200904630 九、發明說明： 【發明所屬之技術領域】 ^發明侧於❹衝擊吸收性、_熱性、及 =㈣凝膠材料形成薄板片狀，並使用為、= 材4的矽酮凝膠片之製造方法。 緩衝 【先前技術】 因為㈣凝膝材料的衝擊吸收性、财熱性及耐候 將被加工為各種形狀，並使用 話等電子機器，或汽車、機器人等::子 ς牛〇 ’頗適用為緩衝材、密封材、絕緣材等。此外， 呈=膠材料特有的吸附性能，便可重複貼附，屬於 且不會在被貼附面上發生絲情況等特性 = = =:媒體的素材。但是，此㈣酮凝 „ 、有，旋膠材料特有的黏著性，且因為機械強度較 ，’因而會從凝膠材料的加卫性及使用凝膠材料的加工產 口口組裝性等觀點，會有產品較難處置的問題。所以，針對 =有適度強度的片狀料凝膠片，係渴求加工性及組裝性 等均良好，同時簡易的製造方法。 、十、寸此種矽酮凝膠材料的問題，例如在日本專利公開公 報，特開+ 2-196453號中記載有在矽酮橡膠片上施行矽 酉同凝勝材料塗佈並—體成形的方法。但是，根據此種成形 方法、’因為需要成形梦酮橡膠片的步驟以及在其上面施行 夕-同疑勝材料塗佈的步驟等2項步驟，因而不僅製造複 雜’且製造時間亦變長。所以，會有導致矽酮凝膠片製造 97114492 200904630 成本變為高單價的問題。 中纪載有例：本專利公開公報的特開平9,7275號 ====材上，將-分子中至少具有3 狀，並. S , 土的有機矽氧烷，塗佈成薄膜 使加成反應硬化型石夕酮組成物硬化成片 成辦膠層，而内層則仍保物凝 膠狀悲的片材成形方法。但是，依日g 凝脈H m ^ . 依知该方法所成形的矽酮 屬於卿膠狀，而内層則獅 時，会右你切齡t 中孔次裁男加工為既定形狀 才θ有從切斷面滲出凝膠狀石夕酮的問題。 中：ΐ右例：在曰本專利公開公報的特開2_-26733號 埴施行石夕酮凝膠片成形之際，於調配原料中投 入填充劑並將施行原料塗佈德 β 1寸土师之後，經靜置，利用填充劑的 使單側表面層局部性存在填充劑的方法。但 二it成形方法’為了使填充劑沉殺於單側表面，需 ，因而導致成形時間拉長，會有製造成本變為 咼早價的問題。 中=古壯|a |專利公開公報的特開2〇〇5_1 61 780號 施行㈣疑膠片形成之後，藉由對表面施行 光化線照射而進行交聯，使表面層等硬化的方 开1根據5亥成形方法’因為需要施行石夕鲷凝膠片成 开 1步驟以及對其上面照射紫外線的步驟等2項步驟，因 而曰使製造趨於複雜且製造時間將 照射紫外線用的職置。因此，會有靖膠片 97114492 200904630 成本變為高單價的問題。 本發明係為解決上述問題 使表面橡膠化，不僅 成、、目的在於提供藉由 μ皇j加強表面強 廉償地製造出提高整體產σ "且此依間皁方法且 的彈性力，亦不會且保持凝膠特有 面渗出石夕銅凝膠的薄板石夕綱凝膠片之製獲得產品截 f發明内容】 义以万汝。 本發明構造上的特徵，係將以 加成反應硬化型㈣疑膠材料與以有分的 分的加成反應硬化型石夕㈣膠材料 X夕乳燒為主成 原料，再利用塗敷裝置將^進仃5周配而形成調配 形成原料塗佈於片狀基材上，而 d J s κ⑽所較針插人度為2q 片。另外，隶好矽酮凝膠材料設定在q / 矽酮橡膠材料設定在0.1〜99.9重旦置伤、 呼舌曰 里伤靶圍内，且二者合 : 重…尤以㈣凝膠材料係設定為50〜99重量 伤、矽酮橡膠材料係設定為^0 里 以石夕酮凝踢材料設定在70〜99重旦里:摩巳内為佳’更 在重量份範圍内為更佳重料橡膠材料設定 根f本發明，藉由使㈣凝膠片的表面橡膠化’不僅可 加強表面強度，且在保持凝膠特有彈性力的情況下，可提 高產品的機械強度，因而當施行石夕綱凝膠片沖孔或裁煎加 工之際’不會從切斷面渗出㈣凝膠。另外，本發明可低 價地形成JIS K2207所規定之針插入度為I·，且保 持著凝膠特有彈性力的薄板矽酮凝膠片。 97114492 8 200904630 本發明中，在調配原料中可更進一步添加觸媒。觸媒係 具有硬化促進作用，例如白金觸媒、過氧化物系觸媒、辞 系觸媒等。藉此，可加速石夕酮凝膠片的硬化速度，並可 低製造成本。 本發明中，在基材的塗佈面上可預先塗佈底漆。藉此， 可將矽酮凝膠片一體形成於基材上，俾確保強度。 本發明中，對基材的塗佈面係可預先施行電漿處理。藉 此，可將矽酮凝膠片一體形成於基材上，俾確保強度。9 再者，本發明中，基材係可設為能容易地將矽酮凝膠片 亲J，的材貝。此種基材係有如經預先施行離型處理過的聚 ^苯二子酸乙二醋薄膜（PET薄膜）、聚丙稀薄膜等。離型 处理^•所使用的材料，主要係為石夕 石夕酮凝膠片從基材上剝離便可形成單體。』猎此將 ，者，本發明中，可在石夕酉同凝膠片之石夕酮材側貼合著保 遵片並施行捲取。藉此’可使㈣凝膠片的處置趨於容易。 刻再f，本發明中，在調配原料中可更進—步添加填充 :: 真广可舉例如氫氧化紹、氧化鐵、碳_、陶究、 ==維、碳纖維'碳材料等無機質填充劑；及將 用有機烧氧基石夕烧化合物、有機氣石夕烧化合物、有 :::::合物、低分子量彻化合物等有機 等等。依此的話，藉由填充劑的添加，便 ^ Λ m ±\ λ, 书P值專。另外，本發明中， 二?：調配入填充劑時，藉由填充劑的沉殿效 果而使早側表面上局部性存在填充劑，不僅可確保石夕嗣 97114492 200904630 喊膝片的表面強声，n 性佳的片材。'’彳依較短的成形時間形成產品均勻 根據本發明，脾ιν + ,, 化型矽酮凝膊材料盥“聚矽氧烷為主成分的加成反應硬 應硬物，橡膠材料 成刀的加成反 敷裝置將調配原料在:4狀比例進仃調配’並利用塗 丄：ΪΓ:成經提高整體片材強度，且保持凝膠特有 5早性力的溥板矽鲖凝膠片。 男 【實施方式】 料，係將以7:::實施形態進行說明。紗酮凝膠片的原 凝膠材料0 H9 :二為：成分的加成反應硬化型石夕嗣 西？，廿游士、1 η Λ Λ 重^里Υ刀進Ί丁 5周 促純^ 量份’進一步視需要在其中添加具硬化 進作用的觸媒而形成調配原料。 纸H二吏:二對本一甲酸乙二酯薄膜、聚丙烯薄膜、 者:: 可撓性溥板片狀材料’通常係使用捲繞呈捲筒狀 :二:係：用塗敷裝置施行底漆塗佈。底漆係使 塗佈底漆的基材上，將經調配入石夕酮凝膠 同橡膠材料及觸媒的上述調配原料，利用塗敷裝 ::連、，、賣塗佈。產品厚度就實用上而言最好設為 1 5000#ni。另外，塗敷裝詈传可 馼裒置係了使用間歇滾筒塗佈機、 反向塗佈機、刮刀塗佈機、氣刀塗佈機、棒塗機 '狹縫 塗佈機等。另外，亦可取代在基材上施行底漆塗佈，改^ 97114492 10 200904630 對基材預先施行電漿處理，藉此亦可將矽酮凝膠片一體形 成於基材上。 利用塗敷裝置在基材上施行調配原料塗佈後，便依 1/0〜30Gt：施行5分鐘左右的加熱而硬化，藉此形成石夕嗣 凝膠片。加熱溫度的範圍尤以12〇〜25(rc為佳。但，雖硬 化時間拉長，但是即使不對調配原料施行加熱而是利用自 放置/亦可硬化。藉由在依此所形成的石夕酉同凝朦片之石夕 嗣材側的表面上貼合著保護片，可保護石夕綱凝膠片’使處 置，於簡單。保護片的材料係如同基材材質，可舉例如聚 對苯二f酸乙二酯薄膜、聚丙烯薄膜、紙、布等可撓性 板片狀材料。 / 依如上述’本實施形態中’將以有機聚石夕氧烧為主成分 ^加成反應硬化型㈣凝膠材料'以有機聚石夕氧燒為主成 =的加成反應硬化型相橡膠材料以及觸媒，依既定比例 進仃調配’並利用塗敷裳置在片狀基材上施行塗佈，進一 =用加熱，便可簡單且短時間地低價形成皿2 ，疋之針插入度為20〜20。之薄板石夕酮凝膠片。结果，2 :施形態中，僅將矽，凝膠片的表面橡膠化，不僅可加強 特力且可m體！1材的機械強度，同時保有凝膠 截面，a不“^施彳了沖孔、裁剪加卫而獲得產品的 此外’因為在調配原料中 口填充劑’因而成形時間較短，可形成產品均句性 :的片材。