SU1060095A3 - Фунгицидное средство (его варианты) - Google Patents

Фунгицидное средство (его варианты) Download PDF

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SU1060095A3
SU1060095A3 SU803008192A SU3008192A SU1060095A3 SU 1060095 A3 SU1060095 A3 SU 1060095A3 SU 803008192 A SU803008192 A SU 803008192A SU 3008192 A SU3008192 A SU 3008192A SU 1060095 A3 SU1060095 A3 SU 1060095A3
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alanine
methyl
naphthyl
substituted
surfactant
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Рентцеа Костин
Це Бернд
Поммер Эрнст-Гейнрих
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Басф Аг (Фирма)
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    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)
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  • Furan Compounds (AREA)

Abstract

1. Фунгицидное средство в форме i эмульгируемого концентрата, содержа- щве активное вещество на основе Производного аланина и поверхностноактивное вещество, отличаю . щ вес   тем, что, с целью усилени , фунгицидной активности, оно в качестве производного аланина содержит метиловый .эфир N -

Description

Изобретение относитс  к химическим средствам борьбы с вредител ми, а именно, к фунгицидиому средству н основе производного аланина (его ва рианты). Известно фунгицидное средство, с держащее в качестве активного вещес васоединение общей формулы „ „jf СОИ где X - галоген, V - водород, галоген l . Известно фунгицидное средство в форме эмульгируемого концентрата, содержащее в качестве активного вещества метиловый ФИР К-(2-фуранкарбЬнил )-М-(2, 6 -диметилфенил)-аланина и вспомогательны .кокшоне ты - поверхностно-активное вещество и стабилизатор И . Однако активность этого средств недостаточна. Цель изобретени  - усиление .фун гицидной активности, Указанна  цель достигаетс  фунг цидным средством в его вариантных решени х. 1. Фунгицидное средство в форме эмульгируемого концентрата, содерж щее в качестве производного аланин метиловый ЭФИР М -(2-фуранкарбонил) -И- (2-метил 4-бром- -нафтил) -алани формулы - ц Н$ . J «Н-СООН ВгЧ . . , в качестве поверхностно-активного вещества лигнинсульфонат натри  при следующем соотношении компонентов, мае. % : Метиловый эфир H-{2-фypaнкapбoнИл )-N - (2-к:етил-4-бром 1-нафтил ) апанина8р Лигнинсульфонат натри  . -20 2 Фунгицидное средство в фор|ме .эмульгируемого концентрата, содерж щее в качестве производного аданин метиловый эфир N-(3-изоксазолкарбо нил)-М-(2-метил-1-нафвил)-аланина формулы СН, « в качестве поверхностно-активного вещества натриевую соль диизобутилнафталин-й-сульфокислоты и лигнинсульфонат натри , а в качестве стабилизатора гель кремневой кислоты при следующем соотношении компонентов , мае. % : Метиловый эфир f4 - ( 3-изоксазолкарбонил )-N - (2-меТйл- т .