200829281 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種棒狀化妝料。更詳細為關於一種保 里1·生使用感（特別是塗布時之塗抹性、光澤）極為優里之 棒狀化妝料。 【先前技術】 杯狀化妝料作為例如口紅、唇膏、唇蜜、唇筆等嘴唇 用化妝料係為重要。 、 /等田中油性型之嘴唇用化妝料係於液狀油成分（例 如，藥麻油、荷荷色油、1:烧、羊毛脂、各種合成醋油、 液態石蝶)與壞（固㈣：例如卡拿巴蝶（car贿ba挪）、堪 里拉V (candelilla wax)、地蠟（ceresin评紅）、微晶蠟 (micr〇crystalline wax )、硬化動物油、硬化植物油、蜜樣) 之混合物分散有粉體。 八上述油性型之嘴唇用化妝料係必須藉由壤與液狀油成 刀之混合比例之調節來使製品滿足必要之保型十生以及使用 感(特別是塗布時之塗抹性、光澤）。然而，同時滿足充分 之保型性與使用感為非常地困難。 因為壤係液狀油成分固化之必須成分，於使用時為了 :持製品之外形(保型性），必需要配合足夠的量。然而， 右蠟之配合量多’貝塗布時需以較重之塗抹力道，另外， 因液狀油成分造成所發揮之光澤降低。因&，由於此矛盾 現象，要提供滿^保型性與使用感兩方面之唇用化妝料係 極為困難。 5 200829281 保型性與使用感兩者均優異之嘴唇用化妝料為市場之 長年需求’目前多研究者正進行著許開發努力。 為了解決上述課題，少量即賦予充分保型性之蠟有將 費托蠟（FiSCher-Tr0pschwax)與微晶蠟混合之蠟，而作為保 型劑方面’係使用有口紅等棒狀固體化妝料（專利文獻U。 然而’費托蝶由於其碳分布狹窄，故將使用此蠟之嘴 唇用化妝料塗布於唇時，有表面打滑感之課題存在。 另一方面’使用感佳之蠟方面，於嘴唇用化妝料係廣 泛使用有聚乙烯蠟（專利文獻2)。 專利文獻1 :特開2002-348204 專利文獻2 :特開昭58-15904 【發明内容】 本發明人等為了解決上述課題努力進行研究之結果， 發現在使用於口紅等之各種聚乙烯蠟之中，將結晶化開始 概度為80〜95 C者與結晶化開始溫度為以〜丨〇(rc之微晶蠟 以特定之比例加以混合之蠟組成物，作為棒狀化妝料之固 體劑係賦予優異之硬度。然後，發現若將此蠟組成物配合 於a ΙΟΒ値為0.2以上之極性較高之油成分為3〇%以上之 油成刀貝丨不會損及聚乙烯特有之使用性良好程度，即使 蠟組成物為少量，亦可製造具備優異保型性、優異塗抹性 與光澤之棒狀化妝料，而本發明於焉完成。 本發明之目的係提供一種棒狀化妝料，藉由將特定之 蠟組成物作為固體劑使用，即使少量配合亦可賦予製品充 刀之硬度，且亦無結晶化開始溫度之問題，具備優異保型 6 200829281 性、優異之塗抹性與光澤。 本發明係如下述。 1 : 一種棒狀化妝料，其特徵為：含有 (a) 結晶化開始溫度為80〜951之聚乙烯蠟、與 (b) 、、、口日日化開始溫度為$ $〜1⑼。c之微晶躐， 質量比為（a) ·· (b) = 99 : 1 〜60 : 40， 且進一步含有 (c) I〇B為〇·2以上之液狀油成分3〇質量％以上。 2 ·如上述之棒狀化妝料，其中，該成分與成分 之結晶化開始溫度之差係丨〇°c以下。 3 ·如上述之棒狀化妝料，其中，該棒狀化妝料之硬度 係 〇· 1 〜0.3N。 4 ·如上述之棒狀化妝料，其中，該棒狀化妝料係嘴唇 用化妝料。 5 ·如上述之棒狀化妝料，其中，前述嘴唇用化妝料係 進一步含有色材之口紅。 使用於本發明之聚乙烯蠟、微晶蠟與所構成之蠟纟且 物對於特定極性油成分，可發揮優異固體劑之機能。其沾 果，即使配合量少、，亦可賦予含有特定極性油&分之= 化妝料充分之硬度，因此可確保優異保型性。進一步7 ^ 提供具有優異之塗抹性與光澤之棒狀化妝料。 可 【實施方式】 以下，詳述本發明。 「（a)結晶化開始溫度為8〇〜95°C之聚乙烯蠟」 7 200829281 。使用於本發明之聚乙烯蠟之結晶化開始温度為80〜95 為8 5 9 5 C。結晶化開始溫度未滿8 0 °C則油成分 之固化力會變低。結晶化開始溫度若超過95°C，則由併用 微晶蝶所產生之硬度上昇效果會變小，並且，棒狀化妝料 之製造亦變得困難。 聚乙烯蠟可使用市售品。具體而言，使用下述市售品。 「PERFORMALENE400/500/PL、聚蠟 400/500」（貝克 百特來公司製）、「A-C17〇2」（漢威公司製）、「Ep〇lene_N34 •35」（伊士曼公司製） (a) 成分之配合量係因應（b)成分之配合量，適當地決定 以滿足本發明要件之質量比。 相對於棒狀化妝料總量，通常為1〜2〇質量％，較佳為 3〜15質量％，更佳為5〜12質量°/〇。 「（…結晶化開始溫度為以〜丨㈧它之微晶蝶」 。 本發明所使用之微晶蠟之結晶化開始溫度為85〜1〇〇 C，更佳為85〜95。(：。結晶化開始溫度未滿85^者，其之 添加效果小。另外，結晶化開始溫度若超過1〇〇χ：，則製 造變為困難。 於本發明可利用市售品。具體而言，使用下述市售品。 「Hi-Mic-2095/1090」（曰本精蠟公司製）、「畢斯查爾 A」 ST AR WAX 100」（以上為貝克百特來公司製）、 「阿斯塔蠟8618/95 08」（IGI公司製） (b) 成分之配合量係依照（a)成分之配合量，滿足本發明 要件之質量比之方式適當地決定。 200829281 相對於嘴唇用化妝料總量，通常為〇·1〜10質量0/。，較 佳為0·3〜8質量％，更佳為1〜5質量％。 將（a)成分與（b)成分以（a) : (b) = 99 ·· 1〜60 : 40之質量 比加以混合之蠟組成物係作為固體劑使用於本發明之嘴唇 用化妝料。 較佳質量比為（a) : (b) = 97 ·· 5〜70 : 30。200829281 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a rod-shaped cosmetic. More specifically, it is a stick-shaped cosmetic which is extremely excellent in the use of the lining 1 (especially the spreadability and gloss at the time of coating). [Prior Art] Cup-shaped cosmetics are important as lip cosmetics such as lipsticks, lipsticks, lip glosses, and lip pencils. / / Tanaka oily type of lip cosmetics used in liquid oil components (for example, sesame oil, lotus oil, 1: burning, lanolin, various synthetic vinegar oil, liquid stone butterfly) and bad (solid) (four): For example, a mixture of Carnauba butterfly, candelilla wax, celesin (ceresin red), microcrystalline wax (micr〇crystalline wax), hardened animal oil, hardened vegetable oil, honey-like) There is powder. The above-mentioned oily type of lip cosmetic material must be adjusted by the mixing ratio of the soil and the liquid oil forming knife to satisfy the necessary shape retention and the feeling of use (especially the spreadability and gloss at the time of coating). However, it is extremely difficult to satisfy sufficient shape retention and use at the same time. Because the essential components for the solidification of the liquid oil component of the soil are used, it is necessary to mix a sufficient amount in order to maintain the shape of the product (conformity). However, the blending amount of the right wax is required to be applied with a heavier coating force, and the gloss due to the liquid oil component is lowered. Because of this contradiction, it is extremely difficult to provide a lip cosmetic that is both full and protective. 5 200829281 Cosmetics for the lips, which are both excellent in both shape retention and use, are the market's long-term needs. At present, many researchers are working on development efforts. In order to solve the above problem, a wax which imparts a sufficient amount of shape retention property is a wax which blends Fischer-Tropsch wax (FiSCher-Tr0pschwax) with a microcrystalline wax, and as a shape-retaining agent, a stick-like solid cosmetic such as lipstick is used. Patent Document U. However, due to the narrow carbon distribution of the Fischer-Tropsch butterfly, the application of this wax lip cosmetic to the lips has a problem of slippery surface. On the other hand, the use of wax is good in the lips. In particular, the