TW200420346A - Preparation of vanadium antimony oxide based catalysts using nano-scale iron - Google Patents
Preparation of vanadium antimony oxide based catalysts using nano-scale ironInfo
- Publication number
- TW200420346A TW200420346A TW092131829A TW92131829A TW200420346A TW 200420346 A TW200420346 A TW 200420346A TW 092131829 A TW092131829 A TW 092131829A TW 92131829 A TW92131829 A TW 92131829A TW 200420346 A TW200420346 A TW 200420346A
- Authority
- TW
- Taiwan
- Prior art keywords
- ammoxidation
- antimony oxide
- preparation
- oxygen
- iron
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 8
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052742 iron Inorganic materials 0.000 title abstract 4
- HBNLSMCCHISJHZ-UHFFFAOYSA-N [Sb]=O.[V] Chemical compound [Sb]=O.[V] HBNLSMCCHISJHZ-UHFFFAOYSA-N 0.000 title abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- FFNVQNRYTPFDDP-UHFFFAOYSA-N 2-cyanopyridine Chemical compound N#CC1=CC=CC=N1 FFNVQNRYTPFDDP-UHFFFAOYSA-N 0.000 abstract 1
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- LAQPNDIUHRHNCV-UHFFFAOYSA-N isophthalonitrile Chemical compound N#CC1=CC=CC(C#N)=C1 LAQPNDIUHRHNCV-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229940078552 o-xylene Drugs 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B01J35/23—
-
- B01J35/40—
-
- B01J35/615—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/306,017 US6864384B2 (en) | 2002-11-27 | 2002-11-27 | Preparation of vanadium antimony oxide based catalysts using nano-scale iron |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200420346A true TW200420346A (en) | 2004-10-16 |
Family
ID=32325572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW092131829A TW200420346A (en) | 2002-11-27 | 2003-11-13 | Preparation of vanadium antimony oxide based catalysts using nano-scale iron |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6864384B2 (zh) |
| AU (1) | AU2003302599A1 (zh) |
| TW (1) | TW200420346A (zh) |
| WO (1) | WO2004050237A1 (zh) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100671978B1 (ko) * | 2005-07-19 | 2007-01-24 | 한국과학기술연구원 | 탈질환원촉매 |
| JP4670603B2 (ja) * | 2005-11-18 | 2011-04-13 | 株式会社デンソー | 触媒用粒子およびその製造方法 |
| US7678735B2 (en) * | 2005-11-28 | 2010-03-16 | Engelhard Corporation | FCC additive for partial and full burn NOx control |
| US7709541B2 (en) * | 2006-07-14 | 2010-05-04 | Headwaters Technology Innovation, Llc | Fischer-Tropsch catalysts incorporating promoter for increasing yields of C5+ hydrocarbons and methods for making and using same |
| WO2010114096A1 (ja) * | 2009-04-03 | 2010-10-07 | 日本たばこ産業株式会社 | 喫煙物品用一酸化炭素低減触媒およびその製造方法 |
| CN103736496B (zh) * | 2012-10-17 | 2015-10-21 | 中国石油化工股份有限公司 | 氨氧化制不饱和腈流化床催化剂制备方法 |
| US9409156B2 (en) | 2012-10-19 | 2016-08-09 | Instituto Mexicano Del Petroleo | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
| PL3027310T3 (pl) | 2013-07-31 | 2023-07-24 | Research Triangle Institute | Mieszane tlenki metalicznego żelaza i ich wykorzystanie |
| US11612880B2 (en) * | 2016-08-12 | 2023-03-28 | Asahi Kasei Kabushiki Kaisha | Method for producing oxide catalyst, and method for producing unsaturated nitrile and unsaturated acid |
| CN107376928A (zh) * | 2017-08-04 | 2017-11-24 | 南京邮电大学 | 一种一步法合成α‑Fe2O3/Bi复合物的方法 |
| CN114950404B (zh) * | 2022-05-19 | 2023-11-17 | 中国科学院兰州化学物理研究所 | 一种耐磨损的氨氧化催化剂及其制备方法和应用 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT829026A (zh) | 1967-04-18 | |||
