SA515360389B1 - عملية مؤكسدة لإزالة الكبريت ونظام يستخدم تغذية معززة بمادة مؤكسدة غازية - Google Patents
عملية مؤكسدة لإزالة الكبريت ونظام يستخدم تغذية معززة بمادة مؤكسدة غازية Download PDFInfo
- Publication number
- SA515360389B1 SA515360389B1 SA515360389A SA515360389A SA515360389B1 SA 515360389 B1 SA515360389 B1 SA 515360389B1 SA 515360389 A SA515360389 A SA 515360389A SA 515360389 A SA515360389 A SA 515360389A SA 515360389 B1 SA515360389 B1 SA 515360389B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- gaseous oxidant
- hydrocarbon
- mpa
- feedstock
- hydrocarbon feedstock
- Prior art date
Links
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 47
- 239000007800 oxidant agent Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 34
- 230000008569 process Effects 0.000 title claims abstract description 26
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 16
- 230000023556 desulfurization Effects 0.000 title claims abstract description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 42
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 41
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 32
- 239000007791 liquid phase Substances 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 150000002978 peroxides Chemical class 0.000 claims abstract 8
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 7
- 230000002000 scavenging effect Effects 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- -1 organic sulfur compounds hydrocarbon Chemical class 0.000 claims description 4
- 230000033228 biological regulation Effects 0.000 claims description 3
- 239000002638 heterogeneous catalyst Substances 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims 3
- 238000000926 separation method Methods 0.000 claims 2
- 241000196324 Embryophyta Species 0.000 claims 1
- 101100033673 Mus musculus Ren1 gene Proteins 0.000 claims 1
- KWRGRUMGKJGCKH-OXQOHEQNSA-N allad Chemical compound C1=CC=C2C3=C[C@@H](C(=O)N(CC)CC)CN(CC=C)[C@@H]3CC3=CN=C1[C]32 KWRGRUMGKJGCKH-OXQOHEQNSA-N 0.000 claims 1
- 238000004321 preservation Methods 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 description 51
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 50
- 239000011593 sulfur Substances 0.000 description 50
- 239000007789 gas Substances 0.000 description 21
- 239000003921 oil Substances 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 17
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 17
- 239000000446 fuel Substances 0.000 description 13
- 239000012071 phase Substances 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000009835 boiling Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 229930192474 thiophene Natural products 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000003577 thiophenes Chemical class 0.000 description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 230000002452 interceptive effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- AXDZBUZLJGBONR-UHFFFAOYSA-N 1,2-dimethyldibenzothiophene Chemical compound C1=CC=C2C3=C(C)C(C)=CC=C3SC2=C1 AXDZBUZLJGBONR-UHFFFAOYSA-N 0.000 description 1
- VUQVGKNLSOSINI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1.C1=CC=C2SC=CC2=C1 VUQVGKNLSOSINI-UHFFFAOYSA-N 0.000 description 1
- XMAUFBKXKDZDLJ-UHFFFAOYSA-N 1-benzothiophene;dibenzothiophene Chemical compound C1=CC=C2SC=CC2=C1.C1=CC=C2C3=CC=CC=C3SC2=C1 XMAUFBKXKDZDLJ-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- XRJUVKFVUBGLMG-UHFFFAOYSA-N naphtho[1,2-e][1]benzothiole Chemical class C1=CC=CC2=C3C(C=CS4)=C4C=CC3=CC=C21 XRJUVKFVUBGLMG-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261724672P | 2012-11-09 | 2012-11-09 | |
