BR112015011123A2 - electrolytic production of manganese ions in strong sulfuric acid - Google Patents
electrolytic production of manganese ions in strong sulfuric acidInfo
- Publication number
- BR112015011123A2 BR112015011123A2 BR112015011123A BR112015011123A BR112015011123A2 BR 112015011123 A2 BR112015011123 A2 BR 112015011123A2 BR 112015011123 A BR112015011123 A BR 112015011123A BR 112015011123 A BR112015011123 A BR 112015011123A BR 112015011123 A2 BR112015011123 A2 BR 112015011123A2
- Authority
- BR
- Brazil
- Prior art keywords
- sulfuric acid
- manganese
- ions
- electrolytic production
- strong sulfuric
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/22—Roughening, e.g. by etching
- C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/21—Manganese oxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
Abstract
resumo produção eletrolítica de íons manganês (iii) em ácido sulfúrico forte a presente invenção descreve uma célula eletrolítica e um método de oxidação eletroquímica de íons manganês (ii) para íons manganês (iii) nesta célula. a célula eletrolítica compreende (1) uma solução de eletrólitos de íons manganês (ii) em uma solução de ácido sulfúrico 9 a 15 molar; (2) um catodo imerso na solução de eletrólitos; e (3) um anodo imerso na solução de eletrólitos e separado do catodo. vários materiais do anodo são descritos incluindo carbono vítreo, carbono vítreo reticulado e tecido de fibras de carbono.abstract electrolytic production of manganese (iii) ions in strong sulfuric acid the present invention describes an electrolytic cell and a method of electrochemical oxidation of manganese (ii) ions to manganese (iii) ions in this cell. the electrolytic cell comprises (1) a solution of manganese ion electrolytes (ii) in a 9 to 15 molar sulfuric acid solution; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and separated from the cathode. various anode materials are described including glassy carbon, crosslinked glassy carbon and carbon fiber fabric.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/677,798 US9752241B2 (en) | 2012-01-23 | 2012-11-15 | Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode |
US13/677,798 | 2012-11-15 | ||
PCT/US2013/061860 WO2014077957A1 (en) | 2012-11-15 | 2013-09-26 | Electrolytic generation of manganese (iii) ions in strong sulfuric acid |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112015011123A2 true BR112015011123A2 (en) | 2017-07-11 |
BR112015011123B1 BR112015011123B1 (en) | 2021-08-03 |
Family
ID=50731593
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015011123-8A BR112015011123B1 (en) | 2012-11-15 | 2013-09-26 | METHOD OF ELECTROCHEMICAL OXIDATION FROM MANGANESE IONS (II) TO MANGANESE IONS (III) |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP2920341B1 (en) |
JP (1) | JP6060270B2 (en) |
KR (2) | KR20170039315A (en) |
CN (1) | CN104838044B (en) |
BR (1) | BR112015011123B1 (en) |
CA (2) | CA2889342C (en) |
ES (1) | ES2704672T3 (en) |
MX (1) | MX2015006178A (en) |
PL (1) | PL2920341T3 (en) |
TR (1) | TR201900116T4 (en) |
TW (1) | TWI500582B (en) |
WO (1) | WO2014077957A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2971260T3 (en) * | 2013-03-12 | 2020-03-31 | Macdermid Acumen, Inc. | Electrolytic generation of manganese (iii) ions in strong sulfuric acid |
PL3168326T5 (en) | 2014-07-10 | 2024-02-05 | Okuno Chemical Industries Co., Ltd. | Resin plating method |
US20170306511A1 (en) * | 2014-08-28 | 2017-10-26 | Inkron Ltd | Crystalline transition metal oxide particles and continuous method of producing the same |
US10889905B2 (en) * | 2018-12-11 | 2021-01-12 | Rohm And Haas Electronic Materials Llc | Methods of generating manganese (III) ions in mixed aqueous acid solutions using ozone |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3065155A (en) * | 1960-09-02 | 1962-11-20 | Manganese Chemicals Corp | Electrolytic manganese dioxide process |
AT310285B (en) | 1966-02-22 | 1973-09-25 | Photocircuits Corp | Process for the production of a laminated body for printed circuits |
US4042729A (en) | 1972-12-13 | 1977-08-16 | Kollmorgen Technologies Corporation | Process for the activation of resinous bodies for adherent metallization |
IT1159931B (en) * | 1978-10-13 | 1987-03-04 | Oronzio De Nora Impianti | INDUSTRIAL PROCEDURE FOR THE PRODUCTION OF TITANIUM DIOXIDE FROM ILMENITE |
US4279705A (en) * | 1980-02-19 | 1981-07-21 | Kerr-Mcgee Corporation | Process for oxidizing a metal of variable valence by constant current electrolysis |
