SE465543B - Foerfarande foer framstaellning av en katod foer en elektrokemisk cell med smaelt elektrolyt, katod framstaelld enligt foerfarandet samt cell foersedd med katoden - Google Patents
Foerfarande foer framstaellning av en katod foer en elektrokemisk cell med smaelt elektrolyt, katod framstaelld enligt foerfarandet samt cell foersedd med katodenInfo
- Publication number
- SE465543B SE465543B SE8702332A SE8702332A SE465543B SE 465543 B SE465543 B SE 465543B SE 8702332 A SE8702332 A SE 8702332A SE 8702332 A SE8702332 A SE 8702332A SE 465543 B SE465543 B SE 465543B
- Authority
- SE
- Sweden
- Prior art keywords
- matrix
- electrolyte
- sodium
- molten salt
- cell
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 28
- 239000011159 matrix material Substances 0.000 claims description 106
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 105
- 239000003792 electrolyte Substances 0.000 claims description 63
- 239000011780 sodium chloride Substances 0.000 claims description 52
- 239000002245 particle Substances 0.000 claims description 48
- -1 sodium-aluminum halide Chemical class 0.000 claims description 30
- 238000010438 heat treatment Methods 0.000 claims description 27
- 239000007858 starting material Substances 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 22
- 239000011734 sodium Substances 0.000 claims description 20
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 230000015572 biosynthetic process Effects 0.000 claims description 16
- 230000003647 oxidation Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- 230000009467 reduction Effects 0.000 claims description 15
- 230000002829 reductive effect Effects 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 14
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- 239000004020 conductor Substances 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 230000001590 oxidative effect Effects 0.000 claims description 9
- 229910001415 sodium ion Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- 238000005470 impregnation Methods 0.000 claims description 7
- 150000003624 transition metals Chemical class 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 238000010348 incorporation Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 239000004283 Sodium sorbate Substances 0.000 claims 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 claims 1
- 235000019250 sodium sorbate Nutrition 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 54
- 239000000126 substance Substances 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 13
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 230000003750 conditioning effect Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- 239000002923 metal particle Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- ZSFZQNSWHYVSDP-UHFFFAOYSA-G dialuminum;sodium;heptachloride Chemical compound [Na+].[Al+3].[Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-] ZSFZQNSWHYVSDP-UHFFFAOYSA-G 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910001508 alkali metal halide Inorganic materials 0.000 description 2
- 150000008045 alkali metal halides Chemical class 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 229910018965 MCl2 Inorganic materials 0.000 description 1
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 230000022131 cell cycle Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940050561 matrix product Drugs 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 210000000352 storage cell Anatomy 0.000 description 1
- 229910052645 tectosilicate Inorganic materials 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB868613799A GB8613799D0 (en) | 1986-06-06 | 1986-06-06 | Electrochemical cell |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE8702332D0 SE8702332D0 (sv) | 1987-06-04 |
| SE8702332L SE8702332L (sv) | 1987-12-07 |
| SE465543B true SE465543B (sv) | 1991-09-23 |
Family
ID=10599061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8702332A SE465543B (sv) | 1986-06-06 | 1987-06-04 | Foerfarande foer framstaellning av en katod foer en elektrokemisk cell med smaelt elektrolyt, katod framstaelld enligt foerfarandet samt cell foersedd med katoden |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4772449A (cs) |
| JP (1) | JPS62291873A (cs) |
| AU (1) | AU584573B2 (cs) |
| CA (1) | CA1290806C (cs) |
| DE (1) | DE3718921C2 (cs) |
| FR (1) | FR2599894B1 (cs) |
| GB (2) | GB8613799D0 (cs) |
| IT (1) | IT1205125B (cs) |
| SE (1) | SE465543B (cs) |
| ZA (1) | ZA873940B (cs) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8613800D0 (en) * | 1986-06-06 | 1986-07-09 | Lilliwyte Sa | Electrochemical cell |
| GB8613796D0 (en) * | 1986-06-06 | 1986-07-09 | Lilliwyte Sa | Electrochemical cell |
| GB8812586D0 (en) * | 1988-05-27 | 1988-06-29 | Lilliwyte Sa | Electrochemical cell |
| GB8828230D0 (en) * | 1988-12-02 | 1989-01-05 | Lilliwyte Sa | Electrochemical cell |
