SI9520007A - Method and device for polymerising binders in fibrous materials especially mineral wool insulation - Google Patents

Method and device for polymerising binders in fibrous materials especially mineral wool insulation Download PDF

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Publication number
SI9520007A
SI9520007A SI9520007A SI9520007A SI9520007A SI 9520007 A SI9520007 A SI 9520007A SI 9520007 A SI9520007 A SI 9520007A SI 9520007 A SI9520007 A SI 9520007A SI 9520007 A SI9520007 A SI 9520007A
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Slovenia
Prior art keywords
mineral wool
irradiation
polymerization
ultraviolet radiation
radiation
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Application number
SI9520007A
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English (en)
Inventor
Frederic Mertz
Pascal Chartier
Christian Decker
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Saint Gobain Isover
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Publication date
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Publication of SI9520007A publication Critical patent/SI9520007A/sl

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/655Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the apparatus for applying bonding agents
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/0288Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/248Moulding mineral fibres or particles bonded with resin, e.g. for insulating or roofing board
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209Inorganic fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/554Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving by radio-frequency heating
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/645Impregnation followed by a solidification process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0827Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/0854Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2503/00Use of resin-bonded materials as filler
    • B29K2503/04Inorganic materials

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Polymerisation Methods In General (AREA)
  • Moulding By Coating Moulds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Paper (AREA)

Claims (15)

1. Postopek za polimeriziranje snovi v vlaknenih materialih, predvsem veziv v materialih iz mineralne volne za izolacijske namene, pri katerem se vlakneni material, ki ima dano debelino (d) in ki se v danem primeru lahko neprekinjeno premika po izdelovalni liniji, se podvrže ultravijoličnemu obsevanju, da se polimerizira snov, ki ima obliko predpolimera, ki impregnira vlakna, označen s tem, da se obsevanje materiala izvede pri dovolj visokem intenzitetnem nivoju (1^), da se pri maksimalni globini nameravane polimerizacije doseže rezidualno intenziteto, ki presega takšno vrednost praga, pri kateri je zagotovljena polimerizacija izbranega veziva pod vplivom ultravijoličnega sevanja znotraj dane časovne meje, pri čemer pa takšna časovna meja izključuje z učinki sevanja povzročeno nezaželjeno degradacijo organskih snovi v predelu ob površini omenjenega materiala, in je v primeru vlaknenega materiala, ki se neprekinjeno premika po izdelovalni liniji, kompatibilna s hitrostjo linije, in da se trajanje (t) obsevanja dane površinske enote omenjenega materiala drži znotraj omenjene časovne meje.
2. Postopek po zahtevku 1, označen s tem, da omenjeni intenzitetni nivo (1,^) na površini omenjenega materiala iz mineralne volne presega 500 mW/cm2, prednostno presega 1 W/cm2 in še posebno presega 2 W/cm2.
3. Postopek po zahtevku 1 ali 2, označen s tem, da valovna dolžina uporabljenega ultravijoličnega sevanja presega 250 nm in prednostno 310 nm.
4. Postopek po kateremkoli izmed zahtevkov 1 do 3, označen s tem, da je trajanje (t) obsevanja omenjene površinske enote krajše od 10 s, prednostno krajše od 1 s in predvsem krajše od 0,5 s.
5. Postopek po kateremkoli izmed zahtevkov 1 do 4, označen s tem, da se površina omenejnega materiala iz mineralne volne pred obsevanjem ohladi.
6. Postopek po kateremkoli izmed zahtevkov 1 do 5, označen s tem, da je delež kisika, ki je vsebovan v atmosferi znotraj omenjenega materiala iz mineralne volne, zmanjšan na manj kot 10 %, prednostno manj kot 5 % in še posebej manj kot 1 %.
7. Postopek po kateremkoli izmed zahtevkov 1 do 6, označen s tem, da se obsevata obe večji ploskvi omenjenega materiala.
8. Postopek po zahtevku 7, označen s tem, da se obe strani obsevata hkrati.
9. Postopek po zahtevku 7 ali 8, označen s tem, da je področje z nizko stopnjo polimerizacije predvideno v središčnem področju omenjenega materiala.
10. Postopek po kateremkoli izmed zahtevkov 1 do 9, označen s tem, da se kot predpolimer za oblikovanje veziva uporablja zmes snovi, ki obsegajo epoksiakrilat.
11. Priprava za polimeriziranje snovi v vlaknenih materialih, kot je predvsem vezivo v materialu iz mineralne volne za izoalcijske namene, obsegajoča vsaj en izvor (10) ultravijoličnega sevanja, označena s tem, da so predvidena sredstva (12) za fokusiranje ultravijoličnega sevanja v vsaj enem fokusiranem snopu (18) majhne širine (b).
12. Priprava po zahtevku 11, označena s tem, da je fokusiran snop (18) izoblikovan tako, daje linearen, in se ga prednostno drži stacionarnega.
13. Priprava po zahtevku 11, označena s tem, da ima omenjeni fokusiran snop (18) obliko točke, ki se hitro giba po omenjenem materialu (16) iz mineralne volne z ene strani na drugo, tako da prednostno obseva vso njegovo površino.
14. Priprava po kateremkoli izmed zahtevkov 11 do 13, označena s tem, da ima omenjeni fokusirani snop (18) žarišče (14), ki se nahaja znotraj omenjenega materiala (16) iz mineralne volne, ki ga je treba obdelati.
15. Priprava po kateremkoli izmed zahtevkov 11 do 14, označena s tem, da sta izvora (10) ultravijoličnega sevanja nameščena na obeh straneh večjih ploskev omenjenega materiala (16) iz mineralne volne.
SI9520007A 1994-06-17 1995-06-16 Method and device for polymerising binders in fibrous materials especially mineral wool insulation SI9520007A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4421254A DE4421254A1 (de) 1994-06-17 1994-06-17 Verfahren und Vorrichtung zum Polymerisieren von Substanzen in Fasermaterialien, insbesondere Bindemittel in Mineralwollematerialien für Dämmzwecke