inventors of the present invention have tried to solve the above problems by using the polyethylene wax (Patent Document 2). Patent Document 1: JP-A-2002-348204 Patent Document 2: JP-A-58-15904 As a result, it has been found that among various polyethylene waxes used for lipsticks and the like, the crystallization starting degree is 80 to 95 C and the crystallization starting temperature is 丨〇 (the microcrystalline wax of rc is specified in a specific ratio. The mixed wax composition imparts excellent hardness as a solid agent of the rod-shaped cosmetic. Then, it was found that when the wax composition is blended with a ΙΟΒ値 of 0.2 or more, the oil component having a higher polarity is 3% by weight or more. The oil-formed scallop does not impair the practicability of the polyethylene, and even if the wax composition is small, a rod-shaped cosmetic having excellent shape retention, excellent spreadability and gloss can be produced, and the present invention is The object of the present invention is to provide a rod-shaped cosmetic which can be used as a solid agent by using a specific wax composition, and can impart a hardness to the product without a crystallization start temperature even if it is blended in a small amount. Excellent shape retention 6 200829281 Properties, excellent spreadability and gloss. The present invention is as follows. 1 : A rod-shaped cosmetic material comprising: (a) a polyethylene wax having a crystallization start temperature of 80 to 951, and (b), ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, I 〇 B is 3% or more of the liquid oil component of 〇 2 or more. 2 The above-mentioned rod-shaped cosmetic material, wherein the difference between the crystallization start temperature of the component and the component is 丨〇 ° c or less. a stick-shaped cosmetic material as described above, wherein the stick-shaped cosmetic material The above-mentioned stick-shaped cosmetic, wherein the stick-shaped cosmetic is a cosmetic for lips. 5 - The above-mentioned stick-shaped cosmetic, wherein the lip cosmetic is Further, the lipstick containing the color material is used. The polyethylene wax, the microcrystalline wax and the wax composition used in the present invention can exhibit an excellent solid agent function for a specific polar oil component. It is also possible to impart a sufficient hardness to a specific polar oil & = cosmetic, so that excellent shape retention can be ensured. Further, a bar-shaped cosmetic having excellent spreadability and gloss can be provided. The invention is described in detail. "(a) Polyethylene wax having a crystallization start temperature of 8 〇 to 95 ° C" 7 200829281 . The crystallization starting temperature of the polyethylene wax used in the present invention is from 80 to 95, which is 8 5 9 5 C. When the crystallization start temperature is less than 80 °C, the solidification force of the oil component becomes low. When the crystallization starting temperature exceeds 95 °C, the effect of increasing the hardness caused by the combined use of the microcrystalline butterfly becomes small, and the production of the rod-shaped cosmetic material becomes difficult. Commercially available products can be used for the polyethylene wax. Specifically, the following commercial items are used. "PERFORMALENE 400/500/PL, Poly Wax 400/500" (Baker Baxter), "A-C17〇2" (manufactured by Hanwei), "Ep〇lene_N34 •35" (manufactured by Eastman) (a) The blending amount of the components is appropriately determined in accordance with the blending amount of the component (b) to satisfy the mass ratio of the requirements of the present invention. The total amount of the rod-shaped cosmetic is usually 1 to 2% by mass, preferably 3 to 15% by mass, more preferably 5 to 12% by mass. "(...the crystallization start temperature is 微(8) its microcrystalline butterfly." The crystallization start temperature of the microcrystalline wax used in the present invention is 85 to 1 〇〇C, more preferably 85 to 95. When the crystallization start temperature is less than 85, the effect of addition is small. When the crystallization start temperature exceeds 1 〇〇χ, the production becomes difficult. In the present invention, a commercially available product can be used. Specifically, The following commercial products are available: "Hi-Mic-2095/1090" (manufactured by Sakamoto Fine Chemical Co., Ltd.), "Bischar A" ST AR WAX 100" (above is Beck Baxter), "Aspen (B) Wax 8618/95 08" (manufactured by IGI) (b) The amount of the component is appropriately determined according to the blending amount of the component (a), and the quality ratio of the requirements of the present invention is appropriately determined. The amount is usually 〇·1 to 10 mass%, preferably 0. 3 to 8 mass%, more preferably 1 to 5 mass%. The component (a) and the component (b) are (a) : ( b) = 99 ··1 to 60: 40 The mass of the wax composition to be mixed is used as a solid agent for the lip cosmetic of the present invention. (A): (b) = 97 ·· 5~70: 30.
