SK5492002A3 - Start up methods for multiple catalyst systems - Google Patents

Start up methods for multiple catalyst systems Download PDF

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Publication number
SK5492002A3
SK5492002A3 SK549-2002A SK5492002A SK5492002A3 SK 5492002 A3 SK5492002 A3 SK 5492002A3 SK 5492002 A SK5492002 A SK 5492002A SK 5492002 A3 SK5492002 A3 SK 5492002A3
Authority
SK
Slovakia
Prior art keywords
catalyst
reactor
group
catalysts
activator
Prior art date
Application number
SK549-2002A
Other languages
English (en)
Slovak (sk)
Inventor
John F Szul
Kersten Anne Erickson
Simon Mawson
Paul T Daniell
Mark G Goode
Matthew G Mckee
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/425,387 external-priority patent/US6274684B1/en
Priority claimed from US09/456,234 external-priority patent/US6372868B1/en
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of SK5492002A3 publication Critical patent/SK5492002A3/sk

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/18Suspension polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
SK549-2002A 1999-10-22 2000-05-15 Start up methods for multiple catalyst systems SK5492002A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/425,387 US6274684B1 (en) 1999-10-22 1999-10-22 Catalyst composition, method of polymerization, and polymer therefrom
US09/456,234 US6372868B1 (en) 1999-12-07 1999-12-07 Start up methods for multiple catalyst systems
PCT/US2000/013378 WO2001030862A1 (fr) 1999-10-22 2000-05-15 Procedes de mise en route de systemes a catalyseurs multiples

Publications (1)

Publication Number Publication Date
SK5492002A3 true SK5492002A3 (en) 2002-12-03

Family

ID=27026665

Family Applications (1)

Application Number Title Priority Date Filing Date
SK549-2002A SK5492002A3 (en) 1999-10-22 2000-05-15 Start up methods for multiple catalyst systems

Country Status (19)

Country Link
EP (1) EP1242476B1 (fr)
JP (1) JP3831664B2 (fr)
KR (1) KR100567303B1 (fr)
CN (1) CN100347206C (fr)
AR (1) AR023992A1 (fr)
AT (1) ATE361324T1 (fr)
AU (1) AU763705B2 (fr)
BR (1) BR0015236B1 (fr)
CA (1) CA2388145C (fr)
CZ (1) CZ20021400A3 (fr)
DE (1) DE60034705T2 (fr)
IL (1) IL149263A0 (fr)
MX (1) MXPA02004001A (fr)
NO (1) NO20021861L (fr)
PL (1) PL356716A1 (fr)
SA (1) SA00210260B1 (fr)
SK (1) SK5492002A3 (fr)
TW (1) TW503242B (fr)
WO (1) WO2001030862A1 (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6828397B2 (en) * 2000-11-07 2004-12-07 Symyx Technologies, Inc. Methods of copolymerizing ethylene and isobutylene and polymers made thereby
CN1271089C (zh) * 2000-12-18 2006-08-23 尤尼威蒂恩技术有限责任公司 多成分催化剂聚合体系的启动程序
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
CA2499951C (fr) 2002-10-15 2013-05-28 Peijun Jiang Systeme catalyseur multiple pour la polymerisation d'olefines et polymeres ainsi produits
US7094848B2 (en) 2003-05-13 2006-08-22 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system
CN1938341B (zh) * 2004-04-07 2011-08-10 尤尼威蒂恩技术有限责任公司 控制烯烃聚合的方法
US7323523B2 (en) * 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
EP2231723B1 (fr) 2007-11-20 2012-05-16 Univation Technologies, LLC Procédés de préparation de polyoléfines
ES2407121T3 (es) 2007-12-18 2013-06-11 Univation Technologies, Llc Método para controlar la actividad de un catalizador bimodal durante una polimerización
US8242198B2 (en) 2008-06-09 2012-08-14 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
US8431642B2 (en) 2008-06-09 2013-04-30 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US8283400B2 (en) 2008-06-09 2012-10-09 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
CN102731694B (zh) 2008-08-01 2015-04-01 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
EP2435526A4 (fr) 2009-05-29 2012-10-31 Exxonmobil Chem Patents Inc Compositions d'adhésif polyoléfiniques et leur procédé de fabrication
ES2975195T3 (es) 2010-10-21 2024-07-03 Univation Tech Llc Polietileno y proceso para la producción del mismo
US20130281340A1 (en) 2012-04-19 2013-10-24 Exxonmobil Chemical Patents Inc. Lubricant Compositions Comprising Ethylene Propylene Copolymers and Methods for Making Them
US9809667B2 (en) * 2014-02-11 2017-11-07 Univation Technologies, Llc Producing polyolefin products
JP6990032B2 (ja) 2017-03-28 2022-02-03 三井化学株式会社 オレフィン重合体の製造方法および遷移金属錯体の保存方法
WO2020092599A1 (fr) * 2018-11-01 2020-05-07 Exxonmobil Chemical Patents Inc. Modifications du dispositif d'alimentation en catalyseur d'appoint en suspension

