RU2476584C2 - Способ извлечения ароматических углеводородов из коксового газа абсорбцией - Google Patents
Способ извлечения ароматических углеводородов из коксового газа абсорбцией Download PDFInfo
- Publication number
- RU2476584C2 RU2476584C2 RU2010102933/05A RU2010102933A RU2476584C2 RU 2476584 C2 RU2476584 C2 RU 2476584C2 RU 2010102933/05 A RU2010102933/05 A RU 2010102933/05A RU 2010102933 A RU2010102933 A RU 2010102933A RU 2476584 C2 RU2476584 C2 RU 2476584C2
- Authority
- RU
- Russia
- Prior art keywords
- aromatic hydrocarbons
- scrubber
- diesel
- absorption
- diesel biofuel
- Prior art date
Links
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 44
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title claims abstract description 32
- 239000000571 coke Substances 0.000 title claims abstract description 30
- 238000000605 extraction Methods 0.000 title description 2
- 239000002551 biofuel Substances 0.000 claims abstract description 44
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims description 35
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 13
- 150000004702 methyl esters Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 239000003225 biodiesel Substances 0.000 claims 2
- 238000011010 flushing procedure Methods 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 4
- 238000001704 evaporation Methods 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 54
- 239000003921 oil Substances 0.000 description 30
- 235000019198 oils Nutrition 0.000 description 30
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 239000008096 xylene Substances 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000002283 diesel fuel Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 239000002641 tar oil Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 150000003738 xylenes Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000002262 irrigation Effects 0.000 description 2
- 238000003973 irrigation Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 241001133760 Acoelorraphe Species 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 239000004165 Methyl ester of fatty acids Substances 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7027—Aromatic hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Industrial Gases (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Processing Of Solid Wastes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007030367 | 2007-06-29 | ||
| DE102007030367.1 | 2007-06-29 | ||
| PCT/EP2008/005253 WO2009003644A1 (de) | 2007-06-29 | 2008-06-27 | Verfahren zur entfernung von aromatischen kohlenwasserstoffen aus kokereigas durch absorption |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010102933A RU2010102933A (ru) | 2011-08-10 |
| RU2476584C2 true RU2476584C2 (ru) | 2013-02-27 |
Family
ID=39773003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010102933/05A RU2476584C2 (ru) | 2007-06-29 | 2008-06-27 | Способ извлечения ароматических углеводородов из коксового газа абсорбцией |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US8241429B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2162511B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5762741B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101542265B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101688136B (cg-RX-API-DMAC7.html) |
| AR (1) | AR067187A1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2008271586B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0813478B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2691366C (cg-RX-API-DMAC7.html) |
| CL (1) | CL2008001917A1 (cg-RX-API-DMAC7.html) |
| CO (1) | CO6251329A2 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2574982T3 (cg-RX-API-DMAC7.html) |
| MX (1) | MX2009013792A (cg-RX-API-DMAC7.html) |
| MY (1) | MY147784A (cg-RX-API-DMAC7.html) |
| PL (1) | PL2162511T3 (cg-RX-API-DMAC7.html) |
| RU (1) | RU2476584C2 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI455754B (cg-RX-API-DMAC7.html) |
| UA (1) | UA98336C2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2009003644A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102021044B (zh) * | 2009-09-15 | 2013-02-27 | 中国海洋石油总公司 | 一种碎煤加压获取合成气的方法 |
| DE102012107333A1 (de) | 2012-08-09 | 2014-02-13 | Thyssenkrupp Uhde Gmbh | Verfahren zur Regeneration einer für eine Gaswäsche vorgesehenen und mit aromatischen Kohlenwasserstoffen angereicherten Waschflüssigkeit sowie Regenerationsanordnung |
| DE102012107336A1 (de) | 2012-08-09 | 2014-02-13 | Thyssenkrupp Uhde Gmbh | Verfahren zur Entfernung von aromatischen Kohlenwasserstoffen aus Kokereigas mit Biodiesel als Waschflüssigkeit und Vorrichtung zur Durchführung des Verfahrens |
| US20150209719A1 (en) * | 2012-08-09 | 2015-07-30 | Thyssenkrupp Industrial Solutions Ag | Method for removing aromatic hydrocarbons from coke oven gas having biodiesel as washing liquid and device for carrying out said method |
| CN102816609A (zh) * | 2012-09-13 | 2012-12-12 | 上海梅山工业民用工程设计研究院有限公司 | 焦炉煤气干湿结合法精制净化工艺 |
