SG11201809747TA - Catalytic support and uses thereof - Google Patents

Catalytic support and uses thereof

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Publication number
SG11201809747TA
SG11201809747TA SG11201809747TA SG11201809747TA SG11201809747TA SG 11201809747T A SG11201809747T A SG 11201809747TA SG 11201809747T A SG11201809747T A SG 11201809747TA SG 11201809747T A SG11201809747T A SG 11201809747TA SG 11201809747T A SG11201809747T A SG 11201809747TA
Authority
SG
Singapore
Prior art keywords
road
international
bangkok
oxford
bangsue
Prior art date
Application number
SG11201809747TA
Inventor
Dermot O'hare
Jean-Charles Buffet
Alexander Kilpatrick
Ekisath Somsook
Nitiphat Nealmongkolrattana
Sumate Charoenchaidet
Saovalak Sripothongnak
Original Assignee
Scg Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scg Chemicals Co Ltd filed Critical Scg Chemicals Co Ltd
Publication of SG11201809747TA publication Critical patent/SG11201809747TA/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01Sulfonic acids
    • C07C309/02Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/04Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing only one sulfo group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/24Halogenated derivatives
    • C07C39/26Halogenated derivatives monocyclic monohydroxylic containing halogen bound to ring carbon atoms
    • C07C39/27Halogenated derivatives monocyclic monohydroxylic containing halogen bound to ring carbon atoms all halogen atoms being bound to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/061Aluminium compounds with C-aluminium linkage
    • C07F5/066Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 11111110111101111111111111111111111 0111011111111111011111100111111111011110111111 Organization 0 International Bureau (10) International Publication Number (43) International Publication Date .......'\" WO 2017/191467 Al 09 November 2017 (09.11.2017) W I P0 I P C T (51) International Patent Classification: SCG Chemicals Co., Ltd., 1 Siam Cement Road, Bangsue, C07F 5/06 (2006.01) Bangkok, 10800 (TH). CHAROENCHAIDET, Sumate; (21) International Application Number: SCG Chemicals Co., Ltd., 1 Siam Cement Road, Bangsue, PCT/GB2017/051257 Bangkok, 10800 (TH). SRIPOTHONGNAK, Saovalak; SCG Chemicals Co., Ltd., 1 Siam Cement Road, Bangsue, (22) International Filing Date: Bangkok, 10800 (TH). 05 May 2017 (05.05.2017) (74) Agent: HGF LIMITED; 4th Floor, Merchant Exchange, (25) Filing Language: English 17-19 Whitworth Street West, Manchester M1 5WG (GB). (26) Publication Language: English (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, (30) Priority Data: AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, 1607989.9 06 May 2016 (06.05.2016) GB CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, (71) Applicant: SCG CHEMICALS CO., LTD. [TH/TH]; 1 DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, Siam Cement Road, Bangsue, Bangkok, 10800 (TH). HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, (72) Inventors: O'HARE, Dermot; University of Oxford, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, Chemistry Research Laboratory, 12 Mansfield Road, Ox- PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, ford OX1 3TA (GB). BUFFET, Jean-Charles; University SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, of Oxford, Chemistry Research Laboratory, 12 Mansfield TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. _ Road, Oxford OX1 3TA (GB). KILPATRICK, Alexan- der; University of Oxford, Chemistry Research Laboratory, (84) Designated States (unless otherwise indicated, for every 12 Mansfield Road, Oxford OX1 3TA (GB). SOMSOOK, kind of regional protection available): ARIPO (BW, GH, = Ekisath; Mahidol University, NANOCAST Laboratory, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, Center for Catalysis, Department of Chemistry and Cen- UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, = — ter of Excellence for Innovation in Chemistry, Faculty TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, of Science, 272 Rama VI Road, Ratchathewi, Bangkok, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, _ 10400 (TH). NEALMONGKOLRATTANA, Nitiphat; MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, = Title: CATALYTIC SUPPORT AND USES THEREOF = (54) = • .,.g.. .... „ ,. = ni i ii / , . , = = = = A 1 ' .., SI„ 3i:' WV\" qn, , / , W4. M :,,, y/ Vi% Il c, ove V: 04,, so s 4 '1 , 0'V 4%('‘ , :: , „, VW, z. , /,: , 1\", ,, , 'MI V , eA , :0/$ IN 71- 1-1 FIGURE 1 01 1-1 IN ,-1 (57) : Solid-phase supported materials are described for use in supporting metallocene catalytic compounds. The supported 0 metallocene catalytic compositions are efficient olefm polymerisation catalysts, which show notably higher catalytic activity compared ei to catalytic compounds employing conventional support materials. [Continued on next page] WO 2017/191467 Al MIDEDIMOMMIDIRMEMOMOICIMMIEINHHEVOIMIE TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3))
SG11201809747TA 2016-05-06 2017-05-05 Catalytic support and uses thereof SG11201809747TA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1607989.9A GB201607989D0 (en) 2016-05-06 2016-05-06 Catalytic support and the uses thereof
PCT/GB2017/051257 WO2017191467A1 (en) 2016-05-06 2017-05-05 Catalytic support and uses thereof

