SU333830A1 - - Google Patents

Info

Publication number

SU333830A1

SU333830A1 SU1627877A SU1627877A SU333830A1 SU 333830 A1 SU333830 A1 SU 333830A1 SU 1627877 A SU1627877 A SU 1627877A SU 1627877 A SU1627877 A SU 1627877A SU 333830 A1 SU333830 A1 SU 333830A1

Authority

SU

USSR - Soviet Union

Prior art keywords

yield

water

alcohol

catalyst

amount

Prior art date

1971-03-05

Links

• Espacenet
• Global Dossier
• Discuss

• 238000000034 method Methods 0.000 description 17
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
• GNTDGMZSJNCJKK-UHFFFAOYSA-N Vanadium(V) oxide Inorganic materials O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 8
• 239000003054 catalyst Substances 0.000 description 7
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
• 239000011593 sulfur Substances 0.000 description 6
• MPPPKRYCTPRNTB-UHFFFAOYSA-N 1-bromobutane Chemical compound CCCCBr MPPPKRYCTPRNTB-UHFFFAOYSA-N 0.000 description 5
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
• 229910052717 sulfur Inorganic materials 0.000 description 5
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
• MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
• 150000001347 alkyl bromides Chemical class 0.000 description 3
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
• 229910052794 bromium Inorganic materials 0.000 description 3
• 230000003247 decreasing effect Effects 0.000 description 3
• CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
• 150000001298 alcohols Chemical class 0.000 description 2
• 238000004821 distillation Methods 0.000 description 2
• 239000000203 mixture Substances 0.000 description 2
• 238000002360 preparation method Methods 0.000 description 2
• 239000011541 reaction mixture Substances 0.000 description 2
• MYMSJFSOOQERIO-UHFFFAOYSA-N 1-bromodecane Chemical compound CCCCCCCCCCBr MYMSJFSOOQERIO-UHFFFAOYSA-N 0.000 description 1
• CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
• 150000001262 acyl bromides Chemical class 0.000 description 1
• -1 alcohol alkyl bromides Chemical class 0.000 description 1
• 125000000217 alkyl group Chemical group 0.000 description 1
• 238000006243 chemical reaction Methods 0.000 description 1
• 239000003153 chemical reaction reagent Substances 0.000 description 1
• 238000004587 chromatography analysis Methods 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 230000002950 deficient Effects 0.000 description 1
• TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
• 238000000605 extraction Methods 0.000 description 1
• 150000002191 fatty alcohols Chemical class 0.000 description 1
• 238000000746 purification Methods 0.000 description 1
• 238000010992 reflux Methods 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 238000003786 synthesis reaction Methods 0.000 description 1
• 229910052720 vanadium Inorganic materials 0.000 description 1
• LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1