TW200810948A - Insulating material excelling in metallic gloss and molded article making use of the same - Google Patents
Insulating material excelling in metallic gloss and molded article making use of the same Download PDFInfo
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- TW200810948A TW200810948A TW096130100A TW96130100A TW200810948A TW 200810948 A TW200810948 A TW 200810948A TW 096130100 A TW096130100 A TW 096130100A TW 96130100 A TW96130100 A TW 96130100A TW 200810948 A TW200810948 A TW 200810948A
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- insulating
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- insulating material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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Abstract
Description
200810948 九、發明說明： 【發明所屬之技術領域】 本發明關於一 使用其之成形品。 種使用錫等金屬薄膜 之絕緣性材料 及 【先前技術】200810948 IX. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a molded article using the same. Insulating material using a metal film such as tin and [prior art]
習^為了在、S緣性材料上形成具有金屬光澤的絕緣被膜， ^知係形成錫等絕緣性金屬薄膜（參照專利文獻卜小缺 ’僅士早早形成錫等絕緣性金屬薄膜，例如m⑽X 小時此種高溫高濕條件下，由於錫等絕緣性金屬薄膜合 ^腐钱，導致全光線透過率超過6〇%，外觀發生激烈^ :故亚無法實用化在行動電話等。尤其全光線透過率高 的絕緣性材料，於上述條件下，絕緣性金屬薄膜的金屬光 :將會消失’接近於透明。i，由於錫等絕緣性金屬薄膜 會形成不連續的島狀構造，因此並不耐於摩擦，非常容易 產生到傷，而難以得到外觀良好的絕緣性材料。 且，專利文獻4，雖揭示一種在金屬蒸鍍層表面，設 置三聚氰胺樹脂、或丙烯酸多元醇/異氰酸酯雙液硬化型 樹脂之層作為氧化防止層，但即使設置該氧化防止層，在 南/風兩濕條件下亦無法充分承受，難以使全光線透過率在 5〇%以下。 專利文獻1 :日本特公平3 — 25353號公報 專利文獻2:曰本特公平7 — 71880號公報 專利文獻3 ··曰本特公平7—37111號公報 專利文獻4 :日本特許第3756171號公報 5 200810948 【發明内容】 ，本發明之目的在於提供一種使用絕緣性金屬薄膜，金 屬光澤及絕緣性優異且具耐久性的絕緣性材料，尤其是一 種即使在高溫高濕條件下，金屬光澤亦不會產生實質變 化，全光線透過率可保持在5〇%以下之絕緣性材料與使用 其之成形品。 本卷明，係以含有鋅化合物微粒與樹脂之絕緣性樹脂 層，被覆絕緣性金屬薄膜之至少—面，藉此來解決上述問 — 題。 本發明之第一絕緣性材料，係在塑膠薄膜上，至少依 序形成絕緣性金屬薄膜、及含有辞化合物微粒與樹脂之絕 緣性樹脂層，在塑谬薄膜與絕緣性金屬薄膜之間亦可形成 保護層，且亦可在絕緣性樹脂層上形成接著層。 此絕緣性材料，可適用作為行動電話或聲音產品等框 體、家電等遠端用紅外線透過蓋板、汽車用毫米波透過蓋 #板、其他塑膠基材所使用之中間墊（insen mm)，其他亦可 適用作為微波爐用食品容器、包裝材料、農園藝用反射膠 帶、金屬線等。 且’本發明之第二絕緣性材料，係在塑膠薄膜上，依 序形成離型層、保護層、絕緣性金屬薄膜、及含有辞化人 物微粒與樹脂之絕緣性樹脂層，並且再於該絕緣性樹脂層 上形成接著層的轉印絕緣性材料。在塑膠薄膜與離型層之 間，亦可形成底塗層。 藉由將此絕緣性材料轉印在塑膠基材表面，可輕易得 200810948 η且具金屬光澤之成形品，適用作為行動電話或聲音 波紅外線透過蓋板、汽車用毫米 觀的轉=膜或為了在其他塑膠基材上形成具金屬光澤外 徵後^第―、第二絕緣性材料之任—者，含有鋅化合物 夕^ :絕緣性樹脂層，除了鋅化合物微粒與樹脂以 人'、可合有例如染料等著色劑或氧化石夕等潤滑劑。且， =辞化合物錄㈣紅料性樹脂層的厚度，較佳為 旦,左右，而絕緣性樹脂層中的辞化合物微粒含 1，則在1〜30重量％左右即可。 且，絕緣性樹脂層中的鋅化合物微粒，只要是可 為微粒狀的辞化合物即可，氧化鋅、硫 微粒皆可使用。 鮮寺 ± t用以形成含有鋅化合物微粒與樹脂之絕緣性樹脂層的 樹脂：如酚系樹脂、環氧系樹脂、三聚氰胺系樹脂、尿素 糸樹脂、聚酉旨系樹脂、酸醇系樹脂、丙烯酸系樹脂、胺甲 系树脂、聚乙稀系樹脂、聚丙稀系樹脂、聚氯乙烯 系树月曰*偏—氯乙烯系樹脂、聚苯乙婦系樹脂、聚酷酸 乙烯醋系樹脂、ABS(丙烯腈-丁二歸_苯乙浠)系樹脂、As(丙 烯酸-苯乙浠)系樹脂等，皆可使用。且，此等樹鹿可單獨 使用’或亦可混合兩種以上使用，亦可與異氰酸醋等交聯 劑組合使用。 且，此處絕緣性金屬薄膜，係指兼具金屬光澤與絕緣 !·生的玉屬薄膜’可依先前技術以蒸錢法形成。通常，較佳 7 200810948 :〜製成島尺寸為1〇A〜2。㈣n—m)、島的間隔為2〇 〇〇〇 (2nm〜 500nm)之島狀構造的薄膜，用以形成妒 緣性金屬薄膜的金屬，則可使用錫、銦、鉛、n = =鐵、銘、鎳、石夕、錯或選自此等合金所構成之群者， ^、以錫或銦較佳’以錫為特佳。為了將絕緣性金 製成上述之島狀構造’例如在轉印絕緣性材料 / 、 佳為使塑膠薄W保護層/絕緣性金屬^所^In order to form an insulating film having a metallic luster on the S-edge material, it is known to form an insulating metal film such as tin (refer to the patent document "Bao Xiao", an early formation of an insulating metal film such as tin, for example, m (10) X hours. Under such high-temperature and high-humidity conditions, due to the insulative metal film such as tin, the total light transmittance exceeds 6〇%, and the appearance is fierce. ^: Therefore, it cannot be practically used in mobile phones, etc. Especially the total light transmittance. High insulating material, under the above conditions, the metallic light of the insulating metal film will disappear 'close to transparency. i, because the insulating metal film such as tin will form a discontinuous island structure, it is not resistant to In addition, it is difficult to obtain an insulating material which is excellent in appearance, and it is difficult to obtain an insulating material having a good appearance. Further, Patent Document 4 discloses a layer in which a melamine resin or an acrylic polyol/isocyanate two-liquid hardening resin is provided on the surface of the metal deposition layer. As the oxidation preventing layer, even if the oxidation preventing layer is provided, it cannot be sufficiently absorbed under the conditions of south/wind and wet conditions, and it is difficult to make the total light transmittance. In the case of 5% or less. Patent Document 1: Japanese Patent Publication No. 3-25353 Patent Document 2: 曰本特公平 7-71880 pp. Patent Document 3 · 曰本特公平 7-37111号 Patent Document 4: Japan Patent Document No. 3556171 5 200810948 SUMMARY OF THE INVENTION An object of the present invention is to provide an insulating material which is excellent in metallic luster and insulating properties and has durability, in particular, under high temperature and high humidity conditions, using an insulating metal film. An insulating material that does not substantially change its metallic luster and has a total light transmittance of less than 5% by weight, and a molded article using the same. The present invention relates to an insulating resin layer containing zinc compound particles and a resin. The above-mentioned problem is solved by coating at least the surface of the insulating metal film. The first insulating material of the