SU68330A1 - The method of obtaining alpha-oxyanthraquinone - Google Patents
The method of obtaining alpha-oxyanthraquinoneInfo
- Publication number
- SU68330A1 SU68330A1 SU87146A SU87146A SU68330A1 SU 68330 A1 SU68330 A1 SU 68330A1 SU 87146 A SU87146 A SU 87146A SU 87146 A SU87146 A SU 87146A SU 68330 A1 SU68330 A1 SU 68330A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- oxyanthraquinone
- obtaining alpha
- alpha
- obtaining
- autoclave
- Prior art date
Links
- 239000002253 acid Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 241000193738 Bacillus anthracis Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000015450 Tilia cordata Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000002378 acidificating Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 230000001131 transforming Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
-Окскантрахлнон, примен емый дл синтеза прочных красителей антрах нонового р да, получаетс об.но зЕменоЯ сульфогртпп на isurpoKсйл щелочным ИЛИ известковым плавом солеЗ сС - суль 4окислоты азтрахкно а в автоклаве при высокой температтрв. -Oxcantraxlone, used to synthesize durable anthrax dyes, is obtained by refining sulfogram on isurpoxyl by alkaline OR lime saltyc anthraxide in an autoclave at high temperatures.
Однако помимо продолжительного времени, трсбугмого дл rajroro превращенг (15-30 час), выделение оч -окснантрастнона св зано, во-первых, с об зательным нагревом или разваркой реакционноЯ кассы и ее нейтрализвцией минералъноЯ кислотой , во-вторюс, с ее переосавдением или перекристаллизацией .However, in addition to a long period of time, for rajroro transformation (15-30 hours), the release of och-oxnantrastnon is associated, firstly, with the necessary heating or boiling-up of the reactionary cash and its neutralization with mineral acid, secondly, with its re-recovery or recrystallization .
Предлагаемый способ отличаетс , тем, что cd--оксиантрахинон может бнть получен автоклавным гидролизом о -сульфокислоты а трахинона или ее солей в воде или слабой минеральной кислоте при высокой температуре. Таким образом, в отличие от кислого гидролиза сульфокнслот различных ароматических производных, приводдго.эго обычно к замене сульфогруппы на водород с образованием несульфгрова ных исходных соединений (например углеводородов ), в 8ТОЖ случае ггдроллз в кислой среде ведет к образованип оксиспедй ек«1Я .The proposed method is different in that cd-hydroxyanthraquinone can be obtained by autoclave hydrolysis of o-sulfonic acid a of traquinone or its salts in water or a weak mineral acid at high temperature. Thus, in contrast to the acid hydrolysis of sulfoxlslot of various aromatic derivatives, the drive usually replaces the sulfo group with hydrogen to form non-sulphate starting compounds (for example, hydrocarbons), in the case of SHOUT in the acidic medium, hydroxypedylation of the “1H.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU68330A1 true SU68330A1 (en) | 1947-04-30 |
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