SU1674689A3 - Roller steel treatment method - Google Patents

Roller steel treatment method Download PDF

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Publication number
SU1674689A3
SU1674689A3 SU884356320A SU4356320A SU1674689A3 SU 1674689 A3 SU1674689 A3 SU 1674689A3 SU 884356320 A SU884356320 A SU 884356320A SU 4356320 A SU4356320 A SU 4356320A SU 1674689 A3 SU1674689 A3 SU 1674689A3
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Prior art keywords
carried out
coating
cooling
water
rolled
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SU884356320A
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Russian (ru)
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Айхер Макс
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Штальверк Аннахютте Макс Айхер Гмбх Унд Ко, Кг (Фирма)
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Publication of SU1674689A3 publication Critical patent/SU1674689A3/en
Priority to LV930903A priority Critical patent/LV5416A3/en
Priority to LTRP1020A priority patent/LT2587B/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/04Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
    • B21B45/08Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing hydraulically
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/08Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires for concrete reinforcement
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/024Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • B21B2001/383Cladded or coated products

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Manufacturing & Machinery (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Heat Treatment Of Steel (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating With Molten Metal (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Prevention Of Electric Corrosion (AREA)
  • Rolls And Other Rotary Bodies (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Heat Treatment Of Articles (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Excavating Of Shafts Or Tunnels (AREA)
  • Electric Cable Arrangement Between Relatively Moving Parts (AREA)
  • Pit Excavations, Shoring, Fill Or Stabilisation Of Slopes (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)
  • Laminated Bodies (AREA)

Abstract

Изобретение касаетс  обработки стального проката, в частности арматурной стали, арматурной проволоки или тому подобных изделий, с нанесением покрытий из цветного металла, преимущественно цинка, причем с проката после нагрева сначала удал ют окалину и затем при исключении образовани  новой окалины на гор чий прокат наноситс  покрытие. Цель изобретени  - повышение коррозионной стойкости. В процессе обработки стальной прокат в непрерывном продолжении процесса прокатки подвергаетс  обработке водой высокого давлени , при этом с поверхности удал етс  окалина, непосредственно после этого дл  предотвращени  образовани  новой окалины с использованием воды давлением 200 - 1000 бар поверхность проката охлаждаетс  до температуры ниже 600°С. Это позвол ет упростить процесс. 6 з.п. ф-лы.The invention relates to the processing of rolled steel, in particular reinforcing steel, reinforcing wire or the like, with the application of coatings of non-ferrous metal, mainly zinc, and scale is first removed from the rolled stock after heating and then, with the exception of the formation of new scale, hot rolled products are coated . The purpose of the invention is to improve corrosion resistance. In the course of treatment, the rolled steel is subjected to high-pressure water treatment in the continuous continuation of the rolling process, while scale is removed from the surface, immediately after that, to prevent the formation of new scale, using water at a pressure of 200-1000 bar, the surface of the rolled product is cooled to a temperature below 600 ° C. This simplifies the process. 6 w.p. f-ly.

Description

Способ осуществл ют следующим образомThe method is carried out as follows.

Со стального проката при непрерывно продолжающемс  процессе прокатки удал ют окалину. Прокат подвергают обработке водой под давлением, при этом поверхность стали непосредственно после удалени  окалины дл  предотвращени  образовани  новой окалины с помощью воды быстро охлаждают до температуры ниже 6СО°С, после чего нанос т покрытие.Scale is removed from rolled steel with a continuous rolling process. Rolled is treated with water under pressure, while the surface of the steel immediately after the removal of scale to prevent the formation of new scale with water is rapidly cooled to a temperature below 6 ° C, after which the coating is applied.

