarn is processed. 6 fi Axis is used to evaluate the above antistatic properties.

6, 6 false twisted silk processing paste, dry, month I = (four) nylon 6,6 fake two = scouring, woven; SAND〇LANBLUE-E-hRLN), ^ t$; The fabric will be dyed in a private, earthy, social > Laiwu's iron shovel is washed in two waters, dried and then attached to the diameter of the iron garment, and the surface of the flat fabric is calculated by the naked eye. The number of nine points, the implementation of the 5 New Zealand evaluation, (4) the evaluation results obtained = the number of flat fabrics, with the processing of polyethylene terephthalate false 擒: 1 97112518 25 200907138 dyeing evaluation same benchmark Evaluation ❶ • Evaluation of the dyeability of polylactic acid-based false-twisted silk The warp-elastic is used to evaluate the above-mentioned antistatic “acid false-twisted silk paste paste • dry, fine, and revered. Adding the obtained polylactic acid false 捻 :: over = type iron. The flat fabric is 9 (rc into, '' ', woven woven woven dyes (曰本化制药公司::商练理's use points) EBL-E), at 10 (rCx4{) points ° YAL0N polyester blue dyed flat fabric is dyed in the general square 2. After that, it is attached to a diameter of 70mm, long lm, reduction, washing, drying The number of thick dyed parts on the surface, the actual R 卩 卩 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算 计算Benchmarking of the stupid acid bismuth dioxide J. 97112518 200907138 (Table 4)

Type of sorting agent Heater surface temperature (°C) Processing speed (m/min) Attachment amount (°/〇) Antistatic dyeability Example 36 P-1 212 700 2. 2 BB 37 P-2 212 700 0. 7 AA 38 P-3 212 700 1.3 AA 39 P-4 212 700 2. 0 AA 40 P-5 212 700 1.9 AA 41 P-6 212 700 2. 6 AA 42 P-7 212 700 1.8 CC 43 P -8 212 500 2. 3 CC 44 P-9 212 500 0.4 CC 45 P-10 212 700 2. 6 CC 46 P-11 212 800 1.8 BC 47 P-12 200 500 1.2 BC 48 P-13 200 500 2.2 BC 49 P-14 190 500 2. 1 BB 50 P-15 190 500 2. 4 BB 51 P-16 200 500 2. 3 BB 52 P-17 200 800 2. 7 AA 53 P-18 200 800 1.8 AA 54 P -19 200 800 2. 0 AA 55 P-20 200 900 1.2 AA 56 P-21 200 1000 0. 9 AA 57 P-22 200 1000 1.2 BB 58 P-23 225 1000 1.8 BB 59 P-24 225 1000 2. 7 BB 60 P-25 190 900 3. 5 BB 61 P-26 190 900 3. 0 BB 62 P-27 190 900 2. 6 BB 63 P-28 190 600 0. 8 AA 64 P-29 200 700 2. 0 AA 65 P-30 180 700 2. 7 AA 66 P-31 180 900 1. 15 AA 67 P-32 210 1200 1.3 BB 68 P-33 210 1200 1.8 BB 69 P-34 210 1200 4. 0 BB 7 0 P-35 210 1200 0. 8 BB 71 P-1 210 300 0. 5 CB 72 P-4 210 800 4. 6 AB Comparative Example 11 R-1 210 800 1.9 EE 12 R-2 210 800 2. 2 EE 13 R-3 210 800 2.4 EE 14 R-4 210 800 2. 3 DE 15 R-5 210 800 2. 2 EE 16 R-6 210 800 2. 3 EE 17 R-7 210 800 2. 0 CD 18 R -8 210 800 1. 9 DE 19 R-9 210 800 2. 0 EE 20 R-10 210 800 2. 5 EE 97112518 27 200907138 (Table 5)

