200829182 九、發明說明： 【發明所屬之技術領域】 本發明為-種蔬果的營養物的萃取系統。本技#以二氧化礙(c〇2)超臨界 流體(^percritical脇)萃取蔬果的營養物，使得蔬果的營養物可以有效 地被卒取妹，本胁在萃取過財無須添加不良溶劑，卿萃取物之 品質安全可靠。 【先前技術】 目=癌症《比料年增加，包括紐的肺癌、大職、直腸癌和前 广的減°、大腸癌、直職和胃鱗。天顏抗氧化物多 抗氧化物可抑繼症細_發生和生長，降低細胞的 .乳化彳㈣。时飲食中含大量絲，可鶴降低癌症的發生。 的抗氧化性’兹以蘋果為例，蘋果含有多盼，1⑻g新鮮 =:r=:果:當，的維生素c，_果的抗 i癌峨，辦取物有抑 從蘋果萃取出來的多紛，容易被人 體吸收，所產生的健康效益也比吃一 顆蘋果來得好。蔬菜哎水罢会主A / U王丄 多的蘋果多盼，需要連皮讀主要存在頻果皮中，要攝取較 外，頻叫=皮去/果失益大打折扣。另 5 200829182 國内生產的蔬果，深受國人的喜愛，^ ^ 作用、瘵政作用、乙烯生成、顏色改變、 _. 的影響，純時魏代謝喊，呼齡&。生化反應洙焚溫度 味下降老化加快。作用快，聽的消耗快速，蔬果的風 疏果白呆...平包括腐敗性高的種類優先處理、低溫的應用、渴度的管理、 广=制、臭氣的處理i實際朗上依不同的情況，採用不 目*气些人在縣添加化信，來處理，猶礙 f %疏果的生化代謝侧，降低乙烯產生量，延緩品質劣變，為較安 全的·方法，例如低溫冷藏的保鮮效果可達數星期。 、、乂 ψ ^ U果汁機打汁法，-般在蔬果汁機操作時，必須加水，且益 言養物有效卒取出來。營養物只能保留，無法萃取。萃取作業本身 -種透過萃取介質將目標物質從天然原料中分離。像=ς 萃取(st，extraction)，以水蒸氣加熱、水及溶劑作為萃媒 ；ι distillation), m认而不被破壞的成分的提取。此類#養成分的沸點多在贈 上，與水不概溶或健溶，且⑽成分在約謂。c時存在有 ^壓。當與水在-起加熱時，其蒸氣壓和水的蒸氣壓總和為_個大= 時’液體就開始沸騰，水蒸氣將揮發性物質―併帶出。水 = 於高溫下操作，蔬果因溫度提高而破壞了營養成分。…m 白知的V令束乾燥萃取法(cry〇 extrati〇n)，為將蔬果經製聚除逢後人 魏燥法處理成粉末狀產品，再財和乙醇溶鮮取。冷;東真 : 以急^東結將蔬果先行@化，在真婦件下使冰昇轉錢氣， =去蔬果中水份的方法。其後再以溶劑萃取，但營養物無法有效萃取出 200829182 f 111种’泡茶葉、煮咖啡和煎藥包75卿高溫狀態的水，將茶葉、 二2，中的成分溶解出來，此種過程稱為萃取。超臨界流體萃取 咖啡因、啤酒花萃取。目前，在蔬果的營養物的萃 之植物_ t見財應用超臨界越者。f知的超臨界流體去除縠物中 娜=_： 不欲物質，係利用壓力範圍在⑽至島Γ之液態 ί t 度範圍3G至5G°C，及添加或未添加辅助溶劑下， 萃Γ、預乾燥、且萃取物係藉由—清絲柱，在等壓操 mi預分離器及—清絲柱以二步驟方式及降壓處理 中。刀*。已知的先前技術，可見中華民國專利公報第〇〇迎％號 【發明内容】 ^=二氧化碳(c〇2)超臨界流體(supercriticai fluid)對 2二；：程中無須添加不良溶劑，製程安全且大幅提高蔬果萃^ 氣化碳超臨界流體的臨界溫度低接近室溫(㈣」 匕子壓力低(Pc=72.8atm 或 7.38MPa)。 c〇2是對人體無害的化學物。c〇2的臨界溫度為31•丨。c，臨凡 因此萃取、分離及溶劑的回收都能在低溫下進行 及 添加劑、·醫藥、香料等天然„的萃取尤具意義。 * 態下’兼具有氣體的高擴散性與液體的高溶解力特性。 起L，丨肌脰具有不同於液體溶劑的獨特溶劑特性，且又 劑’可作為下-代溶劑，打破目前溶劑就是液體的固有概念，二二化:: 超臨界流體可深人蔬果的組_，將其中的營養物有效^取出來。^ 二2Γ1共溶劑，以調整萃取物的溶解度，是為最具發展潛力的溶 果卞取軸。二梳碳超臨界流體的溶解度對極性低的化合帅旨類、_ 200829182 類等)較大，可在較低壓如l〇MPa下進行萃取。對極性高的化合物(醣類、 胺基1等溶解度會變小，但可添加共溶劑(c〇s〇lvent 〇r e_iner modifier)東改善，例如乙醇。也可在高壓2〇Mpa下操作，利用溫度和壓 力，以控制其溶解性。二氧化碳超臨界流體符合自然、環保、綠色、健 康的需求，為天然營養物萃取的未來發展趨勢。 二氧化碳超臨界流體對於蔬果#養_萃取技術可為靜態方式㈣^ mode)或動態、方式(dynamicm〇de)，靜態方式為直接將蔬果置於高壓處理 槽中，把高壓處理槽封閉後加熱及加壓到達所設定的溫度及壓力，並保 持-，時間平衡後，打開高壓處理槽，將蔬果取出。另—方面，動態方 式為常時加熱及加壓，二氧化碳超臨界流體持續進出高壓處理槽。〜 -乳化碳超臨界赫的躲#養物之萃取社錢點包括：⑴於低溫下 操作，可避免蔬溫度提高而改變其#無原有雛，品佳。對 溫度敏感易變質而欲鱗其原味，超臨界流體不破壞組織、不變質，可 保留完好的營養成份和原味。⑺不使用有害的有機溶劑，沒有溶劑殘留 能夠迅速進人待萃取的物f内部，可有效的提高f傳速率。⑷ 取’可大幅降低操作日销’有效提高萃取產轉。（5)具有低黏 度和*透性，比溶敝能穿透待萃取的物f，可深人萃取，可萃取出 ’提南卒取效率。⑹高選擇性萃取，萃取選擇性可由溫度和 出來，不顧雜_縮精製過程。⑻可將植物上的農藥殘留物 =於中早騎狀植物’天錄㈣超臨界 都適用於中《的萃取。在超臨界二氧 取=、、= 壓力，可將植物上的農藥萃取出來，避免農藥岐 ，_界溫度接近室溫(Te=3Ut:)，可在室溫條件喿^二= 的，容殘二旦易分離無溶劑殘留，符合藥物食品 貝里沾’不會危害人體的健康。此外，植物殘渣乾燥後， 200829182 的超臨界二祕鱗取她，而顧處理和油脂的超 >界，俨一虱化碳的溶解度不同。深層海水的海藻以二 流體，可萃取出天然凝膠，絲製作深層海水化妝品== 膠、瘦身凝膠等。 h合性/旋 【實施方式】 流體萃取的反應彻，以高壓二氧化初«糾㈣ 择果4生產最新鮮的原汁。超臨界流體萃取蔬果可適時處理 有腐爛的損失，可保留蔬果原有營養物，使萃取出來 、呂養勿月b取代蔬果的永鮮。將待萃取之蔬果置於萃取 碳加壓升溫到所需要的超臨界狀態，維持_ 匕 態，然後_解取㈣祕與二減碳錄。I取相平衡狀 =1顯示本㈣之二氧化碳超臨界流體的蔬果營養物的萃取純之示音 圖。此糸統的基本元件包含液態二氧化 ^王 二 壓閥、低壓分離槽、收集容器、真空幫浦、二 疫、㈣…[力’及以溫度調整器控制萃取槽⑽溫度。待壓力和、、w 角Ϊ而計時。超臨界流體進人高祕簡3G與蔬果4〇 Ϊ ；：：：^ 離開A、s2认界'"斯的營養物，隨二氧化碳流體 ’從與二氧化碳溶劑在碰分離槽60内 70的收集，收集容器内可置乙醇以捕捉萃取 全性。‘無 9 200829182 ' 真空幫浦將系統内的空氣抽走。而以90磁石攪拌器或1〇〇超音波授 拌器，將使萃取槽内的待萃取物充份攪拌。 液態二氧化碳10 ··液態二氧化碳，以二氧化碳的高壓鋼瓶供應。 南壓^浦20 ·南壓幫浦為超臨界二氧化碳流體的驅動心臟，用於單縮二 氧化碳，提高二氧化碳之壓力。 咼壓處理槽30 :高壓處理槽為蔬果樣品反應槽，材質要耐高壓、耐熱、 且不會與蔬果樣品發生反應，材料可以使用不銹鋼。高壓處理槽以加熱 器控制槽内的溫度，以壓力調整器控制槽内的壓力。高壓處理槽須經常 打開與關閉，以便更換疏果樣品，設計上必須要求拆卸方便而且防漏。 