SG11201811605YA - Controlled pressure hydrothermal treatment of odh catalyst - Google Patents

Controlled pressure hydrothermal treatment of odh catalyst

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Publication number
SG11201811605YA
SG11201811605YA SG11201811605YA SG11201811605YA SG11201811605YA SG 11201811605Y A SG11201811605Y A SG 11201811605YA SG 11201811605Y A SG11201811605Y A SG 11201811605YA SG 11201811605Y A SG11201811605Y A SG 11201811605YA SG 11201811605Y A SG11201811605Y A SG 11201811605YA
Authority
SG
Singapore
Prior art keywords
international
calgary
rule
alberta
applicant
Prior art date
Application number
SG11201811605YA
Inventor
Vasily Simanzhenkov
Xiaoliang Gao
David Sullivan
Hanna Drag
Marie Barnes
Original Assignee
Nova Chem Int Sa
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Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of SG11201811605YA publication Critical patent/SG11201811605YA/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057Selenium or tellurium; Compounds thereof
    • B01J27/0576Tellurium; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/28Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0036Grinding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/04Ethylene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/55Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/56Niobium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/68Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20Vanadium, niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20Vanadium, niobium or tantalum
    • C07C2523/22Vanadium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/057Selenium or tellurium; Compounds thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property MD 1101111 0 DOI HIM 011101 0 011111111111111111111111111011111111111110111111 Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\"\" WO 2018/015851 A3 25 January 2018 (25.01.2018) WI P0 I P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every B01J 37/10 (2006.01) B01J 23/28 (2006.01) kind of national protection available): AE, AG, AL, AM, B01J 23/00 (2006.01) CO7C 5/48 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, BO1J 3/04 (2006.01) CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, (21) International Application Number: DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, PCT/IB2017/054255 HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, (22) International Filing Date: MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, 13 July 2017 (13.07.2017) OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, (25) Filing Language: English SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (26) Publication Language: English (84) Designated States (unless otherwise indicated, for every (30) Priority Data: kind of regional protection available): ARIPO (BW, GH, 2936448 19 July 2016 (19.07.2016) CA GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, (71) Applicant: NOVA CHEMICALS (INTERNATIONAL) UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, S.A. [CH/CH]; Avenue de la Gare 14, 1700 Fribourg (CH). EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, (72) Inventors: SIMANZHENKOV, Vasily; 484 Rocky Ridge MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, Drive NW, Calgary, Alberta T3G 5C3 (CA). GAO, Xi- TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, _ aoliang; 811 Edgemont Road NW, Calgary, Alberta T3A KM, ML, MR, NE, SN, TD, TG). 2J1 (CA). SULLIVAN, David; 534 - 28th Avenue NW, Calgary, Alberta T2M 2K8 (CA). DRAG, Hanna; 59 = = Cranbrook Crescent SE, Calgary, Alberta T3M 2C3 (CA). BARNES, Marie; 236 Panamount View NW, Calgary, Al- = - berta T3K 0A6 (CA). = = Title: CONTROLLED PRESSURE HYDROTHERMAL TREATMENT OF ODH CATALYST = (54) = (57) : The preparation of an oxidative dehydrogenation catalyst comprising Mo, V, Nb and FIGURE 1 Te using a hydrothermal step the activity and reproducibility of the catalyst is improved by conduction the hydrothermal step at higher pressures while permitting gaseous products to leave the reactor. In some instances a condenser may be upstream of the pressure relief valve. = = = -- 11 = 1 711 II I — = ildoi = NI HOE ill = = HOE _ — 11 = M 11 ir) GC ir) 12 11 -Ill © ,-.... I 11 © ei C [Continued on next page] WO 2018/015851 A3 MIDEDIMOMOIDEIRDERIO 0111111 VIII 1111111111 1111111111111101110 II Declarations under Rule 4.17: — as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(11)) — as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) — of inventorship (Rule 4.17(iv)) Published: — with international search report (Art. 21(3)) — before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) (88) Date of publication of the international search report: 01 March 2018 (01.03.2018)
SG11201811605YA 2016-07-19 2017-07-13 Controlled pressure hydrothermal treatment of odh catalyst SG11201811605YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2936448A CA2936448C (en) 2016-07-19 2016-07-19 Controlled pressure hydrothermal treatment of odh catalyst
PCT/IB2017/054255 WO2018015851A2 (en) 2016-07-19 2017-07-13 Controlled pressure hydrothermal treatment of odh catalyst

Publications (1)

Publication Number Publication Date
SG11201811605YA true SG11201811605YA (en) 2019-02-27

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Country Status (14)

