MX2015006178A - Electrolytic generation of manganese (iii) ions in strong sulfuric acid. - Google Patents

Electrolytic generation of manganese (iii) ions in strong sulfuric acid.

Info

Publication number
MX2015006178A
MX2015006178A MX2015006178A MX2015006178A MX2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A MX 2015006178 A MX2015006178 A MX 2015006178A
Authority
MX
Mexico
Prior art keywords
manganese
ions
iii
sulfuric acid
electrolytic cell
Prior art date
Application number
MX2015006178A
Other languages
Spanish (es)
Inventor
Trevor Pearson
Terence Clarke
Roshan V Chapaneri
Original Assignee
Macdermid Acumen Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/677,798 external-priority patent/US9752241B2/en
Application filed by Macdermid Acumen Inc filed Critical Macdermid Acumen Inc
Publication of MX2015006178A publication Critical patent/MX2015006178A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/042—Electrodes formed of a single material
    • C25B11/043—Carbon, e.g. diamond or graphene
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22—Roughening, e.g. by etching
    • C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/21—Manganese oxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Chemically Coating (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

An electrolytic cell and a method of electrochemical oxidation of manganese (II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises ( 1 ) an electrolyte solution of manganese(II) ions in a solution of 9 to 15 molar sulfuric acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, and woven carbon fibers.
MX2015006178A 2012-11-15 2013-09-26 Electrolytic generation of manganese (iii) ions in strong sulfuric acid. MX2015006178A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/677,798 US9752241B2 (en) 2012-01-23 2012-11-15 Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode
PCT/US2013/061860 WO2014077957A1 (en) 2012-11-15 2013-09-26 Electrolytic generation of manganese (iii) ions in strong sulfuric acid

Publications (1)

Publication Number Publication Date
MX2015006178A true MX2015006178A (en) 2015-11-06

Family

ID=50731593

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015006178A MX2015006178A (en) 2012-11-15 2013-09-26 Electrolytic generation of manganese (iii) ions in strong sulfuric acid.

Country Status (12)

Country Link
EP (1) EP2920341B1 (en)
JP (1) JP6060270B2 (en)
KR (2) KR20170039315A (en)
CN (1) CN104838044B (en)
BR (1) BR112015011123B1 (en)
CA (2) CA3056665A1 (en)
ES (1) ES2704672T3 (en)
MX (1) MX2015006178A (en)
PL (1) PL2920341T3 (en)
TR (1) TR201900116T4 (en)
TW (1) TWI500582B (en)
WO (1) WO2014077957A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK2971260T3 (en) * 2013-03-12 2019-09-23 Macdermid Acumen Inc ELECTROLYTIC GENERATION OF MANGANE (III) IONS IN HIGH SULFURIC ACID
ES2828459T5 (en) 2014-07-10 2024-04-30 Okuno Chem Ind Co Resin galvanization method
EP3186410A1 (en) * 2014-08-28 2017-07-05 Inkron Ltd. Crystalline transition metal oxide particles and continuous method of producing the same
US10889905B2 (en) * 2018-12-11 2021-01-12 Rohm And Haas Electronic Materials Llc Methods of generating manganese (III) ions in mixed aqueous acid solutions using ozone

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3065155A (en) * 1960-09-02 1962-11-20 Manganese Chemicals Corp Electrolytic manganese dioxide process
AT310285B (en) 1966-02-22 1973-09-25 Photocircuits Corp Process for the production of a laminated body for printed circuits
US4042729A (en) 1972-12-13 1977-08-16 Kollmorgen Technologies Corporation Process for the activation of resinous bodies for adherent metallization
IT1159931B (en) * 1978-10-13 1987-03-04 Oronzio De Nora Impianti INDUSTRIAL PROCEDURE FOR THE PRODUCTION OF TITANIUM DIOXIDE FROM ILMENITE
US4279705A (en) * 1980-02-19 1981-07-21 Kerr-Mcgee Corporation Process for oxidizing a metal of variable valence by constant current electrolysis
IT1132194B (en) * 1980-07-15 1986-06-25 Anic Spa ELECTROCHEMICAL PROCESS FOR THE SYNTHESIS OF ORGANIC COMPOUNDS
JPS58502027A (en) * 1981-11-23 1983-11-24 バロ−ス・コ−ポレ−ション Peripherals adapted to monitor low data rate serial input/output interfaces
US4610895A (en) 1984-02-01 1986-09-09 Shipley Company Inc. Process for metallizing plastics
US4948630A (en) 1984-06-07 1990-08-14 Enthone, Inc. Three step process for treating plastics with alkaline permanganate solutions
JPS6447890A (en) * 1987-08-13 1989-02-22 Kenzo Yamaguchi Electrolytic synthesis method
US5213665A (en) * 1988-02-29 1993-05-25 Nippon Shokubai Kagaku Kogyo, Co., Ltd. Process for producing 1-aminoanthraquinones
US4936970A (en) * 1988-11-14 1990-06-26 Ebonex Technologies, Inc. Redox reactions in an electrochemical cell including an electrode comprising Magneli phase titanium oxide
US5160600A (en) * 1990-03-05 1992-11-03 Patel Gordhanbai N Chromic acid free etching of polymers for electroless plating
US5648125A (en) 1995-11-16 1997-07-15 Cane; Frank N. Electroless plating process for the manufacture of printed circuit boards
GB9714275D0 (en) * 1997-07-08 1997-09-10 Ciba Geigy Ag Oxidation process
JP2004511803A (en) 2000-10-16 2004-04-15 オーソ−マクニール・フアーマシユーチカル・インコーポレーテツド Improved ligand binding assay for vanilloid receptor
CA2408951C (en) * 2002-10-18 2008-12-16 Kvaerner Canada Inc. Mediated hydrohalic acid electrolysis
US8394289B2 (en) 2006-04-18 2013-03-12 Okuno Chemicals Industries Co., Ltd. Composition for etching treatment of resin molded article
US8734992B2 (en) * 2007-02-14 2014-05-27 Tosoh Corporation Electrolytic manganese dioxide, and method for its production and its application
PL2025708T3 (en) * 2007-08-10 2010-03-31 Enthone Chromium-free etchant for plastic surfaces
JP2010121143A (en) * 2008-11-17 2010-06-03 Okuno Chem Ind Co Ltd Post-processing agent of etching for resin-formed body, post-processing method using the same, and plating method for resin-formed body
WO2011094295A1 (en) * 2010-01-29 2011-08-04 Eveready Battery Company, Inc. Method of making an electrochemical cell with a catalytic electrode including manganese dioxide
US10260000B2 (en) * 2012-01-23 2019-04-16 Macdermid Acumen, Inc. Etching of plastic using acidic solutions containing trivalent manganese

