SU509206A3 - Катализатор дл окислени этиленав окись этилена - Google Patents
Катализатор дл окислени этиленав окись этиленаInfo
- Publication number
- SU509206A3 SU509206A3 SU1958292A SU1958292A SU509206A3 SU 509206 A3 SU509206 A3 SU 509206A3 SU 1958292 A SU1958292 A SU 1958292A SU 1958292 A SU1958292 A SU 1958292A SU 509206 A3 SU509206 A3 SU 509206A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- silver
- ethylene
- catalysts
- potassium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 87
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 18
- 239000005977 Ethylene Substances 0.000 title claims description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title claims description 18
- 238000007254 oxidation reaction Methods 0.000 title claims description 11
- 230000003647 oxidation Effects 0.000 title claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 31
- 239000004332 silver Substances 0.000 claims description 31
- 229910052700 potassium Inorganic materials 0.000 claims description 22
- 239000011591 potassium Substances 0.000 claims description 22
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 21
- 229910052783 alkali metal Inorganic materials 0.000 claims description 17
- 150000001340 alkali metals Chemical class 0.000 claims description 16
- 229910052792 caesium Inorganic materials 0.000 claims description 8
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 8
- 229910052701 rubidium Inorganic materials 0.000 claims description 8
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 30
- 238000000034 method Methods 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000002245 particle Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000000969 carrier Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 150000003378 silver Chemical class 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 241000212342 Sium Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- RTHYXYOJKHGZJT-UHFFFAOYSA-N rubidium nitrate Inorganic materials [Rb+].[O-][N+]([O-])=O RTHYXYOJKHGZJT-UHFFFAOYSA-N 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- KHAUBYTYGDOYRU-IRXASZMISA-N trospectomycin Chemical compound CN[C@H]([C@H]1O2)[C@@H](O)[C@@H](NC)[C@H](O)[C@H]1O[C@H]1[C@]2(O)C(=O)C[C@@H](CCCC)O1 KHAUBYTYGDOYRU-IRXASZMISA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21618872A | 1972-01-07 | 1972-01-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU509206A3 true SU509206A3 (ru) | 1976-03-30 |
Family
ID=22806078
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1958292A SU509206A3 (ru) | 1972-01-07 | 1973-01-05 | Катализатор дл окислени этиленав окись этилена |
| SU731882101A SU482935A3 (ru) | 1972-01-07 | 1973-01-05 | Способ получени катализатора дл окислени этилена |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU731882101A SU482935A3 (ru) | 1972-01-07 | 1973-01-05 | Способ получени катализатора дл окислени этилена |
Country Status (16)
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4207210A (en) | 1973-10-26 | 1980-06-10 | Shell Oil Company | Process for preparing an ethylene oxide catalyst |
| GB1489335A (en) * | 1973-10-26 | 1977-10-19 | Shell Int Research | Catalyst for the production of ethylene oxide |
| CA1026763A (en) * | 1974-05-20 | 1978-02-21 | Robert P. Nielsen | Silver catalysts used in ethylene oxide production |
| GB1569974A (en) * | 1976-03-05 | 1980-06-25 | Ici Ltd | Restoration of selectivity to catalysts used in the production of olefine oxides |
| DE2704197A1 (de) * | 1977-02-02 | 1978-08-31 | Basf Ag | Katalysator zur herstellung von aethylenoxid |
| US4168247A (en) * | 1976-05-28 | 1979-09-18 | Imperial Chemical Industries Limited | Catalysts for the production of alkylene oxides |
| US4206128A (en) | 1976-06-16 | 1980-06-03 | Texaco Development Corporation | Ethylene oxide production |
| US4066575A (en) * | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
| US4097414A (en) * | 1976-08-30 | 1978-06-27 | Texaco Development Corp. | Modified ethylene oxide catalyst and a process for its preparation |
| GB1594362A (en) * | 1977-05-23 | 1981-07-30 | Ici Ltd | Production of alkylene oxides and catalysts therefor |
