EP2844646A4 - Catalyst for epoxidation of alkenes - Google Patents

Catalyst for epoxidation of alkenes

Info

Publication number
EP2844646A4
EP2844646A4 EP13784593.9A EP13784593A EP2844646A4 EP 2844646 A4 EP2844646 A4 EP 2844646A4 EP 13784593 A EP13784593 A EP 13784593A EP 2844646 A4 EP2844646 A4 EP 2844646A4
Authority
EP
European Patent Office
Prior art keywords
epoxidation
alkenes
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13784593.9A
Other languages
German (de)
French (fr)
Other versions
EP2844646A1 (en
Inventor
Tobias Rosendahl
Torsten Maeurer
Dirk Hensel
Andreas Lehr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP13784593.9A priority Critical patent/EP2844646A4/en
Publication of EP2844646A1 publication Critical patent/EP2844646A1/en
Publication of EP2844646A4 publication Critical patent/EP2844646A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
EP13784593.9A 2012-05-04 2013-04-22 Catalyst for epoxidation of alkenes Withdrawn EP2844646A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP13784593.9A EP2844646A4 (en) 2012-05-04 2013-04-22 Catalyst for epoxidation of alkenes

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12166830 2012-05-04
PCT/IB2013/053169 WO2013164727A1 (en) 2012-05-04 2013-04-22 Catalyst for epoxidation of alkenes
EP13784593.9A EP2844646A4 (en) 2012-05-04 2013-04-22 Catalyst for epoxidation of alkenes

Publications (2)

Publication Number Publication Date
EP2844646A1 EP2844646A1 (en) 2015-03-11
EP2844646A4 true EP2844646A4 (en) 2016-03-23

Family

ID=49514256

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13784593.9A Withdrawn EP2844646A4 (en) 2012-05-04 2013-04-22 Catalyst for epoxidation of alkenes

Country Status (6)

Country Link
EP (1) EP2844646A4 (en)
JP (1) JP2015518421A (en)
KR (1) KR20150013704A (en)
CN (1) CN104321315A (en)
BR (1) BR112014026976A2 (en)
WO (1) WO2013164727A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106492798B (en) * 2016-11-02 2018-12-11 漯河职业技术学院 The catalyst and preparation method thereof of Direct Epoxidation production propylene oxide