Преимущество изобретени  заключаетс  прежде всего в том, что дл  удалени  окалины, предотвращени  образовани  новой окалины и охлаждени  примен етс  одна среда, а именно вода, благодар  чему охлаждение можно вести так, что прокат ный нагрев оптимально используетс  дл  нанесени  покрыти , все операции по реализации способа или процессы обработки осуществл ютс  при непрерывно продолжающемс  процессе прокатки и их можно вести гри такой скорости прокатки, что конечный продукт сходит с производственной пинии так же. как не прошедший обработку прокат.The advantage of the invention lies primarily in the fact that a single medium, namely water, is used to remove scale, prevent the formation of new scale and cooling, so that cooling can be carried out so that rolling heating is optimally used for coating or the processes are carried out with a continuous rolling process and they can be driven with such a rolling speed that the final product leaves the production line as well. as not processed hire.

При обработке поверхности стали во- дой под очень высоким давлением образовавша с  и- прокате окалина, котора  при д .формировании в последней ю.ети, напри- . ер пои переходе от овального к круглому попаречнлму сечению, уже получила разрыхление , полностью и легко удал етс  с поверхности проката. Давление воды должно быть выше 200 бар, преим/i .естаенно бар, а при необходимости может быть повышено до 1000 бар Этого требует очень коротка  обработка, а именно проход проката через распылительное сопло, в ре- чультате чего будет очень незначительно снижена температура стального проката.When the surface of the steel was treated with water under very high pressure, the scale generated with i-hire, which, when formed, is in the last Yu network, for example. The transition from the oval to the circular cross section, which has already received loosening, is completely and easily removed from the rental surface. The water pressure should be above 200 bar, preferably / i is naturally bar, and if necessary can be increased to 1000 bar. This requires very short treatment, namely the passage of the car through the spray nozzle, as a result of which the temperature of the steel bar will be very slightly reduced. .

Удаление окалины с помощью воды под давлением осуществл етс  при 900- 1000°С, Согласно изобретению в продолжении обработки водой в непрерывном процессе с применением той же среды ведетс  охлаждение, причем так что температура образовани  окалины около 600°С - быстро снижаетс , чтобы не произошло образовани  новой окалины, и дмстигает температуры , при которой может быть нанесено покрытие С этой целью прокат можно пропускать через вод ную баню или распыл ть воду из форсунки Соответствующа  температура дл  нанесени  коррозионно-стойких покрытий составл ет, например, дл  чистого алюмини  560-570°С. а дл  чистого цинка около 415°С При легировании могут создаватьс  промежуточные ступени. Дл  легировани  можно примен ть любоеDescaling using water under pressure is carried out at 900-1000 ° C. According to the invention, the continuation of treatment with water in a continuous process using the same medium leads to cooling, and so that the formation of scale about 600 ° C decreases rapidly to avoid forming a new scale, and setting the temperature at which the coating can be applied. To this end, rental can be passed through a water bath or sprayed from a nozzle. Appropriate temperature for applying corrosion-resistant coatings. The yield is, for example, for pure aluminum at 560-570 ° C. for pure zinc, about 415 ° C. When doping, intermediate stages can be created. For doping, you can use any

покрытие, так как прокатываемый материал проходит все области температуры от прокатного нагрева до полного охлаждени . Нанесение покрыти  осуществл ют любым способом. Цветной металл, образующий покрытие, может быть нанесен в форме порошка, при этом он расплавл етс , прокат можно также пропускать через ванну с жидким цветным металлом.the coating, as the material being rolled goes through all the temperature ranges from rolling heat to full cooling. The coating is carried out by any method. The non-ferrous metal forming the coating can be applied in the form of a powder, while it melts, rolling can also be passed through a bath with a liquid non-ferrous metal.