| US4224194A (en) * | 1979-02-26 | 1980-09-23 | Texaco Development Corp. | Process for preparing an ethylene oxide catalyst |
| US4229321A (en) * | 1979-02-26 | 1980-10-21 | Texaco Development Corp. | Process for making a silver catalyst |
| US4419276A (en) | 1981-09-30 | 1983-12-06 | Union Carbide Corporation | Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst |
| US4455392A (en) * | 1981-10-05 | 1984-06-19 | Union Carbide Corporation | Process for preparing a supported silver catalyst |
| US4760042A (en) * | 1982-03-24 | 1988-07-26 | Scientific Design Company, Inc. | Process for preparing an alkali metal-promoted silver catalyst |
| JPS6110570A (ja) * | 1984-06-25 | 1986-01-18 | Mitsui Toatsu Chem Inc | エチレンオキシドの製造方法 |
| DE3582097D1 (de) * | 1984-08-21 | 1991-04-18 | Mitsubishi Petrochemical Co | Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung. |
| GB8613818D0 (en) * | 1986-06-06 | 1986-07-09 | Ici Plc | Catalysts |
| GB8610441D0 (en) * | 1986-04-29 | 1986-06-04 | Shell Int Research | Preparation of silver-containing catalyst |
| GB2190855A (en) * | 1986-05-28 | 1987-12-02 | Shell Int Research | Process for the preparation of a silver-containing catalyst |
| DE3643248A1 (de) * | 1986-12-18 | 1988-06-30 | Basf Ag | Silberkatalysator, seine herstellung und verwendung |
| GB8716653D0 (en) * | 1987-07-15 | 1987-08-19 | Shell Int Research | Silver-containing catalyst |
| DE3905578A1 (de) * | 1989-02-23 | 1990-08-30 | Basf Ag | Verfahren zur herstellung eines silberkatalysators |
| US5407888A (en) * | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| US5705661A (en) * | 1995-09-25 | 1998-01-06 | Mitsubishi Chemical Corporation | Catalyst for production of ethylene oxide |
| DE19803890A1 (de) * | 1998-01-31 | 1999-08-05 | Erdoelchemie Gmbh | Silberhaltige Trägerkatalysatoren und Katalysator-Zwischenprodukte, Verfahren zu ihrer Herstellung und ihre Verwendung |
| RU2177829C1 (ru) * | 2001-04-17 | 2002-01-10 | Общество с ограниченной ответственностью "Научно-производственное предприятие "Оксит" | Способ приготовления катализатора для получения окиси этилена |
| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US8357812B2 (en) | 2005-12-22 | 2013-01-22 | Shell Oil Company | Process for preparing a rejuvenated epoxidation catalyst |
| US7704908B2 (en) | 2005-12-22 | 2010-04-27 | Shell Oil Company | Method for reusing rhenium from a donor spent epoxidation catalyst |
| DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
| DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
| ES2391809T3 (es) | 2008-10-08 | 2012-11-30 | Basf Se | Método para producir óxidos de alquileno |
| EP2440538B1 (de) | 2009-06-09 | 2014-07-16 | Basf Se | Verwendung strukturierter katalysatorbetten zur herstellung von ethylenoxid |
| US8921587B2 (en) | 2011-04-14 | 2014-12-30 | Basf Se | Process for producing a catalyst for the oxidation of ethylene to ethylene oxide |
| US8629079B2 (en) | 2011-04-14 | 2014-01-14 | Basf Se | Process for producing a catalyst for the oxidation of ethylene to ethylene oxide |
| US8987482B2 (en) | 2011-10-28 | 2015-03-24 | Basf Se | Process for producing a supported silver catalyst |
| JP2015518421A (ja) | 2012-05-04 | 2015-07-02 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | アルケンのエポキシ化のための触媒 |
| US9079154B2 (en) | 2012-05-04 | 2015-07-14 | Basf Se | Catalyst for the epoxidation of alkenes |
| US9714227B2 (en) | 2013-12-09 | 2017-07-25 | Basf Se | Catalyst for the epoxidation of alkenes |
| US11400437B2 (en) | 2016-08-08 | 2022-08-02 | Basf Se | Catalyst for the oxidation of ethylene to ethylene oxide |
| WO2019020793A1 (en) | 2017-07-28 | 2019-01-31 | Basf Se | PROCESS FOR PRODUCING A MOLDED CATALYST BODY COMPRISING SILVER APPLIED TO AN ALUMINUM CARRIER |
| TWI808125B (zh) | 2018-02-07 | 2023-07-11 | 德商巴斯夫歐洲公司 | 有效地將乙烯氧化轉化為環氧乙烷之催化劑 |
| EP3639923A1 (en) | 2018-10-15 | 2020-04-22 | Basf Se | Process for producing ethylene oxide by gas-phase oxidation of ethylene |
| EP3639924A1 (en) | 2018-10-15 | 2020-04-22 | Basf Se | Catalyst for producing ethylene oxide by gas-phase oxidation |
| EP3659703A1 (en) | 2018-11-28 | 2020-06-03 | Basf Se | Catalyst for producing ethylene oxide by gas-phase oxidation |
