AU2009327162B2 - Regeneration of a Fischer Tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water - Google Patents

Regeneration of a Fischer Tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water Download PDF

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Publication number
AU2009327162B2
AU2009327162B2 AU2009327162A AU2009327162A AU2009327162B2 AU 2009327162 B2 AU2009327162 B2 AU 2009327162B2 AU 2009327162 A AU2009327162 A AU 2009327162A AU 2009327162 A AU2009327162 A AU 2009327162A AU 2009327162 B2 AU2009327162 B2 AU 2009327162B2
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AU
Australia
Prior art keywords
catalyst
catalyst particle
process according
particle
fischer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2009327162A
Other languages
English (en)
Other versions
AU2009327162A1 (en
Inventor
Gerrit Leendert Bezemer
Stephen Nkrumah
Heiko Oosterbeek
Erwin Roderick Stobbe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of AU2009327162A1 publication Critical patent/AU2009327162A1/en
Application granted granted Critical
Publication of AU2009327162B2 publication Critical patent/AU2009327162B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • B01J38/66—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts using ammonia or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
AU2009327162A 2008-12-18 2009-12-16 Regeneration of a Fischer Tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water Ceased AU2009327162B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08172162 2008-12-18
EP08172162.3 2008-12-18
PCT/EP2009/067242 WO2010069978A1 (en) 2008-12-18 2009-12-16 Regeneration of a fischer tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water

Publications (2)

Publication Number Publication Date
AU2009327162A1 AU2009327162A1 (en) 2010-06-24
AU2009327162B2 true AU2009327162B2 (en) 2013-07-18

Family

ID=41120012

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2009327162A Ceased AU2009327162B2 (en) 2008-12-18 2009-12-16 Regeneration of a Fischer Tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water

Country Status (8)

Country Link
US (1) US20100160146A1 (enExample)
EP (1) EP2367630A1 (enExample)
JP (1) JP2012512735A (enExample)
AU (1) AU2009327162B2 (enExample)
MY (1) MY156352A (enExample)
RU (1) RU2522324C2 (enExample)
WO (1) WO2010069978A1 (enExample)
ZA (1) ZA201103396B (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8729140B2 (en) * 2010-12-23 2014-05-20 Shell Oil Company Process for regenerating a catalyst
FR3022471A1 (fr) * 2014-06-23 2015-12-25 Lab Sa Procede de regeneration d'un catalyseur de denitrification contenant des oxydes de fer et/ou de manganese
EP3229957B1 (en) * 2014-12-12 2021-04-07 Bp P.L.C. Fischer-tropsch process using reduced cobalt catalyst
EP3230408B1 (en) * 2014-12-12 2020-02-05 Bp P.L.C. Fischer-tropsch process using reductively-activated cobalt catalyst
GB201505668D0 (en) * 2015-04-01 2015-05-13 Compactgtl Ltd Processing a methane-containing feed gas
CN108339552A (zh) * 2017-01-25 2018-07-31 中国石油化工股份有限公司 一种费托反应过程中恢复催化剂性能的方法及费托合成方法
CN108339576A (zh) * 2017-01-25 2018-07-31 中国石油化工股份有限公司 一种费托反应过程中恢复催化剂性能的方法及费托合成方法
US12515210B2 (en) * 2020-07-06 2026-01-06 Topsoe A/S Regenerating the catalytic activity of a spent catalyst
KR20230069085A (ko) * 2020-07-09 2023-05-18 커먼웰쓰 사이언티픽 앤 인더스트리알 리서치 오거니제이션 촉매 활성 스캐폴드의 제조 방법
GB202306879D0 (en) 2023-05-10 2023-06-21 Johnson Matthey Davy Technologies Ltd Method of passivating a fischer-tropsch catalyst
WO2025249514A1 (ja) * 2024-05-29 2025-12-04 古河電気工業株式会社 液化石油ガス合成用触媒の再生方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6753354B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Fischer-tropsch catalyst enhancement

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1292422B1 (it) * 1997-06-26 1999-02-08 Agip Petroli Reattore a bolle con draft tube e procedimento per la rigenerazione del catalizzatore in esso contenuto
US6559191B1 (en) * 2000-09-01 2003-05-06 Exxonmobil Research And Engineering Company Carbon monoxide hydrogenation (JSS-0004)
US6800579B2 (en) * 2002-01-29 2004-10-05 Exxonmobil Research And Engineering Company Catalyst regeneration
US20050173297A1 (en) * 2002-05-22 2005-08-11 Yasuhiro Toida Adsorption desulfurization agent for desulfurizing petroleum fraction and desulfurization method using the same
US6838487B1 (en) * 2003-12-04 2005-01-04 Rentech, Inc. Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst
WO2009118372A1 (en) * 2008-03-28 2009-10-01 Shell Internationale Research Maatschappij B.V. Process for regenerating a catalyst
WO2011080073A2 (en) * 2009-12-16 2011-07-07 Shell Internationale Research Maatschappij B.V. Process for regenerating a catalyst

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6753354B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Fischer-tropsch catalyst enhancement

Also Published As

Publication number Publication date
RU2011129680A (ru) 2013-01-27
AU2009327162A1 (en) 2010-06-24
WO2010069978A1 (en) 2010-06-24
US20100160146A1 (en) 2010-06-24
MY156352A (en) 2016-02-15
JP2012512735A (ja) 2012-06-07
ZA201103396B (en) 2012-01-25
RU2522324C2 (ru) 2014-07-10
EP2367630A1 (en) 2011-09-28

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MK14 Patent ceased section 143(a) (annual fees not paid) or expired