Also Published As

Publication number Publication date
TR201900116T4 (en) 2019-01-21
JP2016504492A (en) 2016-02-12
CA2889342A1 (en) 2014-05-22
BR112015011123A2 (en) 2017-07-11
CA3056665A1 (en) 2014-05-22
ES2704672T3 (en) 2019-03-19
TWI500582B (en) 2015-09-21
BR112015011123B1 (en) 2021-08-03
KR20170039315A (en) 2017-04-10
CA2889342C (en) 2019-11-12
EP2920341A4 (en) 2016-04-27
CN104838044B (en) 2017-12-05
KR20150082636A (en) 2015-07-15
JP6060270B2 (en) 2017-01-11
KR101950169B1 (en) 2019-02-20
PL2920341T3 (en) 2019-05-31
EP2920341B1 (en) 2018-11-14
CN104838044A (en) 2015-08-12
EP2920341A1 (en) 2015-09-23
WO2014077957A1 (en) 2014-05-22
TW201431793A (en) 2014-08-16

Similar Documents

Publication Publication Date Title
SG10201901001YA (en) A battery system
MX2015012584A (en) Electrolytic generation of manganese (iii) ions in strong sulfuric acid.
WO2012122353A3 (en) Metal free aqueous electrolyte energy storage device
WO2012061429A3 (en) Batteries for efficient energy extraction from a salinity difference
WO2012167057A3 (en) Iron based flow batteries
PL404171A1 (en) Apparatus for use in electrolytic refining and in the electrolytic production of metals
EA201890645A1 (en) SYSTEM AND METHOD OF MANUFACTURE OF GAS-HYDROGEN AND GAS-OXYGEN
WO2011107794A3 (en) Fuel cells
IN2015DN04003A (en)
WO2010088524A3 (en) Conversion of carbon dioxide to organic products
MX2014004820A (en) Polyurethane based electrolyte systems for electrochemical cells.
WO2014014548A3 (en) Metal-air flow batteries using oxygen enriched electrolyte
FR2969179B1 (en) HYDROGEN PRODUCTION CELL COMPRISING A HIGH TEMPERATURE WATER VAPOR ELECTROLYSER CELL
WO2012048280A3 (en) Electrochemical systems and methods for operating electrochemical cell with an acidic anolyte
EA201101104A1 (en) ELECTROLYTE FOR BATTERY
MX2014009506A (en) System for power control in cells for electrolytic recovery of a metal.
MY173524A (en) Electro-deposited copper foil, method of manufacturing electro-deposited copper foil, and surface-treated copper foil manufactured by using electro-deposited copper foil
MX2015006178A (en) Electrolytic generation of manganese (iii) ions in strong sulfuric acid.
DK201370805A (en) Aluminum smelter including cells with cathode output at the bottom of the pot shell and cell stabilizing means
EA201590039A1 (en) ELECTROLYTIC CELL SUPPLIED BY CONCENTRIC ELECTRODE PAIRS
WO2013166505A3 (en) LITHIUM TRITIDE (LiT) ELECTROLYSIS CELL FOR REMOVING TRITIUM FROM LITHIUM METAL
KR101514881B1 (en) Method of manufacturing electrolyte for Vanadium secondary battery and apparatus thereof
WO2014177870A3 (en) Redox fuel cells with regeneration of catholyte
SA517382132B1 (en) Enhanced Electrochemical Oxidation of Carbonaceous Deposits in Liquid-Hydrocarbon Fueled Solid Oxide Fuel Cells
SA518400041B1 (en) In-Situ Gravitational Separation of Electrolyte Solutions in Flow Redox Battery Systems