TR201900116T4 - Electrolytic Formation of Manganese (III) Ions in Strong Sulfuric Acid - Google Patents
Electrolytic Formation of Manganese (III) Ions in Strong Sulfuric Acid Download PDFInfo
- Publication number
- TR201900116T4 TR201900116T4 TR2019/00116T TR201900116T TR201900116T4 TR 201900116 T4 TR201900116 T4 TR 201900116T4 TR 2019/00116 T TR2019/00116 T TR 2019/00116T TR 201900116 T TR201900116 T TR 201900116T TR 201900116 T4 TR201900116 T4 TR 201900116T4
- Authority
- TR
- Turkey
- Prior art keywords
- manganese
- ions
- iii
- sulfuric acid
- electrolytic cell
- Prior art date
Links
- -1 Manganese (III) Ions Chemical class 0.000 title abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title 1
- 239000008151 electrolyte solution Substances 0.000 abstract 3
- 229910021397 glassy carbon Inorganic materials 0.000 abstract 2
- 229920000049 Carbon (fiber) Polymers 0.000 abstract 1
- 239000010405 anode material Substances 0.000 abstract 1
- 239000004917 carbon fiber Substances 0.000 abstract 1
- 238000006056 electrooxidation reaction Methods 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/22—Roughening, e.g. by etching
- C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/21—Manganese oxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
Abstract
Bir elektrolitik hücre ve elektrolitik hücre içinde manganez (II) iyonlarının manganez (III) iyonlarına elektrokimyasal oksidasyonu açıklanmıştır. Elektrolitik hücre (1) 9 ila 15 molarlık bir sülfürik asit çözeltisi içinde manganez (II) iyonlarının bir elektrolit çözeltisini; (2) elektrolit çözeltisine daldırılmış bir katot; ve (3) elektrolit çözeltisine daldırılmış ve katota mesafeli yerleştirilmiş bir anot içerir. Camsı karbon, ağ şeklinde camsı karbon ve dokunmuş karbon elyaf dahil olmak üzere çeşitli anot malzemeleri açıklanmıştır.Electrochemical oxidation of manganese (II) ions to manganese (III) ions in an electrolytic cell and electrolytic cell has been described. The electrolytic cell (1) comprises an electrolyte solution of manganese (II) ions in a 9 to 15 molar sulfuric acid solution; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced from the cathode. Various anode materials have been disclosed, including glassy carbon, reticulated glassy carbon, and woven carbon fiber.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/677,798 US9752241B2 (en) | 2012-01-23 | 2012-11-15 | Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR201900116T4 true TR201900116T4 (en) | 2019-01-21 |
Family
ID=50731593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2019/00116T TR201900116T4 (en) | 2012-11-15 | 2013-09-26 | Electrolytic Formation of Manganese (III) Ions in Strong Sulfuric Acid |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2920341B1 (en) |
| JP (1) | JP6060270B2 (en) |
| KR (2) | KR101950169B1 (en) |
| CN (1) | CN104838044B (en) |
| BR (1) | BR112015011123B1 (en) |
| CA (2) | CA3056665A1 (en) |
| ES (1) | ES2704672T3 (en) |
| MX (1) | MX2015006178A (en) |
| PL (1) | PL2920341T3 (en) |
| TR (1) | TR201900116T4 (en) |
| TW (1) | TWI500582B (en) |
| WO (1) | WO2014077957A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2014249521B2 (en) * | 2013-03-12 | 2018-03-01 | Macdermid Acumen, Inc. | Electrolytic generation of manganese (III) ions in strong sulfuric acid |
| SG11201610462WA (en) | 2014-07-10 | 2017-02-27 | Okuno Chem Ind Co | Resin plating method |
| EP3186410A1 (en) * | 2014-08-28 | 2017-07-05 | Inkron Ltd. | Crystalline transition metal oxide particles and continuous method of producing the same |
| US10889905B2 (en) * | 2018-12-11 | 2021-01-12 | Rohm And Haas Electronic Materials Llc | Methods of generating manganese (III) ions in mixed aqueous acid solutions using ozone |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3065155A (en) | 1960-09-02 | 1962-11-20 | Manganese Chemicals Corp | Electrolytic manganese dioxide process |
| AT310285B (en) | 1966-02-22 | 1973-09-25 | Photocircuits Corp | Process for the production of a laminated body for printed circuits |
| US4042729A (en) | 1972-12-13 | 1977-08-16 | Kollmorgen Technologies Corporation | Process for the activation of resinous bodies for adherent metallization |
| IT1159931B (en) * | 1978-10-13 | 1987-03-04 | Oronzio De Nora Impianti | INDUSTRIAL PROCEDURE FOR THE PRODUCTION OF TITANIUM DIOXIDE FROM ILMENITE |
