JP2017535665A5 - - Google Patents
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- Publication number
- JP2017535665A5 JP2017535665A5 JP2017547067A JP2017547067A JP2017535665A5 JP 2017535665 A5 JP2017535665 A5 JP 2017535665A5 JP 2017547067 A JP2017547067 A JP 2017547067A JP 2017547067 A JP2017547067 A JP 2017547067A JP 2017535665 A5 JP2017535665 A5 JP 2017535665A5
- Authority
- JP
- Japan
- Prior art keywords
- complexing agent
- aqueous
- aqueous solution
- range
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000008139 complexing agent Substances 0.000 claims description 93
- 229920000642 polymer Polymers 0.000 claims description 50
- 239000007864 aqueous solution Substances 0.000 claims description 49
- 229910052783 alkali metal Inorganic materials 0.000 claims description 38
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 31
- 239000013011 aqueous formulation Substances 0.000 claims description 30
- 150000003839 salts Chemical class 0.000 claims description 27
- -1 alkali metal cations Chemical class 0.000 claims description 22
- 150000001340 alkali metals Chemical class 0.000 claims description 20
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 16
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 12
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000009472 formulation Methods 0.000 claims description 9
- 229960002989 glutamic acid Drugs 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 6
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 claims description 6
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 5
- 235000013922 glutamic acid Nutrition 0.000 claims description 5
- 239000004220 glutamic acid Substances 0.000 claims description 5
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 229920001281 polyalkylene Polymers 0.000 claims description 5
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 150000002466 imines Chemical class 0.000 claims description 2
- 235000011056 potassium acetate Nutrition 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
- 229920002873 Polyethylenimine Polymers 0.000 description 16
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229920000768 polyamine Polymers 0.000 description 8
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 7
- 235000019253 formic acid Nutrition 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 235000011054 acetic acid Nutrition 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 229920000333 poly(propyleneimine) Polymers 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 125000001302 tertiary amino group Chemical group 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical compound CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 238000007059 Strecker synthesis reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 238000000711 polarimetry Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462084601P | 2014-11-26 | 2014-11-26 | |
| US62/084,601 | 2014-11-26 | ||
| PCT/EP2015/077194 WO2016083253A1 (en) | 2014-11-26 | 2015-11-20 | Aqueous solution containing combination of complexing agents |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020130003A Division JP7076506B2 (ja) | 2014-11-26 | 2020-07-31 | 錯化剤の組み合わせを含有する水溶液 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2017535665A JP2017535665A (ja) | 2017-11-30 |
| JP2017535665A5 true JP2017535665A5 (enExample) | 2018-12-27 |
| JP7086604B2 JP7086604B2 (ja) | 2022-06-20 |
| JP7086604B6 JP7086604B6 (ja) | 2022-07-04 |
Family
ID=54697565
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017547067A Active JP7086604B6 (ja) | 2014-11-26 | 2015-11-20 | 錯化剤の組み合わせを含有する水溶液 |
| JP2020130003A Active JP7076506B2 (ja) | 2014-11-26 | 2020-07-31 | 錯化剤の組み合わせを含有する水溶液 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020130003A Active JP7076506B2 (ja) | 2014-11-26 | 2020-07-31 | 錯化剤の組み合わせを含有する水溶液 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10160937B2 (enExample) |
| EP (1) | EP3224338B1 (enExample) |
| JP (2) | JP7086604B6 (enExample) |
| KR (1) | KR20170109524A (enExample) |
| CN (2) | CN111925875B (enExample) |
| BR (1) | BR112017010968A2 (enExample) |
| CA (1) | CA2966844A1 (enExample) |
| ES (1) | ES2735735T3 (enExample) |
| MX (1) | MX2017006900A (enExample) |
| PL (1) | PL3224338T3 (enExample) |
| RU (1) | RU2696284C2 (enExample) |
| TR (1) | TR201909699T4 (enExample) |
| WO (1) | WO2016083253A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2714084T3 (es) * | 2014-11-26 | 2019-05-27 | Procter & Gamble | Bolsa limpiadora |
| BR112018077082B1 (pt) * | 2016-07-15 | 2023-03-28 | Basf Se | Processo para fabricação de grânulos de sais, grânulo, uso de um grânulo |
| ES2882568T3 (es) * | 2017-04-27 | 2021-12-02 | Basf Se | Recipiente que comprende una composición detergente que contiene sales de mgda y glda |
| CN107523427B (zh) * | 2017-07-28 | 2021-02-19 | 广州立白企业集团有限公司 | 液体无磷洗涤剂组合物及其应用 |
| EP3746535A1 (en) | 2018-01-30 | 2020-12-09 | Eastman Chemical Company | Compositions comprising aminocarboxylate chelating agents |
