RU92004481A - Способ получения полиолефинов и катализатор полимеризации олефинов - Google Patents

Способ получения полиолефинов и катализатор полимеризации олефинов

Info

Publication number
RU92004481A
RU92004481A RU92004481/13A RU92004481A RU92004481A RU 92004481 A RU92004481 A RU 92004481A RU 92004481/13 A RU92004481/13 A RU 92004481/13A RU 92004481 A RU92004481 A RU 92004481A RU 92004481 A RU92004481 A RU 92004481A
Authority
RU
Russia
Prior art keywords
polyolofins
olefins
obtaining
polymerization catalyst
alkyl
Prior art date
Application number
RU92004481/13A
Other languages
English (en)
Other versions
RU2111211C1 (ru
Inventor
Винтер Андреас
Рорманн Юрген
Долле Фолькер
Кюбер Франк
Original Assignee
Хехст АГ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Хехст АГ filed Critical Хехст АГ
Publication of RU92004481A publication Critical patent/RU92004481A/ru
Application granted granted Critical
Publication of RU2111211C1 publication Critical patent/RU2111211C1/ru

Links

Claims (1)

  1. Предложен способ получения высокомолекулярного полиолефина. Очень эффективная система катализаторов для полимеризации олефина состоит из катализатора, чаще всего, алюминоксана, металлоцена:
    Figure 00000001

    где M′-Zr или Hf, R1 и R2 - алкил или галоген, R3 - водород, R4 - R6 - алкил или арил, -(CR8R9)mR7-(CR8R9)n одно или многоступенчатая цепь, в которой R7 также может быть гетероатомом (замещенным), а m + n = 0 или 1.
RU92004481A 1991-11-30 1992-11-30 Способ получения полиолефинов RU2111211C1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4139596 1991-11-30
DEP4139596.4 1991-11-30

Publications (2)

Publication Number Publication Date
RU92004481A true RU92004481A (ru) 1996-05-10
RU2111211C1 RU2111211C1 (ru) 1998-05-20

Family

ID=6446020

Family Applications (1)

Application Number Title Priority Date Filing Date
RU92004481A RU2111211C1 (ru) 1991-11-30 1992-11-30 Способ получения полиолефинов

Country Status (12)

Country Link
US (2) US5328969A (ru)
EP (2) EP0545303B1 (ru)
JP (1) JP3464231B2 (ru)
KR (1) KR100261362B1 (ru)
AT (2) ATE321015T1 (ru)
AU (1) AU651914B2 (ru)
CA (1) CA2084015A1 (ru)
DE (2) DE59208944D1 (ru)
ES (2) ES2256866T3 (ru)
RU (1) RU2111211C1 (ru)
TW (1) TW318184B (ru)
ZA (1) ZA929214B (ru)