將（a)成为與（b )成分以上述質量比混合時，本發明之棒 狀化妝料之硬度係表現出臨界之非常高之値。亦即，上述 蠟組成物作為固體劑係發揮極優異之效果。 虫k組成物只要將（a)成分與（b)成分以上述之質量比加以 加熱攪拌即可。較佳為將此蠟組成物作為棒狀化妝料之固 體劑配合於液狀油成分。 此蠟組成物作為以往固體劑（特別是多用於口紅之地蠟） 之代替品之使用價値大。 力 ......* π苁的it況下， 2滿足上述質量比之方式分別配合於液狀油成分並攪拌， 藉此製造棒狀化妝料。 壤組成物之配合量{(a)成分與（b)成分之合計配合 依照棒狀化妝料之種類適當地決定。 旦 和對於棒狀化妝料總 里，以2〜20質量％以上為佳，更佳 皂ς 1 人丨土馬5〜2〇質量％，特佳 為5〜15質量％。 寸1 能 ㈤合量為未滿2質 ^货輝作為固體劑之機 有時對於製品之保型性會產生問題 配口里若超過20質量％，則製品有 ’過硬、塗抹性與光 9 200829281 澤受到阻礙之情況。 效果之範圍内， 分之合計配合量 亦 另外，於本發明中，在不損及發明 可含其他犧。其量相對於⑷成分與（b)成 以50°/。以下為佳。 本發明之棒狀化妝料而言，將咖為〇.2以上之油成 分，相對於棒狀化妝料總量配合3〇%以上，更佳$桃以 上。右非如此，則本發明之效果無法發揮。大量使用【OB 低之油成分的情況時，即使I组成物之配合量多亦無法期 待有高硬度。上限為95%’就成型而言以9〇%左右為佳。 此蠟組成物即使少量配合亦可賦予棒狀化妝料充分之 硬度。因此，可提供一種棒狀化妝料（特別是嘴唇用化妝 料），其由液狀油成分所產生之塗抹性與光澤不會受損，且 具有優異保型性。 進一步而言’在棒狀化妝料之製造中，由結晶化開始 溫度之觀點來看亦無問題。 本Is明所使用之IOB為0.2以下之油成分並無特別限 定。可列舉例如以下之油成分。 二癸酸新戊基乙二醇酯、三2-乙基己酸甘油酯、四2_ 乙基己酸新戊四醇酯、三（辛/癸）酸甘油酯、癸二酸二乙基 己酉旨、辛基十二醇、二異硬脂酸甘油酯、三異硬脂酸二甘 油醋、蘋果酸二異硬脂醇酯、三2-乙基己酸三羥曱基丙烧 酉旨、羥硬脂酸羥硬脂醇酯、四（乙基己酸/苯甲酸）新戊四醇 酯、蓖麻油。 另外，除上述之IOB為〇·2以下之油成分之外，亦可 10 200829281 配合通常化妝料所使用之油成分。 較佳之液狀油成分如以下。 一甲基聚石夕氧烧、十甲美援21^7 > 丁1f I%五矽氧烷、澳洲胡桃 (macadamia nuts)油、荷荷芭油、鲨 订巴冲魚说、液狀羊毛脂、三（氫 化权香-異硬脂酸）甘油酉旨、 日T基本基聚矽氧烷、三異硬脂 酉文甘油酯、聚丁烯、聚異丁稀。 特別是’於口紅配合液狀羊毛脂、三（氫化松香異硬 脂酸）甘油醋、曱基苯基聚石夕氧烧、三異硬脂酸甘油醋、聚 丁烯者為佳。 為了使口紅之化妝持久性變佳，揮發性之液狀油成分 甲基環四錢垸、十甲基環五㈣燒、十二曱基環六石夕 氧烷等之環狀矽油）亦佳。 液狀油成分之配合量相對於棒狀化妝料總量通常為 3二98質量％，較佳為5q〜95 f量％。若液狀油成分之配合 里又v，則由於塗抹性有變差之傾向，故5〇質量％以上之 配合量為佳。 於本發明之棒狀化妝料，除了液狀油成分之外，視需 要亦可併用固體油成分、半固體油成分。 本發明之棒狀化妝料除上述必須成分之外，在不損及 本發明效果之範圍内，可視需要適當地配合其他之蠟、其 之油成为、保濕劑、防腐劑、抗氧化劑、紫外線吸收劑、 、 :刀子、界面活性劑、色素、顏料、粉末、藥劑、醇、溶 ^、香料’並可依照製品之種類以通常之方法製造。 本發明之棒狀化妝料因使用時之折斷或安定性而需要 11 200829281 0· IN〜0.3N左右之適度的硬度。於此處所述之硬度意指使 用流變技術公司（Rheotech Industrial CO·，Ltd.)製流變儀， 將於30°C放置1小時之試樣，以感壓軸1 0、穿入速度 2cm/min、穿入度3mm測定之情況之値。 本發明之棒狀化妝料只要是具有一定硬度之固體狀棒 狀化妝料即無限定。可列舉例如··口紅、唇蜜、唇膏等棒 狀嘴唇用化妝料；粉底、眼影等棒狀化妝用之化妝料；髮 犧條（hair stick)、髮油（pomade)等棒狀毛髮化妝料。以令 人感到良好使用感之嘴唇用化妝料為佳、特別是以配合粉 末色材之口紅為佳。 本發明之棒狀化妝料藉由特定結晶化開始溫度之（^成 刀與（b)成分所構成之虫鼠組成物來達成優異之保型性及使用 感。 其理由不明，但推測如以下所述。 亦即，本發明之棒狀化妝料各蠟之微細結晶係網眼狀 彼此互相連結而形成骨架。液狀油成分係被包含在此骨架 中’全體被保持為固體狀。 各壤之微細結晶構 因此吾人推測本發 為最適之方式，將 棒狀化妝料之構造及性質係受到 造、大小、液狀油成分之種類所影響， 明之％組成物可能是以保型性及使用感 液狀油成分固化。 實施例 接著列舉實施例進一步 不受到以下之實施例限定。 具體地説明本發曰月 配合量只要無特別 。本發明並 限定係以質 12 200829281 量％表示。 「固體劑：蠟組成物」 藉由（a)成分與（b)成分之結晶化開始溫度、混合比為相 異之蠟組成物，使液狀油成分固化。該固體物係可直接作 為唇膏使用者。 首先，（a)成分方面係使用結晶化開始溫度80°C、87°C 之聚乙烯蠟，作為此比較例係使用97°C之聚乙烯蠟。 以下使用之聚乙烯蠟係下述者。 「聚乙烯蠟（1)」—「PERFORMALENE400(結晶化開 始溫度80°C )」 「聚乙烯蠟（2)」—「PERFORMALENEPL(結晶化開始 溫度87°C )」 「聚乙烯蠟（3)」->「PERFORMALENE655(結晶化開 始溫度97°C )」 (全部為貝克百特來公司製） (b)成分方面，係表示組合有結晶化開始溫度86°C之微 晶蠟（「微晶蠟（1)」—曰本精蠟公司製「Hi-Mic_1090」）之 情況下之硬度。 ， 測定蠟組成物10質量％與IOB為0.2以上之液狀油成 分（四2-乙基己酸新戊四醇酯）90質量％混合所得到之固體 物之硬度。 所使用之硬度計係流變技術公司製流變儀。將於30°C 放置1小時之試樣，以感壓軸1 0、穿入速度2cm/min、 穿入度3mm測定。 13 200829281 將結果表示於「表1」。 [表1] 結晶化 開始溫 度 實施例 1 實施例 2 比較例 1 比較例 2 比較例 3 比較例 4 比較例 5 聚乙烯蠟(1) 80°C 8 10 聚乙烯蠟(2) 87〇C 8 10 聚乙烯蠟(3) 97〇C 8 10 微晶蝶⑴ 86〇C 2 2 2 10 四2-乙基己酸新戊四醇酯 90 90 90 90 90 90 90 合計 100 100 100 100 100 100 100 製造 無問題 無問題 困難 無問題 無問題 困難 無問題 硬度(N) 0.29 0.36 0.53 0.19 0.25 0.54 0.Π 由此結果可明瞭若併用結晶化開始溫度80〜95°c之聚 乙烯蠟與微晶蠟，相較於單獨使用之情況，可得到高硬度。 另一方面，蠟組成物之結晶化開始溫度在製造上完全無問 接著，藉由（a)成分與（b)成分之結晶化開始溫度、混合 比為相異之堪組成物，使液狀油成分固化。測定將總鐵組 成物定為5.6質量％，並與液狀油成分（四2-乙基己酸新戊 四醇）94.4質量％混合所得到之固體物之硬度。 (a)成分係使用結晶化開始溫度87°C之聚乙烯蠟（貝克 百特來公司製PERFORMALENEPL)。（b)成分係使用結晶 化開始溫度為86、87、98°C之微晶蠟，以及作為比較例之 80°C之微晶蠟。 所使用之微晶蠟係下述者。 「微晶蠟（1)」—「日本精蠟公司製Hi-Mic-1090(結晶 化開始溫度86°C )」 14 200829281 「微晶蠟（2)」->「IGI公司製阿斯塔蠟9508(結晶化 開始溫度87°C )」 「微晶蠟（3)」「日本精蠟公司製Hi-Mic-2095(結晶 化開始溫度99°C )」 「微晶蠟（4)」—「威特科公司製MULTIWAXW-445(結 晶化開始溫度80°C )」 將結果表示於「圖1」。 由此結果明瞭混合比為（a) : (b) = 99 : 1〜60 : 40，較佳 為（a) ·· (b) = 95 ·· 5〜60 ·· 40，更佳為（a) : (b) = 90 : 10〜7〇 : 30 時，固體物（棒狀化妝料）之硬度大幅地增大。 另外，成分（a)與（b)之結晶化開始溫度差為10°C以下 之情況下，可得到高相乘效果，上述數値有臨界的意義。 另一方面，堪組成物之結晶化開始溫度在製造上完全 無問題。 「嘴唇用化妝料」 製造於表2所表示之口紅，並檢討本發明之效果。 〔表2之口紅之製造方法〕 將各處方成分加熱至l〇〇°C，攪拌混合、脫泡之後， 流入金屬模，冷卻至5 °C而製造口紅。 [保型性] 藉由目視評估。 (評估基準） ◎:優異（優異之固體狀態） 〇··稍優異（稍優異之固體狀態） 15 200829281 △:不良（糊狀〜柔軟） X :極不良（液狀） [塗布時之塗抹性] 八專門W平審員（1 0名）係使用口紅進行5階段感覺性的評 數）藉由分數之平均値，以下述評估基準判定。 (分數） 5點··塗布時之塗抹力道為輕 4點··塗布時之塗抹力道為稍輕 3點·塗布時之塗抹力道為普通 點.塗布時之塗抹力道為稍重 1點：塗布時之塗抹力道為重 (評估基準） ◎•分數（平均値）4·〇以上、5〇點以下 〇·分數（平均値）3·〇以上、未滿4〇點 厶·分數（平均値）2·0以上、未滿3〇點 X ·分數（平均値口.0以上、未滿 2.0點 [光澤] (八* 、員（1 〇名）使用口紅進行5階段感覺性的評估 藉由分數之平均値，以下述評估基準判定。 (分數） 5點：有光澤 4點：稍有光澤 3點：光澤為普通 2點：稍無光澤 16 200829281 1點：無光澤 (評估基準） ◎•分數（平均値）4·〇以上、5 〇點以下 〇 ·分數（平均値）3·〇以上、未滿4 〇點 △•分數（平均値）2·〇以上、未滿3〇點 X ·分數（平均値）1〇以上、未滿2 〇點 [表2] _ —--- 實施制 比較例 _ 配合成分 IOB 1 2 3 1 2 3 聚乙烯壤(2) 6.3 5.6 5.6 5.6 7 10 — 微晶蠟⑴ 0.7 1.4 1.4 1.4 聚異丁烯 0 20 20 20 20 20 20 液態石蠟 0 29.5 69.5 二聚一亞油酸二(異硬脂-植物固醇)酯 0.11 10 10 10 10 10 二異硬脂酸二甘油酯 0.26 10 10 10 10 10 蘋果酸一異硬脂醇酷 0.27 10 10 10 10 10 四2-乙基己酸新戊四醇酷 0.35 39.5 39.5 10 39.5 36.5 紅色202號 - 0.1 0.1 0.1 0.1 0.1 0.1 氧化鐵紅 '~ 1.5 1.5 1.5 1.5 1.5 1.5 黄氧化鐵 J 0.5 0.5 0.5 0.5 0.5 0.5 氧化鈦 1.2 1.2 1.2 1.2 1.2 1.2 生育酚 '^' ~ -- 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 _______ 合計 100 100 100 100 100 100 IQB0^^油成分合計 59.5 59.5 30 0 59.7 56.7 _____^_ 硬度 0.23 0.22 0.18 0.09 0.12 0.24 _^__ 保型性 ◎ ◎ 〇 X r Δ ◎ ___步時之塗抹性 ◎ ◎ ◎ ◎ ◎ V ____先澤 ◎ ◎ ◎ ◎ /\ Λ 總合地考慮上述檢討結果，發現藉由特定結晶化開始 溫度之（a)成分與（b)成分所構成之堪組成物，可達成優異保 型性以及使用感。 