此外，本實施形態之製造方法，亦 線照射之類的特別裝置，可簡單地構成製造步驟，因而 97114492 11 200904630 可使製造成本更加廉價。 另外’本貫施形離φ 么 _ 〜、中係使调配原料黏合於基材上並一 體形成矽酮凝膠片，帷* 丁没& 准並不僅侷限於此，亦可將矽酮凝膠 幸攸:ι㈣㈣成單體。例如當在所使用的周邊部位 處，表背雙面並非呈追蹤艰业&卜主、 ^ πσ 迫舨开^狀的炀況，係將矽酮凝膠片依 早體形式使用。此情況，基材係使用經預先施行離型處理 過的聚對苯二甲酸7 i 曰溥膜、聚丙烯薄膜等基材，或氟 史曰相餘施行氟加工過的紙等形成㈣凝膠片。 μ m形態中’雖在調配原料中並未含有填充 3 ’但視需要’亦可添加氫氧化紹、氧化鐵、礙_、陶 =、玻璃纖維、碳纖維、碳材料等域f填充劑；及將該 ^真充劑制有機烧氧基㈣化合物、有機氣我化合 有A石夕氮院化合物、低分子量砂氧烧化合物等有機石夕 :合物施行表面處理過者。依此的話，藉由填充劑的添 加，便呈可對石夕酮凝膠片的熱導率、電阻值等進行控制狀 心此外，當在調配原料調配入填充劑時，利用填充劑的 沉殺效果’使單側表面上局部性存在填充劑，便可確保矽 明减膠片的表面強度’且可依較短成形時間形成產品均勻 性佳的片材。 ，再者’本實施形態中，雖在調配原料中含有觸媒，但是 :需要亦可省略。此外，亦可取代觸媒，改為在調配原料 中添加填充劑。 另外，本實施形態中，在矽酮凝膠片之矽酮材側的表面 上貼合著保護片，而保護矽酮凝膠片，但是視需要亦可省 97114492 12 200904630 略。 接著’針對實施例進行說明。 圖1所不係形成在聚對苯二甲酸乙二酯薄膜（基材）上 黏合著矽酮凝膠片的步驟概略情形。矽酮凝膠材料係將 CY52~276(T0RAY · Dow Corning 股份有限公司製）94 重量 份、矽酮橡膠材料的 LR6200(WackerAsahikaseiSilic〇ne 股份有限公司製）6重量份以及白金觸媒〇5重量份進行 ，混合，而調整為調配原料。將該調配原料u供應給塗敷 ^裝置12。將捲繞於捲筒丨3上連續供應且經預先施行過底 漆塗佈的聚對笨二甲酸乙二酯薄膜14(厚度5〇#m)，供應 給塗敷裝置12’形成在薄膜14表面上經塗佈調配原料u 的整體厚度為3 0 0 /z m。經調配原料11塗佈過的薄膜14 , 在150C乾燥爐15中依5分鐘通過而硬化。藉此，可獲 得單面將與聚對苯二甲酸乙二酯薄膜呈一體化，而背後= 則保持著表面強度，且具有凝膠特有緩衝性的矽酮凝膠片 (16。此外，在矽酮凝膠片之矽酮材側貼合著保護片的保護 薄膜17之狀態18下連續地的捲取於捲筒19上。 接著，針對本發明的矽酮凝膠片，經施行拉伸強度與針 插入度測定的結果進行說明。試驗品係除上述實施例的試 驗品之外，尚有將矽酮凝膠材料（T〇RAY· D〇w ^『“叩股 知有限公司製CY52-276)依如下表1所示，設為98、9〇、 70、50重量份，與矽酮橡膠材料（Wacke；r Silicone股份有限公司製lR7665)設為2、10、30、50重 量份的試驗品1〜5等5種。此外，參考品！、2係就準備 97114492 13 200904630 就CY52-276分別為100、0重量份與LR7665分別為〇、 100重量份的2種。拉伸強度測定試驗片的形狀係根據】Js Κ6251啞鈴3號，針插入度測定用試驗片的形狀係5〇办 x30mm。 拉伸強度的試驗方法係根據JIS K6251，針插入度的試 驗方法係根據JISK2207的方法實施。試驗結果係如下表 1所示。 [表1 ] 試驗品 參考品 2 3 調配比率 酮凝膠/矽酮梭豚 拉伸強度（MPa) 針插入度 4 5 2 98/2 94/6 90/10 70/30 50/50 100/0 0.0043 197 0/100 I. 0079 117 0. 25 81 0. 42 41 0.60 0.0023 - -----L_u__28 16 如表1所示’得知試驗品1〜5係 插入度為20〜200’且保持著凝膠特有的適當彈性，並具 有拉伸強度0.0030〜〇.60MPa之適當機械強度。 此，僅石夕酮凝膠材料的參如相較於試驗品之下，丄寻 拉伸強度較低的結果’而僅矽酮橡膠材料的參考品2相較 於試驗品之下’獲得針插人度較低且欠缺彈性的結果。 (產業上之可利用性） 本發明係藉由將以有機聚矽氧烷為主成分的加成反應 石化型料凝膠材料與以有機聚石夕氧炫為主成分的加成 反應硬化型矽酮橡膠材料， 成 塗敷裝置在片狀A材上二疋例進仃調配，並利用 片狀基材上苑行塗佈，經硬化，有助於簡易且 310 97114492 14 200904630 低價地形成經提高整體片材機械強度，且保持著凝膠特有 彈性力的薄板石夕_凝膠片。 【圖式簡單說明】 圖1為本發明一實施例的矽酮凝膠片之製造步驟概略 說明圖。 【主要元件符號說明】 11 調配原料 12 塗敷裝置 f 13 捲筒 14 聚對笨二曱酸乙二酯薄膜 15 乾燥爐 16 矽酮凝膠片 17 保護薄膜 18 貼合著保護片的保護薄膜狀態 19 捲筒 97114492 15200904630 IX. Description of the invention: [Technical field to which the invention pertains] ^Inventive side is formed into a sheet-like shape in the impact absorption, _heat, and = (4) gel materials, and is used as an anthrone gel sheet of ? Production method. Buffering [Prior Art] Because (4) the impact absorption, heat and weather resistance of the knee-hook material will be processed into various shapes, and electronic devices such as automobiles, robots, etc.:: 子ς牛〇' is quite suitable as a cushioning material. , sealing materials, insulation materials, etc. In addition, the adsorption properties unique to the rubber material can be repeatedly attached, and the characteristics of the wire do not occur on the attached surface = = =: media material. However, this (four) ketone condensation, and the unique adhesiveness of the rubber material, and because of the mechanical strength, 'therefore, from the viewpoint of the gelatinity of the gel material and the assembly of the gel material using the mouth, There is a problem that the product is difficult to handle. Therefore, for