CA2787482C - Process for reforming hydrocarbons - Google Patents

Process for reforming hydrocarbons Download PDF

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Publication number
CA2787482C
CA2787482C CA2787482A CA2787482A CA2787482C CA 2787482 C CA2787482 C CA 2787482C CA 2787482 A CA2787482 A CA 2787482A CA 2787482 A CA2787482 A CA 2787482A CA 2787482 C CA2787482 C CA 2787482C
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CA
Canada
Prior art keywords
heat exchange
reformer
synthesis gas
stream
temperature
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Active
Application number
CA2787482A
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English (en)
French (fr)
Other versions
CA2787482A1 (en
Inventor
Pat A. Han
Niklas Bengt Jakobsson
Anders Helbo Hansen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
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Publication of CA2787482A1 publication Critical patent/CA2787482A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00157—Controlling the temperature by means of a burner
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2787482A 2010-01-19 2011-01-18 Process for reforming hydrocarbons Active CA2787482C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA201000039 2010-01-19
DKPA201000039 2010-01-19
PCT/EP2011/000178 WO2011088981A1 (en) 2010-01-19 2011-01-18 Process for reforming hydrocarbons

Publications (2)

Publication Number Publication Date
CA2787482A1 CA2787482A1 (en) 2011-07-28
CA2787482C true CA2787482C (en) 2018-11-13

Family

ID=43778227

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2787482A Active CA2787482C (en) 2010-01-19 2011-01-18 Process for reforming hydrocarbons

Country Status (10)

Country Link
US (1) US8696935B2 (OSRAM)
EP (1) EP2526044B1 (OSRAM)
JP (1) JP5980686B2 (OSRAM)
KR (1) KR101820336B1 (OSRAM)
CN (2) CN102844267A (OSRAM)
BR (1) BR112012017633B1 (OSRAM)
CA (1) CA2787482C (OSRAM)
PL (1) PL2526044T3 (OSRAM)
RU (1) RU2560363C2 (OSRAM)
WO (1) WO2011088981A1 (OSRAM)

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US8882890B2 (en) 2012-12-27 2014-11-11 Uop Llc Apparatuses and methods for separating liquefiable hydrocarbons from hydrogen-, hydrocarbon-containing gas streams
US20150175416A1 (en) * 2013-01-14 2015-06-25 Haldor Topsoe A/S Feed ratio control for hter
WO2015155256A1 (en) * 2014-04-08 2015-10-15 Haldor Topsøe A/S A process for heating an atr
US9592487B2 (en) 2014-06-25 2017-03-14 Zoneflow Reactor Technologies, LLC Steam methane reformer system and method of performing a steam methane reforming process
DE102015004214A1 (de) 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas aus einem CO2-reichen, kohlenwasserstoffhaltigen Einsatzgas
DE102015004215A1 (de) 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas
GB201519139D0 (en) * 2015-10-29 2015-12-16 Johnson Matthey Plc Process
CN105623716B (zh) * 2016-02-23 2017-08-25 石玉林 一种半再生催化重整反应系统及方法
EP3658491B1 (en) 2017-07-25 2023-08-30 Topsoe A/S Method for the preparation of ammonia synthesis gas
WO2019020519A1 (en) 2017-07-25 2019-01-31 Haldor Topsøe A/S PROCESS FOR THE PREPARATION OF A SYNTHESIS GAS
IL271938B2 (en) 2017-07-25 2024-04-01 Haldor Topsoe As Method for the preparation of synthesis gas
AU2018308861B2 (en) 2017-07-25 2024-03-07 Haldor Topsøe A/S Process for the co-production of methanol and ammonia in parallel
WO2019110269A1 (en) * 2017-12-08 2019-06-13 Haldor Topsøe A/S System and process for production of synthesis gas
EP3574991A1 (en) 2018-05-31 2019-12-04 Haldor Topsøe A/S Steam reforming heated by resistance heating
EP3801871B1 (en) 2018-05-31 2026-03-04 Topsoe A/S Endothermic reactions heated by resistance heating
CN121847002A (zh) 2019-04-08 2026-04-14 托普索公司 化学合成设备
GB201908450D0 (en) 2019-06-12 2019-07-24 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol
GB201908449D0 (en) 2019-06-12 2019-07-24 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol
BR112022003964A2 (pt) 2019-09-03 2022-05-24 Haldor Topsoe As Forno reformador com tubos reformadores suportados
JP7840261B2 (ja) 2019-10-01 2026-04-03 トプソー・アクチエゼルスカベット メタノールからオンデマンド水素
CA3153229A1 (en) 2019-10-01 2021-04-08 Haldor Topsoe A/S Synthesis gas on demand
CN119660676A (zh) 2019-10-01 2025-03-21 托普索公司 由甲醇按需生产合成气
MX2022003308A (es) 2019-10-01 2022-04-12 Haldor Topsoe As Cianuro bajo demanda.
KR20220075347A (ko) 2019-10-01 2022-06-08 할도르 토프쉐 에이/에스 암모니아로부터 맞춤형 수소
US12246298B2 (en) 2019-10-01 2025-03-11 Haldor Topsøe A/S Offshore reforming installation or vessel
BR112022009054A2 (pt) 2019-11-12 2022-08-09 Haldor Topsoe As Craqueador a vapor elétrico
KR102531992B1 (ko) * 2023-01-30 2023-05-15 고등기술연구원연구조합 이산화탄소 무포집 온실가스 저감 합성가스 생산 공정
EP4559870A1 (de) * 2023-11-21 2025-05-28 Linde GmbH Verfahren und anlage zur gewinnung eines wasserstoff enthaltenden produkts
GB202416059D0 (en) * 2024-10-31 2024-12-18 Johnson Matthey Plc Plant for the production of synthesis gas

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DK167864B1 (da) 1990-02-02 1993-12-27 Topsoe Haldor As Fremgangsmaade og reaktorsystem til reforming af carbonhydrider under varmeveksling
DE69736438T2 (de) 1996-10-03 2007-08-02 Kato, Hajime, Kawasaki Methode zur dampfreformierung von kohlenwasserstoffen
DK173742B1 (da) * 1998-09-01 2001-08-27 Topsoe Haldor As Fremgangsmåde og reaktorsystem til fremstilling af syntesegas
PT1106570E (pt) * 1999-12-02 2013-10-15 Haldor Topsoe As Processo e reactor para realizar reacções catalíticas não adiabáticas
JP4477432B2 (ja) * 2004-06-29 2010-06-09 東洋エンジニアリング株式会社 改質器
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Also Published As

Publication number Publication date
EP2526044B1 (en) 2018-12-05
EP2526044A1 (en) 2012-11-28
US20120326090A1 (en) 2012-12-27
BR112012017633B1 (pt) 2021-10-13
WO2011088981A1 (en) 2011-07-28
JP5980686B2 (ja) 2016-08-31
CN105771812A (zh) 2016-07-20
KR20120127454A (ko) 2012-11-21
CA2787482A1 (en) 2011-07-28
PL2526044T3 (pl) 2019-05-31
RU2560363C2 (ru) 2015-08-20
US8696935B2 (en) 2014-04-15
KR101820336B1 (ko) 2018-01-19
RU2012135380A (ru) 2014-02-27
CN102844267A (zh) 2012-12-26
JP2013517197A (ja) 2013-05-16
BR112012017633A2 (pt) 2016-04-12

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