Publications (1)

Publication Number Publication Date
SI9520007A true SI9520007A (en) 1996-06-30

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ID=6520848

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Application Number Title Priority Date Filing Date
SI9520007A SI9520007A (en) 1994-06-17 1995-06-16 Method and device for polymerising binders in fibrous materials especially mineral wool insulation

Country Status (16)

Country Link
EP (1) EP0717798A1 (sl)
JP (1) JPH09505117A (sl)
KR (1) KR960705097A (sl)
CN (1) CN1129020A (sl)
AU (1) AU2792795A (sl)
BR (1) BR9506267A (sl)
CA (1) CA2168014A1 (sl)
CZ (1) CZ337595A3 (sl)
DE (1) DE4421254A1 (sl)
FI (1) FI960127A0 (sl)
HU (1) HUT72828A (sl)
NO (1) NO960018L (sl)
PL (1) PL313167A1 (sl)
SI (1) SI9520007A (sl)
WO (1) WO1995035402A1 (sl)
ZA (1) ZA954731B (sl)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004003262A1 (de) * 2004-01-21 2005-08-11 Basf Ag Thermisch polymerisierbare Mischungen aus multifunktionellen Makromonomeren und Polymerisationsinitiatoren und ihre Verwendung als Bindemittel für Substrate
US11858215B2 (en) 2018-04-30 2024-01-02 Hewlett-Packard Development Company, L.P. Build material heaters with baffles

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1349058A (en) * 1970-05-19 1974-03-27 Ici Ltd Non-woven webs
GB2036039B (en) * 1978-09-11 1983-04-13 Unisearch Ltd Imparting permanent press characteristics to textiles
US4300468A (en) * 1980-03-24 1981-11-17 The United States Of America As Represented By The Secretary Of The Navy Position interlock system for submarine masts and closure
CH660489A5 (de) * 1984-08-31 1987-04-30 Bernhard Glaus Verfahren und vorrichtung zum aushaerten polymerisierbarer beschichtungsmassen auf nicht textilen substraten.
US5227229A (en) * 1990-12-20 1993-07-13 Minnesota Mining And Manufacturing Company Nonwoven polyester articles and method of making same
US5275874A (en) * 1991-12-23 1994-01-04 Owens-Corning Fiberglas Technology Inc. Glass fiber insulation bonded with a UV cured system

Also Published As

Publication number Publication date
FI960127A (fi) 1996-01-11
AU2792795A (en) 1996-01-15
CN1129020A (zh) 1996-08-14
KR960705097A (ko) 1996-10-09
ZA954731B (en) 1996-01-26
HUT72828A (en) 1996-05-28
EP0717798A1 (en) 1996-06-26
JPH09505117A (ja) 1997-05-20
PL313167A1 (en) 1996-06-10
CZ337595A3 (en) 1996-05-15
DE4421254A1 (de) 1995-12-21
NO960018D0 (no) 1996-01-03
NO960018L (no) 1996-01-03
BR9506267A (pt) 1997-08-12
WO1995035402A1 (en) 1995-12-28
CA2168014A1 (en) 1995-12-28
HU9503489D0 (en) 1996-02-28
FI960127A0 (fi) 1996-01-11

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