於以下進一步列舉本發明之實施例。 實施例4 口紅 17 200829281 (1)聚乙烯蠟（2) 5.0 % (2)微晶蠟（2) 3.0 (3)卡拿巴蠟 1.0 (4)四（乙基己酸/苯甲酸）新戊四醇酯 20.0 (5)蓖麻油 15.0 (6)葵花油 2.0 (7)二甲基聚矽氧烷 10.0 (8)板狀氫氧磷灰石 3.0 (9)雲母 10.0 (10)氧化鐵紅 1.0 (11)氧化鈦 2.0 (12)紅色202號 0.1 (13)紅色218號 0.02 (14)維生素A棕櫊酸 0.1 (15)生育酚 0.1 (16)香料 0.1 (17)二癸酸新戊基乙二醇酯 殘餘量 將於此例所示之各處方成分加熱至95°C， 攪拌混合、 脫泡之後，充填於口紅容器，冷卻至5 °C得到 口紅。此化 妝料係無色材凝集等製造中之問題，保型性、 時之塗抹性、光澤）優異。 實施例5 口紅 使用感（塗布 (1)聚乙烯蠟（2) 8.0 % (2)微晶蠟（1) 2.0 (3)聚異丁烯 10.0 18 200829281 (4)液狀羊毛脂 (5) 月桂酸基麵胺酴_ — 土您妝歧一（植固醇/辛基十 (6) 嶺果酸二異硬脂醇酉旨 (7) 二異硬脂酸甘油酉旨 (8) 經硬脂酸異硬脂醇醋 (9) 甲氧基桂皮酸辛酉旨 2.0 二烷基）酯 10.0 20.0 10.0 10.0 (10)硫酸鋇 5.0 (11) 氧化鐵紅被覆雲母鈦 (12) 氧化鈦 l ·0 1.0 "5 Λ (13)紅色202號 ό . U 〇 ς (14)紅色201號 0 1 (15)紅色218號 0.1 (16)尼龍-12 3.0 (17)生育酚 0.1 (18)香料 0.1 (19)二2 -乙基己酸甘油酉旨 殘餘量 將於此例所示之各處方成分加熱至9 5 °C，攪拌混合、 脫泡之後、充填於口紅容器、冷卻至5 °C得到口紅。此化 妝料亦無色材凝集等製造中之問題，保型性、使用感（塗布 時之塗抹性、光澤）優異。 實施例6 口紅 (1)聚乙烯蠟（2) 6.0 % (2)微晶蠟（1) 1.5 (3)堪地里拉蠟 2.0 (4)鯊烷 10.0 19 200829281 (5)蓖麻油 20.0 (6)三異硬脂酸甘油酯 10.0 (7)三甲基五苯基三矽氧烷 5.0 (8)醋酸生育酚 0.1 (9)紅色201號 0.5 (10)紅色202號 0.3 (11)黃色4號 1.5 (12)氧化鈦 1.0 (13)胭脂紅被覆雲母鈦 1.0 (14)生育酚 0.1 (15)香料 0.1 (16)二癸酸新戊基乙二醇酯 殘餘量 (製法） 將於此例所示之各處方成分加熱至95°C，攪拌混合、 脫泡之後，充填口紅容器，冷卻至 5 °C得到口紅。此化妝 料係亦無色材凝集等製造中之問題 ，保型性、使用感（塗布 時之塗抹性、光澤）優異。 實施例7 口紅 (1)聚乙烯蠟（2) 8.5 % (2)微晶蠟（2) 1.5 (3)費托蠟 1.0 (4)合成異構石蠟 10.0 (5)三2 -乙基己酸甘油酯 30.0 (6)蘋果酸二異硬脂醇酯 10.0 (7)甲基苯基聚矽氧烷 10.0 20 200829281 (8)橄欖油 5.0 (9 )卵石粦脂 0.1 (10) 球狀纖維素粉末 1.0 (11) 氧化鈦被覆玻璃粉末 2.5 (12) 黃氧化鐵 0.8 (13) 紅色 202 號 1.1 (14) 氧化鈦 2.0 (15) 雲母鈦 1.0 (16) 生育酚 0.1 (17) 二異硬脂酸甘油酯 殘餘量 (製法） 將於此例所示之各處方成分加熱至90°C，攪拌混合、 脫泡之後，充填口紅容器，冷卻至5 °C得到口紅。此化妝 料亦無色材凝集等製造中之問題，保型性、使用感（塗布時 之塗抹性、光澤）優異。 實施例8 口紅 (1)聚乙烯蠟（2) 10.0 (2)微晶蠟（1) 2.0 (3)聚丁烯 5.0 (4)三異硬脂酸甘油酯 15.0 (5)四2-乙基己酸新戊四醇酯 15.0 (6)鯊烷 10.0 (7)磷酸氫鈣 0.5 (8)氧化鐵紅 2.1 (9)黑氧化鐵 0.1 21 200829281 (10)氧化鈦 2.3 (11)藍色1號 0.2 (12)生育酉分 0.1 (1 3)液態石虫鼠 殘餘量 (製法） 將於此例所示之各處方成分加熱至9 0 °C，授拌混合、 脫泡之後，充填口紅容器，冷卻至5 °C得到口紅。此化妝 料亦無色材凝集等製造中之問題，保型性、使用感（塗布時 之塗抹性、光澤）優異。 實施例9乳化口紅 乳化基底： (1)精製水 1.5 (2)四乙酸三鈉 0.01 (3)甘油 0.2 (4)澳洲胡桃油脂肪酸植物固醇酯 3.0 (5)— 曱基石夕油聚醇（dimethiconepolyol) 0.5 (6)甲基苯基聚矽氧烷 10.0 油相： (7)聚乙烯蠟（！） 1.0 (8)微晶蠟（1) 14.0 (9 )二2 -乙基己酸甘油酉旨 35.0 U〇)氫化聚丁烯 10.0 (11)曱氧基肉桂酸辛酯 5.0 (12)二丁基羥基甲苯 0.1 (13)醋酸生育酚 0.1 U4)氧化鐵紅 2.0 22 200829281 GO 一氧化欽 4.0 (16)生育酚 0.1 U7)香料 0.1 , (18)三2-乙基己酸三羥甲基丙烷酯 殘餘旦 β (製法） 首先，將（4)〜(6)加熱混合（油相部份），將（2)、（3)、、六解 於（1)(水相部）之後，於7(TC將此添加分散於前述油相$， - 付到礼化糊。之後，將（7)〜（18)加熱並溶解、混人 4 4 Μ ^ ’添加 该乳化糊，於951：充分攪拌混合，充填至口紅容哭，人乂 問題，保型性、使用感（塗布時之塗抹性、光澤）優異\之 實施例 1 0唇膏 (1)聚乙烯蠟（1) (2)微晶犧（1) 12-〇 % Ο /Λ (3)凡士林 j .0 (4) 六羥基硬脂酸二新戊四醇酉旨 (5) 三異硬脂酸二甘油酯 (6) 蘋果酸二異硬脂醇酯 (7) 醋酸生育酚 (8) L-薄荷腦 (9) 生育酚 (10) 液態石蠟 10.0 l〇.0 15.0 10.0 0.2 〇·〇5 0.1 殘餘量 (製法） 至5 C得到乳化口紅。此化妝料亦無色材凝集等製造中17 23 200829281 將不於此例之各處方成分加熱至85°C，攪拌混合，並 脫泡之後，充填於唇膏容器，冷卻至5 t得到唇膏。此化 妝料亦無製造中之問題，保型性、使用感（塗布時之塗抹性、 光澤）優異。 使用發揮優異固體 品硬度，保型性、 本發明提供一種棒狀化妝料，藉由 劑機此之特定的蠟組成物，而具有高製 使用感極優異。 【圖式簡單說明】 圖1係表示固體物之硬度。 【主要元件符號說明】 無 24When (a) is mixed with the component (b) in the above mass ratio, the hardness of the rod-shaped cosmetic of the present invention exhibits a very high criticality. That is, the above wax composition exerts an extremely excellent effect as a solid agent. The insect k composition may be obtained by heating and stirring the component (a) and the component (b) in the above-mentioned mass ratio. Preferably, the wax composition is blended as a solid agent for a rod-shaped cosmetic with a liquid oil component. This wax composition is used as a substitute for a conventional solid agent (especially a wax which is mostly used for lipstick). In the case of π 苁 , , , , 满足 满足 满足 满足 满足 满足 满足 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The blending amount of the soil composition {the total amount of the component (a) and the component (b) is appropriately determined depending on the type of the stick cosmetic. For the total amount of the rod-shaped cosmetic, it is preferably 2 to 20% by mass or more, more preferably saponin 1 to 5 to 2% by mass, and particularly preferably 5 to 15% by mass. Inch 1 can (5) the total amount is less than 2 quality ^ goods as a solid agent machine sometimes has problems with the shape retention of the product if the mouth is more than 20% by mass, the product has 'excessive, smearing and light 9 200829281 Ze is hindered. In addition, in the range of the effect, the total amount of blending is also included, and in the present invention, other sacrifices may be included without impairing the invention. The amount is 50 ° / with respect to the component (4) and (b). The following is better. In the stick-like cosmetic of the present invention, the oil component of