RU2522324C2 - Регенерация катализатора фишера-тропша путем его окисления и обработки смесью карбоната аммония, гидроксида аммония и воды - Google Patents
Регенерация катализатора фишера-тропша путем его окисления и обработки смесью карбоната аммония, гидроксида аммония и воды Download PDFInfo
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- RU2522324C2 RU2522324C2 RU2011129680/04A RU2011129680A RU2522324C2 RU 2522324 C2 RU2522324 C2 RU 2522324C2 RU 2011129680/04 A RU2011129680/04 A RU 2011129680/04A RU 2011129680 A RU2011129680 A RU 2011129680A RU 2522324 C2 RU2522324 C2 RU 2522324C2
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- Prior art keywords
- catalyst
- particles
- fischer
- ammonium
- stage
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- 239000003054 catalyst Substances 0.000 title claims abstract description 190
- 239000000203 mixture Substances 0.000 title claims description 44
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 title claims description 29
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 title claims description 29
- 239000001099 ammonium carbonate Substances 0.000 title claims description 29
- 235000012501 ammonium carbonate Nutrition 0.000 title claims description 29
- 239000000908 ammonium hydroxide Substances 0.000 title claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 28
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims description 21
- 230000003647 oxidation Effects 0.000 title claims description 13
- 238000007254 oxidation reaction Methods 0.000 title claims description 13
- 238000011069 regeneration method Methods 0.000 title description 8
- 230000008929 regeneration Effects 0.000 title description 5
- 239000002245 particle Substances 0.000 claims abstract description 137
- 238000000034 method Methods 0.000 claims abstract description 82
- 239000007789 gas Substances 0.000 claims abstract description 44
- 239000002904 solvent Substances 0.000 claims abstract description 40
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 35
- 239000010941 cobalt Substances 0.000 claims abstract description 35
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- 239000001257 hydrogen Substances 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000011065 in-situ storage Methods 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 10
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- 238000012545 processing Methods 0.000 claims description 35
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- 238000003786 synthesis reaction Methods 0.000 claims description 27
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 26
- 238000011049 filling Methods 0.000 claims description 21
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- 150000007524 organic acids Chemical class 0.000 claims description 8
- 235000005985 organic acids Nutrition 0.000 claims description 8
- 150000003863 ammonium salts Chemical class 0.000 claims description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Chemical group 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 125000005537 sulfoxonium group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/02—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
- B01J38/66—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts using ammonia or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08172162 | 2008-12-18 | ||
| EP08172162.3 | 2008-12-18 | ||
| PCT/EP2009/067242 WO2010069978A1 (en) | 2008-12-18 | 2009-12-16 | Regeneration of a fischer tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2011129680A RU2011129680A (ru) | 2013-01-27 |
| RU2522324C2 true RU2522324C2 (ru) | 2014-07-10 |
Family
ID=41120012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2011129680/04A RU2522324C2 (ru) | 2008-12-18 | 2009-12-16 | Регенерация катализатора фишера-тропша путем его окисления и обработки смесью карбоната аммония, гидроксида аммония и воды |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20100160146A1 (enExample) |
| EP (1) | EP2367630A1 (enExample) |
| JP (1) | JP2012512735A (enExample) |
| AU (1) | AU2009327162B2 (enExample) |
| MY (1) | MY156352A (enExample) |
| RU (1) | RU2522324C2 (enExample) |
