MX2015006178A - Electrolytic generation of manganese (iii) ions in strong sulfuric acid. - Google Patents
Electrolytic generation of manganese (iii) ions in strong sulfuric acid.Info
- Publication number
- MX2015006178A MX2015006178A MX2015006178A MX2015006178A MX2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A
- Authority
- MX
- Mexico
- Prior art keywords
- manganese
- ions
- iii
- sulfuric acid
- electrolytic cell
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/22—Roughening, e.g. by etching
- C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/21—Manganese oxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Chemically Coating (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
An electrolytic cell and a method of electrochemical oxidation of manganese (II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises ( 1 ) an electrolyte solution of manganese(II) ions in a solution of 9 to 15 molar sulfuric acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, and woven carbon fibers.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/677,798 US9752241B2 (en) | 2012-01-23 | 2012-11-15 | Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode |
PCT/US2013/061860 WO2014077957A1 (en) | 2012-11-15 | 2013-09-26 | Electrolytic generation of manganese (iii) ions in strong sulfuric acid |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2015006178A true MX2015006178A (en) | 2015-11-06 |
Family
ID=50731593
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015006178A MX2015006178A (en) | 2012-11-15 | 2013-09-26 | Electrolytic generation of manganese (iii) ions in strong sulfuric acid. |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP2920341B1 (en) |
JP (1) | JP6060270B2 (en) |
KR (2) | KR101950169B1 (en) |
CN (1) | CN104838044B (en) |
BR (1) | BR112015011123B1 (en) |
CA (2) | CA3056665A1 (en) |
ES (1) | ES2704672T3 (en) |
MX (1) | MX2015006178A (en) |
PL (1) | PL2920341T3 (en) |
TR (1) | TR201900116T4 (en) |
TW (1) | TWI500582B (en) |
WO (1) | WO2014077957A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112015021067B1 (en) * | 2013-03-12 | 2021-06-08 | Macdermid Acumen, Inc | electrolytic cell and method of electrochemical oxidation of manganese ions (ii) to manganese ions (iii) |
WO2016006301A1 (en) | 2014-07-10 | 2016-01-14 | 奥野製薬工業株式会社 | Resin plating method |
US20170306511A1 (en) * | 2014-08-28 | 2017-10-26 | Inkron Ltd | Crystalline transition metal oxide particles and continuous method of producing the same |
US10889905B2 (en) * | 2018-12-11 | 2021-01-12 | Rohm And Haas Electronic Materials Llc | Methods of generating manganese (III) ions in mixed aqueous acid solutions using ozone |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3065155A (en) * | 1960-09-02 | 1962-11-20 | Manganese Chemicals Corp | Electrolytic manganese dioxide process |
AT310285B (en) | 1966-02-22 | 1973-09-25 | Photocircuits Corp | Process for the production of a laminated body for printed circuits |
US4042729A (en) | 1972-12-13 | 1977-08-16 | Kollmorgen Technologies Corporation | Process for the activation of resinous bodies for adherent metallization |
IT1159931B (en) * | 1978-10-13 | 1987-03-04 | Oronzio De Nora Impianti | INDUSTRIAL PROCEDURE FOR THE PRODUCTION OF TITANIUM DIOXIDE FROM ILMENITE |
US4279705A (en) * | 1980-02-19 | 1981-07-21 | Kerr-Mcgee Corporation | Process for oxidizing a metal of variable valence by constant current electrolysis |
IT1132194B (en) * | 1980-07-15 | 1986-06-25 | Anic Spa | ELECTROCHEMICAL PROCESS FOR THE SYNTHESIS OF ORGANIC COMPOUNDS |
JPS58502027A (en) * | 1981-11-23 | 1983-11-24 | バロ−ス・コ−ポレ−ション | Peripherals adapted to monitor low data rate serial input/output interfaces |
US4610895A (en) | 1984-02-01 | 1986-09-09 | Shipley Company Inc. | Process for metallizing plastics |