a sheet-like gel sheet having moderate strength, it is desirable for a good manufacturing process and assembly, and a simple manufacturing method. A method of coating and forming a bismuth gel material on an fluorenone rubber sheet is described in Japanese Laid-Open Patent Publication No. Hei No. 2-196453. However, according to such a molding method, 'Because there are two steps, such as the step of forming the ketone rubber sheet and the step of applying the coating on the whispering and the suspicion material, the manufacturing process is not complicated and the manufacturing time is also long. Therefore, there is a cause of fluorenone. Gel sheet manufacturing 97114492 200904630 The cost becomes a problem of high unit price. The medium is loaded with an example: the special opening of this patent publication No. 9,7275 ==== on the material, the - molecule has at least 3 shapes, and. , organic soil The oxane is coated into a film to harden the addition reaction-hardening type linoleic acid composition into a sheet to form a rubber layer, and the inner layer is still a gel-like sorrow sheet forming method. m ^ . According to the method, the fluorenone formed by the method belongs to the jelly-like state, and when the inner layer is the lion, it will be right when you cut the age of the hole and cut the male into a predetermined shape. The problem of ketones. In the case of ΐ ΐ : : : : : ΐ 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 石After the β 1 inch, after standing, the filler is used to locally deposit the filler on the one-side surface layer. However, the two-forming method is required to kill the filler on the one-sided surface, thus causing the forming time. If the length is long, there will be a problem that the manufacturing cost becomes a premature price. Zhong = Gu Zhuang|a | Patent Publication No. 2〇〇5_1 61 780 (4) After the formation of the suspect film, the actinic line is applied to the surface Cross-linking by irradiation, and the surface layer and the like are hardened. The method 'has to perform the two steps of the step of opening the stone and the step of irradiating the ultraviolet ray on the stone, so that the manufacturing tends to be complicated and the manufacturing time is to illuminate the ultraviolet ray. Therefore, there will be Jingfilm 97114492 200904630 The cost becomes a problem of high unit price. The present invention is to solve the above problems to make the surface rubberized, not only to achieve, but also to provide a strong and cost-effective manufacturing of the overall production by μ Huang j. Moreover, the elastic force of the method according to the soap method does not prevent the gel-specific surface from oozing out of the thin slab of the Shishi copper gel, and the product is obtained. The structural feature of the invention is that the addition reaction hardening type (4) suspected rubber material and the addition reaction hardening type Shixi (four) rubber material X-ray milk are mainly used as raw materials, and then the coating device is used. ^ 5 weeks of mixing to form a formulation to form a raw material coated on a sheet-like substrate, and d J s κ (10) is 2q pieces. In addition, the 矽 矽 凝胶 gel material is set in the q / 矽 橡胶 橡胶 橡胶 橡胶 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 It is set to 50~99 weight injury, and the ketone rubber material is set to ^0. The setting of the stone ketone kneading material is set at 70~99 heavy denier: the inside of the squid is better, and the weight is more in the weight range. The rubber material is set to the root f. According to the invention, by rubberizing the surface of the (4) gel sheet, not only the surface strength can be enhanced, but also the mechanical strength of the product can be improved while maintaining the specific elastic force of the gel, and thus the stone is applied. When the ecclesia gel sheet is punched or cut, it will not ooze out from the cut surface (4) gel. Further, according to the present invention, a sheet crepe ketone gel sheet having a needle insertion degree of I· as defined in JIS K2207 and maintaining the gel-specific elastic force can be formed at a low price. 97114492 8 200904630 In the present invention, a catalyst may be further added to the raw material to be formulated. The catalyst system has a hardening promoting action such as a platinum catalyst, a peroxide catalyst, a catalyst, and the like. Thereby, the hardening speed of the lithopone gel sheet can be accelerated, and the manufacturing cost can be low. In the present invention, a primer may be applied in advance to the coated surface of the substrate. Thereby, the anthrone gel sheet can be integrally formed on the substrate, and the strength can be ensured. In the present invention, the coating surface of the substrate may be subjected to a plasma treatment in advance. Thereby, the anthrone gel sheet can be integrally formed on the substrate to ensure strength. Further, in the present invention, the substrate may be a material which can easily form a fluorenone gel sheet. Such a substrate is, for example, a polyethylene phthalate film (PET film) or a polypropylene film which has been subjected to release treatment in advance. Release The material used in the treatment is mainly used to form a monomer by peeling off the substrate from the stone. In the present invention, in the present invention, the Baoshou tablet can be attached to the side of the Shixi 酉 凝胶 gel sheet and the coil can be taken up. Thereby, the treatment of the (4) gel sheet tends to be easy. In the present invention, the filling can be further added in the preparation of the raw materials:: Generally, inorganic filling such as hydrazine hydroxide, iron oxide, carbon _, ceramics, == dimensional, carbon fiber 'carbon material, etc. And an organic alkoxylated compound, an organic gas stone compound, a :::: compound, a low molecular weight compound, and the like. In this case, by adding the filler, ^ Λ m ±\ λ, the book P value is exclusive. In addition, in the present invention, when the filler is blended into the filler, the filler is locally present on the early side surface by the sinking effect of the filler, which not only ensures the strong sound of the surface of the knee-slapper 9714492 200904630 , n good sheet. ''The formation of a uniform product according to the shorter forming time according to the present invention, spleen ιν + , 化 矽 凝 凝 凝 盥 盥 盥 矽 矽 矽 矽 矽 矽 为主 为主 为主 为主 为主 为主 为主 为主 为主 为主 为主 