咼壓處理槽所用的壓力為30〜400 kg/cm2，所用的溫度為3〇〜9〇。〇。 減壓閥50 :利用壓力調節，進行蔬果樣品分離的工作，蔬果樣品於高壓 ，進行萃取後，含有溶質的二氧化碳超臨界流體通過減壓閥後釋出溶 夤，一导化碳流體可釋放於大氣中或經由壓縮機回收再使用。減壓閥依 序降傳壓力，以期得不同不純物。此外，可在不同壓力下，調整流速。 低壓分離槽60 ··低壓分離槽材質要耐高壓耐熱，使用不銹鋼。低壓分離 槽，以加_器控制溫度，而以減壓閥調整壓力。一次和二次低壓分離槽 的壓力依序降低，必要時可以分別收集而得到不同的蔬果營養物成分。 低壓分離槽所用的壓力為Uookg/cm2，所用的溫度為3〇〜9〇。〇。 =集容器70 :蔬果營養物以收集容器的方式收集。超臨界流體減壓時， 降溫會造參氣相的萃取物冷卻，營養物可留置在收集容器内。此外，收 集谷為置於低溫循環水槽或低溫冷凍槽内，所用的溫度為〇〜1(rc，可將 氣相的萃取物加速凝結，而留存於收集容器内。 真空幫浦80:對欲完全無氧化的萃取物，可將待萃取物置於萃取槽 10 200829182 後，以真空幫浦將系統内的空氣抽走。在真空環境下，將可完全避免 氧化現象的發生，以生產高品質的萃取物。真空幫浦所用的壓力為 1 〜750 mrriHg。 f石攪拌器9〇和超音波攪拌器100:可將待萃取物置於萃取槽後，在 卒取蚪加以攪拌。攪拌可增加超臨界二氧化碳與待萃取物的質傳效 果，可深入萃取物無遮蔽效應，進行有效的萃取，提昇萃取產量與產 率。句於超臨界二氧化碳為高壓設備，接觸式機械攪拌困難度較高，以 非接觸式的磁石攪拌或超音波攪拌，將使萃取槽内的待萃取物可得到 充份的攪拌。磁石攪拌器所用的攪拌速度1〇_1〇〇〇卬瓜。超音波攪拌器 所用的頻率為40-120 KHz。 ^ 在，臨界=氧化碳萃取過程中，將待萃取物細小化後，質傳效率提高， 的卒取率。—氧化碳超臨界越的蔬果營養物的萃取控制來 數包括壓力、溫度、共溶劑。萃取時，溶質於溶劑中之溶解 容 二=度高表示萃取愈容易進行。二氧化碳超:界流體利 用狐度桃力.聽來控雛溶雜。萃取壓 溶質的溶解力提高，萃__短。萃取溫度提=== 祕壓提南’揮發性成分萃取能力提高。添加 ^ 臨界流體的溶解力增加。 L乳化石反起 ίίΪΓί化碳的萃取速率快、效率高、耗能少、產率高，萃取摔作夫 數易於控制，萃取物的品f穩定。超臨界二氧化碳萃 二乍二 u刀離· n度和ι力及改f劑， 而留下有副作时㈣雜f。此外，超分’ 菌作用，可提高萃取物品質。基於相_理，更⑲化和滅 化碳超臨《«獅、巾_ 7 ’也可利用二氧 水的臨界溫度約為1〇Ut早_能性成份萃取出來。 品特坪改變，故水較不適用。㈣殊^進仃各種反應，使產 从殊的待卒取物，财考慮使用超臨 200829182 界水流體技術。 '體技術可制在高健«、健康食 鶴、吸附_合=紐驗，财與其齡軸術例精 而务展出低成本、高品質的萃取產業。 行機能^成超取=系可將同屬植物的草藥進 上。 j _在料、枸杞、靈芝、茶葉、藻類等之草藥 ΐ ’ ^用3,$超气的轉處理系統’可將植物的精油萃取出 &用在末利涛何、玫魂、柑橘、檸檬等之植物上。卜取出 二氧化碳超臨界流體的萃取處理系％，可將動物義处叫“ 卞取出來，可應用在魚油等之動物上。 』妝勁物的拽此性成份 本技藝為-突破習知技藝的新穎方法及裝置， :示性而非限制性。所有改變只要合乎本案的專利申== 4圍等效者，都應包含在本技#之權利範_。胃喊或與 12 200829182 【圖式簡單說明】 圖1 本發明之二氧化碳超臨界流體的蔬果營養物的萃取系統之示意 【主要元’件符號說明】 10液態二氧化碳 20高壓幫浦 30高壓萃取槽 40待萃取物 50減壓閥 60低壓分離槽 70收集容器 80真空幫浦 90磁石攪拌器 100超音波攪拌器 13200829182 IX. Description of the invention: [Technical field to which the invention pertains] The present invention is an extraction system for nutrients of fruits and vegetables. This technology uses the oxidizing barrier (c〇2) supercritical fluid (^percritical threat) to extract the nutrients of fruits and vegetables, so that the nutrients of fruits and vegetables can be effectively taken by the sisters, and this threat does not need to add bad solvents in the extraction. The quality of the extract is safe and reliable. [Prior Art] The target of cancer is increased year by year, including New Zealand's lung cancer, large-time, rectal cancer, and pre-existing reduction, colorectal cancer, direct occupation, and stomach scale. Tianyan antioxidants and antioxidants can inhibit the occurrence of fine _ occurrence and growth, lowering the cells. Emulsified 彳 (4). When the diet contains a lot of silk, the crane can reduce the incidence of cancer. The antioxidant capacity of the apple is taken as an example. Apple contains more hope, 1 (8) g fresh =: r =: fruit: when, vitamin C, _ fruit anti-icarcinoma, do not take more from the apple extract It is easy to be absorbed by the body, and the health benefits are better than eating an apple. Vegetable drowning will be the main A / U Wang Yu More apples look forward to, need to even read the skin in the main frequency of the peel, to take more, frequency = skin / fruit loss is greatly reduced. Another 5 200829182 The domestically produced fruits and vegetables are deeply loved by the Chinese people, ^ ^ function, ruthenical