SU213781A1 - - Google Patents

Info

Publication number

SU213781A1

SU213781A1 SU1138421A SU1138421A SU213781A1 SU 213781 A1 SU213781 A1 SU 213781A1 SU 1138421 A SU1138421 A SU 1138421A SU 1138421 A SU1138421 A SU 1138421A SU 213781 A1 SU213781 A1 SU 213781A1

Authority

SU

USSR - Soviet Union

Prior art keywords

iodine

fluorene

acetic acid

room temperature

diiodofluorene

Prior art date

Links

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• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
• NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 11
• 238000000034 method Methods 0.000 description 9
• 229910052740 iodine Inorganic materials 0.000 description 7
• 239000011630 iodine Substances 0.000 description 7
• 229960000583 acetic acid Drugs 0.000 description 6
• 238000006243 chemical reaction Methods 0.000 description 5
• ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
• YCWGCTPMBCOCLT-UHFFFAOYSA-N 2,7-diiodo-9h-fluorene Chemical compound IC1=CC=C2C3=CC=C(I)C=C3CC2=C1 YCWGCTPMBCOCLT-UHFFFAOYSA-N 0.000 description 3
• VNYQUOAQPXGXQO-UHFFFAOYSA-N 2-iodo-9h-fluorene Chemical compound C1=CC=C2C3=CC=C(I)C=C3CC2=C1 VNYQUOAQPXGXQO-UHFFFAOYSA-N 0.000 description 3
• 239000012362 glacial acetic acid Substances 0.000 description 3
• 239000000203 mixture Substances 0.000 description 3
• 230000003647 oxidation Effects 0.000 description 3
• 238000007254 oxidation reaction Methods 0.000 description 3
• 230000015572 biosynthetic process Effects 0.000 description 2
• PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
• 230000007935 neutral effect Effects 0.000 description 2
• 239000000047 product Substances 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• 238000003786 synthesis reaction Methods 0.000 description 2
• -1 2,7-diiodofluorenol Chemical compound 0.000 description 1
• GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
• 241000907661 Pieris rapae Species 0.000 description 1
• PFRUBEOIWWEFOL-UHFFFAOYSA-N [N].[S] Chemical compound [N].[S] PFRUBEOIWWEFOL-UHFFFAOYSA-N 0.000 description 1
• 239000002253 acid Substances 0.000 description 1
• 150000007513 acids Chemical class 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• 239000003153 chemical reaction reagent Substances 0.000 description 1
• GRYLNZFGIOXLOG-DYCDLGHISA-N deuterio nitrate Chemical compound [2H]O[N+]([O-])=O GRYLNZFGIOXLOG-DYCDLGHISA-N 0.000 description 1
• 238000006193 diazotization reaction Methods 0.000 description 1
• 238000004090 dissolution Methods 0.000 description 1
• 229940079593 drug Drugs 0.000 description 1
• 239000003814 drug Substances 0.000 description 1
• 239000000975 dye Substances 0.000 description 1
• 238000002474 experimental method Methods 0.000 description 1
• 238000005984 hydrogenation reaction Methods 0.000 description 1
• 230000003993 interaction Effects 0.000 description 1
• 150000002496 iodine Chemical class 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 229910017604 nitric acid Inorganic materials 0.000 description 1
• 238000007747 plating Methods 0.000 description 1
• 238000002360 preparation method Methods 0.000 description 1
• PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 1
• KIEOKOFEPABQKJ-UHFFFAOYSA-N sodium dichromate Chemical compound [Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KIEOKOFEPABQKJ-UHFFFAOYSA-N 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000012265 solid product Substances 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1