EP2844646A4 - Katalysator zur epoxidation von alkenen - Google Patents

Katalysator zur epoxidation von alkenen

Info

Publication number
EP2844646A4
EP2844646A4 EP13784593.9A EP13784593A EP2844646A4 EP 2844646 A4 EP2844646 A4 EP 2844646A4 EP 13784593 A EP13784593 A EP 13784593A EP 2844646 A4 EP2844646 A4 EP 2844646A4
Authority
EP
European Patent Office
Prior art keywords
epoxidation
alkenes
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13784593.9A
Other languages
English (en)
French (fr)
Other versions
EP2844646A1 (de
Inventor
Tobias Rosendahl
Torsten Maeurer
Dirk Hensel
Andreas Lehr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP13784593.9A priority Critical patent/EP2844646A4/de
Publication of EP2844646A1 publication Critical patent/EP2844646A1/de
Publication of EP2844646A4 publication Critical patent/EP2844646A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP13784593.9A 2012-05-04 2013-04-22 Katalysator zur epoxidation von alkenen Withdrawn EP2844646A4 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP13784593.9A EP2844646A4 (de) 2012-05-04 2013-04-22 Katalysator zur epoxidation von alkenen

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12166830 2012-05-04
EP13784593.9A EP2844646A4 (de) 2012-05-04 2013-04-22 Katalysator zur epoxidation von alkenen
PCT/IB2013/053169 WO2013164727A1 (de) 2012-05-04 2013-04-22 Katalysator zur epoxidation von alkenen

Publications (2)

Publication Number Publication Date
EP2844646A1 EP2844646A1 (de) 2015-03-11
EP2844646A4 true EP2844646A4 (de) 2016-03-23

Family

ID=49514256

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13784593.9A Withdrawn EP2844646A4 (de) 2012-05-04 2013-04-22 Katalysator zur epoxidation von alkenen

Country Status (6)

Country Link
EP (1) EP2844646A4 (de)
JP (1) JP2015518421A (de)
KR (1) KR20150013704A (de)
CN (1) CN104321315A (de)
BR (1) BR112014026976A2 (de)
WO (1) WO2013164727A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106492798B (zh) * 2016-11-02 2018-12-11 漯河职业技术学院 直接环氧化生产环氧丙烷的催化剂及其制备方法
CN116196922B (zh) * 2021-12-01 2024-08-23 中国石油化工股份有限公司 一种银催化剂及其制备方法与应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248740A (en) * 1977-07-01 1981-02-03 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for preparing silver-supported catalyst for the production of ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5112795A (en) * 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US20080177106A1 (en) * 2007-01-19 2008-07-24 Manhua Lin Selective oxidation of alkanes and/or alkenes to valuable oxygenates
US20110034710A1 (en) * 2007-05-09 2011-02-10 Marek Matusz Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL261755A (de) * 1960-04-01 1900-01-01
BE793658A (fr) 1972-01-07 1973-07-04 Shell Int Research Catalyseur utilisable pour la production d'oxyde d'ethylene
DE2454972A1 (de) 1973-12-05 1975-06-12 Ici Ltd Katalysator und verfahren zur herstellung von alkylenoxiden
CA1026763A (en) 1974-05-20 1978-02-21 Robert P. Nielsen Silver catalysts used in ethylene oxide production
DE2454927A1 (de) 1974-11-20 1976-05-26 Draloric Electronic Verfahren und vorrichtung zum herstellen eines kunststofformkoerpers
DE2753359A1 (de) 1977-11-30 1979-06-07 Basf Ag Katalysator zur herstellung von aethylenoxid
JPS5844021B2 (ja) 1978-11-01 1983-09-30 東レ株式会社 酸化エチレン製造用触媒組成物
DE2904919A1 (de) 1979-02-09 1980-08-21 Basf Ag Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid
JPS57107240A (en) 1980-12-26 1982-07-03 Nippon Shokubai Kagaku Kogyo Co Ltd Production of silver catalyst for producing ethylene oxide
EP0082609B1 (de) 1981-12-14 1987-01-14 Imperial Chemical Industries Plc Chemischer Reaktor und Verfahren
DE3272383D1 (en) 1981-12-30 1986-09-04 Ici Plc Catalysts for the production of alkylene oxides
US4774222A (en) 1982-06-16 1988-09-27 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide and process for preparing the catalyst
DE3414717A1 (de) 1984-04-18 1985-10-31 Linde Ag, 6200 Wiesbaden Verfahren und reaktor zur durchfuehrung exothermer katalytischer reaktionen
EP0172565B1 (de) 1984-08-21 1991-03-13 Mitsubishi Petrochemical Co., Ltd. Silberkatalysator für die Herstellung von Ethylenoxid aus Ethylen und Verfahren zu dessen Herstellung
AU586048B2 (en) 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
IN169589B (de) 1986-10-31 1991-11-16 Shell Int Research
GB8810006D0 (en) 1988-04-27 1988-06-02 Shell Int Research Process for preparation of ethylene oxide
DE68925767T2 (de) 1988-08-30 1996-08-14 Union Carbide Corp Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung
DE3905578A1 (de) 1989-02-23 1990-08-30 Basf Ag Verfahren zur herstellung eines silberkatalysators
CA2053411C (en) 1990-10-12 1997-06-03 Albert Cheng-Yu Liu Alkylene oxide catalysts having enhanced activity and/or stability
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
CN1089039C (zh) * 1998-09-28 2002-08-14 中国石油化工集团公司 一种大孔氧化铝载体及其制备方法
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
TWI334363B (en) 2005-06-07 2010-12-11 Saint Gobain Ceramics A catalyst carrier
US20090270640A1 (en) 2006-04-21 2009-10-29 Basf Aktiengesellschaft Method for production of ethylene oxide in a microchannel reactor
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
CN102099346A (zh) * 2008-07-14 2011-06-15 巴斯夫欧洲公司 制备环氧乙烷的方法
WO2010040688A1 (de) * 2008-10-08 2010-04-15 Basf Se Verfahren zur herstellung eines alkylenoxids
SG10201401617WA (en) 2009-04-21 2014-06-27 Dow Technology Investments Llc Epoxidation Reactions And Operating Conditions Thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248740A (en) * 1977-07-01 1981-02-03 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for preparing silver-supported catalyst for the production of ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5112795A (en) * 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US20080177106A1 (en) * 2007-01-19 2008-07-24 Manhua Lin Selective oxidation of alkanes and/or alkenes to valuable oxygenates
US20110034710A1 (en) * 2007-05-09 2011-02-10 Marek Matusz Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2013164727A1 *

Also Published As

Publication number Publication date
BR112014026976A2 (pt) 2017-06-27
CN104321315A (zh) 2015-01-28
EP2844646A1 (de) 2015-03-11
KR20150013704A (ko) 2015-02-05
JP2015518421A (ja) 2015-07-02
WO2013164727A1 (de) 2013-11-07

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