effect, ethylene production, color change, _. The effect of pure time Wei metabolism, call age & The biochemical reaction burns the temperature and the aging is accelerated. The effect is fast, the consumption of hearing is fast, and the wind and fruit of fruits and vegetables are thin and white. The flat includes the high-corruption species priority treatment, the application of low temperature, the management of thirst, the treatment of scent, and the treatment of odor. In different situations, it is safer to use a chemical letter in the county to treat the biochemical metabolism side of the fruit, reduce the amount of ethylene produced, and delay the deterioration of quality, which is a safer method, such as low temperature. The freshness of the refrigerator can last for several weeks. , 乂 ψ ^ U juice machine juice method, generally in the operation of the vegetable juice machine, water must be added, and the benefits of the nutrients are effectively taken out. Nutrients can only be retained and cannot be extracted. The extraction operation itself - the separation of the target substance from the natural material through the extraction medium. Like = ς extraction (st, extraction), with steam heating, water and solvent as the medium; ι distillation), m recognition without the destruction of the extraction of components. The boiling point of this type of nutrient ingredient is mostly given, it is not soluble or soluble in water, and (10) is in the composition. There is a pressure at c. When heated with water, the sum of the vapor pressure of the vapor pressure and the water is _ large = when the liquid begins to boil, and the water vapor carries the volatile matter. Water = Operating at high temperatures, fruits and vegetables destroy nutrients due to increased temperature. ...m Baizhi's V-dried dry extraction method (cry〇 extrati〇n), in order to make the fruits and vegetables into a powdery product, and then replenish it with ethanol and ethanol. Cold; Dong Zhen: Take the fruits and vegetables first in the emergency ^ East knot, and make the ice rise to the money under the real woman, = the method of water in the fruits and vegetables. After that, it is extracted with solvent, but the nutrients can not effectively extract the water of the 200829182 f 111 kinds of 'bubble tea, brewed coffee and decocting bag 75 liters, and dissolve the components of tea, 2, 2, this process It is called extraction. Supercritical fluid extraction Caffeine, hop extraction. At present, the extraction of nutrients in fruits and vegetables is seen in the application of supercritical Yue. F know the supercritical fluid to remove the sputum Na = _: do not want substances, the pressure range is from (10) to the island Γ liquid ί ° range 3G to 5G ° C, with or without the addition of auxiliary solvents, extraction Pre-drying, and the extract is processed by a two-step method and a pressure-reducing process by means of a clear wire column, an equal pressure operation mi pre-separator and a clear wire column. Knife*. Known prior art, it can be seen that the Republic of China patent publication No. 