SU677028A1 - Oxydation inhibitor for negative electrode of lead storage battery - Google Patents

Oxydation inhibitor for negative electrode of lead storage battery

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Publication number
SU677028A1
SU677028A1 SU772555911D SU2555911D SU677028A1 SU 677028 A1 SU677028 A1 SU 677028A1 SU 772555911 D SU772555911 D SU 772555911D SU 2555911 D SU2555911 D SU 2555911D SU 677028 A1 SU677028 A1 SU 677028A1
Authority
SU
USSR - Soviet Union
Prior art keywords
inhibitor
negative electrode
oxydation
storage battery
lead storage
Prior art date
Application number
SU772555911D
Other languages
Russian (ru)
Inventor
Евгений Иванович Остапенко
Галина Израйлевна Эйдман
Original Assignee
Ленинградский Аккумуляторный Завод Производственного Объединения "Источник"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ленинградский Аккумуляторный Завод Производственного Объединения "Источник" filed Critical Ленинградский Аккумуляторный Завод Производственного Объединения "Источник"
Application granted granted Critical
Publication of SU677028A1 publication Critical patent/SU677028A1/en

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Battery Electrode And Active Subsutance (AREA)

Description

1one

Изобретение относитс  к электротехнической нромышленности и может быть использовано дл  производства сухозар женных электродов свинцовых аккумул торов.The invention relates to the electrical industry and can be used for the production of dry-charged lead-acid electrodes.

Известен ингибитор окислени  дл  отрицательного электрода свинцового аккумул тора - литейный крепитель, представл ющий собой концентрат сульфитно-спиртовой бражки 1.A known oxidation inhibitor for the negative electrode of a lead battery is a foundry binder, which is a concentrate of sulphite-alcohol brew 1.

Дл  получени  необходимого процента окисленности обработки электрода этим ингибитором необходимо производить при высокой температуре, использу  раствор высокой концентрации. В этих )слови х ингибитор приобретает смолообразную консистенцию , что затрудн ет обработку.To obtain the required percentage of oxidation of the electrode treatment with this inhibitor, it is necessary to perform at high temperature using a solution of high concentration. In these terms, the inhibitor acquires a resinous consistency, which makes processing difficult.

Наиболее близким по технической сущности и достигаемым результатам  вл етс  ингибитор окислени  дл  отрицательного электрода свинцового аккумул тора, содержащий неорганическую составл ющую - борную кислоту, органическую составл ющую и воду 2. В качестве органической составл ющей беретс  1-2-оксинафтойна  кислота. Такой ингибитор обеспечиваетбкйелейность пор дка ., .;.;., ,.The closest in technical essence and achievable results is an oxidation inhibitor for the negative electrode of a lead battery, containing an inorganic component — boric acid, an organic component, and water 2. The organic component is 1-2 oxy-naphthoic acid. Such an inhibitor provides a keenness of the order.,.;.;.,.,.

С целью снижени  окисленности, ттредлагаетс  в качестве органической составл ющей вз ть литейный крепитель, представл ющий собой концентрат сульфитно-спиртовой бражки, при следующем соотношении компонентов (в мас.%):In order to reduce oxidation, it is proposed that the foundry binder, which is a sulphite-alcohol concentrate, be taken as an organic component in the following ratio of components (wt.%):

Борна  кислота1- 8Borna acid1-8

Литейный крепитель0,5-18Foundry keeper 0,5-18

ВодаОстальноеWaterEverything

Литейный крепитель состоит из солей лигносульфоновой кислоты, редуцирующих и минеральных веществ. При взаимодейстВИИ его с борной кислотой образуетс  р д бороорганических соединений, обладающих восстановительными свойствами. После обработки электрода таким ингибитором его поверхность защищена от воздействи  кислорода воздуха во врем  сушки слоем восстановительной среды ингибитора, а образовавша с  из него на кристаллах свинца в результате окислени  и испарени  влаги в процессе сушки плотна  пленка, состо ща  из сухого лигнина, боратов свинца и свинецорганических соединений, защищает губчатый свинец отрицательного электрода от воздействи  атмосферного кислорода и влаги в процессе последующегоThe foundry keeper consists of salts of lignosulfonic acid, reducing and mineral substances. During its interaction with boric acid, a series of organoboron compounds with reducing properties is formed. After the treatment of the electrode with such an inhibitor, its surface is protected from exposure to oxygen by air during drying with a layer of reducing medium of the inhibitor, and the dense film formed from it on lead crystals as a result of oxidation and evaporation of moisture during the drying process consists of dry lignin, lead borates and organic compounds, protects the spongy lead of the negative electrode from exposure to atmospheric oxygen and moisture during the subsequent

хранени  электродов, причем эта пленкаstoring electrodes, and this film

дегко разрушаетс  при взаимодействии с серной кислотой в процессе приведени  аккумул тор1а в рабочее состо ние, не затрудн   доступ электролита в поры активнойIt is easily destroyed by interaction with sulfuric acid in the process of bringing the battery 1 to the working state, it is not difficult for the electrolyte to enter the pores of the active

массы. masses.

Пример. ГЗерут ингибитор, состо шли из 4% борной кислоты, 7% литейного крепител  и 89% воды. Этот ингибитор обеспечивает 5% окислеииости, т. е. вдвое меньше , чем ингибитор-прототип.Example. The Zerut inhibitor consisted of 4% boric acid, 7% foundry keeper, and 89% water. This inhibitor provides 5% oxidation, that is, half as much as the inhibitor prototype.

Claims (2)

1.Авторское свидетельство 1. Author's certificate СССР № 152009, кл. Н 01М 4/23, 1961.USSR № 152009, cl. H 01 M 4/23, 1961. 2.Авторское свидетельство СССР № 337858, кл. Н 01М 4/62, 1970.2. USSR author's certificate number 337858, cl. H 01M 4/62, 1970.
SU772555911D 1977-12-19 1977-12-19 Oxydation inhibitor for negative electrode of lead storage battery SU677028A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU772555911A SU677027A1 (en) 1977-12-19 1977-12-19 Method of conservation of lead storage battery negative electrode

Publications (1)

Publication Number Publication Date
SU677028A1 true SU677028A1 (en) 1979-07-30

Family

ID=20738402

Family Applications (2)

Application Number Title Priority Date Filing Date
SU772555911A SU677027A1 (en) 1977-12-19 1977-12-19 Method of conservation of lead storage battery negative electrode
SU772555911D SU677028A1 (en) 1977-12-19 1977-12-19 Oxydation inhibitor for negative electrode of lead storage battery

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SU772555911A SU677027A1 (en) 1977-12-19 1977-12-19 Method of conservation of lead storage battery negative electrode

Country Status (1)

Country Link
SU (2) SU677027A1 (en)

Also Published As

Publication number Publication date
SU677027A1 (en) 1979-07-30

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