SU108135A1 - The method of obtaining organic compounds containing sulfur and nitrogen - Google Patents
The method of obtaining organic compounds containing sulfur and nitrogenInfo
- Publication number
- SU108135A1 SU108135A1 SU551266A SU551266A SU108135A1 SU 108135 A1 SU108135 A1 SU 108135A1 SU 551266 A SU551266 A SU 551266A SU 551266 A SU551266 A SU 551266A SU 108135 A1 SU108135 A1 SU 108135A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- nitrogen
- organic compounds
- compounds containing
- containing sulfur
- obtaining organic
- Prior art date
Links
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Предла1-аетс способ получении органических соединений, содерл ащих азот и серу, сущност которого состоит в том, что соединени5т, содержагиие кето-группу, ввод т во взаимодействие с серой или иолисульфидом при одновременном воздействии аммиака. По.лученные соединени представл ют собой ценные промежуточные или готовые продукты дл фармацевтичееко иромьпп.пенности. Кроме того, эти продукты могут найти применение в качестве средств дл борьбы с з|)едител ми, дл уничтожени еорных трав, дл запшты против ржавчины и старени .A method is proposed for the preparation of organic compounds containing nitrogen and sulfur, the essence of which is that the compound containing a keto group is brought into contact with sulfur or iolysulfide with simultaneous exposure to ammonia. The resulting compounds are valuable intermediates or finished products for the pharmaceutical industry. In addition, these products can be used as a means for combating s | | with agents, for the destruction of eorian herbs, for rust and aging.
Описываемы.й способ ио.тучени названных соединений осуществл етс следующим образом.The described procedure for the etching process of the named compounds is carried out as follows.
Во взвесь из 1 мол серы и 2 молей кето-соедипени ввод т при комнатной температуре аммиачный газ. Способ может быть осуществ .leH также и в присутствии растворителей , например спирта, бензола, различных эфиров и друтих соединений . Вместо ееры может быть применен полисульфид, например,A suspension of ammonium gas from 1 mol of sulfur and 2 moles of keto-compound is introduced at room temperature. The method can also be carried out. LeH in the presence of solvents, for example alcohol, benzene, various esters and other compounds. Polysulfide can be used instead of eera, for example,
г.ммонии, натри , а также и органические полисульфиды, например, .теновьп полисульфид.ammonium, sodium, as well as organic polysulfides, for example, .two polysulfide.
Б качестве кего-соеди} ени 1 могут использованы все кетоны, в.хо;|ЯП1ИС в форму., , --- СМ - СО -- СМ2--Rs, где RI Ra ; Rs могут водородом.All ketones, w.cho; | ЯП1ИС in the form.,, --- СМ - СО - СМ2 - Rs, where RI Ra; Rs can be hydrogen.
пример 1. С меипшают 144 г люти.-эгплкетома с 32 г серы (серного цвета м.ти по|.1он1ка черенково се;;ы).. В чту взвесь ввод т амглиачны: газ до тех нор, пока сера не перейдет в раетпор; при этом А оже1 нроизводитье подогрев до 80°. К темно-коричневой реакционной смеси прибавл ют эфир и щелочной раствор г ромьшают водой. Пр1-5 дистил .1 н,ии освобожденпо от фира части получепно1о продукта выдел ют 135 г соединени состава ( с темпсрату;)ой кипени 70°. Выход составл ет 85% от теоретического .Example 1. With 144 g of lute.-egplequtome with 32 g of sulfur (sulfur-gray, m. ti | .111ka cherenkovo se ;; s). raetpor; at the same time, the Auger1 produces heating up to 80 °. Ether is added to the dark brown reaction mixture and the alkaline solution is rinsed with water. Ex. 1–5 distillate .1 n, o and freed from the portion of the receptacle product, 135 g of the compound of the composition (with temperature; boiling point 70 °) were isolated. The yield is 85% of theoretical.
Пример 2. Ввод т 196 г циклогексаиона в водный раствор полису Пзфида натри . Эта смесь при тщательном размешивании обрабаТглваетс в течение 2 часов приExample 2. 196 g of cyclohexaion are added to an aqueous solution of Pzfida sodium. This mixture, while thoroughly stirring, is processed for 2 hours at
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU551266A SU108135A1 (en) | 1956-05-04 | 1956-05-04 | The method of obtaining organic compounds containing sulfur and nitrogen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU551266A SU108135A1 (en) | 1956-05-04 | 1956-05-04 | The method of obtaining organic compounds containing sulfur and nitrogen |
Publications (1)
Publication Number | Publication Date |
---|---|
SU108135A1 true SU108135A1 (en) | 1956-11-30 |
Family
ID=48381275
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU551266A SU108135A1 (en) | 1956-05-04 | 1956-05-04 | The method of obtaining organic compounds containing sulfur and nitrogen |
Country Status (1)
Country | Link |
---|---|
SU (1) | SU108135A1 (en) |
-
1956
- 1956-05-04 SU SU551266A patent/SU108135A1/en active
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