TW200711718A - Process for making cation exchange membranes with reduced methanol permeability - Google Patents

Process for making cation exchange membranes with reduced methanol permeability

Info

Publication number
TW200711718A
TW200711718A TW095128575A TW95128575A TW200711718A TW 200711718 A TW200711718 A TW 200711718A TW 095128575 A TW095128575 A TW 095128575A TW 95128575 A TW95128575 A TW 95128575A TW 200711718 A TW200711718 A TW 200711718A
Authority
TW
Taiwan
Prior art keywords
cation exchange
exchange membranes
methanol permeability
reduced methanol
making cation
Prior art date
Application number
TW095128575A
Other languages
English (en)
Inventor
Raj G Rajendran
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of TW200711718A publication Critical patent/TW200711718A/zh

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B01D67/00933—Chemical modification by addition of a layer chemically bonded to the membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C08J5/2293—After-treatment of fluorine-containing membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/881—Electrolytic membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/34—Use of radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
TW095128575A 2005-08-05 2006-08-04 Process for making cation exchange membranes with reduced methanol permeability TW200711718A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/198,461 US20070031716A1 (en) 2005-08-05 2005-08-05 Process for making cation exchange membranes with reduced methanol permeability

Publications (1)

Publication Number Publication Date
TW200711718A true TW200711718A (en) 2007-04-01

Family

ID=37654820

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095128575A TW200711718A (en) 2005-08-05 2006-08-04 Process for making cation exchange membranes with reduced methanol permeability

Country Status (6)

Country Link
US (1) US20070031716A1 (zh)
JP (1) JP2009503802A (zh)
KR (1) KR20080034189A (zh)
DE (1) DE112006002073T5 (zh)
TW (1) TW200711718A (zh)
WO (1) WO2007019157A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112198210A (zh) * 2020-08-26 2021-01-08 广东省微生物研究所（广东省微生物分析检测中心） 一种基于MOF-AuNPs涂层的超低阻抗电极界面的制备方法

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JP5211418B2 (ja) * 2005-07-08 2013-06-12 トヨタ自動車株式会社 電解質膜の製造方法
US20070116996A1 (en) * 2005-11-22 2007-05-24 Teledyne Technologies Incorporated Regenerative fuel cell/electrolyzer stack
EP2420310A4 (en) * 2009-04-13 2013-04-17 Univ Yamaguchi ION EXCHANGE MEMBRANE AND MANUFACTURING METHOD THEREFOR
ES2748340T3 (es) 2009-08-26 2020-03-16 Evoqua Water Tech Pte Ltd Membranas de intercambio iónico
US20110240203A1 (en) * 2010-04-01 2011-10-06 Korea Institute Of Science & Technology Method for producing a membrane-electrode assembly for a fuel cell
SG189894A1 (en) 2010-10-15 2013-06-28 Siemens Industry Inc Process for making a monomer solution for making cation exchange membranes
JP2013545595A (ja) 2010-10-15 2013-12-26 シーメンス インダストリー インコーポレイテッド アニオン交換膜及び製造方法
JP5389768B2 (ja) * 2010-11-02 2014-01-15 株式会社日立製作所 高分子電解質膜並びにこれを用いた膜電極接合体及び固体高分子形燃料電池
US9941523B2 (en) 2011-07-18 2018-04-10 Daimler Ag Bilayer cathode catalyst structure for solid polymer electrolyte fuel cell
DE112012005339B4 (de) 2011-12-19 2019-02-14 National Research Council Of Canada Verfahren zur Herstellung coextrudierter Ionenaustauschvorläufer- Harzmembranen und deren Verwendung
US20150315042A1 (en) 2012-10-04 2015-11-05 Evoqua Water Technologies Llc High-Performance Anion Exchange Membranes and Methods of Making Same
US9540261B2 (en) 2012-10-11 2017-01-10 Evoqua Water Technologies Llc Coated ion exchange membranes
KR102225982B1 (ko) * 2013-05-14 2021-03-11 존슨 맛쎄이 푸엘 셀스 리미티드 촉매
KR101655409B1 (ko) * 2014-05-30 2016-09-09 한국원자력연구원 가교 고분자 블렌드 양이온 교환막 및 이의 제조방법
KR101637711B1 (ko) * 2014-10-30 2016-07-07 현대자동차주식회사 연료전지의 고분자 전해질막-전극 접합체용 전극의 분리방법과 그 장치
KR102266006B1 (ko) * 2015-09-16 2021-06-16 에보쿠아 워터 테크놀로지스 엘엘씨 할로겐화 불순물을 제거하기 위한 이온교환수지의 감마선 조사
WO2019059570A1 (ko) * 2017-09-19 2019-03-28 주식회사 엘지화학 연료전지용 촉매의 제조 방법 및 이에 의하여 제조된 연료전지용 촉매
CN112752789A (zh) 2018-09-25 2021-05-04 懿华水处理技术有限责任公司 通过uv引发的聚合的离子交换膜
CN113594519B (zh) * 2021-04-23 2022-06-07 西安交通大学 一种碱性甲醇燃料电池的异相阴离子导电膜的制备方法

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US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3644915A (en) * 1969-08-27 1972-02-22 Allis Chalmers Mfg Co Filter bypass indicator
US3962153A (en) * 1970-05-21 1976-06-08 W. L. Gore & Associates, Inc. Very highly stretched polytetrafluoroethylene and process therefor
CA962021A (en) * 1970-05-21 1975-02-04 Robert W. Gore Porous products and process therefor
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5128014A (en) * 1991-03-01 1992-07-07 E. I. Du Pont De Nemours And Company Irradiation of cation exchange membranes
US5264093A (en) * 1992-04-30 1993-11-23 E. I. Du Pont De Nemours And Company Irradiation of cation exchange membranes to increse current efficiency and reduce power consumption
US5330626A (en) * 1993-02-16 1994-07-19 E. I. Du Pont De Nemours And Company Irradiation of polymeric ion exchange membranes to increase water absorption
US5422411A (en) * 1993-09-21 1995-06-06 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US6025092A (en) * 1998-02-13 2000-02-15 E. I. Du Pont De Nemours And Company Fluorinated ionomers and their uses
CZ2001915A3 (cs) * 1998-09-15 2001-09-12 Regenesys Technologies Limited Způsob přípravy zesíťěného polymeru roubovaného monomerem
ATE478913T1 (de) * 2000-06-02 2010-09-15 Stanford Res Inst Int Polymermembranzusammensetzung
JP3670565B2 (ja) * 2000-09-29 2005-07-13 株式会社東芝 液体供給型メタノール燃料電池用イオン導電性膜およびそれを用いた燃料電池
EP1444748B1 (en) * 2001-10-15 2008-08-13 E.I. Du Pont De Nemours And Company Solid polymer membrane for fuel cell with polyvinylamine imbibed therein for reducing methanol permeability
US20080038624A1 (en) * 2003-09-04 2008-02-14 Jorg Belack Proton-conducting polymer membrane coated with a catalyst layer, said polymer membrane comprising phosphonic acid polymers, membrane/electrode unit and use thereof in fuel cells

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112198210A (zh) * 2020-08-26 2021-01-08 广东省微生物研究所（广东省微生物分析检测中心） 一种基于MOF-AuNPs涂层的超低阻抗电极界面的制备方法

Also Published As

Publication number Publication date
KR20080034189A (ko) 2008-04-18
DE112006002073T5 (de) 2008-06-12
WO2007019157A1 (en) 2007-02-15
JP2009503802A (ja) 2009-01-29
US20070031716A1 (en) 2007-02-08

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