present invention is formed on the plastic film, at least sequentially forming an insulating metal film, and containing the compound particles and the resin. The insulating resin layer may form a protective layer between the plastic film and the insulating metal film, and may also be formed on the insulating resin layer. This insulating material can be used as a frame for mobile phones or sound products, infrared transmissive covers for remote applications such as home appliances, millimeter-wave transmissive cover plates for automobiles, and intermediate pads for other plastic substrates (insen mm) Others can also be used as food containers for microwave ovens, packaging materials, reflective tapes for agricultural and gardening, metal wires, etc. And the second insulating material of the present invention is formed on a plastic film to form a release layer and protect them in sequence. a layer, an insulating metal film, and an insulating resin layer containing the resin layer and the resin, and further forming a transfer insulating material on the insulating resin layer. Between the plastic film and the release layer, The undercoat layer can also be formed. By transferring the insulating material on the surface of the plastic substrate, a molded article of 200810948 η and having a metallic luster can be easily obtained, which is suitable for use as a mobile phone or a sound wave infrared illuminating cover, and a vehicle for millimeters. The transfer of the film = in order to form a metallic luster on other plastic substrates, the second and second insulating materials, including zinc compounds Resin layer, the resin fine particles in addition to zinc compound people ', can be combined with a colorant such as a dye, for example, oxidation or the like lubricant stone evening. Further, the thickness of the compound material (4) red resin layer is preferably about 10,000 Å, and the content of the compound particles in the insulating resin layer may be about 1 to 30% by weight. Further, the zinc compound fine particles in the insulating resin layer may be any compound which may be in the form of fine particles, and zinc oxide or sulfur fine particles may be used. a resin for forming an insulating resin layer containing zinc compound fine particles and a resin, such as a phenol resin, an epoxy resin, a melamine resin, a urea resin, a polyfluorene resin, an acid alcohol resin, Acrylic resin, amine methyl resin, polyethylene resin, polypropylene resin, polyvinyl chloride resin, vinylidene chloride resin, polystyrene resin, polyacrylic acid vinyl vinegar resin, ABS (acrylonitrile-butadiene _ phenethyl hydrazine) resin, As (acrylic acid styrene) resin, etc. can be used. Further, these tree deer may be used singly or in combination of two or more kinds, or may be used in combination with a crosslinking agent such as isocyanuric acid. Further, the insulating metal thin film herein refers to a jade film which has both metallic luster and insulation, and can be formed by a steaming method according to the prior art. Usually, it is better to have 7 200810948 : ~ made into island size of 1 〇 A ~ 2. (4) n-m), an island-shaped film with an island spacing of 2 〇〇〇〇 (2 nm to 500 nm). For forming a metal of a bismuth metal film, tin, indium, lead, n = = iron can be used. , Ming, nickel, Shi Xi, wrong or selected from the group consisting of these alloys, ^, tin or indium is better 'tin is particularly good. In order to form the insulating gold into the above-described island-like structure, for example, in the transfer of an insulating material / , it is preferable to make a thin plastic W protective layer / insulating metal ^
2積層體的全光線透過率為1G〜鄕。且，此處絕緣性， 係才曰纟巴緣破壞電壓在1000V以上。 、介緣十至屬溥膜、及絕緣性樹脂層，可不必形成為全 ‘亦可積層形成為相同的圖案狀。此處，將絕緣 溥膜及絕緣性樹脂層積層形成為相同圖案狀，绍 性金屬薄膜及絕緣性樹脂層為相同圖帛，且將絕^性= 層積層形成在絕緣性金屬薄膜的正上方。 曰 且，為了將絕緣性金屬薄膜及絕緣性樹脂層積層 為相同圖案狀，例如在轉印絕緣性材料的情形，較佳為採 取下述之方法，在塑膠薄膜上形成離型層及保護層，再= 其上，塗布水溶性塗料（由聚乙烯醇等水溶性物質所構成於 視必要可混入體質顏料等之塗料）成圖案狀（所欲圖案的負 型）以形成水溶性塗料層後，依序形成絕緣性 ^ 、 苟4膜及絕 緣性樹脂層，然後進行水洗，以去除該水溶性塗料層、及 積層在該水溶性塗料層上之該絕緣性金屬薄膜 、 巴緣性樹 月曰層，留下該水溶性塗料層之未存在部分的該絕緣性金屬 薄膜及絕緣性樹脂層。在該方法中，為了充 “ i除絕緣性 8 200810948 金屬薄膜，絕緣性樹脂層的厚度較佳在0.01〜0 4/z m左 右0 且’絕緣性材料及轉印絕緣性材料所使用的塑膠薄 膜，例如聚對苯二甲酸乙二酯薄膜、聚丙烯薄膜、聚碳酸 酯薄膜、聚乙烯薄膜、聚苯乙烯薄膜、聚醯胺薄膜、聚兩 烯酸丁酯薄膜等，皆可使用。 亚且，第一、及第二絕緣性材料所使用的保護層，以 及第二絕緣性材料所使用的離型層、接著層及底塗層，與 以往一般轉印薄膜等相同者皆可適用。 例如，離型層，以醚系、酯系、環氧系、丙烯酸系、 矽系、蠟系等樹脂，及使用一種或兩種以上共聚合物為佳。 保護層，以I系、I系、環氧系、丙稀酸系、胺甲酸 乙酯系等樹脂，及使用一種或兩種以上共聚合物為佳，接 著層，則以醚系、酯系、丙烯酸系、氯乙烯系、乙酸乙烯 酯系等樹脂，及使用一種或兩種以上共聚合物為佳。且， 亦可在與r巴緣性金屬薄膜接觸的保護層，添加辞化合物微 粒。 本發明，係透過接著層將第一絕緣性材料之絕緣性樹 脂層面貼合在塑膠基材表面而成者，亦以至少於塑膠基材 上’依序形成接著層、含有鋅化合物微粒與樹脂之絕緣性 樹脂層、絕緣性金屬薄膜，要之保護層、及塑膠薄膜 的成形品為對象。此成形品，可適用作為行動電話或聲音 產品等框體、家電等遠端用紅外線透過蓋板、汽車用毫米 波透過盍板、其他塑膠成形品、造模材料等。且，接著層， 9 200810948 可預先形成在絕緣性材料之絕緣性樹脂層 在塑膠基材上。 〜力J无形成 再者，本發明，係將第二絕緣性材料之 料轉印在塑髁其从主 付|、、巴緣性材 膠基材表面而製得，且亦以於塑膠基材上， 序形成接著®、人士 & ^ 曰3有鋅化合物微粒與樹脂之絕緣性樹俨 層、絕緣性全屬、镇腊 . m 、< 口 f i屬溥膜 '保護層及離型層的成形品為對象。 