Type of classification treatment agent Heater surface temperature rc) Processing speed (m/min) Attachment amount (%) Antistatic dyeability Example 73 P-1 230 700 1.9 BB 74 P-2 210 700 2.1 AA 75 P-3 210 700 1.2 AA 76 P-4 210 800 2.1 AA 77 P-5 210 800 0.8 AA 78 P-6 210 800 2.6 AA 79 P-7 230 800 0.8 CC 80 P-8 230 300 0.4 CC 81 P-9 210 500 2.0 CC 82 P-10 210 500 0.3 CC 83 P-11 210 800 3.3 BC 84 P-12 220 800 2.7 BC 85 P-13 180 600 1.5 BC 86 P-14 180 600 0.8 BB 87 P-15 180 600 1.2 BB 88 P-16 180 600 1.8 BB 89 P-17 180 600 2.9 AA 90 P-18 190 600 2.0 AA 91 P-19 190 800 2.7 AA 92 P-20 180 700 1.0 AA 93 P - 21 200 800 1.6 AA 94 P -22 225 900 2.6 BB 95 P-23 180 900 0.8 CC 96 P-24 225 700 0.4 CC 97 P-25 225 900 3.2 BC 98 P-26 225 900 1.2 BB 99 P-27 225 900 2.2 BB 100 P-28 190 700 1.7 AA 101 P-29 200 700 1.9 AA 102 P-30 180 700 2.6 AA 103 P-31 200 900 0.8 AA 104 P-32 225 1200 2.3 BB 105 P-33 225 1200 2.1 BB 106 P-34 225 1200 2.2 BB 107 P-35 225 1200 2.1 BB 108 P-1 190 180 0.6 CC 109 P-4 210 700 4.5 AB Comparative Example 21 R-1 1 220 800 2.2 EE 22 R-2 220 800 2.2 EE 23 R-3 220 800 2.4 EE 24 R-4 220 800 1.8 DE 25 R-5 220 800 2.2 EE 26 R-6 220 800 2.0 EE 27 R-7 220 800 2.2 DD 28 R-8 220 800 2.0 EE 29 R-9 220 800 2.2 EE 30 R-10 220 800 1.7 EE 97112518 28 200907138 (Table 6)

Type of sorting treatment agent Heater surface temperature (°C) Processing speed (m/min) Attachment amount (%) Antistatic dyeability Example 110 P-1 130 500 2.0 BB 111 P-2 130 600 0.9 AA 112 P -3 130 500 1.2 AA 113 P-4 130 600 2.3 AA 114 P-5 130 500 2.7 AA 115 P-6 130 600 0.8 AA 116 P-7 130 500 0.3 CC 117 P-8 130 500 1.3 CC 118 P-9 120 400 2.0 CC 119 P-10 100 400 0.8 CC 120 P-11 110 400 2.7 BC 121 P-12 80 300 1.2 BC 122 P-13 130 500 1.2 BC 123 P-14 140 600 2.4 BB 124 P-15 140 500 3.1 BB 125 P-16 140 600 2.8 BB 126 P-17 130 600 2.7 AA 127 P-18 140 600 1.2 AA 128 P-19 130 600 2.5 AA 129 P-20 140 600 1.7 AA 130 P-21 130 500 0.8 AA 131 P-22 130 500 2.7 BB 132 P-23 120 400 3.3 BB 133 P-24 120 400 1.2 BB 134 P-25 120 400 1.6 CD 135 P-26 120 200 0.6 CB 136 P-27 120 300 2.4 CB 137 P -28 130 400 2.4 AA 138 P-29 130 400 1.9 AA 139 P-30 130 400 1.2 AA 140 P-31 130 500 1.6 AA 141 P-32 130 500 2.8 BB 142 P-33 130 500 2.1 BB 143 P-34 130 400 3.4 B B 144 P-35 140 400 1.1 BB 145 P-1 140 500 0.5 CC 146 P-4 140 400 4.4 AB Comparing with the vehicle 31 R-1 130 300 1.8 EE 32 R-2 130 200 1.9 EE 33 R-3 130 500 2.4 EE 34 R-4 130 500 2.2 EE 35 R-5 130 500 2.3 EE 36 R-6 130 500 2.5 EE 37 R-7 130 600 1.7 CD 38 R-8 130 600 1.3 DE 39 R-9 130 600 1.9 EE 40 R-10 130 600 2.4 EE 97112518 29

Claims (1)