Families Citing this family (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700896A (en) * 1988-07-30 1997-12-23 Hoechst Aktiengesellschaft Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts
USRE37573E1 (en) * 1990-11-12 2002-03-05 Basell Polyolefin Gmbh Process for the preparation of an olefin polymer using metallocenes containing specifically substituted indenyl ligands
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
JP3402473B2 (ja) * 1991-08-20 2003-05-06 日本ポリケム株式会社 オレフィン重合用触媒
TW309523B (ru) * 1991-11-30 1997-07-01 Hoechst Ag
TW294669B (ru) * 1992-06-27 1997-01-01 Hoechst Ag
EP0581754A1 (en) * 1992-07-10 1994-02-02 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
ES2114978T3 (es) * 1992-08-03 1998-06-16 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial.
ES2153368T3 (es) * 1992-08-03 2001-03-01 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos especiales.
USRE39156E1 (en) * 1992-08-15 2006-07-04 Basell Polyolefine Gmbh Process for the preparation of polyolefins
EP0584609B1 (de) * 1992-08-15 1999-03-10 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen
EP0586167B1 (en) * 1992-09-04 2000-07-12 BP Chemicals Limited Catalyst compositions and process for preparing Polyolefins
TW275076B (ru) * 1992-12-02 1996-05-01 Hoechst Ag
JPH06271594A (ja) * 1993-03-22 1994-09-27 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
EP0629631B1 (en) * 1993-06-07 2002-08-28 Mitsui Chemicals, Inc. Novel transition metal compound, and polymerization catalyst containing it
EP0629632B2 (en) * 1993-06-07 2015-01-21 Mitsui Chemicals, Inc. Polypropylene
IT1271406B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
JP3423378B2 (ja) * 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
ES2154664T3 (es) * 1993-11-24 2001-04-16 Targor Gmbh Metalocenos, procedimientos para su obtencion, y su empleo como catalizadores.
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
EP0668157B1 (de) 1994-02-21 2003-05-21 Basell Polyolefine GmbH Siegelbare polyolefinische Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
CN1112370C (zh) * 1994-06-24 2003-06-25 埃克森美孚化学专利公司 聚合催化剂体系、它们的制备和用途
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
US5563284A (en) * 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
EP0739897A1 (de) 1995-04-27 1996-10-30 Hoechst Aktiengesellschaft Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
DE19544709A1 (de) * 1995-11-30 1997-06-05 Basf Ag Biaxial orientierte Polypropylenfolie aus Metallocen-Polypropylen
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
DE19548788A1 (de) 1995-12-27 1997-07-03 Hoechst Ag Folien und Schichten
US5908903A (en) 1995-12-27 1999-06-01 Basf Aktiengesellschaft Metallocene catalyst systems containing lewis bases
US6015779A (en) 1996-03-19 2000-01-18 Energy & Environmental International, L.C. Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents
US5869570A (en) * 1996-03-19 1999-02-09 Energy & Environmental International, L.C. Composition of and process for forming polyalphaolefin drag reducing agents
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
DE19617230A1 (de) 1996-04-30 1997-11-06 Basf Ag Oxidierte Metallocen-Polyolefin-Wachse
US5945365A (en) * 1996-05-20 1999-08-31 Fina Technology, Inc. Stereorigid bis-fluorenyl metallocenes
US6107501A (en) * 1997-01-30 2000-08-22 Fina Technology, Inc. Synthesis of metallocenes and enrichment of their rac isomer
DE19738051A1 (de) 1997-09-01 1999-03-04 Targor Gmbh Spritzgieß-Artikel aus Metallocen-Polypropylen
US6211300B1 (en) 1998-04-10 2001-04-03 Chisso Corporation Propylene-ethylene block copolymer compositions and processes for production thereof
EP1078009B1 (en) 1998-05-13 2004-06-16 ExxonMobil Chemical Patents Inc. Propylene homopolymers and methods of making the same
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
BR9913647B1 (pt) * 1998-08-26 2008-11-18 polipropileno ramificado e processo para produzir o mesmo.
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
BR9917139A (pt) 1998-12-30 2001-11-13 Union Carbide Chem Plastic Composições de catalisador não suportadopré-ativado tendo uma dada concentração emétodos para usá-las
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
MXPA01011548A (es) 1999-05-13 2002-07-02 Exxon Chemical Patents Inc Fibras elasticas y articulos hechos de las mismas, incluyendo polimeros de propileno crsitalinos y cristalizables.
US6750284B1 (en) 1999-05-13 2004-06-15 Exxonmobil Chemical Patents Inc. Thermoplastic filled membranes of propylene copolymers
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
ES2210015T3 (es) 1999-11-04 2004-07-01 Exxonmobil Chemical Patents Inc. Espumas de copolimero de propileno y su uso.
US6809168B2 (en) * 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
CA2393414A1 (en) * 1999-12-10 2001-06-14 Main Chang Propylene diene copolymerized polymers
US6977287B2 (en) * 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
CN1333032C (zh) 1999-12-22 2007-08-22 埃克森美孚化学专利公司 聚丙烯基粘合剂组合物
ATE336529T1 (de) * 2000-02-08 2006-09-15 Exxonmobil Chem Patents Inc Schlagzähe propylencopolymerisate
MXPA03001585A (es) * 2000-08-22 2003-07-14 Exxonmobil Chem Patents Inc Peliculas de polipropileno.
US6815011B2 (en) 2000-11-27 2004-11-09 Energy & Environmental International, L.C. Alpha olefin monomer partitioning agents for drag reducing agents and methods of forming drag reducing agents using alpha olefin monomer partitioning agents
CA2434795C (en) 2001-01-16 2010-01-26 Energy & Environmental International, L.C. Methods for forming amorphous ultra-high molecular weight polyolefins for use as drag reducing agents
US7037615B2 (en) * 2001-02-12 2006-05-02 Delphi Technologies, Inc. Trapping method and system for energy conversion devices
DE10126265A1 (de) 2001-05-29 2002-12-05 Basell Polyolefine Gmbh Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
US7012046B2 (en) * 2001-06-08 2006-03-14 Eaton Gerald B Drag reducing agent slurries having alfol alcohols and processes for forming drag reducing agent slurries having alfol alcohols
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US7195806B2 (en) * 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
JP2005099712A (ja) * 2003-08-28 2005-04-14 Sharp Corp 表示装置の駆動回路および表示装置
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
CN101679699B (zh) 2007-04-09 2012-07-04 埃克森美孚化学专利公司 柔软的非均相全同立构聚丙烯组合物
WO2008150572A1 (en) * 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US20090053959A1 (en) * 2007-08-21 2009-02-26 Sudhin Datta Soft and Elastic Nonwoven Polypropylene Compositions
US7906588B2 (en) * 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US7872080B2 (en) 2008-03-06 2011-01-18 Sumitomo Chemical Company, Limited Processes for producing a catalyst component for addition polymerization, a catalyst and an addition polymer
DE102008040736B4 (de) 2008-07-25 2019-03-28 Symrise Ag Verfahren zur Herstellung Alkoxy-substituierter 1-Indanone
JP5181104B2 (ja) * 2008-12-10 2013-04-10 株式会社プライムポリマー プロピレン系ブロック共重合体
KR101359198B1 (ko) 2009-03-30 2014-02-05 미쓰이 가가쿠 가부시키가이샤 올레핀과 공액 다이엔의 공중합체, 및 그의 제조 방법
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
JP2011213804A (ja) 2010-03-31 2011-10-27 Sumitomo Chemical Co Ltd 予備重合方法、予備重合済付加重合触媒成分およびそれを用いる付加重合体の製造方法
CN102971454B (zh) 2010-06-15 2015-05-27 埃克森美孚化学专利公司 由聚合物共混物制造的非织造织物及其制造方法
WO2012149391A1 (en) 2011-04-28 2012-11-01 Adherent Laboratories, Inc. Polyolefin based hot melt adhesive composition
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
JP2013082891A (ja) 2011-09-28 2013-05-09 Sumitomo Chemical Co Ltd 洗浄方法、付加重合方法、予備重合方法、予備重合済付加重合触媒成分およびそれを用いる付加重合体の製造方法
JP6295506B2 (ja) 2011-12-07 2018-03-20 住友化学株式会社 界面活性剤含有粒子を用いた重合方法
US9284386B2 (en) 2012-05-08 2016-03-15 Lg Chem, Ltd. Ansa-metallocene compound and method for preparing supported catalyst using the same
WO2015161241A1 (en) 2014-04-18 2015-10-22 IFS Industries Inc. Low density and high performance packaging hot melt
US20200087495A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
KR20210127954A (ko) 2019-02-20 2021-10-25 피나 테크놀러지, 인코포레이티드 휨이 적은 중합체 조성물
EP4053175A4 (en) 2019-10-30 2023-11-15 China Petroleum & Chemical Corporation METALLOCENE COMPOUND AND PRODUCTION PROCESS THEREOF AND APPLICATION THEREOF
CN117222697A (zh) 2021-04-26 2023-12-12 弗纳技术股份有限公司 单位点催化的聚合物薄片材