此f = σσ，亦可適用作為行動電話或聲音產品等框體、家2 The total light transmittance of the laminate is 1 G to 鄕. Moreover, here, the insulation is only above 1000V. Further, it is not necessary to form all of the tantalum film and the insulating resin layer, and it is also possible to form the same pattern. Here, the insulating ruthenium film and the insulating resin laminated layer are formed in the same pattern shape, and the tempering metal thin film and the insulating resin layer are the same pattern, and the insulating layer = laminated layer is formed directly above the insulating metal thin film. . Further, in order to laminate the insulating metal thin film and the insulating resin into the same pattern, for example, in the case of transferring an insulating material, it is preferable to form a release layer and a protective layer on the plastic film by the following method. And then, coated with a water-soluble paint (a coating material made of a water-soluble substance such as polyvinyl alcohol and optionally mixed with an extender pigment) into a pattern (negative pattern of a desired pattern) to form a water-soluble paint layer Forming an insulating film, a ruthenium film, and an insulating resin layer in sequence, and then performing water washing to remove the water-soluble paint layer and the insulating metal film laminated on the water-soluble paint layer, and the edge of the tree The ruthenium layer leaves the insulating metal thin film and the insulating resin layer in a portion where the water-soluble paint layer is not present. In this method, in order to charge the insulating film of the insulating film of 200810948, the thickness of the insulating resin layer is preferably about 0.01 to 0.4/zm, and the plastic film used for the insulating material and the transfer insulating material is used. For example, a polyethylene terephthalate film, a polypropylene film, a polycarbonate film, a polyethylene film, a polystyrene film, a polyamide film, a polybutylene acrylate film, or the like can be used. The protective layer used for the first and second insulating materials, and the release layer, the adhesive layer and the undercoat layer used for the second insulating material are applicable to the same conventional transfer film and the like. The release layer is preferably a resin such as an ether, an ester, an epoxy, an acrylic, a fluorene or a wax, and one or two or more copolymers are used. The protective layer is an I system or an I system. Resins such as epoxy, acrylic acid, and urethane are preferred, and one or two or more copolymers are preferably used. The subsequent layer is ether, ester, acrylic, vinyl chloride, vinyl acetate. Ester-based resin, and one or two Preferably, the conjugated polymer is added to the protective layer which is in contact with the r-bar-forming metal film. The present invention is characterized in that the insulating resin layer of the first insulating material is bonded to the insulating layer through the adhesive layer. The surface of the plastic substrate is formed by forming at least a plastic layer on the plastic substrate, an insulating resin layer containing zinc compound particles and a resin, an insulating metal film, a protective layer, and a plastic film. This product is suitable for use as a frame for mobile phones or sound products, infrared transmissive covers for remote applications such as home appliances, millimeter-wave transmission slabs for automobiles, other plastic molded products, molding materials, etc. Next layer, 9 200810948 can be formed in advance on the insulating resin layer of the insulating material on the plastic substrate. ~ Force J is not formed, the present invention, the second insulating material is transferred to the plastic material The main payment|,, and the edge of the material of the base material of the base material, and also on the plastic substrate, the order of the formation of the ®, the person & ^ 曰 3 with zinc compound particles and resin insulation tree layer, Insulation is all, town wax. m, < mouth f i is a enamel film 'protective layer and release layer molded article for this object. This f = σσ, can also be applied as a mobile phone or sound products, such as the frame, home
電等遮端用紅外線透過蓋板、汽車用毫米波透過蓋板、发 他塑膠成形品等。 一 ^ j，亦可使用本發明之轉印絕緣性材料，藉由模内成 —/ S面具金屬光澤之成形品，此時，為了提升塑膠 薄膜與離型層之離型性，並防止在轉印時塑膠薄膜的剝離 不良與破裂的發生，較佳在塑膠薄膜與離型層之間形成底 塗層’藉由形成該底塗層，可穩定得到具金屬光澤且複雜 =的成形品。底塗層所使用的樹脂，可使用三聚氛胺系 =知γ胺基醇酸（aminoalkyd)系樹脂、環氧系樹脂、丙烯 酉欠系树月曰、矽系樹脂等熱硬化性樹脂或蠟等，尤其以三聚 氰胺糸樹脂為佳。 ^且，於本發明，如前述，可藉由使用將絕緣性金屬薄 膜、及絕緣性樹脂層積層形成為相同圖案狀的絕緣性材料 ，轉印絕緣性材料，得到具有具金屬光澤之圖案的成形 〗如可透過接著層將絕緣性金屬薄膜、及絕緣性樹 月曰層％層形成為相同圖案狀之絕緣性材料的絕緣性樹脂層 面側，貼合在塑膠基材表面，在塑膠基材上，依序形成接 200810948 者層、含有鋅化合物微粒與樹脂之絕緣性樹脂層、絕緣性 金屬薄膜及塑膠薄膜，並且製成該絕緣性樹脂層及該絕緣 性金屬薄膜積層形成為相同圖案狀的成形品，或者可將絕 緣性金屬薄膜及絕緣性樹脂層積層形成為相同圖案狀的轉 印絕緣性材料’轉印至塑膠基材表面，在塑膠基材上，依 序形成接著層、含有鋅化合物微粒與樹脂之絕緣性樹脂 層:絕緣性金屬薄膜、保護層及離型I，並^製成該絕^ 性樹脂層及該絕緣性金屬薄膜積層形成為相同圖案狀 形品。 >、、欣 本發明之絕緣性材料及成形品，具有下述效果。 1)由於絕緣性金屬薄膜為島狀構造，因此在製造絕緣 ㈣料時，通常在絕緣性金屬薄膜表面容易產生刮傷a但 是具有含鋅化合物微粒與樹脂之絕緣性樹脂層之本發明之 絕緣性材料，為在絕緣性金屬薄膜表面沒有刮傷，呈非常 • 2)在藉由模内成形等製造成形品時，絕緣性金屬薄膜 亦不易出現裂痕，絕緣性金屬薄膜與絕緣性樹脂層的 密合性良好。 曰 3)本發明之成形品，即使是在針對行動電話或聲音產 品等耐久性之評價基準的6(rcx95%x96小時此種高1高 濕測試下，全光線透過率亦不會超過5〇%，且該测試 的全光線透過率之差（變化度）在1〇%以下，由於= 敍導致絕緣性金屬薄膜消失，因此可適用在非常廣^的用 途0 200810948 【實施方式】 以下’根據實施例說明本發明。 