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248740A (en) * 1977-07-01 1981-02-03 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for preparing silver-supported catalyst for the production of ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5112795A (en) * 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US20080177106A1 (en) * 2007-01-19 2008-07-24 Manhua Lin Selective oxidation of alkanes and/or alkenes to valuable oxygenates
US20110034710A1 (en) * 2007-05-09 2011-02-10 Marek Matusz Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL261755A (en) * 1960-04-01 1900-01-01
BE793658A (en) 1972-01-07 1973-07-04 Shell Int Research CATALYST USED FOR THE PRODUCTION OF ETHYLENE OXIDE
DE2454972A1 (en) 1973-12-05 1975-06-12 Ici Ltd Silver olefin oxidation catalysts - supported on specified carriers and promoted esp. with barium
CA1026763A (en) 1974-05-20 1978-02-21 Robert P. Nielsen Silver catalysts used in ethylene oxide production
DE2454927A1 (en) 1974-11-20 1976-05-26 Draloric Electronic Apts. for moulding plastic material - having two component female die, male die, filling boring and calibration boring
DE2753359A1 (en) 1977-11-30 1979-06-07 Basf Ag Catalyst for ethylene oxide prodn. - comprises silver, lithium and heavy alkali metal on a carrier
JPS5844021B2 (en) 1978-11-01 1983-09-30 東レ株式会社 Catalyst composition for producing ethylene oxide
DE2904919A1 (en) 1979-02-09 1980-08-21 Basf Ag METHOD FOR THE PRODUCTION AND REGENERATION OF CARRIER CATALYSTS AND THE USE THEREOF FOR THE PRODUCTION OF AETHYLENE OXIDE
JPS57107240A (en) 1980-12-26 1982-07-03 Nippon Shokubai Kagaku Kogyo Co Ltd Production of silver catalyst for producing ethylene oxide
EP0082609B1 (en) 1981-12-14 1987-01-14 Imperial Chemical Industries Plc Chemical reactor and process
EP0085237B1 (en) 1981-12-30 1986-07-30 Imperial Chemical Industries Plc Catalysts for the production of alkylene oxides
US4774222A (en) 1982-06-16 1988-09-27 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide and process for preparing the catalyst
DE3414717A1 (en) 1984-04-18 1985-10-31 Linde Ag, 6200 Wiesbaden METHOD AND REACTOR FOR CARRYING OUT EXOTHERMAL CATALYTIC REACTIONS
DE3582097D1 (en) 1984-08-21 1991-04-18 Mitsubishi Petrochemical Co SILVER CATALYST FOR THE PRODUCTION OF ETHYLENE OXIDE FROM ETHYLENE AND METHOD FOR THE PRODUCTION THEREOF.
AU586048B2 (en) 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
IN169589B (en) 1986-10-31 1991-11-16 Shell Int Research
GB8810006D0 (en) 1988-04-27 1988-06-02 Shell Int Research Process for preparation of ethylene oxide
EP0357293B1 (en) 1988-08-30 1996-02-28 Union Carbide Corporation Catalysts for the production of ethylene oxide and their preparation processes
DE3905578A1 (en) 1989-02-23 1990-08-30 Basf Ag METHOD FOR PRODUCING A SILVER CATALYST
JP2720124B2 (en) 1990-10-12 1998-02-25 ユニオン・カーバイド、ケミカルズ、アンド、プラスチックス、テクノロジー、コーポレーション Alkylene oxide catalysts with enhanced activity and / or stability
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
CN1089039C (en) * 1998-09-28 2002-08-14 中国石油化工集团公司 Macroporous alumina carrier and preparing process thereof
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
KR101072239B1 (en) 2005-06-07 2011-10-12 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 A catalyst carrier
WO2007122090A2 (en) 2006-04-21 2007-11-01 Basf Se Method for production of ethylene oxide in a microchannel reactor
US7932408B2 (en) 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
CN102099346A (en) * 2008-07-14 2011-06-15 巴斯夫欧洲公司 Process for making ethylene oxide
BRPI0920425A2 (en) * 2008-10-08 2015-08-04 Basf Se Continuous process for producing an alkylene oxide.
EP2421842B1 (en) 2009-04-21 2018-05-30 Dow Technology Investments LLC Epoxidation reactions and operating conditions thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248740A (en) * 1977-07-01 1981-02-03 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for preparing silver-supported catalyst for the production of ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5112795A (en) * 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US20080177106A1 (en) * 2007-01-19 2008-07-24 Manhua Lin Selective oxidation of alkanes and/or alkenes to valuable oxygenates
US20110034710A1 (en) * 2007-05-09 2011-02-10 Marek Matusz Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2013164727A1 *

Also Published As

Publication number Publication date
EP2844646A1 (en) 2015-03-11
JP2015518421A (en) 2015-07-02
KR20150013704A (en) 2015-02-05
BR112014026976A2 (en) 2017-06-27
WO2013164727A1 (en) 2013-11-07
CN104321315A (en) 2015-01-28

Similar Documents

Publication Publication Date Title
GB2525486B (en) Treating of catalyst support
ZA201406073B (en) Tetramerisation of ethylene
SG11201503088QA (en) Process for oligomerization of ethylene
PT2817448T (en) Regeneration of cellulose
ZA201404265B (en) Preparation of an olefin oligomerization catalyst
HK1209767A1 (en) Purification of iduronate-2-sulfatase -2-
HK1209029A1 (en) Zirconium silicate for treatment of hyperkalemia
EP2877280A4 (en) Catalyst materials
ZA201406074B (en) Tetramerisation of ethylene
HUE051648T2 (en) Use of ccr3-inhibitors
EP3079810A4 (en) Catalyst for the epoxidation of alkenes
EP2848623A4 (en) Catalyst for synthesizing polyolefins
GB2518525B (en) Treating of catalyst support
ZA201503155B (en) Post-treatment of deboronated mww zeolite
ZA201409034B (en) Catalysts
EP2898984A4 (en) Interface system of industrial machine
EP2800747A4 (en) Polymorphs of perampanel
HK1212945A1 (en) Carbendazim-based catalytic materials
EP2877459A4 (en) Epoxidation process
IL219244A0 (en) Splitting of user-lists
HK1200106A1 (en) Formulations for enhanced bioavailability of zanamivir
HK1197062A1 (en) Chromene compound
EP3089816A4 (en) Zinc-promoted catalysts for epoxidation of ethylene
EP2892529A4 (en) Uses of (-)-perhexiline
ZA201501030B (en) Catalyst preparation process

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20141204

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
RA4 Supplementary search report drawn up and despatched (corrected)

Effective date: 20160224

RIC1 Information provided on ipc code assigned before grant

Ipc: B01J 23/50 20060101ALI20160218BHEP

Ipc: B01J 23/68 20060101ALI20160218BHEP

Ipc: C07D 301/10 20060101AFI20160218BHEP

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20171103