SU95132A1 - The method of obtaining ammonium sulphate ammonium micronutrient - Google Patents

The method of obtaining ammonium sulphate ammonium micronutrient

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Publication number
SU95132A1
SU95132A1 SU446359A SU445359A SU95132A1 SU 95132 A1 SU95132 A1 SU 95132A1 SU 446359 A SU446359 A SU 446359A SU 445359 A SU445359 A SU 445359A SU 95132 A1 SU95132 A1 SU 95132A1
Authority
SU
USSR - Soviet Union
Prior art keywords
ammonium
sulphate
micronutrient
manganese
obtaining
Prior art date
Application number
SU446359A
Other languages
Russian (ru)
Inventor
Х.Н. Агаев
Г.М. Безменов
К.С. Мамедов
Original Assignee
Х.Н. Агаев
Г.М. Безменов
К.С. Мамедов
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Х.Н. Агаев, Г.М. Безменов, К.С. Мамедов filed Critical Х.Н. Агаев
Priority to SU446359A priority Critical patent/SU95132A1/en
Application granted granted Critical
Publication of SU95132A1 publication Critical patent/SU95132A1/en

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Description

В процессе производства активного пиролюзита образуютс  отходы в виде кислых растворов сернокислого марганца.During the production of active pyrolusite, waste is generated in the form of acidic solutions of manganese sulphate.

В 1 л этих растворов содержитс  от 10 до 50 г серной кислоты (счита  на моногидрат) и от 250 до 300 г сернокислого марганца.1 l of these solutions contains from 10 to 50 g of sulfuric acid (counting on monohydrate) and from 250 to 300 g of manganese sulphate.

Но так как в растворах содержатс  ен1е и примеси в виде сернокислых солей железа, кальци , кобальта , никел  и др. элементов, выделение из этих растворов чистого сернокислого марганца представл ет значительные трудности.But since enle and impurities in the form of sulfate salts of iron, calcium, cobalt, nickel, and other elements are contained in the solutions, the isolation of pure manganese sulfate from these solutions presents considerable difficulties.

Описываемый способ позвол ет использовать сточные воды от производства активного пиролюзита дл  получени  сульфатного аммонийно-марганцевого микроудобрсни  и отличаетс  тем, что кислые растворы сернокислого марганца подвергают нейтрализации аммиаком с образованием смеси солей сульфатов марганца и аммони .The described method allows the use of wastewater from the production of active pyrolusite to produce ammonium manganese sulfate microfluidic fertilizers and is characterized in that acidic solutions of manganese sulphate are neutralized with ammonia to form a mixture of salts of manganese sulphate and ammonium.

Дл  осуществлени  описываемого способа сточные водЕзг от производства активного пиролюзита в виде кислых растворов сернокислого марганца заливают в мешалку, где при комнатной температуре нейтрализуют водным раствором аммиака при непрерывном перемешивании .To implement the described method, wastewater from the production of active pyrolusite in the form of acidic solutions of manganese sulphate is poured into a mixer, where it is neutralized at room temperature with an aqueous solution of ammonia with continuous stirring.

В результате получают нейтральный раствор, содержащий сульфат марганца, сульфат аммони , гидрат окиси аммони  (в виде взвеси) и небольшое количество солей кальци , железа, кобальта и других.The result is a neutral solution containing manganese sulfate, ammonium sulfate, ammonium hydroxide (as a suspension) and a small amount of calcium, iron, cobalt, and others.

Нейтральный раствор уцаривают и затем прогревают до полного удалени  гигроскопической и гидратной влаги, после чего сухую массу подвергают помолу на шаровой мельнице.The neutral solution is concentrated and then heated until complete removal of hygroscopic and hydrated moisture, after which the dry mass is subjected to grinding in a ball mill.

Получепный продукт содержит 10 - 15% сульфата аммони , 80-85% сульфата марганца, до 4% гидрата окиси марганца, до 1% сульфатов кальци , железа, кобальта и др. и используетс  как микроудобрецие в тех случа х, когда сельскохоз йственные культуры нуждаютс  в марганце.The final product contains 10-15% ammonium sulphate, 80-85% manganese sulphate, up to 4% manganese oxide hydrate, up to 1% calcium sulphate, iron, cobalt, etc., and is used as a microfertilizer in those cases when crops are in need. in manganese.

Предмет изобретени Subject invention

Способ получени  сульфатного аммонийно-марганцевого микроудобрени , отличающийс  тем, что, с целью введени  в удобрение соединений марганца, сточные воды от производства активного пиролюзита в виде кислых растворов сернокислого марганца подвергают нейтрализации аммиаком с образованием смеси солей сульфатов мар1анца и аммони .The method of producing ammonium manganese sulfate microfertilizer, characterized in that, with the aim of introducing manganese compounds into fertilizer, wastewater from the production of active pyrolusite in the form of acidic solutions of manganese sulphate is subjected to neutralization with ammonia to form a mixture of salts of marlite and ammonium sulphates.

SU446359A 1951-07-30 1951-07-30 The method of obtaining ammonium sulphate ammonium micronutrient SU95132A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU446359A SU95132A1 (en) 1951-07-30 1951-07-30 The method of obtaining ammonium sulphate ammonium micronutrient

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU446359A SU95132A1 (en) 1951-07-30 1951-07-30 The method of obtaining ammonium sulphate ammonium micronutrient

Publications (1)

Publication Number Publication Date
SU95132A1 true SU95132A1 (en) 1952-11-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU446359A SU95132A1 (en) 1951-07-30 1951-07-30 The method of obtaining ammonium sulphate ammonium micronutrient

Country Status (1)

Country Link
SU (1) SU95132A1 (en)

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