the coffee composition of 2 or more is blended in an amount of 3% by weight or more, more preferably more than $100, based on the total amount of the stick-shaped cosmetic. If this is not the case, the effects of the present invention cannot be exerted. When a large amount of OB low oil component is used in a large amount, even if the amount of the I component is large, the high hardness cannot be expected. The upper limit is 95%', and it is preferably about 9% in terms of molding. This wax composition imparts sufficient hardness to the stick-like cosmetic even if it is blended in a small amount. Therefore, it is possible to provide a stick-shaped cosmetic (especially a cosmetic for lips) which is not damaged by the spreadability and gloss generated by the liquid oil component and which has excellent shape retention property. Further, in the production of the rod-shaped cosmetic, there is no problem from the viewpoint of the crystallization starting temperature. The oil component in which the IOB used in the present invention is 0.2 or less is not particularly limited. For example, the following oil components are mentioned. Neopentyl glycol dicaprate, triethyl 2-ethylhexanoate, tetrakis-2-ethylhexanoic acid pentaerythritol, tris(octyl/decano) glyceride, diethyl sebacate酉, octyldodecanol, diisostearic acid glyceryl ester, triisostearic acid diglyceryl vinegar, diisostearyl malate, tris-2-ethylhexanoic acid trihydroxy decyl propyl hydrazine , hydroxystearyl hydroxystearate, tetrakis (ethylhexanoic acid / benzoic acid) pentaerythritol ester, castor oil. Further, in addition to the above-mentioned IOB being an oil component of 〇·2 or less, it is also possible to mix the oil component used in the usual cosmetics with 10 200829281. Preferred liquid oil components are as follows. 1-methyl poly-stone, Oxygen, 21^7 > Ding 1f I% pentaoxane, macadamia nuts, jojoba oil, sharks, squid, liquid wool Fat, tris(hydrogenated-iso-stearic acid) glycerin, daily T-based polyoxyalkylene, triisostearyl glyceride, polybutene, polyisobutylene. In particular, it is preferred that the lipstick is combined with liquid lanolin, tris(hydrogenated rosin isostearic acid) glycerin vinegar, nonylphenyl polychlorite, triisostearic acid glycerin, and polybutene. In order to make the lipstick makeup more durable, the volatile liquid oil component is preferably ring-shaped eucalyptus oil such as methylcyclotetracycline, decamethylcyclopentaluminum (tetra), twelve-methylcyclohexadecene or the like. . The blending amount of the liquid oil component is usually 3 to 98% by mass, preferably 5 to 95% by volume based on the total amount of the rod-shaped cosmetic. When the composition of the liquid oil component is v, the spreadability tends to be deteriorated, so that the blending amount of 5 〇 by mass or more is preferable. In the stick-like cosmetic of the present invention, in addition to the liquid oil component, a solid oil component or a semi-solid oil component may be used in combination. In addition to the above-mentioned essential components, the rod-shaped cosmetic of the present invention may be appropriately blended with other waxes, oils thereof, moisturizers, preservatives, antioxidants, ultraviolet rays, as needed within the range which does not impair the effects of the present invention. Agents,: knives, surfactants, pigments, pigments, powders, pharmaceuticals, alcohols, solvents, and perfumes can be produced in the usual manner according to the type of the product. The rod-shaped cosmetic of the present invention needs to have an appropriate hardness of about 11 200829281 0·IN~0.3N due to breakage or stability during use. The hardness described herein means a rheometer manufactured by Rheotech Industrial Co., Ltd., which is placed at 30 ° C for 1 hour, with a pressure-sensitive axis of 10 and a penetration speed of 2 cm. /min, the degree of penetration is measured in 3mm. The rod-shaped cosmetic of the present invention is not limited as long as it is a solid rod-shaped cosmetic having a certain hardness. For example, a stick-shaped lip cosmetic such as a lipstick, a lip gloss, or a lipstick; a cosmetic for a stick-like makeup such as a foundation or an eye shadow; and a hair-like cosmetic such as a hair stick or a pomade. . It is preferable to use a cosmetic material for a lip which is good for use, and particularly preferably a lipstick which is compatible with a pink color material. The rod-shaped cosmetic of the present invention achieves excellent shape retention and feeling of use by a pest-forming composition composed of a specific crystallization start temperature and a component of the component (b). The reason is not known, but it is presumed as follows In other words, the fine crystals of each wax of the rod-shaped cosmetic of the present