IT1132194B (en) * | 1980-07-15 | 1986-06-25 | Anic Spa | ELECTROCHEMICAL PROCESS FOR THE SYNTHESIS OF ORGANIC COMPOUNDS |
JPS58502027A (en) * | 1981-11-23 | 1983-11-24 | バロ−ス・コ−ポレ−ション | Peripherals adapted to monitor low data rate serial input/output interfaces |
US4610895A (en) | 1984-02-01 | 1986-09-09 | Shipley Company Inc. | Process for metallizing plastics |
US4948630A (en) | 1984-06-07 | 1990-08-14 | Enthone, Inc. | Three step process for treating plastics with alkaline permanganate solutions |
JPS6447890A (en) * | 1987-08-13 | 1989-02-22 | Kenzo Yamaguchi | Electrolytic synthesis method |
US5213665A (en) * | 1988-02-29 | 1993-05-25 | Nippon Shokubai Kagaku Kogyo, Co., Ltd. | Process for producing 1-aminoanthraquinones |
US4936970A (en) * | 1988-11-14 | 1990-06-26 | Ebonex Technologies, Inc. | Redox reactions in an electrochemical cell including an electrode comprising Magneli phase titanium oxide |
US5160600A (en) * | 1990-03-05 | 1992-11-03 | Patel Gordhanbai N | Chromic acid free etching of polymers for electroless plating |
US5648125A (en) | 1995-11-16 | 1997-07-15 | Cane; Frank N. | Electroless plating process for the manufacture of printed circuit boards |
GB9714275D0 (en) * | 1997-07-08 | 1997-09-10 | Ciba Geigy Ag | Oxidation process |
CA2425961A1 (en) | 2000-10-16 | 2002-04-25 | Ortho-Mcneil Pharmaceutical, Inc. | Improved ligand binding assays for vanilloid receptors |
CA2408951C (en) * | 2002-10-18 | 2008-12-16 | Kvaerner Canada Inc. | Mediated hydrohalic acid electrolysis |
JP5177426B2 (en) | 2006-04-18 | 2013-04-03 | 奥野製薬工業株式会社 | Composition for etching treatment for resin molding |
US8734992B2 (en) * | 2007-02-14 | 2014-05-27 | Tosoh Corporation | Electrolytic manganese dioxide, and method for its production and its application |
ES2334839T3 (en) | 2007-08-10 | 2010-03-16 | Enthone Inc. | CHROME-FREE DECAPANT FOR PLASTIC SURFACES. |
JP2010121143A (en) * | 2008-11-17 | 2010-06-03 | Okuno Chem Ind Co Ltd | Post-processing agent of etching for resin-formed body, post-processing method using the same, and plating method for resin-formed body |
WO2011094295A1 (en) * | 2010-01-29 | 2011-08-04 | Eveready Battery Company, Inc. | Method of making an electrochemical cell with a catalytic electrode including manganese dioxide |
US10260000B2 (en) * | 2012-01-23 | 2019-04-16 | Macdermid Acumen, Inc. | Etching of plastic using acidic solutions containing trivalent manganese |
-
2013
- 2013-09-26 KR KR1020177008782A patent/KR20170039315A/en not_active Application Discontinuation
- 2013-09-26 TR TR2019/00116T patent/TR201900116T4/en unknown
- 2013-09-26 BR BR112015011123-8A patent/BR112015011123B1/en active IP Right Grant
- 2013-09-26 ES ES13854930T patent/ES2704672T3/en active Active
- 2013-09-26 WO PCT/US2013/061860 patent/WO2014077957A1/en active Application Filing
- 2013-09-26 MX MX2015006178A patent/MX2015006178A/en unknown
- 2013-09-26 KR KR1020157015762A patent/KR101950169B1/en active IP Right Grant
- 2013-09-26 EP EP13854930.8A patent/EP2920341B1/en active Active
- 2013-09-26 CA CA2889342A patent/CA2889342C/en active Active
- 2013-09-26 CA CA3056665A patent/CA3056665A1/en not_active Abandoned
- 2013-09-26 CN CN201380059513.3A patent/CN104838044B/en active Active
- 2013-09-26 PL PL13854930T patent/PL2920341T3/en unknown
- 2013-09-26 JP JP2015543041A patent/JP6060270B2/en active Active
- 2013-11-11 TW TW102140858A patent/TWI500582B/en active
Also Published As
Publication number | Publication date |
---|---|
WO2014077957A1 (en) | 2014-05-22 |
CA2889342A1 (en) | 2014-05-22 |
KR20170039315A (en) | 2017-04-10 |
JP2016504492A (en) | 2016-02-12 |
CN104838044A (en) | 2015-08-12 |
PL2920341T3 (en) | 2019-05-31 |
EP2920341A4 (en) | 2016-04-27 |
EP2920341B1 (en) | 2018-11-14 |
KR20150082636A (en) | 2015-07-15 |
ES2704672T3 (en) | 2019-03-19 |
EP2920341A1 (en) | 2015-09-23 |
BR112015011123B1 (en) | 2021-08-03 |
JP6060270B2 (en) | 2017-01-11 |
TR201900116T4 (en) | 2019-01-21 |
MX2015006178A (en) | 2015-11-06 |
TWI500582B (en) | 2015-09-21 |
KR101950169B1 (en) | 2019-02-20 |
CN104838044B (en) | 2017-12-05 |
CA2889342C (en) | 2019-11-12 |
TW201431793A (en) | 2014-08-16 |
CA3056665A1 (en) | 2014-05-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06I | Publication of requirement cancelled [chapter 6.9 patent gazette] |
Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |
|
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 26/09/2013, OBSERVADAS AS CONDICOES LEGAIS. |