RU2360933C2 - Способ приготовления полиолефиновых нанокомпозитов - Google Patents

Info

Publication number

RU2360933C2

RU2360933C2 RU2005117963/04A RU2005117963A RU2360933C2 RU 2360933 C2 RU2360933 C2 RU 2360933C2 RU 2005117963/04 A RU2005117963/04 A RU 2005117963/04A RU 2005117963 A RU2005117963 A RU 2005117963A RU 2360933 C2 RU2360933 C2 RU 2360933C2

Authority

RU

Russia

Prior art keywords

polyolefin

butyl

bis

ditret

poly

Prior art date

2002-11-08

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• 229920000098 polyolefin Polymers 0.000 title claims abstract description 89
• 239000002114 nanocomposite Substances 0.000 title claims abstract description 84
• 238000000034 method Methods 0.000 title claims abstract description 52
• -1 sorbitan ester Chemical class 0.000 claims abstract description 145
• 239000000203 mixture Substances 0.000 claims abstract description 48
• 229920001400 block copolymer Polymers 0.000 claims abstract description 47
• 239000000945 filler Substances 0.000 claims abstract description 35
• 238000002156 mixing Methods 0.000 claims abstract description 25
• 229910052615 phyllosilicate Inorganic materials 0.000 claims abstract description 7
• BHJPEPMMKXNBKV-UHFFFAOYSA-N 4,4-dimethyl-1,3,2-dioxasilolane Chemical compound CC1(C)CO[SiH2]O1 BHJPEPMMKXNBKV-UHFFFAOYSA-N 0.000 claims abstract description 6
• 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 64
• 239000002736 nonionic surfactant Substances 0.000 claims description 60
• 239000004743 Polypropylene Substances 0.000 claims description 56
• 229920001155 polypropylene Polymers 0.000 claims description 54
• 239000004927 clay Substances 0.000 claims description 50
• 239000000654 additive Substances 0.000 claims description 37
• 229920001577 copolymer Polymers 0.000 claims description 25
• 150000001875 compounds Chemical class 0.000 claims description 24
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 19
• 229910052751 metal Inorganic materials 0.000 claims description 15
• 239000002184 metal Substances 0.000 claims description 15
• 238000012545 processing Methods 0.000 claims description 13
• 239000003381 stabilizer Substances 0.000 claims description 13
• 239000004594 Masterbatch (MB) Substances 0.000 claims description 12
• 230000000996 additive effect Effects 0.000 claims description 12
• 150000002148 esters Chemical group 0.000 claims description 10
• 239000004014 plasticizer Substances 0.000 claims description 10
• 230000002209 hydrophobic effect Effects 0.000 claims description 9
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
• 125000000217 alkyl group Chemical group 0.000 claims description 8
• 239000004611 light stabiliser Substances 0.000 claims description 8
• 239000004698 Polyethylene Substances 0.000 claims description 7
• 239000002253 acid Substances 0.000 claims description 7
• 239000002530 phenolic antioxidant Substances 0.000 claims description 7
• 239000000049 pigment Substances 0.000 claims description 7
• 229920000573 polyethylene Polymers 0.000 claims description 7
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 6
• FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 6
• 239000003795 chemical substances by application Substances 0.000 claims description 6
• 239000000155 melt Substances 0.000 claims description 6
• 239000000600 sorbitol Substances 0.000 claims description 6
• 239000000370 acceptor Substances 0.000 claims description 5
• NKCVNYJQLIWBHK-UHFFFAOYSA-N carbonodiperoxoic acid Chemical compound OOC(=O)OO NKCVNYJQLIWBHK-UHFFFAOYSA-N 0.000 claims description 5
• GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 5
• 239000000975 dye Substances 0.000 claims description 5
• 125000000524 functional group Chemical group 0.000 claims description 5
• 229910001701 hydrotalcite Inorganic materials 0.000 claims description 5
• 229960001545 hydrotalcite Drugs 0.000 claims description 5
• 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 5
• 239000004926 polymethyl methacrylate Substances 0.000 claims description 5
• 230000009974 thixotropic effect Effects 0.000 claims description 5
• JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 4
• GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
• KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 4
• 230000001590 oxidative effect Effects 0.000 claims description 4
• CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
• BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
• 230000015556 catabolic process Effects 0.000 claims description 3
• 238000006731 degradation reaction Methods 0.000 claims description 3
• 239000010445 mica Substances 0.000 claims description 3
• 229910052618 mica group Inorganic materials 0.000 claims description 3
• 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
• 239000000440 bentonite Substances 0.000 claims description 2