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2332890A1 (de) * 1972-06-29 1974-01-17 Exxon Research Engineering Co Kontinuierliches verfahren zur herstellung von elastomeren copolymerisaten von aethylen mit einem hoeheren alphaolefin
US4789714A (en) * 1983-06-15 1988-12-06 Exxon Research & Engineering Co. Molecular weight distribution modification in tubular reactor
US5034195A (en) * 1988-11-18 1991-07-23 Brown & Root Usa, Inc. Apparatus for gas phase polymerization of olefins in vertically stacked reactors
ES2163404T3 (es) * 1993-04-07 2002-02-01 Atofina Res Procedimiento para la produccion de poliolefinas y catalizador poliolefinico.
JP2895408B2 (ja) * 1993-12-21 1999-05-24 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション 気相方法による長鎖枝を含有するポリオレフィンの製造
JP3352242B2 (ja) * 1994-08-10 2002-12-03 旭化成株式会社 ポリオレフィンの製造方法
US5672666A (en) * 1995-06-05 1997-09-30 Exxon Chemical Patents Inc. Process for transitioning between incompatible polymerization catalysts
JPH10245418A (ja) * 1997-03-03 1998-09-14 Mitsubishi Chem Corp オレフィン重合体の製造方法
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
CA2247703C (fr) * 1998-09-22 2007-04-17 Nova Chemicals Ltd. Processus de polymerisation ethylene a reaction double

Also Published As

Publication number Publication date
IL149263A0 (en) 2002-11-10
AR023992A1 (es) 2002-09-04
KR100567303B1 (ko) 2006-04-04
PL356716A1 (en) 2004-06-28
CA2388145A1 (fr) 2001-05-03
NO20021861L (no) 2002-06-24
JP2003513115A (ja) 2003-04-08
CN100347206C (zh) 2007-11-07
MXPA02004001A (es) 2002-10-23
AU5018400A (en) 2001-05-08
JP3831664B2 (ja) 2006-10-11
CZ20021400A3 (cs) 2002-11-13
SA00210260B1 (ar) 2006-04-26
CN1391585A (zh) 2003-01-15
EP1242476A1 (fr) 2002-09-25
AU763705B2 (en) 2003-07-31
BR0015236A (pt) 2003-11-04
DE60034705T2 (de) 2008-01-17
DE60034705D1 (de) 2007-06-14
CA2388145C (fr) 2006-12-19
ATE361324T1 (de) 2007-05-15
EP1242476B1 (fr) 2007-05-02
BR0015236B1 (pt) 2011-06-14
KR20020062634A (ko) 2002-07-26
TW503242B (en) 2002-09-21
NO20021861D0 (no) 2002-04-19
WO2001030862A1 (fr) 2001-05-03

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