| WO (1) | WO2010069978A1 (enExample) |
| ZA (1) | ZA201103396B (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8729140B2 (en) * | 2010-12-23 | 2014-05-20 | Shell Oil Company | Process for regenerating a catalyst |
| FR3022471A1 (fr) * | 2014-06-23 | 2015-12-25 | Lab Sa | Procede de regeneration d'un catalyseur de denitrification contenant des oxydes de fer et/ou de manganese |
| EP3229957B1 (en) * | 2014-12-12 | 2021-04-07 | Bp P.L.C. | Fischer-tropsch process using reduced cobalt catalyst |
| EP3230408B1 (en) * | 2014-12-12 | 2020-02-05 | Bp P.L.C. | Fischer-tropsch process using reductively-activated cobalt catalyst |
| GB201505668D0 (en) * | 2015-04-01 | 2015-05-13 | Compactgtl Ltd | Processing a methane-containing feed gas |
| CN108339552A (zh) * | 2017-01-25 | 2018-07-31 | 中国石油化工股份有限公司 | 一种费托反应过程中恢复催化剂性能的方法及费托合成方法 |
| CN108339576A (zh) * | 2017-01-25 | 2018-07-31 | 中国石油化工股份有限公司 | 一种费托反应过程中恢复催化剂性能的方法及费托合成方法 |
| US12515210B2 (en) * | 2020-07-06 | 2026-01-06 | Topsoe A/S | Regenerating the catalytic activity of a spent catalyst |
| KR20230069085A (ko) * | 2020-07-09 | 2023-05-18 | 커먼웰쓰 사이언티픽 앤 인더스트리알 리서치 오거니제이션 | 촉매 활성 스캐폴드의 제조 방법 |
| GB202306879D0 (en) | 2023-05-10 | 2023-06-21 | Johnson Matthey Davy Technologies Ltd | Method of passivating a fischer-tropsch catalyst |
| WO2025249514A1 (ja) * | 2024-05-29 | 2025-12-04 | 古河電気工業株式会社 | 液化石油ガス合成用触媒の再生方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2198868C2 (ru) * | 1997-06-26 | 2003-02-20 | Аджип Петроли С.П.А. | Способ, проводимый в реакторе с барботажной колонной с продувной трубой, и способ регенерации содержащегося в нем катализатора |
| US6559191B1 (en) * | 2000-09-01 | 2003-05-06 | Exxonmobil Research And Engineering Company | Carbon monoxide hydrogenation (JSS-0004) |
| US6753354B2 (en) * | 2002-01-29 | 2004-06-22 | Exxonmobil Research And Engineering Company | Fischer-tropsch catalyst enhancement |
| US6838487B1 (en) * | 2003-12-04 | 2005-01-04 | Rentech, Inc. | Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6800579B2 (en) * | 2002-01-29 | 2004-10-05 | Exxonmobil Research And Engineering Company | Catalyst regeneration |
| US20050173297A1 (en) * | 2002-05-22 | 2005-08-11 | Yasuhiro Toida | Adsorption desulfurization agent for desulfurizing petroleum fraction and desulfurization method using the same |
| WO2009118372A1 (en) * | 2008-03-28 | 2009-10-01 | Shell Internationale Research Maatschappij B.V. | Process for regenerating a catalyst |
| WO2011080073A2 (en) * | 2009-12-16 | 2011-07-07 | Shell Internationale Research Maatschappij B.V. | Process for regenerating a catalyst |
-
2009
- 2009-12-16 EP EP09775199A patent/EP2367630A1/en not_active Withdrawn
- 2009-12-16 JP JP2011541404A patent/JP2012512735A/ja not_active Withdrawn
- 2009-12-16 MY MYPI2011002299A patent/MY156352A/en unknown
- 2009-12-16 US US12/639,707 patent/US20100160146A1/en not_active Abandoned
- 2009-12-16 WO PCT/EP2009/067242 patent/WO2010069978A1/en not_active Ceased
- 2009-12-16 AU AU2009327162A patent/AU2009327162B2/en not_active Ceased
- 2009-12-16 RU RU2011129680/04A patent/RU2522324C2/ru not_active IP Right Cessation
-
2011
- 2011-05-10 ZA ZA2011/03396A patent/ZA201103396B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2198868C2 (ru) * | 1997-06-26 | 2003-02-20 | Аджип Петроли С.П.А. | Способ, проводимый в реакторе с барботажной колонной с продувной трубой, и способ регенерации содержащегося в нем катализатора |
| US6559191B1 (en) * | 2000-09-01 | 2003-05-06 | Exxonmobil Research And Engineering Company | Carbon monoxide hydrogenation (JSS-0004) |
| US6753354B2 (en) * | 2002-01-29 | 2004-06-22 | Exxonmobil Research And Engineering Company | Fischer-tropsch catalyst enhancement |
| US6838487B1 (en) * | 2003-12-04 | 2005-01-04 | Rentech, Inc. | Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2009327162B2 (en) | 2013-07-18 |
| RU2011129680A (ru) | 2013-01-27 |
| AU2009327162A1 (en) | 2010-06-24 |
| WO2010069978A1 (en) | 2010-06-24 |
| US20100160146A1 (en) | 2010-06-24 |
| MY156352A (en) | 2016-02-15 |
| JP2012512735A (ja) | 2012-06-07 |
| ZA201103396B (en) | 2012-01-25 |
| EP2367630A1 (en) | 2011-09-28 |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20201217 |