наФтил)-аланина 80 Натриева  соль диизобутил- нафталин-сс-сульфокислоты 3 Лигнинсульфонат натри  10 Гель кремневой кислоты 7 Соединени  Формулы (I) получают следующим .образом. 22f2 г (0,066 моль) метилового эфира К - (2-фуранкарбонил) -N- (2-кютил-l-нафтил )-аланина и 6 г (0,07 моль) свободного от воды ацетата натри  в 150 -мл уксусной кислоты смешивают с 11 г (0,067 моль) брома и перемешивают в течение 24 ч при . Смесь затем примешивают к 700 мл лед ной воды, продукт 3 раза экстрагируют 100 мл простого эфира« Очищенные эфирные экстракты один раз промывают 100 мл IN натрового щелока и один раз водой, сушат и концентрируют . Получают 17 г (62% теории) метиловый эфир N -(2-фуранкарбониЛ)-N- (2-метил-4-бром- -нафтил) -аланина в виде бесцветной смолы. . ИК-спектр (пленка) (см ) ;3035, 2930, 1730, 1640, 1450, 1360, 1235, 1190j 1126, 1092, 908,810, Аналогично получают соединение (Ц) в виде смолы, характеризующеес  ИК-спектром (пленка) (сМ):3108, 3038, 2935, 1726, 1635, 1532, 14.., 1330, 1200, 1100, 1042, 875, 856, 810, 796, 778, 758, 742. В качестве сравнени  используют .известное соединение А . , сн, сн, сн-сооснз 1-W -СНз П р и м е р 1, Листь  выросших в горшках ростков пшеницы сорта Юбил р опрыскивают водным препаратом фунгицида, состо щего из, мае. %: 80 активного вещества 1 (опыт о ) или активного вещества А (опыт 5 ) и 20 лигнинсульфоната натри . После высы хани  листь  опыл ют кониди ми (спо{рами ) мучнистой росы пшеницы (Erysiphe graminls var. tritici). Подопытные растени  затем став т в теплицу при температуре 2О-22®С и относительной влажности воздуха 75-80%. По истечении 10 дней определ ют степень развити  грибков мучнистой росы. Результаты опытов приведены в таблице . П р и м е р 2, Листь  внросших в горшках росТков пшеницы сорта
Юбил р опрыскивают водным препаратом фунгицида, состо щего из, мас.% 80 активного вещества II (опыт а )
,или активного вещества А (опыт б ), 3 натриевой соли диизЬбутилнафталин-г«Ь-сульфокислоты , 10 лигнинсульфоната .
.натри  и 1 гел  кремневой кислоты Пос те вывыхани  листь  опыл ют KOJIKди ми (QhcTpeuto) мучнистой росы пшёПример
1опыт q , известный опыт S , предлагаемый
2опыта (Известный
опыт 5 , предлагаемый Крнтроль (необработанный)
;О означает отсутствие поражени ; 100 - полное- поражение.
. (Eryslphe qramtale var, tritt.. ШГ). Подопытные растени  затем став У, в теплицу.при температуре ;Н относительной влажности Ъоэдуха 75-80%. По истечении 10 дней опредв л ют степень развити  грибков муч дстрй росы .
Реэультаты опыта приведены в таблице,.
Процентное поражение грибками лист.ьев через 10 дней при концентрации активного вещества, равной 0,025%
О
80 35 80 90
Таким образом, предлагаемое фунцидное средство обладает высокой активностью.