| WO2020094480A1 (en) * | 2018-11-07 | 2020-05-14 | Basf Se | Process for manufacturing granules, and granules and their use |
| JP2020007559A (ja) * | 2019-08-23 | 2020-01-16 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 洗浄用パウチ |
| EP4286364A1 (en) * | 2022-05-30 | 2023-12-06 | Nouryon Chemicals International B.V. | Method of forming a chelating composition |
| JP2025540410A (ja) | 2022-12-20 | 2025-12-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 少なくとも１種のアミノカルボキシレート錯化剤を含む組成物を提供するためのプロセス |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2176215B1 (en) | 2007-08-17 | 2014-10-08 | Akzo Nobel N.V. | Glutamic acid n,n-diacetic amide, glutamic acid n-acetic amide n-acetonitrile, alkali metal salts thereof, process to prepare them and their use |
| EP3181656B1 (en) * | 2008-01-09 | 2018-12-12 | Akzo Nobel Chemicals International B.V. | Acidic aqueous solution containing a chelating agent |
| US7902137B2 (en) * | 2008-05-30 | 2011-03-08 | American Sterilizer Company | Biodegradable scale control composition for use in highly concentrated alkaline hard surface detergents |
| CA2820944C (en) * | 2010-12-17 | 2018-11-27 | Akzo Nobel Chemicals International B.V. | Fluid suitable for treatment of carbonate formations containing a chelating agent |
| KR101947205B1 (ko) | 2011-04-14 | 2019-02-12 | 바스프 에스이 | 시스템의 표면 상의 스케일의 침착을 억제하고/하거나 용해시키는 방법 |
| JP2014522451A (ja) * | 2011-06-13 | 2014-09-04 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップ | クロム含有機器装置においてキレート化剤を使用して改善された耐食性 |
| CN104010510B (zh) * | 2011-12-21 | 2016-10-12 | 巴斯夫欧洲公司 | 含有氨基-/多氨基羧化物和有机磷酸化物、膦酸化物或亚磷酸化物的配制剂及其在农业中的用途 |
| US9732309B2 (en) * | 2012-04-25 | 2017-08-15 | Basf Se | Formulations, their use as or for producing dishwashing detergents and their production |
| WO2013160132A1 (de) * | 2012-04-25 | 2013-10-31 | Basf Se | Feste formulierungen, ihre herstellung und verwendung |
| JP6133971B2 (ja) * | 2012-04-25 | 2017-05-24 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 配合物、食器洗い洗剤としての又は食器洗い洗剤を製造するためのそれらの使用方法、及びそれらの製造 |
| US20130284210A1 (en) | 2012-04-25 | 2013-10-31 | Basf Se | Solid formulations, their preparation and use |
| WO2013160259A1 (de) * | 2012-04-25 | 2013-10-31 | Basf Se | Formulierungen, ihre verwendung als oder zur herstellung von geschirrspülmitteln und ihre herstellung |
| US9068147B2 (en) * | 2012-05-11 | 2015-06-30 | Basf Se | Quaternized polyethylenimines with a high quaternization degree |
| CN105102602B (zh) * | 2013-04-02 | 2018-05-25 | 巴斯夫欧洲公司 | 配制剂、其作为或用于制品器皿洗涤清净剂的用途及其制备 |
| US20160075972A1 (en) * | 2013-04-23 | 2016-03-17 | Basf Se | Formulations, their use as or for producing dishwashing detergents and their production |
| MX2015016424A (es) | 2013-05-27 | 2016-03-03 | Basf Se | Soluciones acuosas que contienen un agente complejante de alto grado de concentracion. |
| US20160097020A1 (en) | 2013-05-27 | 2016-04-07 | Basf Se | Aqueous solutions containing a complexing agent in high concentration |
| EP2821471A1 (en) * | 2013-07-02 | 2015-01-07 | Basf Se | Aqueous solutions containing a complexing agent in high concentration |
| CN105531255B (zh) | 2013-09-13 | 2018-01-02 | 巴斯夫欧洲公司 | 对映体混合物以及生产该混合物的方法 |
| MX374649B (es) | 2014-02-13 | 2025-03-06 | Basf Se | Polvo y gránulo, proceso para fabricar dicho polvo y gránulo, y sus usos. |
| EP3207025B1 (en) | 2014-10-17 | 2019-07-10 | Basf Se | Solutions of trialkali metal salts of aminocarboxylic acids, their manufacture and use |
| TR201819355T4 (tr) | 2014-10-17 | 2019-01-21 | Basf Se | Mgda ihtiva eden bir deterjan bileşimini içeren kap. |
| ES2690335T3 (es) * | 2014-11-26 | 2018-11-20 | The Procter & Gamble Company | Bolsa limpiadora |
| ES2714084T3 (es) * | 2014-11-26 | 2019-05-27 | Procter & Gamble | Bolsa limpiadora |
-
2015
- 2015-11-20 CA CA2966844A patent/CA2966844A1/en not_active Abandoned
- 2015-11-20 CN CN202010836767.3A patent/CN111925875B/zh not_active Expired - Fee Related
- 2015-11-20 WO PCT/EP2015/077194 patent/WO2016083253A1/en not_active Ceased
- 2015-11-20 MX MX2017006900A patent/MX2017006900A/es unknown
- 2015-11-20 ES ES15798402T patent/ES2735735T3/es active Active
- 2015-11-20 JP JP2017547067A patent/JP7086604B6/ja active Active
- 2015-11-20 RU RU2017122218A patent/RU2696284C2/ru active
- 2015-11-20 TR TR2019/09699T patent/TR201909699T4/tr unknown
- 2015-11-20 PL PL15798402T patent/PL3224338T3/pl unknown
- 2015-11-20 KR KR1020177014123A patent/KR20170109524A/ko not_active Withdrawn
- 2015-11-20 EP EP15798402.2A patent/EP3224338B1/en not_active Revoked
- 2015-11-20 US US15/529,820 patent/US10160937B2/en active Active
- 2015-11-20 BR BR112017010968A patent/BR112017010968A2/pt not_active IP Right Cessation
- 2015-11-20 CN CN201580063252.1A patent/CN107001992B/zh not_active Expired - Fee Related
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2020
- 2020-07-31 JP JP2020130003A patent/JP7076506B2/ja active Active
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