TW200504103A - Supported metallocene catalysts - Google Patents

Supported metallocene catalysts

Info

Publication number
TW200504103A
TW200504103A TW093109750A TW93109750A TW200504103A TW 200504103 A TW200504103 A TW 200504103A TW 093109750 A TW093109750 A TW 093109750A TW 93109750 A TW93109750 A TW 93109750A TW 200504103 A TW200504103 A TW 200504103A
Authority
TW
Taiwan
Prior art keywords
alumoxane
support
silica
catalysts
metallocene
Prior art date
Application number
TW093109750A
Other languages
English (en)
Inventor
William J Gauthier
Margaret Elaine Kerr
Jun Tian
David Rauscher
Constance Hayworth Patrick
Henry Shady
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology filed Critical Fina Technology
Publication of TW200504103A publication Critical patent/TW200504103A/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
TW093109750A 2003-04-11 2004-04-08 Supported metallocene catalysts TW200504103A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/412,372 US6855783B2 (en) 2003-04-11 2003-04-11 Supported metallocene catalysts

Publications (1)

Publication Number Publication Date
TW200504103A true TW200504103A (en) 2005-02-01

Family

ID=33131194

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093109750A TW200504103A (en) 2003-04-11 2004-04-08 Supported metallocene catalysts

Country Status (8)

Country Link
US (1) US6855783B2 (zh)
EP (1) EP1613665A4 (zh)
JP (1) JP2007524721A (zh)
KR (1) KR20060006920A (zh)
CN (1) CN1795211A (zh)
CA (1) CA2521652A1 (zh)
TW (1) TW200504103A (zh)
WO (1) WO2004092225A1 (zh)

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US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
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EP1762577A1 (en) * 2005-09-02 2007-03-14 Total Petrochemicals Research Feluy Impact copolymer of propylene prepared in single reactor
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US7683002B2 (en) * 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
US20070299222A1 (en) * 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
KR100968704B1 (ko) * 2006-12-01 2010-07-06 주식회사 엘지화학 페닐렌 브릿지를 가지는 전이 금속 촉매 화합물을 이용한올레핀 중합용 담지촉매, 이의 제조방법, 상기 올레핀중합용 담지촉매를 이용한 올레핀계 중합체의 제조방법, 및이에 의해 제조된 올레핀계 중합체
WO2008088022A1 (ja) * 2007-01-18 2008-07-24 Prime Polymer Co., Ltd. 応力耐久成形体用のプロピレン単独重合体、および該重合体を含む組成物、並びにこれらから得られる応力耐久成形体
US8299188B2 (en) * 2007-05-18 2012-10-30 Fina Technology, Inc. Supported metallocene catalysts
US20080287619A1 (en) * 2007-05-18 2008-11-20 William Gauthier Supported metallocene catalysts
EP2006011A1 (en) * 2007-06-22 2008-12-24 Total Petrochemicals Research Feluy Process for reducing carbon monoxide in olefin-containing hydrocarbon feedstocks
EP2006012A1 (en) * 2007-06-22 2008-12-24 Total Petrochemicals Research Feluy Process for the polymerisation of olefins
KR101084677B1 (ko) 2008-05-14 2011-11-22 주식회사 엘지화학 올레핀 중합체의 제조방법
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US20160145360A1 (en) * 2013-06-24 2016-05-26 Saudi Basic Industries Corporation Titanated chromium-based catalysts to produce high density polyethylene
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JP6199731B2 (ja) * 2013-12-26 2017-09-20 旭化成株式会社 ポリエチレンの製造方法
US10294316B2 (en) * 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
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CN107690442A (zh) * 2015-06-05 2018-02-13 埃克森美孚化学专利公司 双峰丙烯聚合物和顺序聚合
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Also Published As

Publication number Publication date
EP1613665A4 (en) 2011-08-03
JP2007524721A (ja) 2007-08-30
US20040204310A1 (en) 2004-10-14
KR20060006920A (ko) 2006-01-20
WO2004092225A1 (en) 2004-10-28
CA2521652A1 (en) 2004-10-28
CN1795211A (zh) 2006-06-28
US6855783B2 (en) 2005-02-15
EP1613665A1 (en) 2006-01-11

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