为主 为主The addition of the anti-applying device will be formulated in: 4 ratios into the 仃 仃 并 并 并 并 并 并 并 并 并 并 并 并 并 并 并 并 并 并 并 并 利用 利用 利用 利用 利用 利用 利用 利用 成 成 成 成 成 成 成 成 成 成Male [Embodiment] The material will be described in the form of 7::: The original gel material of the ketone gel sheet is 0 H9 : The second is: the addition reaction of the component, the hardening type, Shi Xixixi, 廿游士,1 η Λ Λ ^ Υ Υ Υ 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 Ethylene diester film, polypropylene film,:: Flexible enamel sheet material 'usually used in a roll shape: two: system: primer coating with a coating device. Primer coating On the substrate of the primer, the above formulated raw materials which are blended into the rubber powder and the catalyst are prepared and coated. Packing:: even,, and selling coating. The thickness of the product is preferably set to 1 5000#ni in practical terms. In addition, the coating can be set by using a batch roller coater and reverse coating. Cloth machine, knife coater, air knife coater, bar coater 'slit coater, etc. In addition, instead of applying primer coating on the substrate, it is pre-implemented on the substrate by using 97114492 10 200904630. The plasma treatment can also form the anthrone gel sheet integrally on the substrate. After the application of the preparation material on the substrate by the coating device, the heating is performed for about 5 minutes according to 1/0 to 30 Gt. And hardening, thereby forming a stone scorpion gel sheet. The heating temperature is particularly in the range of 12 〇 to 25 (rc is preferred. However, although the hardening time is elongated, the self-placement is also used even if the mixing material is not heated. It can be hardened. By adhering a protective sheet to the surface of the stone stalk material on the side of the stone stalk formed on the stone stalk, the stone stalk can be protected from the treatment. The material is as the substrate material, and for example, a polyethylene terephthalate film, a polypropylene film, Flexible sheet material such as cloth, etc. / As in the above-mentioned 'in this embodiment', the organic poly-stone is used as the main component, and the reaction-hardening type (four) gel material is added as an organic polysulfide. The additive reaction hardening type phase rubber material and the catalyst of the main assembly = are blended in a predetermined ratio and coated on a sheet substrate by coating, and the heating is simple and short. The time is low to form the dish 2, and the insertion angle of the needle is 20 to 20. The thin plate of the zephyrone gel sheet. As a result, in the form of the application, only the surface of the gel sheet is rubberized, which not only strengthens Special force and can be m body! The mechanical strength of the material, while retaining the gel cross section, a does not "^ 彳 冲 、 、 、 裁 裁 裁 裁 裁 裁 裁 裁 裁 裁 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 彳 ' ' ' ' ' ' ' ' Short, can form a product that is sentence-like: the sheet. Further, in the manufacturing method of the present embodiment, a special device such as a line irradiation can easily constitute a manufacturing step, and thus the manufacturing cost can be made more inexpensive