〇〇 %% [invention content] ^ = carbon dioxide (c 〇 2) supercritical fluid (supercriticai fluid) pair 2 two;: no need to add bad solvents, process safety And greatly increase the temperature of fruits and vegetables. The critical temperature of vaporized carbon supercritical fluid is close to room temperature ((4)" The pressure of the scorpion is low (Pc=72.8atm or 7.38MPa). c〇2 is a chemical that is harmless to the human body. c〇2 The critical temperature is 31•丨.c, so the extraction, separation and solvent recovery can be carried out at low temperatures and the extraction of additives, medicines, spices, etc. is particularly meaningful. High diffusivity and high solubility characteristics of liquid. From L, the tendon tendon has a unique solvent characteristic different from liquid solvent, and the agent 'can be used as a lower-generation solvent, breaking the current concept that the solvent is the liquid, two two Chemical:: Supercritical fluid can be used as a group of deep human fruits and vegetables, and the nutrients can be effectively extracted. ^2 2Γ1 co-solvent to adjust the solubility of the extract is the most promising fruit extraction axis. Two-comb carbon supercritical fluid The solubility is relatively high for the low polarity of the compound, _ 200829182 class, etc., and can be extracted at a lower pressure such as l MPa. For compounds with high polarity (carbohydrate, amine 1 etc., the solubility will become smaller, However, a co-solvent (c〇s〇lvent 〇r e_iner modifier) can be added to improve the east, such as ethanol. It can also be operated under high pressure 2〇Mpa, using temperature and pressure to control its solubility. Carbon dioxide supercritical fluid conforms to nature, Environmental protection, green and healthy demand, the future development trend of natural nutrient extraction. Carbon dioxide supercritical fluid for the fruit and vegetable #养_ extraction technology can be static mode (four) ^ mode) or dynamic, mode (dynamicm〇de), static mode Directly place the fruits and vegetables in a high-pressure treatment tank, close the high-pressure treatment tank, heat and pressurize to reach the set temperature and pressure, and keep - after the time is balanced, open the high-pressure treatment tank to take out the fruits and vegetables. The method is constant heating and pressurization, and the carbon dioxide supercritical fluid continues to enter and exit the high pressure treatment tank. ~ - Emulsified carbon supercritical He's hiding #养物的提取社钱点 includes: (1) at low temperature The operation can avoid the increase of the temperature of the vegetable and change its #无原雏, good product. It is sensitive to temperature and easy to deteriorate and wants to taste the original taste. The supercritical fluid does not destroy the tissue, does not deteriorate, and can retain the intact nutrients and original taste. (7) No harmful organic solvents are used, no solvent residue can quickly enter the inside of the material f to be extracted, which can effectively increase the f-transfer rate. (4) Take 'can greatly reduce the operating daily sales' to effectively improve the extraction yield. (5) Low Viscosity and * permeability, which can penetrate the substance to be extracted f, which can be extracted by deep people, and can extract the 'Tenan stroke efficiency. (6) Highly selective extraction, the extraction selectivity can be obtained by temperature and no matter. The process of shrinking and refining. (8) The pesticide residue on the plant can be used in the medium-early riding plant 'Tianlu (4) supercritical is suitable for the extraction. In supercritical dioxane =, = = pressure, the pesticide on the plant can be extracted to avoid pesticide 岐, the temperature of _ boundary is close to room temperature (Te=3Ut:), and it can be conditioned at room temperature. Residual two deniers are easy to separate without solvent residue, in line with the drug food Berry dip' will not endanger the health of the human body. In addition, after the plant residue is dried, the supercritical second secret scale of 200829182 is taken from her, and the solubility of the carbon in the super > The deep seawater algae is a two-fluid, which can extract natural gels, and make deep seawater cosmetics == glue, slimming gel and so on. H-combination/rotation [Embodiment] The fluid extraction reaction is thorough, and the freshest raw juice is produced by the high-pressure dioxide initial «correction (four) selection fruit 4. Supercritical fluid extraction of fruits and vegetables can be treated in a timely manner. There is a loss of decay, and the original nutrients of fruits and vegetables can be preserved, so that the extraction and the maintenance of the fruits and vegetables can be replaced by Lu Yang. The fruits and vegetables to be extracted are placed in the extracted carbon to be heated to the required supercritical state, and the state of _ 匕 is maintained, and then _ (4) secret and second carbon reduction are recorded. I take the phase balance =1 to show the extracted pure sound of the nutrients of the carbon dioxide supercritical fluid of this (4). The basic components of this system include liquid dioxide two-pressure valve, low pressure separation tank, collection vessel, vacuum pump, quarantine, (four)...[force] and temperature control to control the temperature of the extraction tank (10). Wait for the pressure and , w angle and time. The supercritical fluid enters the high secret 3G and the vegetable and fruit 4〇Ϊ;:::^ leaves A, s2 recognizes the '"s nutrient, with the carbon dioxide fluid' from the collection with the carbon dioxide solvent in the collision separation tank 60 Ethanol can be placed in the collection container to capture the fullness of the extraction. ‘None 9 200829182' The vacuum pump pumped the air out of the system. With a 90 magnet stirrer or a 1 〇〇 ultrasonic mixer, the extract to be extracted in the extraction tank is thoroughly stirred. Liquid carbon dioxide 10 · · Liquid carbon dioxide, supplied in high pressure steel cylinders of carbon dioxide. The South Pressure ^Pu 20 · The South Pressure Pump is the driving heart of supercritical carbon dioxide fluid for carbon dioxide and increases the pressure of carbon dioxide. Rolling treatment tank 30: The high pressure treatment tank is a vegetable and fruit