〈實施例1 >The electric or the like covers the infrared ray through the cover, the millimeter wave through the cover plate for the automobile, and the plastic molded article. In addition, the transfer insulating material of the present invention can also be used to form a molded article of -/S mask metallic luster in the mold. At this time, in order to improve the release property of the plastic film and the release layer, and prevent In the transfer, the peeling of the plastic film and the occurrence of cracking occur, and it is preferred to form an undercoat layer between the plastic film and the release layer. By forming the undercoat layer, a molded article having a metallic luster and complexity = can be stably obtained. The resin used for the undercoat layer may be a thermosetting resin such as a trimeric amine-based compound, an aminoalkyd resin, an epoxy resin, an acrylic resin, or a fluorene resin. Wax, etc., especially melamine resin. Further, in the present invention, as described above, an insulating material can be transferred by using an insulating metal film and an insulating resin laminated layer in an insulating material having the same pattern, thereby obtaining a pattern having a metallic luster. Forming: The insulating metal film and the insulating tree layer layer can be formed into the insulating resin layer side of the insulating material of the same pattern through the adhesive layer, and bonded to the surface of the plastic substrate, in the plastic substrate The insulating layer, the insulating metal film, and the plastic film containing the zinc compound particles and the resin are sequentially formed, and the insulating resin layer and the insulating metal film layer are formed into the same pattern. In the molded article, the transfer insulating material in which the insulating metal film and the insulating resin laminated layer are formed into the same pattern may be transferred onto the surface of the plastic substrate, and the adhesive layer may be sequentially formed on the plastic substrate. An insulating resin layer of a zinc compound fine particle and a resin: an insulating metal film, a protective layer, and a release type I, and the insulating resin layer and the insulating property The metal thin film laminate is formed into the same pattern shape. >, □ Insulating material and molded article of the present invention have the following effects. 1) Since the insulating metal film has an island-like structure, in the case of manufacturing an insulating (four) material, the insulating layer of the insulating metal film is usually easily scratched, but the insulating resin layer containing the zinc compound particles and the resin is insulated. The material is not scratched on the surface of the insulating metal film, and is very large. 2) When a molded article is produced by in-mold forming or the like, the insulating metal film is also less likely to be cracked, and the insulating metal film and the insulating resin layer are Good adhesion.曰3) The molded article of the present invention does not exceed 5 全 even in the high-humidity test of 6 (rcx 95% x 96 hours) for durability evaluation of mobile phones or sound products. %, and the difference (variation degree) of the total light transmittance of the test is 1% or less, and since the insulating metal film disappears due to the description, it can be applied to a very wide application 0 200810948 [Embodiment] The present invention will be described based on examples. <Example 1 >
在厚度25#m的聚對苯二曱酸乙二酯薄膜（三菱化學 聚酯薄膜公司製的「戴亞岣依魯G1〇〇」）的一面，形成由 丙稀酸系樹脂（日立化成工業公司製的「璽它洛依莖 HA3004」）、及異氰酸酯（日本聚胺曱酸乙酯工業公司製的 「咕洛乃都2030」）所構成之厚度的保護層，並在該 保護層上以真空蒸鍍法形成厚度13"m、呈島狀構造且具 絕緣性的錫薄膜，製得到由聚對苯二甲酸乙二酯薄膜/保 護層/錫薄膜所構成之積層薄膜（A)。 接著，在此積層薄膜（A)的錫薄膜上，以反向塗覆法 Obverse coating meth〇d)形成氧化辞微粒（堤加公司製的「氧 化辞漿體濱」）、胺甲酸乙醋系樹脂(三井武田化學公司 氣的「塔景拉庫A-310」）及異氰酸醋（三井武田化學公司 製的「塔景㈣A-3」）所構成之厚度^的絕緣性樹 脂層（氧化辞微粒含量：6重量％)，並且在該絕緣性樹脂 層上’形成由丙烯酸系樹腊（科昵西公司製的「灯595庫力 亞」）所構成之厚度的接著層，而製得本發 性材料。 琢 -人藉由熱輥積層上述絕緣性材料之接著層面、與 作為塑膠基材之厚度2mm的透明丙婦酸樹脂板，製得透明 心μ &板/接著層/絕緣性樹m層/錫薄膜/保護層 々對苯二甲酸乙二酯薄膜依序形成之本發明之成形品。曰 12 200810948 所製得之成形品，在高溫高濕測試（6(TCx95%X96小 時）下，金屬光澤並無發生變化（全光線透過率：測試前3 %，測試後3 1 % )。 <實施例2>On the one side of polyethylene terephthalate film ("Daily Yiyi G1" made by Mitsubishi Chemical Polyester Film Co., Ltd.) having a thickness of 25 #m, an acrylic resin (Hitachi Chemical Industry Co., Ltd.) is formed. A protective layer of a thickness composed of "Italian stalks HA3004" manufactured by the company) and isocyanate ("Daluodu 2030" manufactured by Nippon Polyamine Ethylene Co., Ltd.), and on the protective layer A vacuum film was used to form a tin film having a thickness of 13 "m, an island structure and an insulating property, and a laminated film (A) composed of a polyethylene terephthalate film/protective layer/tin film was obtained. Next, on the tin film of the laminated film (A), an oxidized particle (Oxidation of the oxidized sulphur) and a urethane sulphate were formed by a reverse coating method of Opverse coating meth〇d). Insulating resin layer (oxidation resin layer) composed of resin (Towerview A-310) of Mitsui Takeda Chemical Co., Ltd. and isocyanic acid vinegar (Taojing (4) A-3 made by Mitsui Takeda Chemical Co., Ltd.) The content of the fine particles was 6% by weight, and an adhesive layer composed of an acrylic wax ("Lake 595 Kelly" manufactured by Colesi Co., Ltd.) was formed on the insulating resin layer to obtain an adhesive layer. This material.