invention are meshed with each other to form a skeleton. The liquid oil component is contained in the skeleton, and the whole is kept in a solid state. The fine crystal structure is therefore the most suitable way for us to speculate that the structure and properties of the rod-shaped cosmetic are affected by the type of the composition, the size, and the liquid oil composition. The % composition may be in shape retention and use. The kinetic oil component is solidified. EXAMPLES The following examples are further excluded from the following examples. Specifically, the present invention is not particularly limited as long as it is present. The present invention is also defined by the mass of 12 200829281%. Agent: wax composition" The liquid oil component is solidified by the crystallization start temperature and the mixture ratio of the component (a) and the component (b), and the liquid oil component is solidified. First, as the component (a), a polyethylene wax having a crystallization start temperature of 80 ° C and 87 ° C was used, and as a comparative example, a polyethylene wax of 97 ° C was used. Wax is the following. "Polyethylene Wax (1)" - "PERFORMALENE 400 (crystallization start temperature 80 ° C)" "Polyethylene wax (2)" - "PERFORMALENEPL (crystallization start temperature 87 ° C)" Vinyl wax (3)"-> "PERFORMALENE 655 (crystallization start temperature: 97 °C)" (all manufactured by Beckerbeck) (b) In terms of composition, it means that the crystallization start temperature is 86 °C. Hardness in the case of a crystalline wax ("microcrystalline wax (1)" - "Hi-Mic_1090" manufactured by Sakamoto Seiki Co., Ltd.), a liquid oil component having a wax composition of 10% by mass and an IOB of 0.2 or more (four The hardness of the solid obtained by mixing 90% by mass of 2-ethylhexanoic acid pentaerythritol ester. The hardness meter used is a rheometer manufactured by Rheology Co., Ltd., which is placed at 30 ° C for 1 hour. It is measured by the pressure sensing axis 10, the penetration speed of 2 cm/min, and the penetration degree of 3 mm. 13 200829281 "Table 1" [Table 1] Crystallization start temperature Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Polyethylene wax (1) 80 ° C 8 10 Polyethylene wax (2 87〇C 8 10 Polyethylene wax (3) 97〇C 8 10 Microcrystalline butterfly (1) 86〇C 2 2 2 10 Tetrakis(2-ethylhexanoate) 90 90 90 90 90 90 90 Total 100 100 100 100 100 100 100 No problem, no problem, no problem, no problem, no problem, no problem, no problem. Hardness (N) 0.29 0.36 0.53 0.19 0.25 0.54 0. Π This result shows that the polyethylene with a crystallization start temperature of 80 to 95 ° C can be used together. Wax and microcrystalline wax can be obtained with high hardness compared to the case of use alone. On the other hand, the crystallization start temperature of the wax composition is completely irrelevant in the production, and the crystallization start temperature and the mixture ratio of the components (a) and (b) are different compositions, and the liquid is obtained. The oil component is solidified. The hardness of the solid obtained by mixing the total iron composition with 5.6% by mass and 94.4% by mass of the liquid oil component (tetraethyl 2-ethylhexanoic acid pentaerythritol) was measured. (a) A polyethylene wax (PERFORMALENEPL manufactured by Baker Baxter Co., Ltd.) having a crystallization start temperature of 87 ° C was used. The component (b) was a microcrystalline wax having a crystallization starting temperature of 86, 87, and 98 ° C, and a microcrystalline wax of 80 ° C as a comparative example. The microcrystalline wax used is as follows. "Microcrystalline Wax (1)" - "Hi-Mic-1090 made by Nippon Seiko Co., Ltd. (crystallization start temperature: 86 ° C)" 14 200829281 "Microcrystalline wax (2)" -> "IGA company Asta Wax 9508 (crystallization start temperature: 87 ° C)" "Microcrystalline wax (3)" "Hi-Mic-2095 manufactured by Nippon Seiko Co., Ltd. (crystallization start temperature: 99 ° C)" "Microcrystalline wax (4)" - "MULTIWAXW-445 (crystallization start temperature: 80 °C) manufactured by Witco Co., Ltd." The results are shown in Fig. 1. From this result, it is understood that the mixing ratio is (a): (b) = 99 : 1 to 60 : 40, preferably (a) · · (b) = 95 ·· 5 to 60 ·· 40, more preferably (a ) : (b) = 90 : 10 to 7 〇: 30, the hardness of the solid matter (rod-like cosmetic) is greatly increased. Further, when the difference in crystallization starting temperature between the components (a) and (b) is 10 ° C or less, a high multiplication effect can be obtained, and the above number is critical. On the other hand, the crystallization start temperature of the composition is completely problem-free in manufacturing. The "lip cosmetic" was produced in the lipstick shown in Table 2, and the