| US3860534A (en) | 1971-03-24 | 1975-01-14 | Power Gas Ltd | Method of making an antimony-vanadium catalyst |
| CA1108114A (en) * | 1977-04-14 | 1981-09-01 | Gregor H. Riesser | Dehydrogenation catalyst |
| US4746641A (en) | 1984-08-22 | 1988-05-24 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
| US4788317A (en) | 1984-08-22 | 1988-11-29 | Standard Oil Company | Ammoxidation of paraffins and catalysts therefor |
| US4784979A (en) | 1987-12-07 | 1988-11-15 | The Standard Oil Company | Catalyst and catalyst precursor containing vanadium and antimony |
| US4879264A (en) | 1988-11-14 | 1989-11-07 | The Standard Oil Company | Method of making catalyst and catalyst precursor containing vanadium and antimony |
| US5008427A (en) | 1988-12-23 | 1991-04-16 | The Standard Oil Company | Ammoxidation of paraffins |
| US5094989A (en) | 1990-12-21 | 1992-03-10 | The Standard Oil Company | Process for activation of catalysts |
| FR2687670B1 (fr) | 1992-02-20 | 1995-05-19 | Rhone Poulenc Chimie | Procede d'ammoxydation d'hydrocarbures satures. |
| US5214016A (en) | 1992-04-02 | 1993-05-25 | The Standard Oil Company | Method of making catalysts containing vanadium, antimony and tin |
| US5258543A (en) | 1992-06-26 | 1993-11-02 | The Standard Oil Company | Method for ammoxidation of olefins |
| ES2141831T3 (es) | 1993-08-26 | 2000-04-01 | Bp America | Metodo para mejorar catalizadores de oxidacion y amoxidacion. |
| US5432141A (en) | 1994-03-15 | 1995-07-11 | The Standard Oil Company | Preparation of attrition resistant vanadium-antimony oxide catalysts |
| US5498588A (en) | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
| FR2739373B1 (fr) | 1995-09-29 | 1997-10-31 | Rhone Poulenc Fibres | Procede de preparation de catalyseurs d'ammoxydation |
| US5750760A (en) | 1995-10-05 | 1998-05-12 | Mitsubishi Chemical Corporation | Method for producing a nitrile |
| US5821192A (en) | 1996-09-23 | 1998-10-13 | The Standard Oil Company | Method of improving the attrition resistance of V/SB oxide based catalyst |
| US5854172A (en) | 1997-01-17 | 1998-12-29 | The Standard Oil Company | Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O |
| US5866502A (en) | 1997-03-27 | 1999-02-02 | The Standard Oil Co. | Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes |
| US6156920A (en) | 1998-03-26 | 2000-12-05 | The Standard Oil Company | Molybdenum promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
| US5994259A (en) | 1998-07-29 | 1999-11-30 | The Standard Oil Company | Catalysts for the ammoxidation of alkanes |
| US20040102318A1 (en) * | 2002-11-27 | 2004-05-27 | Brazdil James F. | Method for enhancing the productivity of vanadium antimony oxide catalysts |
| US6887825B2 (en) * | 2002-11-27 | 2005-05-03 | The Standard Oil Company | Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media |
-
2002
- 2002-11-27 US US10/306,017 patent/US6864384B2/en not_active Expired - Fee Related
-
2003
- 2003-11-07 WO PCT/US2003/035568 patent/WO2004050237A1/en not_active Application Discontinuation
- 2003-11-07 AU AU2003302599A patent/AU2003302599A1/en not_active Abandoned
- 2003-11-13 TW TW092131829A patent/TW200420346A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20040102642A1 (en) | 2004-05-27 |
| AU2003302599A1 (en) | 2004-06-23 |
| US6864384B2 (en) | 2005-03-08 |
| WO2004050237A1 (en) | 2004-06-17 |
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