RU2418618C2 - Предварительно приготовленная смесь для получения абсорбента для удаления кислых газов из потоков жидкостей - Google Patents
Предварительно приготовленная смесь для получения абсорбента для удаления кислых газов из потоков жидкостей Download PDFInfo
- Publication number
- RU2418618C2 RU2418618C2 RU2008150043/05A RU2008150043A RU2418618C2 RU 2418618 C2 RU2418618 C2 RU 2418618C2 RU 2008150043/05 A RU2008150043/05 A RU 2008150043/05A RU 2008150043 A RU2008150043 A RU 2008150043A RU 2418618 C2 RU2418618 C2 RU 2418618C2
- Authority
- RU
- Russia
- Prior art keywords
- piperazine
- alkanolamine
- water
- mixture according
- mixture
- Prior art date
Links
- 239000002250 absorbent Substances 0.000 title claims abstract description 23
- 230000002745 absorbent Effects 0.000 title claims abstract description 23
- 239000007789 gas Substances 0.000 title claims description 30
- 239000002253 acid Substances 0.000 title description 13
- 239000012530 fluid Substances 0.000 title description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims abstract description 146
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims description 56
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- 238000007711 solidification Methods 0.000 abstract description 18
- 230000008023 solidification Effects 0.000 abstract description 18
- 239000000126 substance Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract 1
- 238000010327 methods by industry Methods 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000003345 natural gas Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009264 composting Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- -1 for example Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- BVEXVMARIREFTJ-TXMWGMRISA-N methyl (2r)-3-[(2s,6r,8s,11r)-2-[(e,2r)-4-[(2s,2'r,4r,4as,6r,8ar)-4-hydroxy-2-[(1s,3s)-1-hydroxy-3-[(2s,3r,6s)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl]butyl]-3-methylidenespiro[4a,7,8,8a-tetrahydro-4h-pyrano[3,2-b]pyran-6,5'-oxolane]-2'-yl]but-3-en-2-yl] Chemical compound O1[C@H](C[C@@](C)(O)C(=O)OC)CC[C@@H](O)[C@@]21C=C(C)C[C@@H]([C@H](C)\C=C\[C@@H]1O[C@@]3(O[C@H]4[C@H](O)C(=C)[C@@H]([C@@H](O)C[C@H](C)[C@@H]5[C@@H](CC[C@@]6(OCCCC6)O5)C)O[C@@H]4CC3)CC1)O2 BVEXVMARIREFTJ-TXMWGMRISA-N 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000003655 absorption accelerator Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06114244 | 2006-05-19 | ||
| EP06114244.4 | 2006-05-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008150043A RU2008150043A (ru) | 2010-06-27 |
| RU2418618C2 true RU2418618C2 (ru) | 2011-05-20 |
Family
ID=38326212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008150043/05A RU2418618C2 (ru) | 2006-05-19 | 2007-05-18 | Предварительно приготовленная смесь для получения абсорбента для удаления кислых газов из потоков жидкостей |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US8476475B2 (en:Method) |
| EP (1) | EP2024060B1 (en:Method) |
| JP (2) | JP5054764B2 (en:Method) |
| AR (1) | AR061033A1 (en:Method) |
| AU (1) | AU2007253355B2 (en:Method) |
| BR (1) | BRPI0711903B1 (en:Method) |
| CA (1) | CA2651265C (en:Method) |
| EG (1) | EG26002A (en:Method) |
| ES (1) | ES2584504T3 (en:Method) |
| HU (1) | HUE029307T2 (en:Method) |
| IN (1) | IN266779B (en:Method) |
| MX (1) | MX2008013856A (en:Method) |
| MY (1) | MY148244A (en:Method) |
| NO (1) | NO20084638L (en:Method) |
| PE (1) | PE20080246A1 (en:Method) |
| PL (1) | PL2024060T3 (en:Method) |
| PT (1) | PT2024060T (en:Method) |
| RU (1) | RU2418618C2 (en:Method) |
| WO (1) | WO2007135100A1 (en:Method) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10449483B2 (en) | 2013-08-29 | 2019-10-22 | Dow Global Technologies Llc | Gas sweetening solvents containing quaternary ammonium salts |