琢-People make a transparent core μ & plate/adhesion layer/insulating tree m layer by laminating the adhesive layer of the above insulating material and a transparent acrylic acid resin board having a thickness of 2 mm as a plastic substrate. The tin film/protective layer of the ethylene terephthalate film is sequentially formed into the molded article of the present invention.曰12 200810948 The molded product obtained has no change in metallic luster under high temperature and high humidity test (6 (TCx95% X 96 hours) (total light transmittance: 3% before test, 31% after test). ; Example 2>
在厚度25"m的聚對苯二甲酸乙二酯薄膜（三菱化學 承西曰薄膜公司製的「戴亞岣依魯G1〇〇」）的一面，以凹版 塗布(g— coat)法，形成由丙稀酸·三聚氰胺系樹脂(大 日精化工業公司製的「Εχ—114美致悟姆」）所構成之厚度 〇.5"m #底塗| ’在其上依序形成丙烯酸系樹脂(大日本 油墨化學工業公司製的「TR—16尼蘇」）所構成之厚度i ^的離型層、由丙烯酸系樹月旨（日立化成工業公司製的「曼 它洛依S HA3004」）及異氰酸醋（三井武田化學公司製的「塔 景内处D-U0N)所構成之厚度1//m的保護層、聚乙婦醇 與體質顏料（昭和油墨卫業公司製的「水洗底漆」）所構成A polyethylene terephthalate film having a thickness of 25 " m ("Daiyin Yilu G1" manufactured by Mitsubishi Chemical Corporation, Co., Ltd.) is formed by a g-coating method. The thickness of 丙.5"m #底涂|' is formed by acrylic acid and melamine resin ("Εχ-114美致悟" by Daisei Seiki Co., Ltd.). The release layer of the thickness i ^ formed by "Nippon Ink Chemical Industry Co., Ltd." "TR-16" is made of Acrylic Tree ("Mandalayi S HA3004" manufactured by Hitachi Chemical Co., Ltd.) and Isocyanic acid vinegar (D-U0N in the tower view made by Mitsui Takeda Chemical Co., Ltd.) is a protective layer of thickness 1/m, polyephedrine and body pigment ("washing bottom" manufactured by Showa Inkjet Co., Ltd. Paint")
之厚度1”的水溶性塗料層（所欲圖案的負型），並在盆 上’以真空蒸鍍法，形成厚度2Gnm、呈島狀構造且具絕緣 性的錫薄膜’而製得由聚對苯二甲酸乙二醋薄膜/底塗層 (離型層/保護層/水溶性塗料層（所欲圖案的負型）/錫 溥膜所構成之積層薄膜（B)。 接著，在此積層薄膜（B)的㈣膜上，以反向塗覆法形 ^化鋅微粒(堤加公司製的「氧化鋅漿體75〇z」卜三聚 齓胺系樹脂（日立化成工業公司製的 酴备與此/ 穴说z/」）、及丙烯 s文糸树脂（日立化成工業公司製 「 邮摄上 4衣的璽匕洛依莖HA3004」） 尸β構成之厚度〇·2 # m的絕绫 緣丨生树知層（軋化鋅微粒含量：6 13 200810948 重量％)，然後，進行水洗，將上述水溶性塗料層及積層於 其上之錫薄膜與絕緣性樹脂層去除，留下上述水溶性塗料 層未存在之部分的錫薄膜及絕緣性樹脂層，積層形成為所 欲之圖案，並於其上以凹版塗布法形成由㈣酸系樹脂（科 =西公司製的「ΚΤ595庫力亞」）所構成之厚度i//m的接 著層，而製得本發明之轉印絕緣性材料。 其次，以使用透明丙烯酸樹脂作為塑膠基材的模内成 形法，轉印上述轉印絕緣性材料，製得在透明丙烯酸基材 上，混合有接著層/保護層/離型層依序形成的透明部 分、與接著層/含有氧化鋅微粒與樹脂之絕緣性樹脂層/ 錫薄膜/保護層/離型層依序形成 < 具有金屬光澤的圖案 部分’且具有漂亮外觀之本發明之成形品。 所製得之成形品的層間密合性良好，以透明膠帶 (sellotape，註冊商標）進行剝離測試，皆無產生剝離，具 =屬光澤之部分亦無傷痕。且，在高溫高濕測試（6〇t：x95 % X96小時）下，金屬光澤亦無發生變化（全光線透過率： 測試前15%，測試後16%)。 <實施例3〜9，及比較例1〜6 > 在厚度25ym的聚對苯二甲酸乙二酯薄膜（三菱化學 =酯薄膜公司製的「戴亞岣依魯G1〇〇」）的一面，以凹版 塗布法形成丙烯酸系樹脂（大日本油墨化學工業公司製的 TR 16尼蘇」）所構成之厚度l"m的離型層、由丙稀 酸系樹脂（日立化成工業公司製的「§它洛依莖HA3〇〇4」） 及異氰酸酯（三井武田化學公司製的「塔景内銓d_ii〇n) 14 200810948 所構成之厚度的保護層， 蒸鐘法形成厚度―島狀構造二;“上’《真空 ·:】得*聚對笨…乙二醋薄膜/離： 缚膜所構成之積層薄膜（c)。 層/保護層/錫 接者，在此積層薄膜（c)的錫薄膜上’以 成含有表！實施例3〜9所示之氧化鋅微二向塗覆法形 性樹脂層（厚声〇2/, %妹 乳化辞减叔與樹脂的絕緣 曰（与度0.2#!!!)，然後形成由 公司製的「KT595廑h 、 巧叫系树脂（科昵西 庫力亞」）所構成之厚度 — 製得實施例3〜9之太^ 的接者層， 9之本發明之轉印絕緣性材料。 且’在上述積層薄膜（c) 性樹脂層及樹脂声之任去4膜上，不形成前述絕緣 心… 者，而直接製得形成有丙烯酸系 树月曰（科昵西公司製的「κτ 矛 /y m ^ ^ « 犀力亞」）所構成之厚度2 '接者層之比較例1之轉印絕緣性材料。並且，在上述 刪膜⑹之錫薄膜上，以反向塗覆法，形成未含= 二較曰例2〜6所不之氧化鋅微粒’而僅由樹脂構成之樹 月曰層（厚度〇 · 2 # m)，铁接，制，η竹，丄、, …、 製仔开》成有丙浠酸系樹脂（科昵 西公司製的「ΚΤ595庫力亞」）所構成之厚度2心接著層 之比較例2〜6之轉印絕緣性材料。 接著，以輥轉印法將上述實施例3〜9之本發明之轉 印、、巴緣11材料、及比較Μ丨〜6之轉印絕緣性材料，轉印 於塑膠基材之厚度2mm的透明丙烯酸樹脂板，製得透明丙 烯&L树朐板/接著層/含氧化鋅微粒與樹脂之絕緣性樹脂 層/鍚薄膜/保護層/離型層依序形成之實施例3〜9之 本發明之成形品、透明丙烯酸樹脂板/接著層/錫薄膜/ 15 200810948 保護層/離型層依序形成之比較例1之成形品、以及透明 丙烯酸樹脂板/接著層/樹脂層/錫薄膜/保護層/離型 層依序形成之比較例2〜6之成形品。 對所製得之上述各成形品的全光線透過率進行測量， 並分別與咼溫高濕測試（6〇°c χ95% χ96小時）後的全光線透 過率比較。其結果示於表！。 且，在實施例3〜9及比較例2〜ό，絕緣性樹脂層或 樹脂層所使用的胺甲酸乙醋系樹脂，為三井武田化學公司 製的「塔景拉庫Α— 310 ,，盥使、曰人从扣 一 」 ” 5使用之異氰酸酯則為 二井武田化學公司製的「塔景 . 樹π炎口六w 厅、内钍Α— 3」。且，丙烯酸系 Μ月曰為日立化成工業公引制 血甘、 司製的「璽它洛依1 HA3004」， /、其混合使用之異氰酸酯則或二 、為二井武田化學公司萝 景内鉦D— 110N」。且，一取— 予A j表的塔 一來氰胺系樹脂（昱丁其X 〆 胺）為日立化成工業公司製的「美 '土二來亂 為堤加公司製的「氧化鋅漿體75、〇:。」，氧化辞微粒則 200810948 【I嚇】 齋歙 如家 in (N (N 〇〇 (N 〇\ r^i in (N 卜 (N o (N 62.1 60.9 τ—4 I 61.5 ι- 49.1 21.0 全光線透過率(％) 測試後 33.5 32.4 1—H' (N m 32.0 30.9 | 32.3 31.6 00 οά as 90.6 80.6 89.4 77.6 50.6 測試前 31.0 29.2 29.3 r—^ ο m 28.4 29.6 29.6 30.7 29.7 29.5 27.9 28.5 29.6 絕緣性樹脂層或樹脂層之組成（重量％) 氧化辞齡 卜 v〇 s vo r-H 1 1 1 1 1 1 集 jjQI 、丨1 1 I Ο i 1 m Os 00 1 1 ο ! (Τ) 100 異氰酸酯 1 1 (N cn CM 1 1 ιη CN S 1 鑛 I 1 i s oo 1 1 i 1 ο S 1 tO餿 瓣 m 〇\ 00 VO m Ό I 1 1 1 1 O 1 I 1 實施例3 實施例4 實施例5 實施例6 實施例7 實施例8 實施例9 比車交例1 比車交例2 比較例3 比較例4 比較例5 比車交例6 200810948 形成有含氧化辞微粒與樹脂之絕緣性樹脂層作為絕緣 性樹脂層之實施例3〜9之本發明所有的成形品，即使經 過咼溫鬲濕測試，金屬光澤亦無發生變化，為具有非常安 定之品質的良品，但反觀未形成絕緣性樹脂層及樹脂層任 一者之比較例1之成形品、及形成有未含氧化鋅微粒之樹 脂層之比較例2〜6之成形品，在高溫高濕測試下，全光 線透過度發生顯著變化，無法得到可安定使用之成形品。 $ <實施例10 > —於實施例3〜9及比較们〜6所製得之積層薄膜⑹的 錫薄膜上，以反向塗覆法形成硫化辞微粒 (日立化成工業公司製的「靈它洛依一4」)所:= 厚度〇.5em的絕緣性樹脂層（硫化鋅微粒含量：8重量， 然後，再形成丙烯酸系樹脂（科昵西公司製的「κτ59 亞」冰構成之厚度i心的的接著層，而製得本 印絕緣性材料。 轉 • 接冑，以輥轉印法將上述轉印絕緣性材料，轉印於塑 膠^材之厚度2mm的透明丙烯酸樹脂板，製得透明丙烯酸 樹脂板/接著層/含硫化辞微粒與樹脂之絕緣性樹脂層/ 錫薄膜/保護層/離型層依序形成之具金屬光澤之朴明 所製得之成形品的層間密合性良好，以透明膠帶 (sell〇tape ’註冊商標)進行剝離測試，無產生剝離。且， 在高温高濕測試（6(TCx95%x96小時）下，金屬 生變化（全光線透過率1試前卿，測試後33%)。 