RU2659787C2 - Водные растворы, содержащие комплексообразующий агент в высокой концентрации - Google Patents
Водные растворы, содержащие комплексообразующий агент в высокой концентрации Download PDFInfo
- Publication number
- RU2659787C2 RU2659787C2 RU2015155965A RU2015155965A RU2659787C2 RU 2659787 C2 RU2659787 C2 RU 2659787C2 RU 2015155965 A RU2015155965 A RU 2015155965A RU 2015155965 A RU2015155965 A RU 2015155965A RU 2659787 C2 RU2659787 C2 RU 2659787C2
- Authority
- RU
- Russia
- Prior art keywords
- aqueous solution
- acid
- complexing agent
- salt
- range
- Prior art date
Links
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 69
- 239000008139 complexing agent Substances 0.000 title claims abstract description 43
- -1 alkali metal salts Chemical class 0.000 claims abstract description 25
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 24
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical class OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims abstract description 22
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 238000003860 storage Methods 0.000 claims abstract description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- 238000004851 dishwashing Methods 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Chemical class OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical class CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Chemical class 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical class OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical class OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Chemical class OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Chemical class [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Chemical class OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Chemical class 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical class OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Chemical class 0.000 claims description 2
- 239000001630 malic acid Chemical class 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Chemical class 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 15
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000007787 solid Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 150000007529 inorganic bases Chemical class 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/264—Aldehydes; Ketones; Acetals or ketals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/34—Organic compounds containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Medicinal Preparation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13169341.8 | 2013-05-27 | ||
| EP13169341 | 2013-05-27 | ||
| PCT/EP2014/059727 WO2014191199A1 (en) | 2013-05-27 | 2014-05-13 | Aqueous solutions containing a complexing agent in high concentration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015155965A RU2015155965A (ru) | 2017-07-04 |
| RU2659787C2 true RU2659787C2 (ru) | 2018-07-04 |
Family
ID=48534208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015155965A RU2659787C2 (ru) | 2013-05-27 | 2014-05-13 | Водные растворы, содержащие комплексообразующий агент в высокой концентрации |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9850453B2 (enExample) |
| EP (1) | EP3004316B1 (enExample) |
| JP (1) | JP2016522857A (enExample) |
| KR (1) | KR20160012209A (enExample) |
| CN (1) | CN105247034B (enExample) |
| BR (1) | BR112015029544A2 (enExample) |
| CA (1) | CA2912309A1 (enExample) |
| ES (1) | ES2628161T3 (enExample) |
| HK (1) | HK1219972A1 (enExample) |
| MX (1) | MX2015016424A (enExample) |
| MY (1) | MY169131A (enExample) |
| PL (1) | PL3004316T3 (enExample) |
| RU (1) | RU2659787C2 (enExample) |
| WO (1) | WO2014191199A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112015029557A2 (pt) * | 2013-05-27 | 2020-03-10 | Basf Se | solução aquosa, processo para fabricação de uma solução aquosa, e, uso de uma solução aquosa |
| MX2017006900A (es) | 2014-11-26 | 2018-06-06 | Basf Se | Solucion acuosa que contiene una combinacion de agentes formadores de complejos. |
| KR102694078B1 (ko) * | 2015-03-12 | 2024-08-09 | 바스프 에스이 | 거울상이성질체의 혼합물의 제조 방법, 및 거울상이성질체의 혼합물 |
| WO2017097637A1 (en) * | 2015-12-08 | 2017-06-15 | Basf Se | Aqueous solution containing a complexing agent in high concentrations |
| RU2019138212A (ru) * | 2017-04-27 | 2021-05-27 | Басф Се | Контейнер, содержащий композицию моющего средства, содержащую соли mgda и glda |
| CN111630143A (zh) | 2018-01-30 | 2020-09-04 | 伊士曼化工公司 | 包含氨基羧酸类螯合剂的组合物 |
| JP2021515820A (ja) | 2018-02-23 | 2021-06-24 | ユニリーバー・ナームローゼ・ベンノートシヤープ | アミノポリカルボキシレートを含む成形洗剤製品組成物 |
| WO2023004106A1 (en) | 2021-07-23 | 2023-01-26 | Ascend Performance Materials Operations Llc | Aqueous solutions containing amino carboxylic acid chelators |
| EP4286365A1 (en) * | 2022-05-30 | 2023-12-06 | Nouryon Chemicals International B.V. | Method of forming a chelating composition |
