SU429580A3 - Способ полученияn-гетероциклических сложных эфиров перфторалкилмонокарбоновой кислоты - Google Patents
Способ полученияn-гетероциклических сложных эфиров перфторалкилмонокарбоновой кислотыInfo
- Publication number
- SU429580A3 SU429580A3 SU1602263A SU1602263A SU429580A3 SU 429580 A3 SU429580 A3 SU 429580A3 SU 1602263 A SU1602263 A SU 1602263A SU 1602263 A SU1602263 A SU 1602263A SU 429580 A3 SU429580 A3 SU 429580A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- mol
- reaction
- residue
- temperature
- product
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 title 1
- 150000002170 ethers Chemical class 0.000 title 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 25
- 150000001875 compounds Chemical class 0.000 description 24
- 239000000047 product Substances 0.000 description 24
- 238000004949 mass spectrometry Methods 0.000 description 22
- 150000002118 epoxides Chemical class 0.000 description 20
- 239000011541 reaction mixture Substances 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 13
- 235000019439 ethyl acetate Nutrition 0.000 description 13
- 229940040526 anhydrous sodium acetate Drugs 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- -1 perfluoroalkyl monocarboxylic acids Chemical class 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 238000001704 evaporation Methods 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 8
- DVMSVWIURPPRBC-UHFFFAOYSA-N 2,3,3-trifluoroprop-2-enoic acid Chemical compound OC(=O)C(F)=C(F)F DVMSVWIURPPRBC-UHFFFAOYSA-N 0.000 description 7
- IIVDXLKRPCUTBL-UHFFFAOYSA-N 2-[4-(oxiran-2-yl)but-2-enyl]oxirane urea Chemical compound NC(=O)N.C(C1CO1)C=CCC1CO1 IIVDXLKRPCUTBL-UHFFFAOYSA-N 0.000 description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 description 7
- 235000011152 sodium sulphate Nutrition 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 6
- 125000003700 epoxy group Chemical group 0.000 description 6
- 230000003993 interaction Effects 0.000 description 6
- 238000004817 gas chromatography Methods 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 125000002993 cycloalkylene group Chemical group 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- YIROYDNZEPTFOL-UHFFFAOYSA-N 5,5-Dimethylhydantoin Chemical compound CC1(C)NC(=O)NC1=O YIROYDNZEPTFOL-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- JKVBWACRUUUEAR-UHFFFAOYSA-N (4-chlorophenyl)sulfanyl-(2,4,5-trichlorophenyl)diazene Chemical compound C1=CC(Cl)=CC=C1SN=NC1=CC(Cl)=C(Cl)C=C1Cl JKVBWACRUUUEAR-UHFFFAOYSA-N 0.000 description 1
- MMTOSBCMFDNOIY-UHFFFAOYSA-N 2-(chloromethyl)-3-methyloxirane Chemical compound CC1OC1CCl MMTOSBCMFDNOIY-UHFFFAOYSA-N 0.000 description 1
- 241000234282 Allium Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- IKZLRVWAFCZXHQ-UHFFFAOYSA-N C(C1CO1)OCC1CO1.CC1(C(NC(N1)=O)=O)C Chemical compound C(C1CO1)OCC1CO1.CC1(C(NC(N1)=O)=O)C IKZLRVWAFCZXHQ-UHFFFAOYSA-N 0.000 description 1
- QXKAIJAYHKCRRA-JJYYJPOSSA-N D-arabinonic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C(O)=O QXKAIJAYHKCRRA-JJYYJPOSSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical class OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011346 highly viscous material Substances 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Plural Heterocyclic Compounds (AREA)
- Epoxy Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1840069 | 1969-12-10 | ||
| CH182770A CH553874A (enExample) | 1969-12-10 | 1970-02-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU429580A3 true SU429580A3 (ru) | 1974-05-25 |
Family
ID=25688777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1602263A SU429580A3 (ru) | 1969-12-10 | 1970-12-10 | Способ полученияn-гетероциклических сложных эфиров перфторалкилмонокарбоновой кислоты |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5114515B1 (enExample) |
| ES (1) | ES386282A1 (enExample) |
| SU (1) | SU429580A3 (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5668904B2 (ja) * | 2008-09-18 | 2015-02-12 | Jsr株式会社 | 液晶配向剤および液晶表示素子 |
-
1970
- 1970-12-09 ES ES386282A patent/ES386282A1/es not_active Expired
- 1970-12-10 JP JP10902570A patent/JPS5114515B1/ja active Pending
- 1970-12-10 SU SU1602263A patent/SU429580A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| ES386282A1 (es) | 1973-03-16 |
| JPS5114515B1 (enExample) | 1976-05-10 |
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