by the use of 97114492 11 200904630. In addition, 'the present application shape is different from φ _ 〜, the middle system is used to bond the raw materials to the substrate and integrally form the fluorenone gel sheet, and the 帷* ding is not limited to this, and the ketone ketone can also be condensed. Glue lucky: ι (four) (four) into a monomer. For example, when at the peripheral part used, the two sides of the front and back are not in the condition of tracking the hardship & master, ^ πσ forced opening, and the anthrone gel sheet is used in the form of an early body. In this case, the substrate is formed by using a substrate such as a polyethylene terephthalate film or a polypropylene film which has been subjected to release treatment in advance, or a fluorine-processed paper which is subjected to fluorine processing, etc. sheet. In the μ m form, 'the filler material is not contained in the blended material, but it may be added as a filler in the domain of hydrogen peroxide, iron oxide, hindered _, pottery, glass fiber, carbon fiber, carbon material, etc.; The organic alkoxy compound (IV) compound and the organic gas are combined with an organic stone such as an Ashixia compound and a low molecular weight sand-oxygen compound to be surface-treated. In this case, by adding the filler, it is possible to control the thermal conductivity and the electric resistance value of the oleanol gel sheet. Further, when the preparation material is blended into the filler, the sinking of the filler is utilized. The killing effect 'the presence of a filler locally on the one-sided surface ensures that the surface strength of the film is reduced' and that a sheet having good product uniformity can be formed with a short forming time. Further, in the present embodiment, the catalyst is contained in the raw material, but it may be omitted. In addition, it is also possible to replace the catalyst and add a filler to the blended raw material. Further, in the present embodiment, a protective sheet is bonded to the surface of the fluorenone gel sheet on the side of the oxime ketone sheet to protect the fluorenone gel sheet, but it may be omitted as needed, in the case of 97114492 12 200904630. Next, the description will be made with respect to the embodiments. Fig. 1 is not a schematic view showing a step of forming an anthrone gel sheet bonded to a polyethylene terephthalate film (substrate). The fluorene ketone gel material is 94 parts by weight of CY52~276 (manufactured by T0RAY Dow Corning Co., Ltd.), 6 parts by weight of NR6200 (made by Wacker Asahikasei Silicon Co., Ltd.), and 5 parts by weight of platinum catalyst. It is carried out, mixed, and adjusted to prepare raw materials. The formulated raw material u is supplied to the coating device 12. A polyethylene terephthalate film 14 (thickness 5 〇 #m) which is continuously supplied and wound with a primer applied to the reel 3 is supplied to the coating device 12' to be formed on the film 14. The overall thickness of the coated raw material u on the surface is 300 μm/zm. The film 14 coated with the raw material 11 was cured by passing through the 150C drying furnace 15 for 5 minutes. Thereby, it is possible to obtain a fluorene ketone gel sheet which is