SG11201807182YA - Method for improving ziegler-natta catalyst activity - Google Patents

Method for improving ziegler-natta catalyst activity

Info

Publication number
SG11201807182YA
SG11201807182YA SG11201807182YA SG11201807182YA SG11201807182YA SG 11201807182Y A SG11201807182Y A SG 11201807182YA SG 11201807182Y A SG11201807182Y A SG 11201807182YA SG 11201807182Y A SG11201807182Y A SG 11201807182YA SG 11201807182Y A SG11201807182Y A SG 11201807182YA
Authority
SG
Singapore
Prior art keywords
catalyst
international
precursor composition
aluminum alkyl
titanium compound
Prior art date
Application number
SG11201807182YA
Other languages
English (en)
Inventor
Kevin J Cann
Michael D Awe
Wesley R Mariott
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of SG11201807182YA publication Critical patent/SG11201807182YA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421Titanium tetrahalides with organo-aluminium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/655Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/655Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C08F4/6555Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
SG11201807182YA 2016-03-01 2017-02-28 Method for improving ziegler-natta catalyst activity SG11201807182YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662301894P 2016-03-01 2016-03-01
PCT/US2017/019910 WO2017151592A1 (en) 2016-03-01 2017-02-28 Method for improving ziegler-natta catalyst activity

Publications (1)

Publication Number Publication Date
SG11201807182YA true SG11201807182YA (en) 2018-09-27

Family

ID=58410438

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201807182YA SG11201807182YA (en) 2016-03-01 2017-02-28 Method for improving ziegler-natta catalyst activity

Country Status (10)

Country Link
US (1) US11180582B2 (ko)
EP (1) EP3423501B9 (ko)
JP (1) JP6880052B2 (ko)
KR (1) KR20180118677A (ko)
CN (1) CN108713030B (ko)
BR (1) BR112018017259B1 (ko)
CA (1) CA3015676C (ko)
ES (1) ES2877475T3 (ko)
SG (1) SG11201807182YA (ko)
WO (1) WO2017151592A1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102331018B1 (ko) * 2016-08-12 2021-11-26 아미리스 인코퍼레이티드 레바우디오시드의 고효율 생산을 위한 udp 의존성 글리코실트랜스퍼라제
SG11202004922SA (en) 2017-12-05 2020-06-29 Univation Tech Llc Modified spray-dried ziegler-natta (pro)catalyst systems
WO2019112927A1 (en) 2017-12-05 2019-06-13 Univation Technologies, Llc Activated spray-dried ziegler-natta catalyst system
US11248066B2 (en) 2018-06-13 2022-02-15 Univation Technologies, Llc Spray-dried Ziegler-Natta (pro)catalyst systems

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3815486A1 (de) 1988-05-06 1989-11-16 Basf Ag Katalysator fuer die polymerisation von ethylen, verfahren zu dessen herstellung und verwendung der erhaltenen ethylenpolymerisate zur herstellung von folien mit geringen blockeigenschaften
US5047468A (en) 1988-11-16 1991-09-10 Union Carbide Chemicals And Plastics Technology Corporation Process for the in situ blending of polymers
JP2752404B2 (ja) * 1989-01-10 1998-05-18 三菱化学株式会社 オレフィン重合用触媒
CN1098867C (zh) 1998-01-14 2003-01-15 中国石油化工集团公司 淤浆法全密度聚乙烯高效催化剂
TR200103809T2 (tr) * 1999-06-30 2002-05-21 Union Carbide Chemicals & Plastics Technology Corporation Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri
US6306985B1 (en) * 1999-07-13 2001-10-23 China Petrochemical Corporation High activity solid catalyst for producing low-, medium-, and high-density polyethylenes by slurry phase polymerization, process for preparing the same and use of the same in ethylene polymerization
EP1572760B1 (en) 2002-12-18 2016-12-07 Borealis Technology Oy Method for the preparation of olefin polymerisation catalyst support and an olefin polymerisation catalyst
US7790818B2 (en) 2004-06-18 2010-09-07 Basell Polidlefine Italia s.r.l. Process for preparing catalyst components for the olefin polymerization
US7078362B2 (en) * 2004-12-09 2006-07-18 Equistar Chemicals, Lp Carbene donor-modified Ziegler-Natta catalysts
US20060281879A1 (en) * 2005-06-13 2006-12-14 Univation Technologies, Llc Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
CN101220113A (zh) * 2007-12-03 2008-07-16 北京凯华创新科技有限公司 聚乙烯催化剂及其制备方法
CN102399325B (zh) * 2010-09-16 2013-06-05 中国石油化工股份有限公司 一种用于烯烃聚合的窄粒径分布的球型催化剂组分、催化剂及应用
WO2015012963A1 (en) * 2013-07-25 2015-01-29 Exxonmobil Chemical Patents Inc. Methods for polyolefin polymerization with high activity catalyst systems
BR112017002059B1 (pt) * 2014-07-31 2021-09-14 Versalis S.P.A. Catalisador sólido para a (co)polimerizaçâo de alfa- olefinas, processo para preparar o mesmo, sistema catalítico para a (co)polimerização de alfa-olefinas e processo para a (co) polimerização de alfa-olefinas

Also Published As

Publication number Publication date
CA3015676A1 (en) 2017-09-08
KR20180118677A (ko) 2018-10-31
WO2017151592A1 (en) 2017-09-08
US11180582B2 (en) 2021-11-23
EP3423501A1 (en) 2019-01-09
CA3015676C (en) 2024-02-13
BR112018017259B1 (pt) 2022-11-16
US20210189024A1 (en) 2021-06-24
EP3423501B9 (en) 2022-03-23
CN108713030A (zh) 2018-10-26
BR112018017259A2 (pt) 2019-01-15
JP2019507224A (ja) 2019-03-14
EP3423501B1 (en) 2021-05-05
CN108713030B (zh) 2021-08-10
ES2877475T3 (es) 2021-11-16
JP6880052B2 (ja) 2021-06-02

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