| PCT/US2013/069353 WO2014074958A1 (en) | 2012-11-09 | 2013-11-09 | Oxidative desulfurization process and system using gaseous oxidant-enhanced feed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA515360389B1 true SA515360389B1 (ar) | 2018-03-18 |
Family
ID=49681138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA515360389A SA515360389B1 (ar) | 2012-11-09 | 2015-05-05 | عملية مؤكسدة لإزالة الكبريت ونظام يستخدم تغذية معززة بمادة مؤكسدة غازية |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9719029B2 (https=) |
| EP (1) | EP2917307B1 (https=) |
| JP (1) | JP6144352B2 (https=) |
| KR (1) | KR102187212B1 (https=) |
| CN (1) | CN104919025B (https=) |
| SA (1) | SA515360389B1 (https=) |
| SG (1) | SG11201503610PA (https=) |
| WO (1) | WO2014074958A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG11201906156UA (en) * | 2017-01-25 | 2019-08-27 | Saudi Arabian Oil Co | Oxidative desulfurization of oil fractions and sulfone management using an fcc |
| JP2020509113A (ja) * | 2017-02-20 | 2020-03-26 | サウジ アラビアン オイル カンパニー | コーカーを用いた脱硫及びスルホン除去 |
| CN110337487A (zh) * | 2017-02-20 | 2019-10-15 | 沙特阿拉伯石油公司 | 使用fcc进行油馏分的氧化脱硫和砜管理 |
| KR20190126172A (ko) * | 2017-03-21 | 2019-11-08 | 사우디 아라비안 오일 컴퍼니 | 용매 탈아스팔팅을 이용한 산화적 탈황 및 설폰 처리 공정 |
| CN108003920B (zh) * | 2017-07-18 | 2020-12-04 | 华南理工大学 | 一种用负载型金属氧化物双功能催化吸附脱硫剂的燃料氧化脱硫方法 |
| CN107803192A (zh) * | 2017-07-18 | 2018-03-16 | 华南理工大学 | 一种燃料氧化脱硫双功能催化吸附剂清洁再生工艺 |
| US10703998B2 (en) * | 2018-10-22 | 2020-07-07 | Saudi Arabian Oil Company | Catalytic demetallization and gas phase oxidative desulfurization of residual oil |
| US11292970B2 (en) * | 2019-11-05 | 2022-04-05 | Saudi Arabian Oil Company | Hydrocracking process and system including separation of heavy poly nuclear aromatics from recycle by oxidation |
| CN116240041A (zh) * | 2023-04-06 | 2023-06-09 | 鞍钢集团北京研究院有限公司 | 一种沥青脱硫方法 |
| US11965135B1 (en) | 2023-04-12 | 2024-04-23 | Saudi Arabian Oil Company | Methods for reactivity based hydroprocessing |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2504429A (en) | 1946-04-18 | 1950-04-18 | Phillips Petroleum Co | Recovery of hydrocarbons from natural gas |
| US2749284A (en) | 1950-11-15 | 1956-06-05 | British Petroleum Co | Treatment of sulphur-containing mineral oils with kerosene peroxides |
| NL86366C (https=) * | 1953-03-12 | |||
| NL101083C (https=) * | 1958-10-24 | |||
| BE625074A (https=) | 1961-11-24 | |||
| US3767563A (en) | 1971-12-23 | 1973-10-23 | Texaco Inc | Adsorption-desorption process for removing an unwanted component from a reaction charge mixture |
| US3847800A (en) * | 1973-08-06 | 1974-11-12 | Kvb Eng Inc | Method for removing sulfur and nitrogen in petroleum oils |
| US3919402A (en) | 1973-08-06 | 1975-11-11 | Kvb Inc | Petroleum oil desulfurization process |
| US4830733A (en) | 1987-10-05 | 1989-05-16 | Uop | Integrated process for the removal of sulfur compounds from fluid streams |
| US4875997A (en) * | 1988-11-17 | 1989-10-24 | Montana Refining Company | Process for treating hydrocarbons containing mercaptans |
| CA2159785C (en) | 1994-11-11 | 2003-04-08 | Tetsuo Aida | Process for recovering organic sulfur compounds from fuel oil and equipment therefor |
| US5730860A (en) | 1995-08-14 | 1998-03-24 | The Pritchard Corporation | Process for desulfurizing gasoline and hydrocarbon feedstocks |