effects of the present invention were reviewed. [Method for Producing Lipstick of Table 2] Each component was heated to 10 ° C, stirred and mixed, and defoamed, and then poured into a metal mold, and cooled to 5 ° C to produce a lipstick. [Shaping type] by visual evaluation. (Evaluation criteria) ◎: Excellent (excellent solid state) 〇··Slightly superior (slightly excellent solid state) 15 200829281 △: Poor (paste~soft) X: Extremely poor (liquid) [Applicability at the time of coating] Eight special W-level examiners (10) use a lipstick for a 5-stage sensory evaluation.) The average score of the scores is determined by the following evaluation criteria. (score) 5 o'clock · · The application force at the time of application is 4 o'clock light · · The application force at the time of application is slightly lighter than 3 o'clock · The application force at the time of application is a normal point. The application force at the time of application is slightly heavier: 1 point: The application power is heavy (evaluation basis) ◎•Score (average 値) 4·〇 or more, 5〇 or less 〇·point (average 値) 3·〇 or more, less than 4〇 points·score (average 値) 2· 0 or more, less than 3 points X · Score (average mouth. 0 or more, less than 2.0 points [gloss] (eight*, member (1 〇 name) using lipstick for 5-stage sensory evaluation by average of scores値, judged by the following evaluation criteria. (Score) 5 points: shiny 4 points: slightly shiny 3 points: gloss is ordinary 2 points: slightly dull 16 200829281 1 point: matt (evaluation basis) ◎• score (average値) 4·〇 or above, 5 〇 or less 〇·point (average 値) 3·〇 or more, less than 4 〇 points △ • score (average 値) 2·〇 or more, less than 3〇 point X · score (average値) 1〇 or more, less than 2 [ [Table 2] _ —--- Implementation comparison example _ Composition IOB 1 2 3 1 2 3 Polyethylene soil (2) 6.3 5.6 5.6 5.6 7 10 — Microcrystalline wax (1) 0.7 1.4 1.4 1.4 Polyisobutylene 0 20 20 20 20 20 20 Liquid paraffin 0 29.5 69.5 Dimerized linoleic acid di(isostearyl) Phytosterol ester 0.11 10 10 10 10 10 diisostearic acid diglyceride 0.26 10 10 10 10 10 malic acid monoisostearyl alcohol 0.27 10 10 10 10 10 tetraethyl 2-ethylhexanoate pentaerythritol Cool 0.35 39.5 39.5 10 39.5 36.5 Red 202 - 0.1 0.1 0.1 0.1 0.1 0.1 Iron oxide red '~ 1.5 1.5 1.5 1.5 1.5 1.5 Yellow iron oxide J 0.5 0.5 0.5 0.5 0.5 0.5 Titanium oxide 1.2 1.2 1.2 1.2 1.2 1.2 Tocopherol '^ ' ~ -- 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 _______ Total 100 100 100 100 100 100 IQB0^^ Total oil composition 59.5 59.5 30 0 59.7 56.7 _____^_ Hardness 0.23 0.22 0.18 0.09 0.12 0.24 _^__ ◎ ◎ r X r Δ ◎ _ _ _ _ _ _ _ _ _ _ _ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ / / Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ The composition of (a) component and (b) component can be achieved Different type of security and the use of sense. Embodiments of the invention are further enumerated below. Example 4 Lipstick 17 200829281 (1) Polyethylene wax (2) 5.0% (2) Microcrystalline wax (2) 3.0 (3) Carnabas wax 1.0 (4) Tetrakis(ethylhexanoic acid/benzoic acid) Tetraol ester 20.0 (5) Castor oil 15.0 (6) Sunflower oil 2.0 (7) Dimethyl polyoxane 10.0 (8) Tabular hydroxyapatite 3.0 (9) Mica 10.0 (10) Iron oxide red 1.0 (11) Titanium oxide 2.0 (12) Red 202 No. 0.1 (13) Red 218 No. 0.02 (14) Vitamin A palmitic acid 0.1 (15) Tocopherol 0.1 (16) Perfume 0.1 (17) Neopentyl diacetate The residual amount of the glycol ester was heated to 95 ° C in the parts shown in this example, stirred and mixed, defoamed, filled in a lipstick container, and cooled to 5 ° C to obtain a lipstick. This cosmetic material is excellent in the production of colorless materials such as agglomeration, shape retention, smearing, and gloss. Example 5 Lipstick Usage (Coating (1) Polyethylene Wax (2) 8.0% (2) Microcrystalline Wax (1) 2.0 (3) Polyisobutylene 10.0 18 200829281 (4) Liquid lanolin (5) Lauric acid group面amine 酴 _ — soil makeup makeup one (phytosterol / octyl ten (6) linoleic acid diisostearyl hydrazine (7) diisostearic acid glycerin 酉 (8) by stearic acid Stearyl alcohol vinegar (9) methoxy cinnamic acid bismuth 2.0 dialkyl) ester 10.0 20.0 10.0 10.0 (10) bismuth sulfate 5.0 (11) iron oxide red coated mica titanium (12) titanium oxide l · 0 1.0 " 5 Λ (13) Red 202 ό . U 〇ς (14) Red 201 0 1 (15) Red 218 0.1 (16) Nylon-12 3.0 (17) Tocopherol 0.1 (18) Spice 0.1 (19) Two The residual amount of 2-ethylhexanoic acid glycerin was heated to 95 ° C in the individual components shown in this example, stirred and mixed, defoamed, filled in a lipstick container, and cooled to 5 ° C to obtain a lipstick. The material is also excellent in the production of colorless materials such as agglomeration, and is excellent in shape retention, feeling of use (coating property at the time of