Claims (2)

  1. , 1. Фунгицидное средство в форме ίэмульгируемого концентрата, содержа— щее активное вещество на основе
    Производного аланина и поверхностноактивное вещество, отличаю. щ е е с я тем, что, с целью усиления.
    фунгицидной активности, оно в качестве производного аланина содержит метиловый эфир N -(2-фуранкарбонил)i -И-(2-метил-4-бром-1' -нафтил)-алани. на формулы следующем соотношении компонентов, мае. % :
    Метиловый эфир N-(2>-фуранкарбонил)-N-(2-метил-4-бром-1-нафтил)-аланина Лигнинсульфонат натрия
  2. 2. Фунгицидное средство в форме эмульгируемого концентр'ата, содержащее активное вещество на основе производного аланина, поверхностно-активное вещество и стабилизатор, отличающееся тем, что, с целью усиления фунгицидной активности, оно содержит в качестве производного аланина метиловый эфир N-(3-изоксазолкарбонил) -N- (г'-метил^-наф’ тил)-аланина формулы
    СН3 I 3 ch-coochj) а в качестве поверхностно-активного вещества лигнинсульфонат натрия при в
    вещества натриевую соль диизобутилнафталин -Л-сульфокислоты и лигнинсульфонат натрия, а в качестве стабилизатора гель кремневой при следующем соотношении тов, мае. ;
    , Метиловый эфир N-(3• -изоксазолкарбонил -Ν- (2-метил-1'-нафтил)- 5 -аланина
    Натриевая соль диизобутил-1 нафталин—ct—сульфокислоты Лигнинсульфонат натрия Гель кремневой кислоты качестве поверхностно-активного кислоты . компонен-
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Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
MA19215A1 (fr) * 1980-07-25 1982-04-01 Ciba Geigy Ag Nouveaux derives arylamines,procede pour leur fabrication et utilisation en tant que microbicides .
DE3126082A1 (de) * 1981-07-02 1983-01-20 Basf Ag, 6700 Ludwigshafen Glykoletheressigsaeurenaphthylamide, verfahren zu ihrer herstellung und diese enthaltende fungizide
DE3126083A1 (de) * 1981-07-02 1983-01-20 Basf Ag, 6700 Ludwigshafen N-substituierte 2-methylnaphthylamide, verfahren zu ihrer herstellung und diese enthaltende fungizide
DE3135238A1 (de) * 1981-09-05 1983-03-17 Basf Ag, 6700 Ludwigshafen N-alkinyl-naphthylamide, verfahren zu ihrer herstellung und diese enthaltende fungizide
DE3135239A1 (de) * 1981-09-05 1983-03-17 Basf Ag, 6700 Ludwigshafen N-substituierte brenztraubensaeureamide, verfahren zu ihrer herstellung und diese enthaltende fungizide
DE3135670A1 (de) * 1981-09-09 1983-03-24 Basf Ag, 6700 Ludwigshafen Oxalamide, verfahren zu ihrer herstellung und diese enthaltende fungizide
DE3144140A1 (de) * 1981-11-06 1983-05-19 Basf Ag, 6700 Ludwigshafen 2-isoxazolincarbonsaeureamide, verfahren zu ihrer herstellung und diese enthaltende fungizide
DE3144951A1 (de) * 1981-11-12 1983-05-19 Basf Ag, 6700 Ludwigshafen Isoxazol-carbonsaeure-amide, ihre herstellung und ihre verwendung als fungizide
JPH0613445B2 (ja) * 1985-09-10 1994-02-23 保土谷化学工業株式会社 水稲種子粉衣剤
WO2000060940A1 (en) * 1999-04-12 2000-10-19 Dow Agrosciences Llc Aqueous dispersions of agricultural chemicals
RU2646058C1 (ru) * 2017-07-06 2018-03-01 Ксения Леонидовна Алексеева Способ борьбы с мучнистой росой томатов в теплицах

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2412510A (en) 1944-06-02 1946-12-10 American Chem Paint Co Methods and compositions for killing weeds
DE1003221B (de) 1953-06-24 1957-02-28 Cassella Farbwerke Mainkur Ag Verfahren zur Herstellung neuer anaesthetisch wirkender Aminocarbonsaeureamide
NL93512C (ru) 1957-04-06 1960-02-15
US3272844A (en) 1965-06-03 1966-09-13 Lilly Co Eli Novel acetylenic amides
DE1670172C3 (de) 1966-12-09 1974-04-04 C.H. Boehringer Sohn, 6507 Ingelheim 2-(3,4-Dichloranilinocarbonyl)isoxazolidin
US3549704A (en) * 1967-05-19 1970-12-22 Philips Corp Salicylamides
NL7402417A (ru) 1973-03-01 1974-09-03
US4098895A (en) 1975-09-30 1978-07-04 Ciba-Geigy Corporation Triazolylacetanilide compounds and microbicidal compositions
DE2845454A1 (de) 1977-11-01 1979-05-10 Chevron Res 3-(n-acyl-n-arylamino)- gamma -butyrolactone und - gamma -butyrothiolactone sowie fungizide mittel
US4221584A (en) 1979-02-09 1980-09-09 Chevron Research Company Herbicidal and plant-growth-regulating N-(heterocyclyl)-methylacetanilides
MA18800A1 (fr) * 1979-04-10 1980-12-31 Ciba Geigy Ag Naphtylamines acylees,procede pour leur preparation et leur application comme phytofongicides

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
1. Патент DE 2525023, кл. С 07 D 261/18, 1976. .2. Патент GB . 1448810, кл. С 07 D 307/54.; опублик. 1976((прототип). ; *

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