| WO2021038027A1 (en) | 2019-08-28 | 2021-03-04 | Basf Se | Process for preparing an epoxidation catalyst |
| EP3885038A1 (en) | 2020-03-27 | 2021-09-29 | Basf Se | Process for producing an epoxidation catalyst |
| WO2021191414A1 (en) | 2020-03-27 | 2021-09-30 | Basf Se | Process for producing a silver-based epoxidation catalyst |
| US20230256420A1 (en) | 2020-06-26 | 2023-08-17 | Basf Se | Shaped catalyst body for the production of ethylene oxide |
| US20230256415A1 (en) | 2020-06-26 | 2023-08-17 | Basf Se | Production of porous alpha-alumina supports from boehmitic derived aluminas |
| WO2021259427A1 (de) | 2020-06-26 | 2021-12-30 | Basf Se | Poröser katalysatorträger-formkörper |
| CN116723893A (zh) | 2021-01-26 | 2023-09-08 | 巴斯夫欧洲公司 | 环氧化催化剂 |
| EP4601789A1 (en) | 2022-10-12 | 2025-08-20 | Basf Se | Epoxidation catalyst |
| EP4608789A1 (en) | 2022-10-28 | 2025-09-03 | Basf Se | <sup2/>? <sub2/>?4?process for the manufacture of a c-olefin-derived chemical of interest, in particular citral, from renewably-sourced ethanol |
| WO2024133081A1 (en) | 2022-12-20 | 2024-06-27 | Basf Se | Manufacture of an ethylene-derived chemical of interest, in particular acrylic acid, in combination with generation of heated steam |
| WO2025078359A1 (en) | 2023-10-09 | 2025-04-17 | Basf Se | Manufacture of ethylene-derived chemicals having a bio-based carbon content from bio-naphtha |
| WO2025078353A1 (en) | 2023-10-09 | 2025-04-17 | Basf Se | Manufacture of ethylene-derived chemicals having a bio-based carbon content from pyrolysis oil |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3125538A (en) * | 1964-03-17 | Thallium |
-
1973
- 1973-01-04 BE BE793658D patent/BE793658A/xx not_active IP Right Cessation
- 1973-01-05 SE SE7300157A patent/SE392044B/xx unknown
- 1973-01-05 CS CS776151A patent/CS191250B2/cs unknown
- 1973-01-05 NL NLAANVRAGE7300162,A patent/NL177662C/xx not_active IP Right Cessation
- 1973-01-05 ES ES410401A patent/ES410401A1/es not_active Expired
- 1973-01-05 RO RO73406A patent/RO61470A7/ro unknown
- 1973-01-05 DE DE2300512A patent/DE2300512C2/de not_active Expired
- 1973-01-05 CA CA160,696A patent/CA1026357A/en not_active Expired
- 1973-01-05 IT IT19060/73A patent/IT978032B/it active
- 1973-01-05 FR FR7300329A patent/FR2167728B1/fr not_active Expired
- 1973-01-05 CS CS73124A patent/CS191210B2/cs unknown
- 1973-01-05 SU SU1958292A patent/SU509206A3/ru active
- 1973-01-05 JP JP48000097A patent/JPS5748554B2/ja not_active Expired
- 1973-01-05 GB GB68973A patent/GB1413251A/en not_active Expired
- 1973-01-05 PL PL1973160171A patent/PL89083B1/pl unknown
- 1973-01-05 CS CS776150A patent/CS191249B2/cs unknown
- 1973-01-05 AU AU50809/73A patent/AU472997B2/en not_active Expired
- 1973-01-05 SU SU731882101A patent/SU482935A3/ru active
- 1973-01-08 DD DD168136A patent/DD104206A5/xx unknown
- 1973-01-08 DD DD178738*A patent/DD112438A5/xx unknown
-
1975
- 1975-05-27 ES ES437964A patent/ES437964A1/es not_active Expired
- 1975-09-04 SE SE7509856A patent/SE423543B/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL177662C (nl) | 1988-08-16 |
| AU472997B2 (en) | 1976-06-10 |
| BE793658A (fr) | 1973-07-04 |
| DD104206A5 (enrdf_load_stackoverflow) | 1974-03-05 |
| SE423543B (sv) | 1982-05-10 |
| CS191249B2 (en) | 1979-06-29 |
| ES437964A1 (es) | 1977-04-01 |
| DE2300512C2 (de) | 1986-01-30 |
| DD112438A5 (enrdf_load_stackoverflow) | 1975-04-12 |
| SE7509856L (sv) | 1975-09-04 |
| CS191250B2 (en) | 1979-06-29 |
| RO61470A7 (enrdf_load_stackoverflow) | 1977-02-15 |
| CA1026357A (en) | 1978-02-14 |
| FR2167728B1 (enrdf_load_stackoverflow) | 1976-06-18 |
| ES410401A1 (es) | 1976-04-01 |
| NL7300162A (enrdf_load_stackoverflow) | 1973-07-10 |
| FR2167728A1 (enrdf_load_stackoverflow) | 1973-08-24 |
| JPS4930286A (enrdf_load_stackoverflow) | 1974-03-18 |
| PL89083B1 (en) | 1976-10-30 |
| DE2300512A1 (de) | 1973-07-26 |
| JPS5748554B2 (enrdf_load_stackoverflow) | 1982-10-16 |
| GB1413251A (en) | 1975-11-12 |
| NL177662B (nl) | 1985-06-03 |
| SE392044B (sv) | 1977-03-14 |
| SU482935A3 (ru) | 1975-08-30 |
| IT978032B (it) | 1974-09-20 |
| AU5080973A (en) | 1974-07-11 |
| CS191210B2 (en) | 1979-06-29 |
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