US4948630A (en) | 1984-06-07 | 1990-08-14 | Enthone, Inc. | Three step process for treating plastics with alkaline permanganate solutions |
JPS6447890A (en) * | 1987-08-13 | 1989-02-22 | Kenzo Yamaguchi | Electrolytic synthesis method |
US5213665A (en) * | 1988-02-29 | 1993-05-25 | Nippon Shokubai Kagaku Kogyo, Co., Ltd. | Process for producing 1-aminoanthraquinones |
US4936970A (en) * | 1988-11-14 | 1990-06-26 | Ebonex Technologies, Inc. | Redox reactions in an electrochemical cell including an electrode comprising Magneli phase titanium oxide |
US5160600A (en) * | 1990-03-05 | 1992-11-03 | Patel Gordhanbai N | Chromic acid free etching of polymers for electroless plating |
US5648125A (en) | 1995-11-16 | 1997-07-15 | Cane; Frank N. | Electroless plating process for the manufacture of printed circuit boards |
GB9714275D0 (en) * | 1997-07-08 | 1997-09-10 | Ciba Geigy Ag | Oxidation process |
AU2001297015A1 (en) | 2000-10-15 | 2002-04-29 | Ortho-Mcneil Pharmaceutical, Inc. | Improved ligand binding assays for vanilloid receptors |
CA2408951C (en) * | 2002-10-18 | 2008-12-16 | Kvaerner Canada Inc. | Mediated hydrohalic acid electrolysis |
JP5177426B2 (en) | 2006-04-18 | 2013-04-03 | 奥野製薬工業株式会社 | Composition for etching treatment for resin molding |
US8734992B2 (en) * | 2007-02-14 | 2014-05-27 | Tosoh Corporation | Electrolytic manganese dioxide, and method for its production and its application |
ES2334839T3 (en) * | 2007-08-10 | 2010-03-16 | Enthone Inc. | CHROME-FREE DECAPANT FOR PLASTIC SURFACES. |
JP2010121143A (en) * | 2008-11-17 | 2010-06-03 | Okuno Chem Ind Co Ltd | Post-processing agent of etching for resin-formed body, post-processing method using the same, and plating method for resin-formed body |
WO2011094295A1 (en) * | 2010-01-29 | 2011-08-04 | Eveready Battery Company, Inc. | Method of making an electrochemical cell with a catalytic electrode including manganese dioxide |
US10260000B2 (en) * | 2012-01-23 | 2019-04-16 | Macdermid Acumen, Inc. | Etching of plastic using acidic solutions containing trivalent manganese |
-
2013
- 2013-09-26 KR KR1020157015762A patent/KR101950169B1/en active IP Right Grant
- 2013-09-26 TR TR2019/00116T patent/TR201900116T4/en unknown
- 2013-09-26 EP EP13854930.8A patent/EP2920341B1/en active Active
- 2013-09-26 CA CA3056665A patent/CA3056665A1/en not_active Abandoned
- 2013-09-26 BR BR112015011123-8A patent/BR112015011123B1/en active IP Right Grant
- 2013-09-26 CA CA2889342A patent/CA2889342C/en active Active
- 2013-09-26 MX MX2015006178A patent/MX2015006178A/en unknown
- 2013-09-26 WO PCT/US2013/061860 patent/WO2014077957A1/en active Application Filing
- 2013-09-26 ES ES13854930T patent/ES2704672T3/en active Active
- 2013-09-26 JP JP2015543041A patent/JP6060270B2/en active Active
- 2013-09-26 CN CN201380059513.3A patent/CN104838044B/en active Active
- 2013-09-26 PL PL13854930T patent/PL2920341T3/en unknown
- 2013-09-26 KR KR1020177008782A patent/KR20170039315A/en not_active Application Discontinuation
- 2013-11-11 TW TW102140858A patent/TWI500582B/en active
Also Published As
Publication number | Publication date |
---|---|
KR101950169B1 (en) | 2019-02-20 |
EP2920341A1 (en) | 2015-09-23 |
BR112015011123B1 (en) | 2021-08-03 |
KR20170039315A (en) | 2017-04-10 |
BR112015011123A2 (en) | 2017-07-11 |
JP6060270B2 (en) | 2017-01-11 |
PL2920341T3 (en) | 2019-05-31 |
WO2014077957A1 (en) | 2014-05-22 |
TR201900116T4 (en) | 2019-01-21 |
JP2016504492A (en) | 2016-02-12 |
ES2704672T3 (en) | 2019-03-19 |
CA2889342A1 (en) | 2014-05-22 |
CA3056665A1 (en) | 2014-05-22 |
TW201431793A (en) | 2014-08-16 |
CN104838044A (en) | 2015-08-12 |
CN104838044B (en) | 2017-12-05 |
EP2920341B1 (en) | 2018-11-14 |
KR20150082636A (en) | 2015-07-15 |
CA2889342C (en) | 2019-11-12 |
TWI500582B (en) | 2015-09-21 |
EP2920341A4 (en) | 2016-04-27 |
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