0 Обработка водой обеспечивает защиту проката после удалени  окалины о г образовани  новой окалины а также защиту сло  нанесенного покрыти  до полною охлаждени  проката. Во многих случа х на покры5 т и е, например, из цинка нанос т добавочную защиту в виде еше одного сло  из синтетической смолы например, эпоксидной . Эти г процесс может быь интпгри- рован в предлагаемом способе с0 Water treatment ensures the protection of the rolled stock after descaling and the formation of a new scale, as well as the protection of the layer of the applied coating until the full cooling of the rolled product. In many cases, additional protection in the form of another layer of synthetic resin, for example, epoxy, is applied to the coating, for example, from zinc. These processes can be integrated in the proposed method with

0 игпользованиом остаточчогс тепла.0 by using residual heat.

Охлаждение проста согласно изобретению после удалени  окалины можно осу- ществл гь любым и, известных способов термической обработки, в котором исполь5 зуетс  вода, например способом, известным под названием Тетрсоге дл  бедных углеоог м и пригсд )ых дп° сварки арматурных сталей, при клтором cr-рзботка водой осуществл ете так. что в прокате непос0 родственно после закалки образуетс  краева  зона из мартенсита и бейнита. в то врем  как теплота, оставша с  в сердечнике стали во врем  последующего охлаждени , не позвол ет перейти при отпускеCooling is simple according to the invention after descaling can be carried out by any and known heat treatment methods in which water is used, for example, by the method known as Tetroger for poor coal and welding of reinforcing steel, with clor cr - use water as follows. that in the rolled product, immediately after quenching, the marginal zone is formed of martensite and bainite. while the heat left in the core of the steel during the subsequent cooling does not allow transition during tempering

5 краевой зоны через бейнитовую структуру. Обработку нодой высокоуглеродистых пригодных дл  использовани  в качестве нат жной арматуры сталей осуществл ют так, что от конечной температуры прокатки меж0 AV 860 и 1060°С при их охлаждении в пограничном спое образуетс  полностью мартенситова  структура и температура пограничного сло  вследствие выравнивани  температуры в промежуток времени 2-6 с5 edge zone through bainitic structure. The high carbon steel suitable for use as tension reinforcement steels are processed so that from the final rolling temperature between AV 860 and 1060 ° C while cooling in the boundary joint, a fully martensitic structure and the temperature of the boundary layer are formed due to temperature equalization in time 2- 6 s

5 после начала процесса охлаждени  составл ет 400-500иС Охлаждение, проводимое согласно изобретению, используетс  преимущественно дл  повышени  прочности стали.5 after the start of the cooling process is 400-500 ° C. The cooling carried out according to the invention is advantageously used to increase the strength of the steel.

0 Преимуществом изобретени   вл етс  то, что все рабочие процессы осуществл ютс  по непрерывно идущему, примыкающему непосредственно к процессу прокатки циклу в отдельной, расположенной за послед5 ней клетью установке по обработке стали. Процесс прокатки заготовок, который ведетс  прерывисто до момента выхода их из последней клети, может быть превращен в непрерывный за счет предварительного свл )ивани  заготовок (преимущественно путем контактной стыковой сварки) в зоне между выходом из печи или из клети трио и первым пропуском линии тонкой прокатки0 The advantage of the invention is that all work processes are carried out along a continuously running, adjacent directly to the rolling process cycle in a separate steel processing plant located behind the last stand. The process of rolling billets, which is conducted intermittently until they leave the last stand, can be turned into continuous by pre-bonding the workpieces (mainly by butt welding) in the zone between the exit from the furnace or the trio stand and the first pass of the thin rolling line.

Claims (7)