200810948 μ ® ί &例7:將氧化鋅微粒添加於離型層而非絕緣性 树月曰層的情形> & 5#m的聚對笨二甲酸乙二酯薄膜（二菱化學 聚酯薄膜公司製的「呷π a分& 、（一夂化予 _亞°句依魯G100」）的-面，以凹版 ^膝乳化鋅微粒（堤加公司製的「氧化鋅聚體750Z」） 及丙婦酸系樹脂(曰立化成工業公司製的「重它洛依笪 HA30=4」）所構成之厚度的離型層（氧化辞微粒含量： 在該離型層上’形成丙烯酸系樹脂(曰立化成 工業公司製的「它、、夂状社 田 璽匕…依丑HA3004」）及異氰酸酿（三井武 「塔景㈣D— UGN)所構成之厚度_ :=’並在該保護層上以真空蒸鐘法形成厚度13_ 王島狀構造且具絕緣性的錫薄膜，製得由聚對苯二甲酸乙 ==含有氧化鋅微粒與樹脂之離型層，保護層/錫 :構成之積層薄膜⑼。接著，在此積層薄膜⑼的錫 薄膜上’以反向金麗法形士山 覆法^成由丙烯酸糸樹脂（科昵西公司製 的「KT595庫力亞」）所構成之厚度的接 得轉印絕緣性材料。 ^ 然後’以較^轉印法，^ I. ^ 將上述轉印絕緣性材料轉印於作 為塑膠基材之厚度2職的透明丙婦酸樹脂板，製得透明丙 烯酸樹脂板/接著層/錫薄膜/保護層/含有氧粒 與樹脂之離型層依序形成之具金屬綺的成形品。 所製得之成形品的層間密合性良好，以透明膠帶 (sellotape’註冊商標）進行剝離測言式’無產生剝離。铁而， 在高溫南濕測試（6(TCx95%x96小時）下金屬光澤消失（全 19 200810948 光線透過率：測試前30.5%，測試後91〇%)。 產業上利用性 ^ :發明之第―、及第二絕緣性材料，由於具有金屬光 澤U具耐久性的絕緣性被膜，因此可在使各種物品之 表面具有絕緣性的狀態下，製成金屬光澤優異纟，可使用 在打動電話之框體、聲音產品之框體、家電等遠端用紅外 線透過蓋板、汽車用毫米波透過蓋板、造膜材料、微波爐 用食品容器或包裝材料、微波爐用容器的封蓋材料、電子 零件用包裝材料、金屬蒸鍍薄膜製氣球、捕鳥用或誘導用 或防蟲用等農園藝用反射膠帶、絕緣性的金屬線、使用該 金屬線之地毯狀覆蓋物或車用地毯等非常廣泛的範圍。 【圖式簡單說明】a water-soluble paint layer having a thickness of 1" (negative pattern of a desired pattern), and formed on the pot by a vacuum deposition method to form a tin film having a thickness of 2 Gnm and having an island structure and having an insulating property. Ethylene terephthalate film/undercoat layer (release layer/protective layer/water-soluble paint layer (negative pattern of desired pattern)/thin film (B) composed of tin-bismuth film. Next, laminate here On the (4) film of the film (B), the zinc particles are formed by reverse coating ("Zinc Oxide Slurry 75〇z", manufactured by Dijia Co., Ltd.), a trimeric amide-based resin (manufactured by Hitachi Chemical Co., Ltd.)与 说 2 / / / / / / / HA 日 日 日 日 日 日 日 日 HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA绫 丨 丨 树 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( a tin film and an insulating resin layer which are not present in the water-soluble paint layer are laminated to form a desired pattern, and A transfer insulating material of the present invention is obtained by forming a bonding layer of thickness i//m composed of (4) an acid resin ("ΚΤ595 kuli" manufactured by K.K.) under the gravure coating method. Next, the transfer insulating material is transferred by using an in-mold forming method using a transparent acrylic resin as a plastic substrate, and the adhesive layer/protective layer/release layer are sequentially formed on the transparent acrylic substrate. The transparent portion, and the adhesive layer/tin film/protective layer/release layer containing the zinc oxide particles and the resin are sequentially formed to form a pattern portion having a metallic luster and having a beautiful appearance. The obtained molded article has good interlayer adhesion, and is peeled off by a scotch tape (registered trademark), and no peeling occurs, and there is no scratch in the portion which is luster. Moreover, in the high temperature and high humidity test ( 6〇t: x95 % X96 hours), the metallic luster did not change (total light transmittance: 15% before the test, 16% after the test). <Examples 3 to 9, and Comparative Examples 1 to 6 > Polyethylene terephthalate at a thickness of 25 μm One side of the ethylene glycol film ("Daily Chemicals Co., Ltd."), which is made by the gravure coating method, forms an acrylic resin (TR 16 Nissan, manufactured by Dainippon Ink and Chemicals, Inc.) The release layer of the thickness l"m, the acrylic resin ("It is a stalk of HA3〇〇4" manufactured by Hitachi Chemical Co., Ltd.), and the isocyanate ("Takeview" by Mitsui Takeda Chemical Co., Ltd.铨d_ii〇n) 14 200810948 The thickness of the protective layer formed by the steaming method to form the thickness - the island-like structure 2; "Upper" "vacuum::] * Poly-pair stupid... Ethylene vinegar film / away: Bonding film A laminated film (c) is formed. The layer/protective layer/tin bond is placed on the tin film of the laminated film (c). The zinc oxide micro-bidirectionally coated resinous resin layer shown in Examples 3 to 9 (thickness 〇 2/, % sister emulsified minus the insulating 曰 of the resin and the resin (degree 0.2#!!!), and then formed The thickness of the "KT595廑h, the smart resin" (Korean Kelly) made by the company - the connector layer of the embodiment 3 to 9 is obtained, and the transfer insulation of the invention of 9 In the above-mentioned laminated film (c) resin layer and resin sound, the above-mentioned insulating core is not formed, and the acrylic tree is formed directly (made by Kexi Co., Ltd.). The transfer insulating material of the comparative example 1 of the thickness 2' connector layer of the "kappa pike/ym ^ ^ « rhinoceros" is formed, and is applied in reverse on the tin film of the above-mentioned film (6). The coating method forms a layer of sapphire layer (thickness 〇· 2 # m) which is not composed of oxidized zinc particles which are not included in the examples 2 to 6 and which is composed only of resin, iron joint, system, η bamboo, 丄, , ..., 制仔开" has a propylene carbonate resin ("ΚΤ595 kulia" made by Kexixi Co., Ltd.), which consists of a thickness of 2 core layers, and a transfer of Comparative Examples 2 to 6. Next, the transfer, the material of the rim 11 and the transfer insulating material of the