| RU2823675C2 (ru) * | 2022-11-30 | 2024-07-29 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского" | Способ повышения эффективности удаления диоксида углерода и сероводорода из метансодержащих газовых смесей |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010004070A1 (de) * | 2010-01-05 | 2011-07-07 | Uhde GmbH, 44141 | CO2-Entfernung aus Gasen mittels wässriger Amin-Lösung unter Zusatz eines sterisch gehinderten Amins |
| US8816078B2 (en) | 2010-01-12 | 2014-08-26 | Board Of Regents, The University Of Texas System | Acidic gas removal by aqueous amine solvents |
| KR101350902B1 (ko) * | 2011-10-13 | 2014-01-16 | 한국에너지기술연구원 | 반응증진제를 포함하는 이산화탄소 흡수제 |
| WO2013110092A1 (en) | 2012-01-20 | 2013-07-25 | Board Of Regents, The University Of Texas System | Blends of amines with piperazine for co2 capture |
| JP2013158718A (ja) * | 2012-02-06 | 2013-08-19 | Ihi Corp | 二酸化炭素吸収液及びその調製方法 |
| US9458367B2 (en) | 2012-03-14 | 2016-10-04 | Exxonmobil Research And Engineering Company | Low temperature transport and storage of amine gas treatment solutions |
| KR20160058296A (ko) * | 2014-11-14 | 2016-05-25 | (주)티피티퍼시픽 | ２-아미노 ２-메틸 １-프로판올(ａｍｐ)를 포함하는 산성가스 제거용 흡수제 조성물 및 이를 이용한 산성가스 제거방법 |
| CA3020219C (en) * | 2016-04-18 | 2024-06-18 | Basf Se | Premix for producing an absorption agent for removing acid gases from a fluid flow |
| ES2697300B2 (es) | 2017-07-21 | 2019-05-24 | Univ Sevilla | Composicion acuosa para la separacion de co2 y/o gases acidos |
| JP6963518B2 (ja) * | 2017-11-28 | 2021-11-10 | 株式会社東芝 | 酸性ガス吸収剤、酸性ガスの除去方法および酸性ガス除去装置 |
| USD907445S1 (en) | 2018-12-11 | 2021-01-12 | Yeti Coolers, Llc | Container accessories |
| MX2023007142A (es) * | 2020-12-16 | 2023-08-25 | Dow Global Technologies Llc | Medio de absorcion acuoso para la eliminacion de gases acidos. |
| JP2024114652A (ja) * | 2023-02-10 | 2024-08-23 | 東ソー株式会社 | 二酸化炭素分離用アミン組成物、及びその製造方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4336233A (en) * | 1975-11-18 | 1982-06-22 | Basf Aktiengesellschaft | Removal of CO2 and/or H2 S and/or COS from gases containing these constituents |
| EP0879631A1 (en) * | 1994-10-06 | 1998-11-25 | The Kansai Electric Power Co., Inc. | Process for removing carbon dioxide from gases |
| WO2002009849A2 (en) * | 2000-07-27 | 2002-02-07 | Continental Engineering B.V. | Method and installation for the recovery of pure co2 from flue gas |
| RU2230599C2 (ru) * | 2000-10-25 | 2004-06-20 | Дзе Кансай Электрик Пауэр Ко., Инк. | Способ извлечения аминосоединения из сопровождающего обезуглероженного выпускного газа в колонне абсорбции |
| RU2239488C2 (ru) * | 1999-05-03 | 2004-11-10 | Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн | Абсорбирующие композиции для удаления кислых газов из газовых потоков |
| US6939393B2 (en) * | 2000-07-25 | 2005-09-06 | Basf Aktiengesellschaft | Method for neutralizing a stream of fluid, and washing liquid for use in one such method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2871335B2 (ja) * | 1992-02-27 | 1999-03-17 | 関西電力株式会社 | 燃焼排ガス中の二酸化炭素を除去する方法 |
| JP3233809B2 (ja) * | 1995-03-23 | 2001-12-04 | 関西電力株式会社 | 燃焼排ガス中の二酸化炭素を除去する方法 |
| DE10135370A1 (de) | 2001-07-20 | 2003-01-30 | Basf Ag | Verfahren zur Entfernung saurer Gase aus einem Gasstrom |
| DE10210729A1 (de) * | 2002-03-12 | 2003-10-02 | Basf Ag | Verfahren zum Entsäuern eines Fluidstroms und Waschflüssigkeit zur Verwendung in einem derartigen Verfahren |
| DE102004011427A1 (de) | 2004-03-09 | 2005-09-29 | Basf Ag | Absorptionsmittel mit verbesserter Oxidationsbeständigkeit und Verfahren zum Entsäuern von Fluidströmen |
-
2007
- 2007-05-18 IN IN6313CHN2008 patent/IN266779B/en unknown
- 2007-05-18 PL PL07729280.3T patent/PL2024060T3/pl unknown