sample reaction tank. The material is resistant to high pressure, heat, and does not react with the fruit and vegetable samples. The material can be stainless steel. The high pressure treatment tank controls the temperature in the tank with a heater, and the pressure regulator controls the pressure in the tank. The high pressure treatment tank must be opened and closed frequently in order to replace the fruit thinning sample. The design must be easy to disassemble and leakproof. The pressure used for the pressure treatment tank is 30 to 400 kg/cm2, and the temperature used is 3 to 9 Torr. Hey. Pressure reducing valve 50: using pressure regulation to perform separation of fruits and vegetables samples, the fruit and vegetable samples are extracted at a high pressure, and the solute-containing carbon dioxide supercritical fluid is released through the pressure reducing valve to release the dissolved enthalpy, and a guided carbon fluid can be released. Recycled in the atmosphere or via a compressor. The pressure reducing valve sequentially reduces the pressure in order to obtain different impurities. In addition, the flow rate can be adjusted at different pressures. Low-pressure separation tank 60 ·· The low-pressure separation tank is made of high-pressure heat-resistant and stainless steel. The low pressure separation tank adjusts the pressure with a pressure reducing valve and the pressure reducing valve. The pressures of the primary and secondary low pressure separation tanks are sequentially reduced, and if necessary, they can be separately collected to obtain different nutrients of fruits and vegetables. The pressure used in the low pressure separation tank is Uookg/cm2, and the temperature used is 3 〇 to 9 〇. Hey. = Set container 70: Fruit and vegetable nutrients are collected in a collection container. When the supercritical fluid is depressurized, the temperature drop causes the extract of the gas phase to cool, and the nutrients can be left in the collection container. In addition, the collection valley is placed in a low temperature circulating water tank or a low temperature freezing tank, and the temperature used is 〇~1 (rc, which can accelerate the condensation of the gas phase extract and remain in the collection container. Vacuum pump 80: Desire A completely non-oxidizing extract, after the extract is placed in the extraction tank 10 200829182, the vacuum is used to evacuate the air in the system. Under vacuum, the oxidation phenomenon can be completely avoided to produce high quality Extract: The pressure used in the vacuum pump is 1 ~ 750 mrriHg. f stone stirrer 9 〇 and ultrasonic mixer 100: After the extract is placed in the extraction tank, it is stirred in the stroke. Stirring can increase the supercritical The effect of carbon dioxide and the mass transfer of the extract can be deep into the extract without masking effect, and effective extraction can be carried out to improve the extraction yield and yield. The supercritical carbon dioxide is a high-pressure equipment, and the contact mechanical stirring difficulty is high. Contact magnet stirring or ultrasonic stirring will make the extract