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE754556A (fr) * 1969-08-08 1971-02-08 Merck & Co Inc Acides indenyl-acetiques et procede pour les
DE2244761A1 (de) * 1972-09-09 1974-03-14 Schering Ag Indan- und tetralinderivate
JPS6015655B2 (ja) * 1979-12-14 1985-04-20 日本原子力研究所 難燃性高分子組成物成形体の製造方法
JPS5684748A (en) * 1979-12-14 1981-07-10 Japan Atom Energy Res Inst Radiation-resistant resin composition
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE3808268A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
DE3826075A1 (de) * 1988-07-30 1990-02-01 Hoechst Ag 1-olefin-isoblockpolymer und verfahren zu seiner herstellung
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
DE4005947A1 (de) * 1990-02-26 1991-08-29 Basf Ag Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
DE4121368A1 (de) * 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
TW300901B (ru) * 1991-08-26 1997-03-21 Hoechst Ag
DE59210001D1 (de) * 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
CA2084017C (en) * 1991-11-30 2006-11-21 Jurgen Rohrmann Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts

Similar Documents

Publication Publication Date Title
RU92004481A (ru) Способ получения полиолефинов и катализатор полимеризации олефинов
ES2114978T3 (es) Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial.
ATE286918T1 (de) Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
IT1203330B (it) Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
DK254988A (da) Ny baererunderstoettet polymerisationskatalysator
ES2086397T3 (es) Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
KR960000910A (ko) 가교되지 않은 인데닐-함유 메탈로센
RU93004653A (ru) Катализатор полимеризации олефинов, способ его получения и способ получения полиолефина
DE3777339D1 (de) Katalysator zur polymerisation von olefinen.
NO893898L (no) Katalysatorer for polymerisering av olefiner.
DE3751495T2 (de) Hafnium-Metalocen-Katalysator für Olefinpolymerisation.
ES2113392T3 (es) Procedimiento para la obtencion de un polimero olefinico.
ZA929213B (en) Metallocenes having benzo-fusen indenyl derivatives as ligands, processes for their preparation and their use as catalysts.
NO900434L (no) Katalysator for polymerisering av olefiner.
CA2023559A1 (en) Process for the preparation of a polyolefin
NO902002D0 (no) Olefin polymerisasjonskatalysator og fremgangsmaate for fremstilling av etylen-copolymerer.
FI101708B1 (fi) Olefiinin polymerointikatalyytti ja -menetelmiä
ES2083378T3 (es) Catalizador de polimerizacion de olefinas y procedimiento para la polimerizacion de olefinas.
RU93049608A (ru) Катализатор и способ (со)полимеризации альфа-олефинов
FI872651A (fi) Katalyyttikomponentti olefiinin polymerointiin
ITMI922180A0 (it) Copolimeri dell'etilene con monomeri olefinici, processo per la loro preparazione e catalizzatore
IT8722761A0 (it) Componente di catalizzatore per catalizzatori ziegler natta emetodo per polimerizzare alfa olefine.
DE69110170T2 (de) Katalysator für Polymerisation von Olefinkohlenwasserstoffen und Verfahren für Olefinpolymerisation.
RU93005242A (ru) Способ получения полиолефиновых восков, полиолефиновые воски
RU94001575A (ru) Каталитические композиции и способ изготовления полиолефинов