SG11201403610YA - A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor - Google Patents

A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Info

Publication number
SG11201403610YA
SG11201403610YA SG11201403610YA SG11201403610YA SG11201403610YA SG 11201403610Y A SG11201403610Y A SG 11201403610YA SG 11201403610Y A SG11201403610Y A SG 11201403610YA SG 11201403610Y A SG11201403610Y A SG 11201403610YA SG 11201403610Y A SG11201403610Y A SG 11201403610YA
Authority
SG
Singapore
Prior art keywords
esters
production
carboxylic acids
ethylenically unsaturated
unsaturated carboxylic
Prior art date
Application number
SG11201403610YA
Other languages
English (en)
Inventor
Ian Andrew York
Sabina Ziemian
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of SG11201403610YA publication Critical patent/SG11201403610YA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/10Chlorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/12Fluorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/16Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/038Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/16Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14Phosphorus; Compounds thereof
    • C07C2527/16Phosphorus; Compounds thereof containing oxygen
    • C07C2527/18Phosphorus; Compounds thereof containing oxygen with metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201403610YA 2012-01-13 2013-01-14 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor SG11201403610YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1200551.8A GB201200551D0 (en) 2012-01-13 2012-01-13 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
PCT/GB2013/050062 WO2013104924A1 (en) 2012-01-13 2013-01-14 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Publications (1)

Publication Number Publication Date
SG11201403610YA true SG11201403610YA (en) 2014-09-26

Family

ID=45813970

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201403610YA SG11201403610YA (en) 2012-01-13 2013-01-14 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Country Status (17)

Country Link
US (1) US9199907B2 (zh)
EP (1) EP2802552B1 (zh)
JP (1) JP6169613B2 (zh)
KR (1) KR102037772B1 (zh)
CN (1) CN104039751B (zh)
AU (1) AU2013208789B2 (zh)
BR (1) BR112014016973B1 (zh)
CA (1) CA2862246C (zh)
ES (1) ES2675968T3 (zh)
GB (1) GB201200551D0 (zh)
IN (1) IN2014MN01558A (zh)
MX (1) MX356173B (zh)
MY (1) MY168415A (zh)
RU (1) RU2621687C2 (zh)
SG (1) SG11201403610YA (zh)
TW (1) TWI616233B (zh)
WO (1) WO2013104924A1 (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG189440A1 (en) * 2010-11-11 2013-05-31 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
GB201506308D0 (en) 2015-04-14 2015-05-27 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters
CN107126970B (zh) * 2017-04-25 2019-10-01 江苏大学 一种Nd-VPO/SiO2催化剂及其制备方法和用途
CN108993612A (zh) * 2018-08-06 2018-12-14 杨彩花 一种用于制备5-己烯酸的催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2859240A (en) * 1956-01-12 1958-11-04 Minnesota Mining & Mfg Production of acrylates by catalytic dehydration of lactic acid and alkyl lactates
GB865379A (en) * 1956-04-04 1961-04-19 Minnesota Mining & Mfg Improved acrylate synthesis
US3014958A (en) * 1960-01-15 1961-12-26 Du Pont Preparation of unsaturated esters
JPS4616728B1 (zh) * 1967-04-08 1971-05-08
US4118588A (en) * 1976-04-10 1978-10-03 Basf Aktiengesellschaft Manufacture of methacrylic acid and methyl methacrylate
CA1249576A (en) * 1984-06-25 1989-01-31 Gary P. Hagen Coformed catalyst
US4967016A (en) * 1989-05-19 1990-10-30 Shell Oil Company Alkoxylation process catalyzed by barium phosphate
GB9807498D0 (en) * 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
CN101186576A (zh) * 2007-11-26 2008-05-28 南京工业大学 一种丙烯酸酯的制备方法
TWI461476B (zh) * 2008-11-14 2014-11-21 Nisshinbo Holdings Inc A resin composition, and a transparent resin molded article and a coating film using the same
GB201011092D0 (en) * 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters
SG189440A1 (en) * 2010-11-11 2013-05-31 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Also Published As

Publication number Publication date
AU2013208789A1 (en) 2014-07-24
RU2014133183A (ru) 2016-03-10
JP6169613B2 (ja) 2017-07-26
TWI616233B (zh) 2018-03-01
CN104039751A (zh) 2014-09-10
MY168415A (en) 2018-11-09
JP2015508410A (ja) 2015-03-19
BR112014016973B1 (pt) 2019-12-24
EP2802552A1 (en) 2014-11-19
BR112014016973A8 (pt) 2017-07-04
MX2014008392A (es) 2014-08-22
GB201200551D0 (en) 2012-02-29
KR102037772B1 (ko) 2019-10-29
US20140364645A1 (en) 2014-12-11
MX356173B (es) 2018-05-17
BR112014016973A2 (pt) 2017-06-13
TW201334869A (zh) 2013-09-01
ES2675968T3 (es) 2018-07-16
CN104039751B (zh) 2017-04-12
IN2014MN01558A (zh) 2015-05-08
RU2621687C2 (ru) 2017-06-07
US9199907B2 (en) 2015-12-01
CA2862246A1 (en) 2013-07-18
WO2013104924A1 (en) 2013-07-18
EP2802552B1 (en) 2018-03-28
KR20140111329A (ko) 2014-09-18
AU2013208789B2 (en) 2017-02-02
CA2862246C (en) 2020-06-02

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