Publications (1)

Publication Number Publication Date
SG11201809747TA true SG11201809747TA (en) 2018-12-28

Family

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SG11201809747TA SG11201809747TA (en) 2016-05-06 2017-05-05 Catalytic support and uses thereof

Country Status (8)

Country Link
US (1) US20190345273A1 (en)
EP (1) EP3452487B1 (en)
JP (1) JP7233929B2 (en)
KR (1) KR20190005176A (en)
CN (1) CN109071569B (en)
GB (1) GB201607989D0 (en)
SG (1) SG11201809747TA (en)
WO (1) WO2017191467A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112645972B (en) * 2019-10-11 2023-11-21 浙江大学 Method for preparing modified alkylaluminoxane

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3196419B2 (en) * 1993-05-20 2001-08-06 出光興産株式会社 Aluminum oxy compound and polymerization catalyst containing the same
US6696379B1 (en) * 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
CN1270595A (en) * 1997-09-19 2000-10-18 陶氏化学公司 Modified alumoxane catalyst activator
US6664208B1 (en) * 1999-09-07 2003-12-16 Sumitomo Chemical Company, Limited Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer
SG74749A1 (en) * 1998-09-09 2000-08-22 Sumitomo Chemical Co Modified aluminium oxy compound polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocaron polymer
JP2001081124A (en) * 1999-09-17 2001-03-27 Sumitomo Chem Co Ltd Catalyst for addition polymerization, and method for producing olefinic polymer
EP1436332A2 (en) * 2001-10-12 2004-07-14 Dow Global Technologies Inc. Metal complex compositions and their use as catalysts to produce polydienes
CA2503461A1 (en) * 2005-04-01 2006-10-01 Nova Chemicals Corporation Modified (mao + aluminum alkyl) activator
US20140142261A1 (en) * 2012-11-20 2014-05-22 Lion Copolymer, Inc Process for the polymerization of alpha olefins and non-conjugated dienes using a toluene free homogenous co-catalyst system with metallocene pro-catalysts
JP6357331B2 (en) * 2014-03-26 2018-07-11 三井化学株式会社 Olefin polymerization catalyst
US10124326B2 (en) * 2014-09-30 2018-11-13 Sumitomo Chemical Company, Limited Modified solid polyalkylaluminoxane and catalyst for olefin oligomerization reaction

Also Published As

Publication number Publication date
CN109071569A (en) 2018-12-21
JP7233929B2 (en) 2023-03-07
EP3452487B1 (en) 2021-09-08
WO2017191467A1 (en) 2017-11-09
EP3452487A1 (en) 2019-03-13
GB201607989D0 (en) 2016-06-22
KR20190005176A (en) 2019-01-15
JP2019514680A (en) 2019-06-06
CN109071569B (en) 2021-07-16
US20190345273A1 (en) 2019-11-14

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