in the extraction tank fully stirred. The stirring speed of the magnet stirrer is 1〇_1〇〇〇卬瓜. The frequency used for the wave agitator is 40-120 KHz. ^ In the critical = carbon oxide extraction process, after the material to be extracted is miniaturized, the mass transfer efficiency is improved, and the yield rate is high. The extraction control of the substance includes pressure, temperature and co-solvent. When extracting, the dissolution capacity of the solute in the solvent is high. The higher the extraction, the easier the extraction. The carbon dioxide super: the boundary fluid uses the fox degree. Miscellaneous. The solvency of the extracted pressure solute is increased, the extraction __ is short. The extraction temperature is increased === The secret pressure is increased. The extraction ability of the volatile component is increased. The solvency of the critical fluid is increased. L emulsified stone is reversed ίίΪΓ The extraction rate is fast, the efficiency is high, the energy consumption is low, the yield is high, the number of extractions is easy to control, and the product f is stable. The supercritical carbon dioxide is extracted by two knives and the n-degree and the force are changed. Agent, while leaving a side effect (four) miscellaneous f. In addition, the effect of super-divided bacteria can improve the quality of the extract. Based on the phase, more 19 and extinguished carbon super-progress "«狮,巾_ 7 'also The critical temperature at which hydrogen peroxide can be used is about 1 〇 Ut early _ energy The extract is extracted. The product is changed, so the water is not suitable. (4) The various reactions are made in order to make the production of the special products to be taken, and the financial considerations are used to superimpose the water fluid technology of 200829182. Gao Jian «, healthy food crane, adsorption _ combined = New test, financial and its age axis fine and excel in the exhibition of low-cost, high-quality extraction industry. Line function ^ into the super take = can be the same plant herbs j _ In the herbs, oysters, ganoderma lucidum, tea, algae, etc. ^ ' ^ With 3, $ super gas transfer processing system' can extract the essential oil of the plant & used in the end of Li Tao, the soul , citrus, lemon, etc. on the plant. Take out the extraction process of carbon dioxide supercritical fluid, the animal's meaning can be taken out, can be applied to animals such as fish oil.妆 劲 劲 拽 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本All changes as long as they meet the patent application of this case == 4 equivalence, should be included in the scope of this technology #. Stomach shouting or with 12 200829182 [Simplified illustration of the drawings] Figure 1 Schematic diagram of the extraction system of the nutrient and nutrient of the carbon dioxide supercritical fluid of the present invention [main element' symbol description] 10 liquid carbon dioxide 20 high pressure pump 30 high pressure extraction tank 40 To be extracted 50 pressure reducing valve 60 low pressure separation tank 70 collection container 80 vacuum pump 90 magnet stirrer 100 ultrasonic mixer 13