Формула изобретени  1. Способ обработки стального прока- та, преимущественно арматурной стали, проволоки, включающий удаление окалины с проката, поступающего с прокатного нагрева после деформации, нанесение покрыти  из цветного металла, предпочти- тельно цинка, о т л и чающийс  тем, что, с целью повышени  коррозионной стойкости, непосредственно после удалени  окалины осуществл ют непрерывное охлаждение поверхности проката до темпе- ратур нанесени  покрыти  ниже 600°С, при этом охлаждение провод т водой под давлением 200-1000 бар, преимущественно в пределах 300-400 бар.Claim 1. A method for treating steel rolled stock, predominantly reinforcing steel, wire, including removing scale from rolled products coming from rolling heat after deformation, applying a non-ferrous metal coating, preferably zinc, that is in order to increase the corrosion resistance, immediately after descaling, the rolling surface is continuously cooled to the coating temperatures below 600 ° C, while cooling is carried out with water under a pressure of 200-1000 bar, but in the range of 300-400 bar. 2. Способ по п. 1,отличающийс  тем, что охлаждение провод т путем транспортировани  проката через емкость с водой .2. A method according to claim 1, characterized in that the cooling is carried out by transporting the rental through a container with water. 3.Способ по п.1, отличающийс  тем, что обработку водой осуществл ют посредством форсунок.3. A method according to claim 1, characterized in that the treatment with water is carried out by means of nozzles. 4.Способ по п.1,отличающийс  тем, что нанесение покрыти  осуществл ют путем напылени  порошкового металла.4. A method according to claim 1, characterized in that the coating is carried out by spraying a powdered metal. 5.Способ по п.1, отличающийс  тем, что нанесение покрыти  осуществл ют путем пропускани  проката через ванну с расплавом.5. A method according to claim 1, characterized in that the coating is carried out by passing the car through a bath with the melt. 6.Способ по п.1,отличающийс  тем, что на покрытие нанос т дополнительный слой, например, из эпоксидной смолы.6. A method according to claim 1, characterized in that an additional layer, for example epoxy resin, is applied to the coating. 7.Способ по п.1.отличающийс  тем, что охлаждение поверхности проката осуществл ют до образовани  в ней мартенсита или бейнита.7. A method according to claim 1, characterized in that the cooling of the rolling surface is carried out before the formation of martensite or bainite therein.
SU884356320A 1987-09-01 1988-08-26 Roller steel treatment method SU1674689A3 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
LV930903A LV5416A3 (en) 1987-09-01 1993-06-30 Seeding of the rolling mill
LTRP1020A LT2587B (en) 1987-09-01 1993-09-21 THE ROLE OF ROLLED STEEL PROCESSING

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3729177A DE3729177C1 (en) 1987-09-01 1987-09-01 Process for treating rolled steel to increase resistance to corrosion

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SU1674689A3 true SU1674689A3 (en) 1991-08-30

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JP (1) JPS6475692A (en)
CN (1) CN1031724A (en)
AT (1) ATE70568T1 (en)
CA (1) CA1306391C (en)
DD (1) DD282246A5 (en)
DE (2) DE3729177C1 (en)
DK (1) DK460688A (en)
ES (1) ES2028964T3 (en)
GR (1) GR3004067T3 (en)
HU (1) HU203586B (en)
NO (1) NO176578C (en)
PL (1) PL158408B1 (en)
PT (1) PT88371B (en)
SU (1) SU1674689A3 (en)

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RU2573304C9 (en) * 2014-03-11 2016-05-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования Пензенский государственный университет архитектуры и строительства Increasing life and hardness of rod- and pipe-type reinforcements
DE202016008333U1 (en) 2016-04-08 2017-08-01 Andrey Senokosov Device for cleaning riser pipes, in particular in petroleum equipment
DE102016106421A1 (en) 2016-04-08 2017-10-12 Andrey Senokosov Cleaning process for riser pipes and equipment therefor

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EP0305914A3 (en) 1989-08-09
JPH0445591B2 (en) 1992-07-27
HU203586B (en) 1991-08-28
CA1306391C (en) 1992-08-18
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DE3866998D1 (en) 1992-01-30
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NO883781D0 (en) 1988-08-24
HUT52178A (en) 1990-06-28
PT88371B (en) 1993-02-26
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DE3729177C1 (en) 1989-01-05
PL158408B1 (en) 1992-08-31
ATE70568T1 (en) 1992-01-15
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PT88371A (en) 1989-07-31
NO176578C (en) 1995-04-26

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