comparative Μ丨6 of the above embodiments 3 to 9 are transferred to a plastic substrate by a roll transfer method. Transparent acrylic resin sheet having a thickness of 2 mm, and an example of producing a transparent propylene & L-tree slab/adhesive layer/insulating resin layer containing zinc oxide particles and resin, ruthenium film/protective layer/release layer sequentially formed 3 to 9 of the molded article of the present invention, transparent acrylic resin sheet/adhesive layer/tin film/15 200810948 Protective layer/release layer sequentially formed of the molded article of Comparative Example 1, and transparent acrylic resin sheet/attach layer/resin The layer/tin film/protective layer/release layer were sequentially formed into the molded articles of Comparative Examples 2 to 6. The total light transmittance of each of the obtained molded articles was measured and tested with the temperature and humidity test respectively ( The total light transmittance after 6〇°c χ95% χ96 hours) is compared. The results are shown in Tables. Further, in Examples 3 to 9 and Comparative Example 2 to ό, the amine used in the insulating resin layer or the resin layer Ethyl formate resin, which is made by Mitsui Takeda Chemical Co., Ltd. 310,, 盥 曰 曰 曰 」 ” ” 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 异 异 异 异 异 异 异 异 异 异 异 异 异 异 异 异 异曰 日 日 日 日 日 日 HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA HA取取—To the tower of the A j table, the cyanamide-based resin (the decylamine and the decylamine) is a "zinc oxide slurry 75 made by the company". 〇:.", oxidized particle is 200810948 [I scare] 歙 歙 home in (N (N 〇〇 (N 〇 \ r^i in (N 卜 (N o (N 62.1 60.9 τ-4 I 61.5 ι- 49.1 21.0 Total light transmittance (%) After test 33.5 32.4 1—H' (N m 32.0 30.9 | 32.3 31.6 00 οά as 90.6 80.6 89.4 77.6 50.6 Before test 31.0 29.2 29.3 r—^ ο m 28.4 29.6 29.6 30.7 29.7 29.5 27.9 28.5 29.6 Composition of insulating resin layer or resin layer (% by weight) Oxidation ageing v〇s vo rH 1 1 1 1 1 1 Set jjQI丨1 1 I Ο i 1 m Os 00 1 1 ο ! (Τ) 100 Isocyanate 1 1 (N cn CM 1 1 ιη CN S 1 Mine I 1 is oo 1 1 i 1 ο S 1 tO馊 mm\ 00 VO m Ό I 1 1 1 1 O 1 I 1 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 1 Comparison Example 2 Comparison Example 3 Comparison Example 4 Comparison Example 5: Example 6 200810948 All of the molded articles of the present invention of Examples 3 to 9 in which an insulating resin layer containing oxidized particles and a resin was formed as an insulating resin layer, even after the temperature and humidity test, the metallic luster There is no change, and it is a good product having a very stable quality, but a molded article of Comparative Example 1 in which neither the insulating resin layer nor the resin layer is formed, and a comparative example in which a resin layer containing no zinc oxide fine particles is formed is observed. In the molded articles of 2 to 6, under the high-temperature and high-humidity test, the total light transmittance was significantly changed, and a molded article that could be used stably could not be obtained. $ <Example 10> - On the tin film of the laminated film (6) obtained in Examples 3 to 9 and Comparative Example ～6, the sulphur particles were formed by reverse coating ("Hitachi Chemical Co., Ltd."灵 洛 洛 」 」 : : = = 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 绝缘 5 绝缘 绝缘 绝缘 绝缘 绝缘 绝缘 绝缘 绝缘 绝缘The insulating layer of the printing material is obtained by the adhesive layer of the thickness i. The transfer insulating material is transferred by a roll transfer method to a transparent acrylic resin plate having a thickness of 2 mm. Interlayer adhesion of a molded article obtained by producing a transparent acrylic resin sheet/adhesive layer/insulating resin layer containing vulcanized particles and resin/tin film/protective layer/release layer formed in a metallic luster Good compatibility, peel test with scotch tape (Sell〇tape 'registered trademark), no peeling occurred. Also, in the high temperature and high humidity test (6 (TCx95% x 96 hours), metal change (total light transmittance 1 test) Qian Qing, 33% after the test. 200810948 μ ® ί & Example 7 : In the case where zinc oxide fine particles are added to the release layer instead of the insulating tree layer, ><5#m of polyethylene terephthalate film (" 呷π" manufactured by Mitsubishi Chemical Polyester Film Co., Ltd. A-point &, (a 夂 予 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ (The release layer of the thickness of the "Heavy yue yue HA30=4" manufactured by the Chemical Industry Co., Ltd.) (oxidized particle content: on the release layer, the formation of an acrylic resin (Yu Lihua Chemical Industry Co., Ltd.) The thickness of the system consists of "it, 夂状社田玺匕...