| US5910440A (en) | 1996-04-12 | 1999-06-08 | Exxon Research And Engineering Company | Method for the removal of organic sulfur from carbonaceous materials |
| US5824207A (en) | 1996-04-30 | 1998-10-20 | Novetek Octane Enhancement, Ltd. | Method and apparatus for oxidizing an organic liquid |
| FR2764610B1 (fr) | 1997-06-12 | 1999-09-17 | Centre Nat Rech Scient | Procede de separation de composes benzothiopheniques d'un melange d'hydrocarbures les contenant, et melange d'hydrocarbures obtenu par ce procede |
| US7291257B2 (en) | 1997-06-24 | 2007-11-06 | Process Dynamics, Inc. | Two phase hydroprocessing |
| US6087544A (en) | 1998-05-07 | 2000-07-11 | Exxon Research And Engineering Co. | Process for the production of high lubricity low sulfur distillate fuels |
| KR20010071679A (ko) * | 1998-06-29 | 2001-07-31 | 추후제출 | 분자체 씨아이티-6 |
| US6171478B1 (en) | 1998-07-15 | 2001-01-09 | Uop Llc | Process for the desulfurization of a hydrocarbonaceous oil |
| US6277271B1 (en) | 1998-07-15 | 2001-08-21 | Uop Llc | Process for the desulfurization of a hydrocarbonaceoous oil |
| US6402940B1 (en) * | 2000-09-01 | 2002-06-11 | Unipure Corporation | Process for removing low amounts of organic sulfur from hydrocarbon fuels |
| US20030094400A1 (en) | 2001-08-10 | 2003-05-22 | Levy Robert Edward | Hydrodesulfurization of oxidized sulfur compounds in liquid hydrocarbons |
| US7279253B2 (en) * | 2003-09-12 | 2007-10-09 | Canon Kabushiki Kaisha | Near-field light generating structure, near-field exposure mask, and near-field generating method |
| US7276152B2 (en) | 2004-11-23 | 2007-10-02 | Cpc Corporation, Taiwan | Oxidative desulfurization and denitrogenation of petroleum oils |
| EA011964B1 (ru) | 2004-12-29 | 2009-06-30 | Бп Корпорейшн Норт Америка Инк. | Способ десульфирования дистиллятного сырья |
| US7297253B1 (en) * | 2005-07-19 | 2007-11-20 | Uop Llc | Process for producing hydroperoxides |
| US7731837B2 (en) * | 2006-09-08 | 2010-06-08 | The Penn State Research Foundation | Oxidatively regenerable adsorbents for sulfur removal |
| US8658027B2 (en) | 2010-03-29 | 2014-02-25 | Saudi Arabian Oil Company | Integrated hydrotreating and oxidative desulfurization process |
| WO2012082851A1 (en) * | 2010-12-15 | 2012-06-21 | Saudi Arabian Oil Company | Desulfurization of hydrocarbon feed using gaseous oxidant |
-
2013
- 2013-11-09 SG SG11201503610PA patent/SG11201503610PA/en unknown
- 2013-11-09 WO PCT/US2013/069353 patent/WO2014074958A1/en not_active Ceased
- 2013-11-09 CN CN201380066824.2A patent/CN104919025B/zh not_active Expired - Fee Related
- 2013-11-09 JP JP2015541969A patent/JP6144352B2/ja not_active Expired - Fee Related
- 2013-11-09 KR KR1020157015212A patent/KR102187212B1/ko not_active Expired - Fee Related
- 2013-11-09 EP EP13798797.0A patent/EP2917307B1/en not_active Not-in-force
- 2013-11-11 US US14/076,329 patent/US9719029B2/en active Active
-
2015
- 2015-05-05 SA SA515360389A patent/SA515360389B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015533927A (ja) | 2015-11-26 |
| KR102187212B1 (ko) | 2020-12-04 |
| EP2917307B1 (en) | 2019-01-09 |
| JP6144352B2 (ja) | 2017-06-07 |
| CN104919025A (zh) | 2015-09-16 |
| WO2014074958A1 (en) | 2014-05-15 |
| KR20150105946A (ko) | 2015-09-18 |
| US20140131255A1 (en) | 2014-05-15 |
| CN104919025B (zh) | 2017-07-28 |
| SG11201503610PA (en) | 2015-06-29 |
| US9719029B2 (en) | 2017-08-01 |
| EP2917307A1 (en) | 2015-09-16 |
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