- 2007-05-18 BR BRPI0711903-8A patent/BRPI0711903B1/pt not_active IP Right Cessation
- 2007-05-18 MY MYPI20084681A patent/MY148244A/en unknown
- 2007-05-18 US US12/301,477 patent/US8476475B2/en active Active
- 2007-05-18 EP EP07729280.3A patent/EP2024060B1/de active Active
- 2007-05-18 ES ES07729280.3T patent/ES2584504T3/es active Active
- 2007-05-18 CA CA2651265A patent/CA2651265C/en active Active
- 2007-05-18 PT PT77292803T patent/PT2024060T/pt unknown
- 2007-05-18 AR ARP070102168A patent/AR061033A1/es not_active Application Discontinuation
- 2007-05-18 PE PE2007000613A patent/PE20080246A1/es not_active Application Discontinuation
- 2007-05-18 WO PCT/EP2007/054836 patent/WO2007135100A1/de not_active Ceased
- 2007-05-18 HU HUE07729280A patent/HUE029307T2/en unknown
- 2007-05-18 MX MX2008013856A patent/MX2008013856A/es active IP Right Grant
- 2007-05-18 JP JP2009511482A patent/JP5054764B2/ja active Active
- 2007-05-18 RU RU2008150043/05A patent/RU2418618C2/ru active
- 2007-05-18 AU AU2007253355A patent/AU2007253355B2/en active Active
-
2008
- 2008-11-04 NO NO20084638A patent/NO20084638L/no not_active Application Discontinuation
- 2008-11-16 EG EG2008111862A patent/EG26002A/en active
-
2012
- 2012-04-23 JP JP2012098144A patent/JP5579222B2/ja not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4336233A (en) * | 1975-11-18 | 1982-06-22 | Basf Aktiengesellschaft | Removal of CO2 and/or H2 S and/or COS from gases containing these constituents |
| EP0879631A1 (en) * | 1994-10-06 | 1998-11-25 | The Kansai Electric Power Co., Inc. | Process for removing carbon dioxide from gases |
| RU2239488C2 (ru) * | 1999-05-03 | 2004-11-10 | Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн | Абсорбирующие композиции для удаления кислых газов из газовых потоков |
| US6939393B2 (en) * | 2000-07-25 | 2005-09-06 | Basf Aktiengesellschaft | Method for neutralizing a stream of fluid, and washing liquid for use in one such method |
| WO2002009849A2 (en) * | 2000-07-27 | 2002-02-07 | Continental Engineering B.V. | Method and installation for the recovery of pure co2 from flue gas |
| RU2230599C2 (ru) * | 2000-10-25 | 2004-06-20 | Дзе Кансай Электрик Пауэр Ко., Инк. | Способ извлечения аминосоединения из сопровождающего обезуглероженного выпускного газа в колонне абсорбции |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10449483B2 (en) | 2013-08-29 | 2019-10-22 | Dow Global Technologies Llc | Gas sweetening solvents containing quaternary ammonium salts |
| RU2823675C2 (ru) * | 2022-11-30 | 2024-07-29 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского" | Способ повышения эффективности удаления диоксида углерода и сероводорода из метансодержащих газовых смесей |
Also Published As
| Publication number | Publication date |
|---|---|
| US8476475B2 (en) | 2013-07-02 |
| EP2024060B1 (de) | 2016-04-27 |
| AU2007253355B2 (en) | 2011-03-17 |
| CA2651265C (en) | 2014-02-04 |
| JP2012152753A (ja) | 2012-08-16 |
| US20100204042A1 (en) | 2010-08-12 |
| PE20080246A1 (es) | 2008-05-10 |
| NO20084638L (no) | 2008-12-05 |
| HUE029307T2 (en) | 2017-02-28 |
| JP2009537318A (ja) | 2009-10-29 |
| MY148244A (en) | 2013-03-29 |
| MX2008013856A (es) | 2008-11-14 |
| BRPI0711903B1 (pt) | 2018-05-29 |
| ES2584504T3 (es) | 2016-09-28 |
| WO2007135100A1 (de) | 2007-11-29 |
| EP2024060A1 (de) | 2009-02-18 |
| PL2024060T3 (pl) | 2016-11-30 |
| JP5054764B2 (ja) | 2012-10-24 |
| IN266779B (en:Method) | 2015-06-01 |
| JP5579222B2 (ja) | 2014-08-27 |
| EG26002A (en) | 2012-12-06 |
| AR061033A1 (es) | 2008-07-30 |
| BRPI0711903A2 (pt) | 2012-07-10 |
| RU2008150043A (ru) | 2010-06-27 |
| PT2024060T (pt) | 2016-07-25 |
| AU2007253355A1 (en) | 2007-11-29 |
| CA2651265A1 (en) | 2007-11-29 |
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