依丑HA3004") and isocyanate (Mitsuiwu "Tajing (4) D-UGN) _ :=' and vacuum steamed on the protective layer The bell method forms a tin film having a thickness of 13 mm and an insulating structure, and a laminated film (9) composed of polyethylene terephthalate == a release layer containing zinc oxide fine particles and a resin, and a protective layer/tin: is formed. Next, on the tin film of the laminated film (9), the reversed gold ray method is used to form the yttrium resin. The thickness of the "KT595" manufactured by the company is transferred to the insulating material. ^ Then 'by the transfer method, ^ I. ^ Transfer the above-mentioned transfer insulating material as a plastic base The thickness of the material is a transparent acrylic acid resin board of the second grade, and a transparent acrylic resin sheet/adhesive layer/tin film/protective layer/formed product containing metal ruthenium formed by the release layer containing oxygen particles and resin is sequentially obtained. The obtained molded article had good interlayer adhesion, and the peeling test was carried out with a transparent tape (sellotape's registered trademark), and no peeling occurred. Iron, and high-temperature south-wet test (6 (TCx 95% x 96 hours) under metal luster Disappeared (all 19 200810948 light transmission rate: 30.5% before the test, 91% after the test). INDUSTRIAL APPLICABILITY The first and second insulating materials of the invention have an insulating coating having a metallic luster and durability, and therefore can be made into a metallic luster in a state in which the surface of each article is insulative. Excellent, you can use the frame for moving the phone, the frame of the sound product, the infrared ray transparent cover for the home appliance, the millimeter wave transmission cover for the automobile, the film-forming material, the food container or packaging material for the microwave oven, and the microwave oven. Cover material for containers, packaging materials for electronic parts, balloons made of metal vapor-deposited film, reflective tape for agriculture and gardening for birding or induction or insect control, insulating metal wire, carpet-like covering using the metal wire A very wide range of objects or car carpets. [Simple description of the map]
Ml 【主要元件符號說明】 無Ml [Main component symbol description] None
2020
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2006/316245 WO2008020482A1 (en) | 2006-08-18 | 2006-08-18 | Insulating material excelling in metallic gloss and molded article making use of the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200810948A true TW200810948A (en) | 2008-03-01 |
| TWI327532B TWI327532B (en) | 2010-07-21 |
Family
ID=39078285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096130100A TW200810948A (en) | 2006-08-18 | 2007-08-15 | Insulating material excelling in metallic gloss and molded article making use of the same |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP4036465B1 (en) |
| TW (1) | TW200810948A (en) |
| WO (1) | WO2008020482A1 (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5401132B2 (en) * | 2009-01-20 | 2014-01-29 | 信越ポリマー株式会社 | Radio wave transmitting decorative member and manufacturing method thereof |
| JP5402109B2 (en) * | 2009-02-27 | 2014-01-29 | デクセリアルズ株式会社 | Anisotropic conductive film and light emitting device |
| JP5346632B2 (en) | 2009-03-17 | 2013-11-20 | 信越ポリマー株式会社 | Radio wave transmitting decorative film and decorative member using the same |
| CN102094175B (en) * | 2010-12-30 | 2012-11-21 | 沈阳金锋特种刀具有限公司 | Powder sintering multicomponent alloy coated target adopting direct water cooling and preparation method thereof |
| JP5970914B2 (en) * | 2012-03-29 | 2016-08-17 | 大日本印刷株式会社 | Three-dimensional decorative film |
| JP6593701B2 (en) * | 2016-02-16 | 2019-10-23 | 株式会社豊田中央研究所 | Dielectric thin film |
| JP6720644B2 (en) * | 2016-03-30 | 2020-07-08 | 大日本印刷株式会社 | Hard coat film for transfer to electromagnetic wave transmissive decorative member, hard coat layer laminate with substrate film, electromagnetic wave transmissive decorative member, and production methods thereof |
| JPWO2020066597A1 (en) * | 2018-09-26 | 2021-08-30 | 富士フイルム株式会社 | Laminate |
| JP7316671B2 (en) * | 2020-11-17 | 2023-07-28 | 尾池工業株式会社 | Scale-like pigment, paint, and painted object having millimeter wave transparency |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62174189A (en) * | 1985-10-21 | 1987-07-30 | Reiko Co Ltd | Insulating transfer material |
| JP3788101B2 (en) * | 1998-04-24 | 2006-06-21 | 凸版印刷株式会社 | Transparent gas barrier composite film material having UV-cutting property and package using the same |
| JP3877318B2 (en) * | 2004-01-19 | 2007-02-07 | 株式会社麗光 | Iris color transfer film and iris color molded product obtained using the same |
| JP2005212339A (en) * | 2004-01-30 | 2005-08-11 | Reiko Co Ltd | Iridescent transfer film and iridescent molded article obtained by using the same |
-
2006
- 2006-08-18 JP JP2007529290A patent/JP4036465B1/en active Active
- 2006-08-18 WO PCT/JP2006/316245 patent/WO2008020482A1/en active Application Filing
-
2007
- 2007-08-15 TW TW096130100A patent/TW200810948A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP4036465B1 (en) | 2008-01-23 |
| WO2008020482A1 (en) | 2008-02-21 |
| JPWO2008020482A1 (en) | 2010-01-07 |
| TWI327532B (en) | 2010-07-21 |
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