| DE102013113933A1 (de) * | 2013-12-12 | 2015-06-18 | Thyssenkrupp Ag | Verfahren zur Erzeugung von Synthesegas im Verbund mit einem Hüttenwerk |
| EP3320963A1 (de) | 2016-11-15 | 2018-05-16 | Basf Se | Verfahren zur abreicherung von aromatischem kohlenwasserstoff aus einen rohgasstrom |
| KR102175834B1 (ko) * | 2018-09-07 | 2020-11-06 | 주식회사 포스코 | 코크스 오븐 가스 정제 방법 및 그 장치 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU242848A1 (ru) * | СПОСОБ ОЧИСТКИ коксового ГАЗА ОТ АРОМАТИЧЕСКИХ | |||
| SU138928A1 (ru) * | 1960-12-28 | 1961-11-30 | Ю.Н. Гарбер | Способ извлечени ароматических соединений из коксовых газов |
| DE19824747A1 (de) * | 1998-06-03 | 1999-12-09 | Ulrich Hattingen | Verfahren zur Entfernung von Holzteer aus Holzgas unter weitestgehendem Ausschluß einer Entsorgungsproblematik |
| RU2152919C1 (ru) * | 1999-09-09 | 2000-07-20 | ОАО "Ярегская нефтетитановая компания" | Способ выделения ароматических углеводородов из коксового газа |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1731716A (en) * | 1926-06-29 | 1929-10-15 | Twitchell Process Company | Process of removing oil from mineral-oil-sulphonic bodies |
| US3312749A (en) * | 1963-07-24 | 1967-04-04 | Bethlehem Steel Corp | Removal of aromatic compounds from coke oven gas |
| JPS5163384A (en) * | 1974-11-29 | 1976-06-01 | Sueji Tsuboi | Haikichuno yozaigasuno jokyohoho |
| JPH05163384A (ja) * | 1991-12-12 | 1993-06-29 | Asahi Chem Ind Co Ltd | コンタクトレンズ用材料 |
| JP4200904B2 (ja) * | 2004-01-08 | 2008-12-24 | 三菱化学株式会社 | ガス中の粗軽油分の回収方法 |
| DE102005009625A1 (de) * | 2005-01-04 | 2006-07-20 | Friedrich Sievers | Verfahren und Vorrichtung zur Behandlung von mit flüchtigen organischen Stoffen beladener Abluft |
| JP4564907B2 (ja) * | 2005-09-05 | 2010-10-20 | 茂人 早藤 | 超臨界水分解ガスの処理方法、及びこれを利用したエネルギー回収システム、有機化合物製造システム |
-
2008
- 2008-06-26 AR ARP080102764A patent/AR067187A1/es not_active Application Discontinuation
- 2008-06-27 AU AU2008271586A patent/AU2008271586B2/en not_active Ceased
- 2008-06-27 MY MYPI20095596A patent/MY147784A/en unknown
- 2008-06-27 US US12/664,906 patent/US8241429B2/en not_active Expired - Fee Related
- 2008-06-27 TW TW097124447A patent/TWI455754B/zh not_active IP Right Cessation
- 2008-06-27 JP JP2010513757A patent/JP5762741B2/ja not_active Expired - Fee Related
- 2008-06-27 CN CN2008800226265A patent/CN101688136B/zh not_active Expired - Fee Related
- 2008-06-27 CL CL2008001917A patent/CL2008001917A1/es unknown
- 2008-06-27 RU RU2010102933/05A patent/RU2476584C2/ru not_active IP Right Cessation
- 2008-06-27 KR KR1020107001952A patent/KR101542265B1/ko not_active Expired - Fee Related
- 2008-06-27 UA UAA201000781A patent/UA98336C2/uk unknown
- 2008-06-27 MX MX2009013792A patent/MX2009013792A/es active IP Right Grant
- 2008-06-27 WO PCT/EP2008/005253 patent/WO2009003644A1/de not_active Ceased
- 2008-06-27 CA CA2691366A patent/CA2691366C/en not_active Expired - Fee Related
- 2008-06-27 ES ES08784561.6T patent/ES2574982T3/es active Active
- 2008-06-27 PL PL08784561.6T patent/PL2162511T3/pl unknown
- 2008-06-27 BR BRPI0813478-2A patent/BRPI0813478B1/pt not_active IP Right Cessation
- 2008-06-27 EP EP08784561.6A patent/EP2162511B1/de not_active Not-in-force
-
2009
- 2009-12-17 CO CO09144705A patent/CO6251329A2/es active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU242848A1 (ru) * | СПОСОБ ОЧИСТКИ коксового ГАЗА ОТ АРОМАТИЧЕСКИХ | |||
| SU218139A1 (ru) * | Е. Я. Кузьмина, Н. Н. Иванова, А. М. Элькес, В. Г. Петренко | Способ извлечения ароматических углеводородов | ||
| SU138928A1 (ru) * | 1960-12-28 | 1961-11-30 | Ю.Н. Гарбер | Способ извлечени ароматических соединений из коксовых газов |
| DE19824747A1 (de) * | 1998-06-03 | 1999-12-09 | Ulrich Hattingen | Verfahren zur Entfernung von Holzteer aus Holzgas unter weitestgehendem Ausschluß einer Entsorgungsproblematik |
| RU2152919C1 (ru) * | 1999-09-09 | 2000-07-20 | ОАО "Ярегская нефтетитановая компания" | Способ выделения ароматических углеводородов из коксового газа |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5762741B2 (ja) | 2015-08-12 |
| CL2008001917A1 (es) | 2009-03-06 |
| MY147784A (en) | 2013-01-31 |
| US8241429B2 (en) | 2012-08-14 |
| EP2162511A1 (de) | 2010-03-17 |
| TWI455754B (zh) | 2014-10-11 |
| EP2162511B1 (de) | 2016-04-06 |
| PL2162511T3 (pl) | 2016-10-31 |
| AR067187A1 (es) | 2009-09-30 |
| BRPI0813478A2 (pt) | 2015-01-06 |
| KR20100041793A (ko) | 2010-04-22 |
| MX2009013792A (es) | 2010-02-03 |
| CA2691366C (en) | 2015-10-13 |
| BRPI0813478B1 (pt) | 2017-09-12 |
| CA2691366A1 (en) | 2009-01-08 |
| UA98336C2 (uk) | 2012-05-10 |
| CN101688136A (zh) | 2010-03-31 |
| RU2010102933A (ru) | 2011-08-10 |
| CN101688136B (zh) | 2013-03-06 |
| TW200920468A (en) | 2009-05-16 |
| US20100294312A1 (en) | 2010-11-25 |
| WO2009003644A1 (de) | 2009-01-08 |
| CO6251329A2 (es) | 2011-02-21 |
| AU2008271586B2 (en) | 2012-08-23 |
| KR101542265B1 (ko) | 2015-08-06 |
| JP2010531903A (ja) | 2010-09-30 |
| ES2574982T3 (es) | 2016-06-23 |
| AU2008271586A1 (en) | 2009-01-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20190628 |