| US4279705A (en) * | 1980-02-19 | 1981-07-21 | Kerr-Mcgee Corporation | Process for oxidizing a metal of variable valence by constant current electrolysis |
| IT1132194B (en) * | 1980-07-15 | 1986-06-25 | Anic Spa | ELECTROCHEMICAL PROCESS FOR THE SYNTHESIS OF ORGANIC COMPOUNDS |
| JPS58502027A (en) * | 1981-11-23 | 1983-11-24 | バロ−ス・コ−ポレ−ション | Peripherals adapted to monitor low data rate serial input/output interfaces |
| US4610895A (en) | 1984-02-01 | 1986-09-09 | Shipley Company Inc. | Process for metallizing plastics |
| US4948630A (en) | 1984-06-07 | 1990-08-14 | Enthone, Inc. | Three step process for treating plastics with alkaline permanganate solutions |
| JPS6447890A (en) * | 1987-08-13 | 1989-02-22 | Kenzo Yamaguchi | Electrolytic synthesis method |
| US5213665A (en) * | 1988-02-29 | 1993-05-25 | Nippon Shokubai Kagaku Kogyo, Co., Ltd. | Process for producing 1-aminoanthraquinones |
| US4936970A (en) * | 1988-11-14 | 1990-06-26 | Ebonex Technologies, Inc. | Redox reactions in an electrochemical cell including an electrode comprising Magneli phase titanium oxide |
| US5160600A (en) * | 1990-03-05 | 1992-11-03 | Patel Gordhanbai N | Chromic acid free etching of polymers for electroless plating |
| US5648125A (en) | 1995-11-16 | 1997-07-15 | Cane; Frank N. | Electroless plating process for the manufacture of printed circuit boards |
| GB9714275D0 (en) * | 1997-07-08 | 1997-09-10 | Ciba Geigy Ag | Oxidation process |
| JP2004511803A (en) | 2000-10-16 | 2004-04-15 | オーソ−マクニール・フアーマシユーチカル・インコーポレーテツド | Improved ligand binding assay for vanilloid receptor |
| CA2408951C (en) * | 2002-10-18 | 2008-12-16 | Kvaerner Canada Inc. | Mediated hydrohalic acid electrolysis |
| WO2007122869A1 (en) | 2006-04-18 | 2007-11-01 | Okuno Chemical Industries Co., Ltd. | Composition for etching treatment of resin molded article |
| US8734992B2 (en) * | 2007-02-14 | 2014-05-27 | Tosoh Corporation | Electrolytic manganese dioxide, and method for its production and its application |
| ES2334839T3 (en) * | 2007-08-10 | 2010-03-16 | Enthone Inc. | CHROME-FREE DECAPANT FOR PLASTIC SURFACES. |
| JP2010121143A (en) * | 2008-11-17 | 2010-06-03 | Okuno Chem Ind Co Ltd | Post-processing agent of etching for resin-formed body, post-processing method using the same, and plating method for resin-formed body |
| US8652685B2 (en) * | 2010-01-29 | 2014-02-18 | Eveready Battery Co., Inc. | Method of making an electrochemical cell with a catalytic electrode including manganese dioxide |
| US10260000B2 (en) * | 2012-01-23 | 2019-04-16 | Macdermid Acumen, Inc. | Etching of plastic using acidic solutions containing trivalent manganese |
-
2013
- 2013-09-26 TR TR2019/00116T patent/TR201900116T4/en unknown
- 2013-09-26 PL PL13854930T patent/PL2920341T3/en unknown
- 2013-09-26 BR BR112015011123-8A patent/BR112015011123B1/en active IP Right Grant
- 2013-09-26 CA CA3056665A patent/CA3056665A1/en not_active Abandoned
- 2013-09-26 WO PCT/US2013/061860 patent/WO2014077957A1/en active Application Filing
- 2013-09-26 JP JP2015543041A patent/JP6060270B2/en active Active
- 2013-09-26 KR KR1020157015762A patent/KR101950169B1/en active IP Right Grant
- 2013-09-26 EP EP13854930.8A patent/EP2920341B1/en active Active
- 2013-09-26 CN CN201380059513.3A patent/CN104838044B/en active Active
- 2013-09-26 MX MX2015006178A patent/MX2015006178A/en unknown
- 2013-09-26 ES ES13854930T patent/ES2704672T3/en active Active
- 2013-09-26 KR KR1020177008782A patent/KR20170039315A/en not_active Application Discontinuation
- 2013-09-26 CA CA2889342A patent/CA2889342C/en active Active
- 2013-11-11 TW TW102140858A patent/TWI500582B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| KR101950169B1 (en) | 2019-02-20 |
| PL2920341T3 (en) | 2019-05-31 |
| EP2920341A4 (en) | 2016-04-27 |
| CA2889342A1 (en) | 2014-05-22 |
| MX2015006178A (en) | 2015-11-06 |
| TWI500582B (en) | 2015-09-21 |
| CN104838044A (en) | 2015-08-12 |
| JP6060270B2 (en) | 2017-01-11 |
| CA2889342C (en) | 2019-11-12 |
| CN104838044B (en) | 2017-12-05 |
| BR112015011123A2 (en) | 2017-07-11 |
| WO2014077957A1 (en) | 2014-05-22 |
| ES2704672T3 (en) | 2019-03-19 |
| BR112015011123B1 (en) | 2021-08-03 |
| CA3056665A1 (en) | 2014-05-22 |
| KR20170039315A (en) | 2017-04-10 |
| JP2016504492A (en) | 2016-02-12 |
| EP2920341B1 (en) | 2018-11-14 |
| KR20150082636A (en) | 2015-07-15 |
| TW201431793A (en) | 2014-08-16 |
| EP2920341A1 (en) | 2015-09-23 |
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