coating, gloss). Example 6 Lipstick (1) Polyethylene wax (2) 6.0% (2) Microcrystalline wax ( 1) 1.5 (3) Cantilra wax 2 .0 (4) Squalane 10.0 19 200829281 (5) Castor oil 20.0 (6) Triisostearate 10.0 (7) Trimethylpentaphenyltrioxane 5.0 (8) Tocopherol acetate 0.1 (9 ) Red 201 0.5 (10) Red 202 0.3 (11) Yellow 4 1.5 (12) Titanium 1.0 (13) Carmine coated mica titanium 1.0 (14) Tocopherol 0.1 (15) Spice 0.1 (16) Diterpenes Residual amount of acid neopentyl glycol ester (preparation method) The ingredients shown in this example were heated to 95 ° C, stirred and mixed, defoamed, filled with a lipstick container, and cooled to 5 ° C to obtain a lipstick. The material system also has problems in the production of colorless materials such as agglomeration, and is excellent in shape retention, feeling of use (coating property at the time of coating, gloss). Example 7 Lipstick (1) Polyethylene wax (2) 8.5 % (2) Microcrystalline wax (2) 1.5 (3) Fischer-Tropsch wax 1.0 (4) Synthesis of isoparaffin wax 10.0 (5) Tris-2-ethylhexanoic acid glyceride 30.0 (6) Diisostearyl malate 10.0 (7) Methylbenzene Polyoxyalkylene 10.0 20 200829281 (8) Olive oil 5.0 (9) Pebble rouge 0.1 (10) Spherical cellulose powder 1.0 (11) Titanium oxide coated glass powder 2.5 (12) Yellow iron oxide 0.8 (13) Red 202 No. 202 (14) Titanium oxide 2.0 (15) Mica titanium 1.0 (16) Tocopherol 0.1 (17) Residual amount of diisostearic acid glyceride (preparation method) Heat the ingredients in this example to 90° C. After stirring and defoaming, fill the lipstick container and cool to 5 °C to obtain a lipstick. This cosmetic material also has problems in the production of agglomerates such as colorless materials, and is excellent in shape retention property, feeling in use (smearing property at the time of coating, gloss). Example 8 Lipstick (1) Polyethylene wax (2) 10.0 (2) Microcrystalline wax (1) 2.0 (3) Polybutene 5.0 (4) Glyceryl triisostearate 15.0 (5) Tetra 2-ethyl Pentaerythritol hexanoate 15.0 (6) Squalane 10.0 (7) Calcium hydrogen phosphate 0.5 (8) Iron oxide red 2.1 (9) Black iron oxide 0.1 21 200829281 (10) Titanium oxide 2.3 (11) Blue No. 1 0.2 (12) Fertility 0.1 0.1 (1 3) Residual amount of liquid stone worm (preparation method) The ingredients in the examples shown in this example are heated to 90 ° C, mixed and defoamed, and filled with a lipstick container. Cool to 5 °C to get a lipstick. This cosmetic material also has problems in the production of agglomerates such as colorless materials, and is excellent in shape retention property, feeling in use (smearing property at the time of coating, gloss). Example 9 Emulsified Lipstick Emulsified Base: (1) Refined Water 1.5 (2) Trisodium Tetraacetate 0.01 (3) Glycerin 0.2 (4) Australian Walnut Oil Fatty Acid Plant Steroid Ester 3.0 (5) - Sulfhydryl Shili Oil Polyol ( Dimethiconepolyol) 0.5 (6) methylphenyl polyoxane 10.0 oil phase: (7) polyethylene wax (!) 1.0 (8) microcrystalline wax (1) 14.0 (9) di-2-ethylhexanoic acid glycerol 35.0 U〇) Hydrogenated Polybutene 10.0 (11) Octyloxycinnamate Octyl 5.0 (12) Dibutylhydroxytoluene 0.1 (13) Tocopherol Acetate 0.1 U4) Iron Oxide Red 2.0 22 200829281 GO Iso Oxide 4.0 ( 16) Tocopherol 0.1 U7) Perfume 0.1 , (18) Trimethylolpropane tris-ethylhexanoate Residual denier β (Preparation method) First, (4) to (6) are heated and mixed (oil phase portion) After (2), (3), and six are solved in (1) (water phase part), after 7 (TC adds this to the oil phase $, - paid to the ritual paste. After that, (7 ) (18) Heat and dissolve, mix 4 4 Μ ^ 'Add the emulsified paste, at 951: Mix well, fill with lipstick, cry, human problems, shape retention, feeling of use (smear when applied) ,Light )Excellent\Example 1 0 Lipstick (1) Polyethylene wax (1) (2) Microcrystalline sacrifice (1) 12-〇% Ο /Λ (3) Vaseline j.0 (4) Hexahydroxystearic acid II Neopentyl alcohol (5) diisostearic acid diglyceride (6) diisostearyl malate (7) tocopherol acetate (8) L-menthol (9) tocopherol (10) liquid Paraffin wax 10.0 l〇.0 15.0 10.0 0.2 〇·〇5 0.1 Residual amount (manufacturing method) Emulsified lipstick is obtained at 5 C. This cosmetic material is also produced without agglomeration of color materials, etc. 17 23 200829281 At 85 ° C, stirring and mixing, and defoaming, filling in a lipstick container and cooling to 5 t to obtain a lipstick. This cosmetic material has no problems in manufacturing, and has excellent shape retention and application feeling (smear and gloss when applied). The use of the excellent solid product hardness and shape retention property, the present invention provides a rod-shaped cosmetic material, which is excellent in high-use feeling by the specific wax composition of the dosage machine. [Simplified illustration] Fig. 1 Indicates the hardness of the solid. [Main component symbol description] No 24