| US4971755A (en) * | 1989-03-20 | 1990-11-20 | Kawasaki Steel Corporation | Method for preparing powder metallurgical sintered product |
| US4975344A (en) * | 1989-12-01 | 1990-12-04 | Lilliwyte Societe Anonyme | Electrochemical cell |
| GB9005485D0 (en) * | 1990-03-12 | 1990-05-09 | Aabh Patent Holdings | Electrochemical cell |
| GB9005484D0 (en) * | 1990-03-12 | 1990-05-09 | Lilliwyte Sa | Electrochemical cell |
| GB9011035D0 (en) * | 1990-05-16 | 1990-07-04 | Programme 3 Patent Holdings | Electrochemical cell |
| CA2042322A1 (en) * | 1990-05-16 | 1991-11-17 | Roger J. Bones | Electrochemical cells |
| FR2668653B1 (fr) * | 1990-10-24 | 1996-04-12 | Aabh Patent Holdings | Procede de fabrication d'un element accumulateur electrochimique et d'un precurseur de celui-ci et precurseur ainsi obtenu. |
| US5229221A (en) * | 1992-04-16 | 1993-07-20 | Electric Power Research Institute, Inc. | Methods of making anodes for high temperature fuel cells |
| US5312580A (en) * | 1992-05-12 | 1994-05-17 | Erickson Diane S | Methods of manufacturing porous metal alloy fuel cell components |
| IT1269906B (it) * | 1993-04-02 | 1997-04-16 | Programme 3 Patent Holding | Cella elettrochimica |
| US5476732A (en) * | 1993-04-02 | 1995-12-19 | Programme 3 Patent Holdings | Electrochemical cell |
| AU686091B2 (en) * | 1994-06-08 | 1998-01-29 | Programme 3 Patent Holdings | Electrochemical cell |
| GB9512971D0 (en) * | 1995-06-26 | 1995-08-30 | Programme 3 Patent Holdings | Electrochemical cell |
| JP3012795B2 (ja) * | 1995-11-01 | 2000-02-28 | 核燃料サイクル開発機構 | 放射性廃液の処理方法 |
| US5972533A (en) * | 1996-02-29 | 1999-10-26 | Electro Chemical Holdings Societe Anonyme | Electrochemical cell comprising a molten salt electrolyte containing sodium iodide |
| US6007943A (en) * | 1997-02-06 | 1999-12-28 | Electro Chemical Holdings Societe Anonyme | High temperature electrochemical cell with molten alkali metal anode |
| GB2445972B (en) * | 2007-01-25 | 2010-12-29 | Beta Res & Dev Ltd | Cathode for an electrochemical cell |
| US20110104563A1 (en) * | 2009-11-04 | 2011-05-05 | General Electric Company | Electrochemical cell |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1011970A (fr) * | 1949-05-07 | 1952-07-02 | Procédé de préparation de dépolarisant pour pile | |
| US3345212A (en) * | 1964-02-18 | 1967-10-03 | Esb Inc | Electrolytic process for preparing iron |
| DE2738456A1 (de) * | 1977-08-26 | 1979-03-01 | Daimler Benz Ag | Verfahren zur herstellung von eisenhaltigen sinterelektroden |
| CA1149865A (en) * | 1979-08-22 | 1983-07-12 | Margaretha J. Nolte | Electrolyte for an electrochemical cell, and an electrochemical cell including the electrolyte |
| US4356101A (en) * | 1981-04-16 | 1982-10-26 | Westinghouse Electric Corp. | Iron active electrode and method of making same |
| ZA828603B (en) * | 1981-12-10 | 1983-09-28 | South African Inventions | Electrochemical cell |
| GB8314235D0 (en) * | 1983-05-23 | 1983-06-29 | Ind Distributors Shannon Ltd | Electrochemical cell |
| GB2143671B (en) * | 1983-07-22 | 1986-10-15 | South African Inventions | Protecting iron/iron chloride/sodium type cells |
| GB8319749D0 (en) * | 1983-07-22 | 1983-08-24 | Ind Distributors Shannon Ltd | Electrochemical cell |
| AU566856B2 (en) * | 1984-05-28 | 1987-10-29 | Lilliwyte Societe Anonyme | Electrochemcial cell with fluoride in electrolyte |
| GB8423961D0 (en) * | 1984-09-21 | 1984-10-31 | Lilliwyte Sa | Electrochemical cells |
| GB8523444D0 (en) * | 1985-09-23 | 1985-10-30 | Lilliwyte Sa | Electrochemical cell |
-
1986
- 1986-06-06 GB GB868613799A patent/GB8613799D0/en active Pending
-
1987
- 1987-06-02 ZA ZA873940A patent/ZA873940B/xx unknown
- 1987-06-03 CA CA000538666A patent/CA1290806C/en not_active Expired - Fee Related
- 1987-06-03 AU AU73773/87A patent/AU584573B2/en not_active Ceased
- 1987-06-04 SE SE8702332A patent/SE465543B/sv not_active IP Right Cessation
- 1987-06-04 GB GB8713065A patent/GB2191333B/en not_active Expired
- 1987-06-05 FR FR8707924A patent/FR2599894B1/fr not_active Expired - Fee Related
- 1987-06-05 IT IT20806/87A patent/IT1205125B/it active
- 1987-06-05 DE DE3718921A patent/DE3718921C2/de not_active Expired - Fee Related
- 1987-06-05 JP JP62141312A patent/JPS62291873A/ja active Granted
- 1987-06-05 US US07/058,829 patent/US4772449A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3718921C2 (de) | 1994-11-17 |
| GB8713065D0 (en) | 1987-07-08 |
| GB2191333B (en) | 1989-12-13 |
| GB8613799D0 (en) | 1986-07-09 |
| SE8702332D0 (sv) | 1987-06-04 |
| AU584573B2 (en) | 1989-05-25 |
| FR2599894A1 (fr) | 1987-12-11 |
| FR2599894B1 (fr) | 1993-12-31 |
| DE3718921A1 (de) | 1987-12-17 |
| AU7377387A (en) | 1987-12-10 |
| JPS62291873A (ja) | 1987-12-18 |
| CA1290806C (en) | 1991-10-15 |
| ZA873940B (en) | 1988-01-27 |
| IT1205125B (it) | 1989-03-15 |
| IT8720806A0 (it) | 1987-06-05 |
| GB2191333A (en) | 1987-12-09 |
| US4772449A (en) | 1988-09-20 |
| SE8702332L (sv) | 1987-12-07 |
| JPH0588516B2 (cs) | 1993-12-22 |
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