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US (1) US10589258B2 (en)
EP (2) EP4212247A1 (en)
JP (1) JP6987118B2 (en)
KR (1) KR102310640B1 (en)
CN (1) CN109475860B (en)
AU (1) AU2017300985A1 (en)
BR (1) BR112019001075B1 (en)
CA (1) CA2936448C (en)
CL (1) CL2019000041A1 (en)
ES (1) ES2942667T3 (en)
MX (1) MX2019000510A (en)
PE (1) PE20190274A1 (en)
SG (1) SG11201811605YA (en)
WO (1) WO2018015851A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2900775C (en) * 2015-08-20 2023-10-10 Nova Chemicals Corporation Improved oxidative dehydrogenation catalyst
CN106092121B (en) * 2016-05-27 2017-11-24 百度在线网络技术(北京)有限公司 Automobile navigation method and device
CA2993683A1 (en) * 2018-02-02 2019-08-02 Nova Chemicals Corporation Method for in situ high activity odh catalyst
CA2999092A1 (en) 2018-03-26 2019-09-26 Nova Chemicals Corporation Calcination process to produce enhanced odh catlyst
WO2020016828A2 (en) 2018-07-19 2020-01-23 Nova Chemicals (International) S.A. Catalysts for the oxidative dehydrogenation of alkanes
CA3050720A1 (en) 2018-08-03 2020-02-03 Nova Chemicals Corporation Oxidative dehydrogenation catalyst compositions
CA3050795A1 (en) 2018-08-03 2020-02-03 Nova Chemicals Corporation Oxidative dehydrogenation catalysts
MX2023007911A (en) 2021-02-04 2023-07-13 Nova Chem Int Sa Mixed metal oxide catalyst containing tantalum for odh of ethane.

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2893539B2 (en) * 1988-10-05 1999-05-24 三菱化学株式会社 Method for producing vanadium-phosphorus crystalline oxide and catalyst containing the same
JP3168716B2 (en) * 1992-02-04 2001-05-21 三菱化学株式会社 Nitrile manufacturing method
JP2000143244A (en) * 1998-07-24 2000-05-23 Mitsubishi Chemicals Corp Production of multiple metal oxide
ES2192983B1 (en) 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. A CATALYST FOR OXIDATIVE DEHYDROGENATION FROM ETANO TO ETENO.
US20050054869A1 (en) * 2003-06-06 2005-03-10 Lugmair Claus G. Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same
JP5517407B2 (en) * 2004-06-09 2014-06-11 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing multi-metal oxide material
DE102004049914A1 (en) * 2004-10-13 2006-04-20 Süd-Chemie AG Hydrothermal synthesis in pressure vessels
US20080248947A1 (en) * 2007-04-03 2008-10-09 Zajac Gerry W Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons
WO2009106474A2 (en) 2008-02-25 2009-09-03 Olaf Timpe Phase-enriched movtenb mixed oxide catalyst and methods for the preparation thereof
JP4979087B2 (en) * 2008-04-23 2012-07-18 株式会社豊田中央研究所 Composite oxide powder, production method and production apparatus thereof, and exhaust gas purification catalyst
US8105971B2 (en) 2009-04-02 2012-01-31 Lummus Technology Inc. Process for making catalysts useful for the conversion of paraffins to olefins
US8519210B2 (en) 2009-04-02 2013-08-27 Lummus Technology Inc. Process for producing ethylene via oxidative dehydrogenation (ODH) of ethane
JP5462074B2 (en) * 2009-05-27 2014-04-02 昭和電工株式会社 Alkene production catalyst, its production method and alkene production method
WO2013026720A1 (en) * 2011-08-25 2013-02-28 Solvay Sa Process for the manufacture of 1,2 - dichloroethane (dce)
EP2830758B1 (en) * 2012-03-28 2018-10-24 Rohm and Haas Company Process for making ethylene and acetic acid
US9409156B2 (en) * 2012-10-19 2016-08-09 Instituto Mexicano Del Petroleo Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
US9908101B2 (en) 2012-11-07 2018-03-06 Council Of Scientific & Industrial Research Catalyst for selective dehydrogenation / oxidative dehydrogenation reactions and process for the preparation thereof
CN203469946U (en) * 2013-08-21 2014-03-12 江苏康恒化工有限公司 Pressure relief device of high pressure kettle
DE102013014241A1 (en) 2013-08-27 2015-03-05 Linde Aktiengesellschaft Process for the preparation of a catalyst, catalyst and process for the oxidative dehydrogenation of hydrocarbons
CA2833822C (en) * 2013-11-21 2020-08-04 Nova Chemicals Corporation Inherently safe odh operation
KR20170076657A (en) * 2014-09-05 2017-07-04 네오 퍼포먼스 메터리얼즈 (싱가포르) 프라이베이트 리미티드 High porosity cerium and zirconium containing oxide
CA2900775C (en) * 2015-08-20 2023-10-10 Nova Chemicals Corporation Improved oxidative dehydrogenation catalyst

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Publication number Publication date
JP2019527134A (en) 2019-09-26
KR102310640B1 (en) 2021-10-12
CN109475860A (en) 2019-03-15
CA2936448C (en) 2024-02-20
JP6987118B2 (en) 2021-12-22
EP3487621B1 (en) 2023-03-08
WO2018015851A2 (en) 2018-01-25
EP4212247A1 (en) 2023-07-19
WO2018015851A3 (en) 2018-03-01
CN109475860B (en) 2022-05-27
MX2019000510A (en) 2019-03-28
CL2019000041A1 (en) 2019-04-26
BR112019001075A2 (en) 2019-08-13
ES2942667T3 (en) 2023-06-05
PE20190274A1 (en) 2019-02-25
CA2936448A1 (en) 2018-01-19
EP3487621A2 (en) 2019-05-29
KR20190030651A (en) 2019-03-22
US10589258B2 (en) 2020-03-17
AU2017300985A1 (en) 2019-01-31
BR112019001075B1 (en) 2022-12-20
US20180021760A1 (en) 2018-01-25

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