integrated with the polyethylene terephthalate film on one side and has a surface strength and has a gel-specific cushioning property (16. In addition, The ketone ketone sheet is continuously wound on the roll 19 in a state 18 in which the protective film 17 of the protective sheet is attached to the side of the ketone material. Next, the fluorenone gel sheet of the present invention is subjected to stretching. The results of the measurement of the strength and the needle insertion degree are described. In addition to the test articles of the above examples, there are still an anthrone gel material (T〇RAY·D〇w ^""CYC-made CY52" -276) Set as 98, 9 〇, 70, 50 parts by weight as shown in the following Table 1, and 2, 10, 30, 50 parts by weight with an anthrone rubber material (Wacke; r Silicone Co., Ltd.) There are five kinds of test products, such as 1 to 5. In addition, reference products!, 2 series are prepared 97114492 13 200904630. Each of CY52-276 is 100, 0 parts by weight and LR7665 are 〇 and 100 parts by weight, respectively. The shape of the test piece was measured according to JS Κ6251 Dumbbell No. 3, and the shape of the test piece for needle insertion measurement was 5〇. X30mm Test method for tensile strength is based on JIS K6251, and the test method for needle insertion degree is carried out according to the method of JIS K2207. The test results are shown in the following Table 1. [Table 1] Test article reference product 2 3 Formulation ratio ketone gel / ketone squid tensile strength (MPa) needle insertion degree 4 5 2 98/2 94/6 90/10 70/30 50/50 100/0 0.0043 197 0/100 I. 0079 117 0. 25 81 0. 42 41 0.60 0.0023 - -----L_u__28 16 As shown in Table 1, 'the test article 1 to 5 is inserted at a degree of 20 to 200' and maintains the appropriate elasticity unique to the gel and has a tensile strength of 0.0030~适当.60MPa of the appropriate mechanical strength. Therefore, only the reference of the oleanone gel material is lower than the test product, and the result of lower tensile strength is found, and only the reference product 2 of the fluorenone rubber material is compared. Under the test article, 'the result of low needle insertion and low elasticity is obtained. (Industrial Applicability) The present invention condenses the petrochemical type by adding an organic polyoxane as a main component. The rubber material and the addition reaction hardening type fluorenone rubber material mainly composed of organic polychlorite and the coating device are in the sheet A material on the A material is blended and spliced, and coated on a sheet-like substrate, which is hardened, which contributes to the simplicity and 310 97114492 14 200904630. The low-cost formation improves the mechanical strength of the overall sheet and maintains the condensation. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic explanatory view showing a manufacturing step of an anthrone gel sheet according to an embodiment of the present invention. [Explanation of main component symbols] 11 Preparation of raw materials 12 Coating device f 13 Reel 14 Polyethylene glycol bismuth acrylate film 15 Drying furnace 16 Indolinone gel sheet 17 Protective film 18 Protective film state of the protective sheet 19 reels 97114492 15