SG11202002380YA - Catalyst for the oxidative esterification of aldehydes to carboxylic esters - Google Patents

Catalyst for the oxidative esterification of aldehydes to carboxylic esters

Info

Publication number
SG11202002380YA
SG11202002380YA SG11202002380YA SG11202002380YA SG11202002380YA SG 11202002380Y A SG11202002380Y A SG 11202002380YA SG 11202002380Y A SG11202002380Y A SG 11202002380YA SG 11202002380Y A SG11202002380Y A SG 11202002380YA SG 11202002380Y A SG11202002380Y A SG 11202002380YA
Authority
SG
Singapore
Prior art keywords
aldehydes
catalyst
carboxylic esters
oxidative esterification
esterification
Prior art date
Application number
SG11202002380YA
Other languages
English (en)
Inventor
Steffen Krill
Marcel Treskow
Original Assignee
Roehm Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm Gmbh filed Critical Roehm Gmbh
Publication of SG11202002380YA publication Critical patent/SG11202002380YA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)
SG11202002380YA 2017-09-19 2018-08-30 Catalyst for the oxidative esterification of aldehydes to carboxylic esters SG11202002380YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17191731.3A EP3456704A1 (de) 2017-09-19 2017-09-19 Katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
PCT/EP2018/073294 WO2019057458A1 (de) 2017-09-19 2018-08-30 Katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern

Publications (1)

Publication Number Publication Date
SG11202002380YA true SG11202002380YA (en) 2020-04-29

Family

ID=59914334

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202002380YA SG11202002380YA (en) 2017-09-19 2018-08-30 Catalyst for the oxidative esterification of aldehydes to carboxylic esters

Country Status (10)

Country Link
US (2) US11279667B2 (ko)
EP (2) EP3456704A1 (ko)
JP (1) JP2020534359A (ko)
KR (1) KR20200051803A (ko)
CN (1) CN111108088B (ko)
BR (1) BR112020005175A2 (ko)
RU (1) RU2020113751A (ko)
SG (1) SG11202002380YA (ko)
TW (1) TW201920060A (ko)
WO (1) WO2019057458A1 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3456704A1 (de) * 2017-09-19 2019-03-20 Evonik Röhm GmbH Katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
BR112020023925A2 (pt) * 2018-06-28 2021-02-09 Dow Global Technologies Llc catalisador heterogêneo, leito de catalisador, e, método para preparar metacrilato de metila.
CN112165987B (zh) * 2018-06-28 2024-05-17 陶氏环球技术有限责任公司 非均相催化剂
EP3608305A1 (en) 2018-08-10 2020-02-12 Röhm GmbH Process for producing methacrylic acid or methacrylic acid esters
CN113166028B (zh) * 2018-11-13 2024-03-12 伊士曼化工公司 使用多相au/tio2催化剂合成酯
CN111185169B (zh) * 2020-01-14 2023-02-03 上海华谊（集团）公司 用于(甲基)丙烯酸酯生产的纳米金催化剂的制备方法
JP2023519126A (ja) 2020-03-17 2023-05-10 ダウ グローバル テクノロジーズ エルエルシー 長寿命触媒による酸化的エステル化の方法及び触媒
CN111389414A (zh) * 2020-03-25 2020-07-10 张磊 用于制备羧酸酯的催化剂、其制备方法及羧酸酯的制备方法
JP2023537205A (ja) 2020-07-14 2023-08-31 ダウ グローバル テクノロジーズ エルエルシー 機械的強度が高くかつ化学的に耐性のある触媒による酸化的エステル化のためのプロセス及び触媒
WO2022248328A1 (en) * 2021-05-28 2022-12-01 Röhm Gmbh Reactor and process for producing alkyl (meth)acrylates
CA3233793A1 (en) 2021-10-08 2023-04-13 Kirk W. Limbach Process and catalyst for oxidative esterification with long-life catalyst

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2855504B2 (de) 1978-12-22 1981-02-19 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von Methacrolein
DE3213681A1 (de) 1982-04-14 1983-10-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von (alpha)-alkylacroleinen
JPH0753577B2 (ja) * 1992-10-23 1995-06-07 工業技術院長 金超微粒子固定化チタン系酸化物の製造法
KR100259743B1 (ko) 1995-07-18 2000-07-01 야마모토 카즈모토 카르복실산 에스테르 제조용 촉매
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
JP3944875B2 (ja) * 2001-09-26 2007-07-18 株式会社日本触媒 カルボン酸エステル合成用触媒及びカルボン酸エステルの製造方法
US7326806B2 (en) * 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
CN1827212A (zh) * 2001-06-04 2006-09-06 株式会社日本触媒 用于制备羧酸酯的催化剂以及制备羧酸酯的方法
WO2003053570A1 (fr) 2001-12-21 2003-07-03 Asahi Kasei Chemicals Corporation Composition catalytique d'oxyde
JP2003277323A (ja) * 2002-03-19 2003-10-02 Asahi Kasei Corp カルボン酸エステルの連続的製造方法
MY152280A (en) 2007-08-13 2014-09-15 Asahi Kasei Chemicals Corp Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters
RU2437715C1 (ru) * 2007-10-26 2011-12-27 Асахи Касеи Кемикалз Корпорейшн Материал с композитными частицами на подложке, способ его получения и способ получения соединений с использованием материала с композитными частицами на подложке в качестве катализатора для химического синтеза
EP2441747A1 (en) * 2010-10-15 2012-04-18 Petrochemicals Research Institute King Abdulaziz City for Science and Technology Method for preparation of dicarboxylic acids from linear or cyclic saturated hydrocarbons by catalytic oxidation
JP2016516732A (ja) 2013-03-18 2016-06-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ メタクリル酸及びメタクリル酸エステルの製造方法
US9890105B2 (en) * 2013-04-19 2018-02-13 Evonik Roehm Gmbh Method for producing methylmethacrylate
EP2886529A1 (en) * 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
EP2886528A1 (de) 2013-12-20 2015-06-24 Evonik Industries AG Verfahren zur Herstellung von ungesättigten Estern ausgehend von Aldehyden durch Direkte Oxidative Veresterung
CN103922929B (zh) * 2014-04-18 2016-01-27 内蒙古大学 一种气相光催化选择性氧化甲醇合成甲酸甲酯的负载型纳米Au催化剂的制备及其应用
EP3023408A1 (de) 2014-11-19 2016-05-25 Evonik Röhm GmbH Optimiertes Verfahren zur Herstellung von Methacrylsäure
US10232353B2 (en) * 2015-01-16 2019-03-19 Evonik Röhm Gmbh Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters
EP3170558A1 (de) * 2015-11-19 2017-05-24 Evonik Röhm GmbH Gold-basierten katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
EP3456704A1 (de) * 2017-09-19 2019-03-20 Evonik Röhm GmbH Katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern

Also Published As

Publication number Publication date
CN111108088A (zh) 2020-05-05
TW201920060A (zh) 2019-06-01
US20210269386A1 (en) 2021-09-02
RU2020113751A (ru) 2021-10-20
EP3456704A1 (de) 2019-03-20
KR20200051803A (ko) 2020-05-13
BR112020005175A2 (pt) 2020-09-15
EP3684751B1 (de) 2021-09-29
US20190084914A1 (en) 2019-03-21
US11279667B2 (en) 2022-03-22
JP2020534359A (ja) 2020-11-26
EP3684751A1 (de) 2020-07-29
CN111108088B (zh) 2023-10-27
WO2019057458A1 (de) 2019-03-28

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