SE329261B - - Google Patents
Info
- Publication number
- SE329261B SE329261B SE893964A SE893964A SE329261B SE 329261 B SE329261 B SE 329261B SE 893964 A SE893964 A SE 893964A SE 893964 A SE893964 A SE 893964A SE 329261 B SE329261 B SE 329261B
- Authority
- SE
- Sweden
- Prior art keywords
- polyamide
- water
- ethenoxylated
- ethylene oxide
- pressure
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/59—Polyamides; Polyimides
- D06M15/595—Derivatives obtained by substitution of a hydrogen atom of the carboxamide radical
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
- D06P1/6073—Nitrogen-containing polyethers or their quaternary derivatives containing CON=, OCON=, SO2N=, OSO2N= groups
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polyamides (AREA)
Abstract
A finishing agent for synthetic fibres and fabrics comprises an aqueous solution of an ethenoxylated polyamide which is produced by reacting 1 part by weight of polyamide with 2.5-3.5 parts by weight of ethylene oxide at 80-100 DEG C. and a pressure between 2 atmospheres gauge and the liquifaction pressure of the ethylene oxide and dissolving the product in water at 90-150 DEG C. The polyamide may be produced in the presence of an acid or neutral catalyst from pentamethylene diamine, hexamethylene diamine, and/or decamethylene diamine or salts thereof, adipic, pimelic, sebacic, terephthalic, phenylene diacetic or phenylene dipropionic acids or derivatives thereof having oxygen or sulphur in the carbon chain, o -amino-butyric, caproic, caprylic, capric, undecanic and dodecanic acids or lactams thereof. Their water content may be reduced to less than 1%. Unreacted ethylene oxide may be recovered by restoring atmospheric pressure within the reaction vessel and condensing the issuing gas. The ethenoxylated polyamide may be dissolved in the presence of a solubilizer, or oxidizing or reducing agent. Solubilizers specified are: ethanol, propanol, ethylene glycol, ethylene glycol monomethyl ether, T.H.F., dioxane, acetone, H2SO4, H3PO4, H3BO3, HCOOH, CH3COOH. 20-200% may be used. 0.05-1% H2O2 may be used as oxidizing or reducing agent. Other suitable reducing agents are NaBH4 and sodium hypophosphite. The colloidal solution may contain 1-50% of the ethenoxylated polymer. The water may be allowed to evaporate and the product redissolved in hot water.ALSO:The water-absorbency of fibres, fabrics and sheets may be increased by impregnating them with an aqueous colloidal dispersion of an ethenoxylated polyamide. The solution is prepared by treating a polyamide with 2.5-3.5 times its own weight of ethylene oxide at 80 DEG -100 DEG C. and a pressure between 2 atmospheres and the liquifaction pressure of ethylene oxide and dispersing the reaction product in water at 90 DEG -150 DEG C. Polyamides specified include nylon 6/66 and nylon 6.20-50% of the ethenoxylated polyamide may be dispersed in water in the presence of a solubilizing agent, e.g. EtoH. 0.05-1% of an oxidizing agent, e.g. H2O2, or 0.05-0.5% of a reducing agent may also be present during dispersion. The pH of the dispersion may be adjusted to 3-7, e.g. with acetic acid. The viscous or gelatinous dispersion may be diluted with water before impregnation to 1-10% concentration. The impregnation may be at elevated temperature using a foulard or by steeping and drying.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1963B0072814 DE1298713B (en) | 1963-07-24 | 1963-07-24 | Process for the preparation of colloidal solutions of alkoxylated polyamides in water |
Publications (1)
Publication Number | Publication Date |
---|---|
SE329261B true SE329261B (en) | 1970-10-05 |
Family
ID=6977600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE893964A SE329261B (en) | 1963-07-24 | 1964-07-22 |
Country Status (7)
Country | Link |
---|---|
AT (1) | AT249630B (en) |
BE (1) | BE650833A (en) |
CH (1) | CH433719A (en) |
DE (1) | DE1298713B (en) |
GB (1) | GB1063629A (en) |
NL (1) | NL6408327A (en) |
SE (1) | SE329261B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1540722A (en) | 1975-04-15 | 1979-02-14 | Unilever Ltd | Fabric treatment compositions |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE907701C (en) * | 1940-05-20 | 1954-03-29 | Basf Ag | Process for the production of conversion products of superpolyamides |
DE913957C (en) * | 1951-12-30 | 1954-06-24 | Basf Ag | Process for the alkoxylation of thermoplastics |
-
1963
- 1963-07-24 DE DE1963B0072814 patent/DE1298713B/en active Pending
-
1964
- 1964-06-25 CH CH835264A patent/CH433719A/en unknown
- 1964-07-10 GB GB2851764A patent/GB1063629A/en not_active Expired
- 1964-07-21 NL NL6408327A patent/NL6408327A/xx unknown
- 1964-07-22 AT AT631164A patent/AT249630B/en active
- 1964-07-22 BE BE650833D patent/BE650833A/xx unknown
- 1964-07-22 SE SE893964A patent/SE329261B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
BE650833A (en) | 1965-01-22 |
AT249630B (en) | 1966-09-26 |
DE1298713B (en) | 1969-07-03 |
CH433719A (en) | 1967-04-15 |
NL6408327A (en) | 1965-01-25 |
GB1063629A (en) | 1967-03-30 |
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