RU2560363C2 - Способ риформинга углеводородов - Google Patents

Способ риформинга углеводородов Download PDF

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Publication number
RU2560363C2
RU2560363C2 RU2012135380/05A RU2012135380A RU2560363C2 RU 2560363 C2 RU2560363 C2 RU 2560363C2 RU 2012135380/05 A RU2012135380/05 A RU 2012135380/05A RU 2012135380 A RU2012135380 A RU 2012135380A RU 2560363 C2 RU2560363 C2 RU 2560363C2
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Russia
Prior art keywords
reforming
heat exchange
reforming device
stream
temperature
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RU2012135380/05A
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English (en)
Russian (ru)
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RU2012135380A (ru
Inventor
Пат А. ХАН
Никлас Бенгт ЯКОБССОН
Андерс Хельбо ХАНСЕН
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Хальдор Топсеэ А/С
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00157—Controlling the temperature by means of a burner
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2012135380/05A 2010-01-19 2011-01-18 Способ риформинга углеводородов RU2560363C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA201000039 2010-01-19
DKPA201000039 2010-01-19
PCT/EP2011/000178 WO2011088981A1 (en) 2010-01-19 2011-01-18 Process for reforming hydrocarbons

Publications (2)

Publication Number Publication Date
RU2012135380A RU2012135380A (ru) 2014-02-27
RU2560363C2 true RU2560363C2 (ru) 2015-08-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2012135380/05A RU2560363C2 (ru) 2010-01-19 2011-01-18 Способ риформинга углеводородов

Country Status (10)

Country Link
US (1) US8696935B2 (OSRAM)
EP (1) EP2526044B1 (OSRAM)
JP (1) JP5980686B2 (OSRAM)
KR (1) KR101820336B1 (OSRAM)
CN (2) CN102844267A (OSRAM)
BR (1) BR112012017633B1 (OSRAM)
CA (1) CA2787482C (OSRAM)
PL (1) PL2526044T3 (OSRAM)
RU (1) RU2560363C2 (OSRAM)
WO (1) WO2011088981A1 (OSRAM)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
RU2712657C2 (ru) * 2015-10-29 2020-01-30 Джонсон Мэтти Паблик Лимитед Компани Способ конверсии водяного газа

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US8882890B2 (en) 2012-12-27 2014-11-11 Uop Llc Apparatuses and methods for separating liquefiable hydrocarbons from hydrogen-, hydrocarbon-containing gas streams
US20150175416A1 (en) * 2013-01-14 2015-06-25 Haldor Topsoe A/S Feed ratio control for hter
WO2015155256A1 (en) * 2014-04-08 2015-10-15 Haldor Topsøe A/S A process for heating an atr
US9592487B2 (en) 2014-06-25 2017-03-14 Zoneflow Reactor Technologies, LLC Steam methane reformer system and method of performing a steam methane reforming process
DE102015004214A1 (de) 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas aus einem CO2-reichen, kohlenwasserstoffhaltigen Einsatzgas
DE102015004215A1 (de) 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas
CN105623716B (zh) * 2016-02-23 2017-08-25 石玉林 一种半再生催化重整反应系统及方法
EP3658491B1 (en) 2017-07-25 2023-08-30 Topsoe A/S Method for the preparation of ammonia synthesis gas
WO2019020519A1 (en) 2017-07-25 2019-01-31 Haldor Topsøe A/S PROCESS FOR THE PREPARATION OF A SYNTHESIS GAS
IL271938B2 (en) 2017-07-25 2024-04-01 Haldor Topsoe As Method for the preparation of synthesis gas
AU2018308861B2 (en) 2017-07-25 2024-03-07 Haldor Topsøe A/S Process for the co-production of methanol and ammonia in parallel
WO2019110269A1 (en) * 2017-12-08 2019-06-13 Haldor Topsøe A/S System and process for production of synthesis gas
EP3574991A1 (en) 2018-05-31 2019-12-04 Haldor Topsøe A/S Steam reforming heated by resistance heating
EP3801871B1 (en) 2018-05-31 2026-03-04 Topsoe A/S Endothermic reactions heated by resistance heating
CN121847002A (zh) 2019-04-08 2026-04-14 托普索公司 化学合成设备
GB201908450D0 (en) 2019-06-12 2019-07-24 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol
GB201908449D0 (en) 2019-06-12 2019-07-24 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol
BR112022003964A2 (pt) 2019-09-03 2022-05-24 Haldor Topsoe As Forno reformador com tubos reformadores suportados
JP7840261B2 (ja) 2019-10-01 2026-04-03 トプソー・アクチエゼルスカベット メタノールからオンデマンド水素
CA3153229A1 (en) 2019-10-01 2021-04-08 Haldor Topsoe A/S Synthesis gas on demand
CN119660676A (zh) 2019-10-01 2025-03-21 托普索公司 由甲醇按需生产合成气
MX2022003308A (es) 2019-10-01 2022-04-12 Haldor Topsoe As Cianuro bajo demanda.
KR20220075347A (ko) 2019-10-01 2022-06-08 할도르 토프쉐 에이/에스 암모니아로부터 맞춤형 수소
US12246298B2 (en) 2019-10-01 2025-03-11 Haldor Topsøe A/S Offshore reforming installation or vessel
BR112022009054A2 (pt) 2019-11-12 2022-08-09 Haldor Topsoe As Craqueador a vapor elétrico
KR102531992B1 (ko) * 2023-01-30 2023-05-15 고등기술연구원연구조합 이산화탄소 무포집 온실가스 저감 합성가스 생산 공정
EP4559870A1 (de) * 2023-11-21 2025-05-28 Linde GmbH Verfahren und anlage zur gewinnung eines wasserstoff enthaltenden produkts
GB202416059D0 (en) * 2024-10-31 2024-12-18 Johnson Matthey Plc Plant for the production of synthesis gas

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US4376717A (en) * 1980-08-29 1983-03-15 Snamprogetti, S.P.A. Process for the preparation of gases which contain hydrogen and nitrogen
RU2261756C2 (ru) * 1999-12-02 2005-10-10 Хальдор Топсеэ А/С Способ и реактор для проведения неадиабатических каталитических реакций

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2712657C2 (ru) * 2015-10-29 2020-01-30 Джонсон Мэтти Паблик Лимитед Компани Способ конверсии водяного газа

Also Published As

Publication number Publication date
EP2526044B1 (en) 2018-12-05
EP2526044A1 (en) 2012-11-28
US20120326090A1 (en) 2012-12-27
CA2787482C (en) 2018-11-13
BR112012017633B1 (pt) 2021-10-13
WO2011088981A1 (en) 2011-07-28
JP5980686B2 (ja) 2016-08-31
CN105771812A (zh) 2016-07-20
KR20120127454A (ko) 2012-11-21
CA2787482A1 (en) 2011-07-28
PL2526044T3 (pl) 2019-05-31
US8696935B2 (en) 2014-04-15
KR101820336B1 (ko) 2018-01-19
RU2012135380A (ru) 2014-02-27
CN102844267A (zh) 2012-12-26
JP2013517197A (ja) 2013-05-16
BR112012017633A2 (pt) 2016-04-12

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