200907138 X. Patent application scope: . 5 kinds of fiber, quasi-use straight type (straight type) treatment agent, including smoothing agent and function-imparting agent, characterized in that the content is 7〇~5质量% of the whole a smoothing agent and a total of 0.5 to 30% by mass of the function-imparting agent, and at least a part of the function-imparting agent contains 0. 0 5 to 15% by mass of the lower jaw, _ 卜达化1不有机有机Made of a metal sulfonic acid compound; [Chemical 1] R1 -S 〇 R2-S Ο 化 (In R1, R1, R2: an alkyl group having 1 to 36 carbon atoms, an alkenyl group having 2 to 24 carbon atoms, a phenyl group, an alkylphenyl group having an alkyl group having 1 to 36 carbon atoms, a naphthyl group, and An alkylnaphthyl group having an alkyl group having a carbon number of 5% or an anthracene, a 2-bis(alkyloxymethyl)-1-ethane group having an alkyl group having 4 to 24 carbon atoms; Μ: having a valence of a divalent atom Metal). 2. For the direct-use type treating agent for synthetic fibers according to item 1 of the patent application scope, wherein R1 and R2 in the organic sulfonic acid metal compound system 1 are alkyl groups having an inverse number of 6 to 22, and having a carbon number of 8~ The case of an alkylphenyl group of an alkyl group of 18 or an alkylnaphthyl group having an alkyl group having 8 to 18 carbon atoms. 3. For the synthetic fiber used in the second paragraph of the patent application, the direct-use treatment agent 'where' the organolithic acid metal compound is the case where the mash of the compound 1 is the mother or the town. 97112518 30 200907138 4. For the synthetic fiber used in the scope of the patent application, the direct use type of the synthetic fiber is 10% by mass of the organic sulfonic acid metal compound. • 5. A direct-use treatment agent for synthetic fibers according to item 3 of the scope of patent application, wherein 'the whole contains 1% by mass of the organic acid-reducting metal compound. 6. For the synthetic fiber according to the patent application range lJf, the direct-use type treatment/eighth, the smoothing agent is from the aliphatic ester compound having a carbon number of 17 to 60, 3 (the viscosity of the TC is 2x10 human 2xl (rV/s One or more selected mineral oils and linear polyorganooxanes having a viscosity of 1x10 2x10 m/s. 7. For the synthetic fibers of the fifth paragraph of the patent scope, the towel is used directly. The smoothing agent is an aliphatic vinegar compound having a carbon number of i 7 to 6 、, 30% of which is 2xl "~2xl 〇-V/s of mineral oil and 3 〇. The viscosity is 1x10 2x10 m/s. One of the linear polyorganisms is selected from the group or the non-ionic surfactant other than the organic sulfonic acid metal compound. The direct use type of the synthetic fiber of the fifth patent scope in May is ==1: / the functional imparting agent other than the metal sulfonic acid metal compound is a non-derivative surfactant. The treatment method, which is for the false-twisted synthetic fiber false 捻 plus wei wire attachment Patent No. 97112518 31 200907138 The direct-use type treating agent for the synthetic fiber of the first item is made into 〇. 1~5 mass%. ' 11 · A method for treating synthetic fiber false twisted silk, which is characterized by Patent application for the processing of synthetic fiber false twisted silk after processing; the direct use type treating agent for the synthetic fiber of item 9 is made to be '〇·1 to 5 mass%. 八' 12. If the scope of application is The processing method of the f-synthesis processing wire of 10 items of synthetic fiber, wherein the false twist processing is performed using a surface temperature of 100 to 22 (rC2 C contact heater, at a processing speed of 200 to 1200 m/min. The method for treating a synthetic fiber false twisted yarn of the ninth aspect, wherein the false twist processing is performed at a processing speed of 200 to 1200 m/min using a contact heater having a surface temperature of 1 〇〇 22 22 。. A synthetic fiber false twist processing wire obtained by the method for treating a synthetic fiber false twisted silk processed in the scope of claim 12 of the patent application.围第(13) The synthetic fiber false twist processing wire obtained by the method of processing. 16. The synthetic fiber false twisted silk processed according to claim 14 of the patent, wherein the synthetic fiber polyester synthetic fiber and the polyamidamide synthesis Lactic acid-based synthetic fiber. 5 I 17. Synthetic fiber false twist processing yarn according to item 15 of the patent application, t, synthetic fiber polyester synthetic fiber, and polyamidamide synthetic lactic acid synthetic fiber. Or poly 97115518 32 200907138 VII. Designated representative map: (1) The representative representative of the case is: No (2) The symbol of the symbol of the representative figure is simple: No. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: [Chemical 1] 97112518 5