| WO2024132413A1 (en) * | 2022-12-20 | 2024-06-27 | Basf Se | Process for providing a composition comprising at least one aminocarboxylate complexing agent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100276152A1 (en) * | 2008-01-09 | 2010-11-04 | Akzo Nobel N.V. | Acidic aqueous solution containing a chelating agent and the use thereof |
| WO2012028203A1 (en) * | 2010-09-03 | 2012-03-08 | Ecolab Inc. | Composition for cleaning with enhanced activity |
| US20120090645A1 (en) * | 2009-06-24 | 2012-04-19 | Henkel Ag & Co. Kgaa | Machine cleaning agent |
| RU2012138455A (ru) * | 2010-02-09 | 2014-03-20 | Басф Се | Детергентная композиция |
| RU2527423C2 (ru) * | 2009-06-19 | 2014-08-27 | Дзе Проктер Энд Гэмбл Компани | Жидкий моющий состав для мытья посуды ручным способом |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8508129D0 (en) | 1985-03-28 | 1985-05-01 | Procter & Gamble Ltd | Textile treatment composition |
| JPH11323393A (ja) * | 1998-05-12 | 1999-11-26 | Kao Corp | 食器洗浄機用洗浄剤 |
| JP5345321B2 (ja) * | 2004-11-03 | 2013-11-20 | ディバーシー・インコーポレーテッド | リサイクル用容器の洗浄方法 |
| EP1908817A4 (en) * | 2005-07-01 | 2008-08-13 | Miz Co Ltd | WASHING AND WASHING MACHINE WASHING PROCESS |
| GB0522659D0 (en) * | 2005-11-07 | 2005-12-14 | Reckitt Benckiser Nv | Delivery cartridge |
| DE102009027162A1 (de) | 2009-06-24 | 2010-12-30 | Henkel Ag & Co. Kgaa | Maschinelles Geschirrspülmittel |
| CA2789277A1 (en) * | 2010-02-09 | 2011-09-01 | Basf Se | Builder composition |
| EP2609185B1 (en) * | 2010-08-27 | 2019-01-16 | Ecolab USA Inc. | Liquid cleaner for automated instrument processing |
| RU2604366C2 (ru) | 2011-04-14 | 2016-12-10 | Басф Се | Способ растворения и/или ингибирования отложения накипи на поверхности системы |
| US8709990B2 (en) | 2011-10-19 | 2014-04-29 | Basf Se | Formulations, their use as or for producing dishwashing detergents and their production |
| PL2768937T3 (pl) | 2011-10-19 | 2016-07-29 | Basf Se | Preparaty, ich zastosowanie jako środków do mycia naczyń lub do wytwarzania środków do mycia naczyń i ich wytwarzanie |
| ES2626819T3 (es) | 2011-10-19 | 2017-07-26 | Basf Se | Formulaciones, su uso como o para la fabricación de detergentes para vajillas y su fabricación |
| EP2794836B1 (en) | 2011-12-22 | 2016-06-01 | Unilever N.V. | Detergent composition comprising glutamic-n,n-diacetate, water and bleaching agent |
| BR112015029557A2 (pt) | 2013-05-27 | 2020-03-10 | Basf Se | solução aquosa, processo para fabricação de uma solução aquosa, e, uso de uma solução aquosa |
| PT3013931T (pt) | 2013-06-25 | 2020-05-14 | Unilever Nv | Composição compreendendo glutâmico-n,n-diacetato (glda), água e enzima |
| US20160130532A1 (en) | 2013-06-25 | 2016-05-12 | Conopco, Inc., D/B/A Unilever | Hygroscopic detergent formulation comprising water, aminocarboxylate chelant and moisture-sensitive ingredients |
-
2014
- 2014-05-13 EP EP14726333.9A patent/EP3004316B1/en not_active Revoked
- 2014-05-13 CN CN201480030285.1A patent/CN105247034B/zh not_active Expired - Fee Related
- 2014-05-13 RU RU2015155965A patent/RU2659787C2/ru not_active IP Right Cessation
- 2014-05-13 ES ES14726333.9T patent/ES2628161T3/es active Active
- 2014-05-13 PL PL14726333T patent/PL3004316T3/pl unknown
- 2014-05-13 WO PCT/EP2014/059727 patent/WO2014191199A1/en not_active Ceased
- 2014-05-13 US US14/893,859 patent/US9850453B2/en not_active Expired - Fee Related
- 2014-05-13 HK HK16108063.7A patent/HK1219972A1/zh unknown
- 2014-05-13 KR KR1020157036430A patent/KR20160012209A/ko not_active Ceased
- 2014-05-13 CA CA2912309A patent/CA2912309A1/en not_active Abandoned
- 2014-05-13 BR BR112015029544A patent/BR112015029544A2/pt not_active Application Discontinuation
- 2014-05-13 MX MX2015016424A patent/MX2015016424A/es unknown
- 2014-05-13 JP JP2016515703A patent/JP2016522857A/ja active Pending
- 2014-05-13 MY MYPI2015002796A patent/MY169131A/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100276152A1 (en) * | 2008-01-09 | 2010-11-04 | Akzo Nobel N.V. | Acidic aqueous solution containing a chelating agent and the use thereof |
| RU2527423C2 (ru) * | 2009-06-19 | 2014-08-27 | Дзе Проктер Энд Гэмбл Компани | Жидкий моющий состав для мытья посуды ручным способом |
| US20120090645A1 (en) * | 2009-06-24 | 2012-04-19 | Henkel Ag & Co. Kgaa | Machine cleaning agent |
| RU2012138455A (ru) * | 2010-02-09 | 2014-03-20 | Басф Се | Детергентная композиция |
| WO2012028203A1 (en) * | 2010-09-03 | 2012-03-08 | Ecolab Inc. | Composition for cleaning with enhanced activity |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105247034A (zh) | 2016-01-13 |
| ES2628161T3 (es) | 2017-08-01 |
| MY169131A (en) | 2019-02-18 |
| KR20160012209A (ko) | 2016-02-02 |
| RU2015155965A (ru) | 2017-07-04 |
| HK1219972A1 (zh) | 2017-04-21 |
| EP3004316B1 (en) | 2017-03-22 |
| EP3004316A1 (en) | 2016-04-13 |
| MX2015016424A (es) | 2016-03-03 |
| US9850453B2 (en) | 2017-12-26 |
| CA2912309A1 (en) | 2014-12-04 |
| JP2016522857A (ja) | 2016-08-04 |
| US20160130531A1 (en) | 2016-05-12 |
| PL3004316T3 (pl) | 2017-09-29 |
| WO2014191199A1 (en) | 2014-12-04 |
| CN105247034B (zh) | 2018-10-16 |
| BR112015029544A2 (pt) | 2017-07-25 |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200514 |