• 229910000278 bentonite Inorganic materials 0.000 claims description 2
• SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
• VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 claims description 2
• 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
• 230000002708 enhancing effect Effects 0.000 claims description 2
• KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 2
• 229910000271 hectorite Inorganic materials 0.000 claims description 2
• 229910000273 nontronite Inorganic materials 0.000 claims description 2
• 239000002667 nucleating agent Substances 0.000 claims description 2
• 229910000275 saponite Inorganic materials 0.000 claims description 2
• 239000010455 vermiculite Substances 0.000 claims description 2
• 229910052902 vermiculite Inorganic materials 0.000 claims description 2
• 235000019354 vermiculite Nutrition 0.000 claims description 2
• 239000000126 substance Substances 0.000 abstract description 5
• 239000004094 surface-active agent Substances 0.000 abstract description 5
• 239000012803 melt mixture Substances 0.000 abstract 2
• 239000000047 product Substances 0.000 description 49
• 239000002202 Polyethylene glycol Substances 0.000 description 29
• 239000000463 material Substances 0.000 description 26
• 229910052757 nitrogen Inorganic materials 0.000 description 25
• 229920000642 polymer Polymers 0.000 description 19
• 229920001684 low density polyethylene Polymers 0.000 description 17
• 239000004702 low-density polyethylene Substances 0.000 description 17
• BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 16
• 239000010408 film Substances 0.000 description 16
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 13
• 238000000576 coating method Methods 0.000 description 13
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
• 150000001412 amines Chemical class 0.000 description 12
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
• 230000000052 comparative effect Effects 0.000 description 11
• 238000002360 preparation method Methods 0.000 description 11
• 239000011734 sodium Substances 0.000 description 11
• 239000011159 matrix material Substances 0.000 description 9
• 238000000465 moulding Methods 0.000 description 9
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• 238000006482 condensation reaction Methods 0.000 description 8
• 238000001746 injection moulding Methods 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
• 239000004793 Polystyrene Substances 0.000 description 7
• 239000003054 catalyst Substances 0.000 description 7
• 239000007789 gas Substances 0.000 description 7
• 239000011521 glass Substances 0.000 description 7
• 125000004432 carbon atom Chemical group C* 0.000 description 6
• 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
• 239000004205 dimethyl polysiloxane Substances 0.000 description 6
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
• 239000011777 magnesium Substances 0.000 description 6
• 238000005192 partition Methods 0.000 description 6
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
• OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 6
• 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 6
• 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
• 229920000974 Poly(dimethylsiloxane-ethylene oxide) Polymers 0.000 description 5
• 239000000853 adhesive Substances 0.000 description 5
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
• 239000011248 coating agent Substances 0.000 description 5
• 238000002474 experimental method Methods 0.000 description 5
• 238000001125 extrusion Methods 0.000 description 5
• 239000000835 fiber Substances 0.000 description 5
• FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
• 239000006259 organic additive Substances 0.000 description 5
• 239000001301 oxygen Substances 0.000 description 5
• 229910052760 oxygen Inorganic materials 0.000 description 5
• 238000004806 packaging method and process Methods 0.000 description 5
• 230000035699 permeability Effects 0.000 description 5
• 238000012360 testing method Methods 0.000 description 5
• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 4
• JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
• 150000001298 alcohols Chemical class 0.000 description 4
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
• 239000012964 benzotriazole Substances 0.000 description 4
• 125000001589 carboacyl group Chemical group 0.000 description 4
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
• 235000013305 food Nutrition 0.000 description 4
• XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
• 229920001903 high density polyethylene Polymers 0.000 description 4
• 239000004700 high-density polyethylene Substances 0.000 description 4
• 238000009830 intercalation Methods 0.000 description 4
• 239000010410 layer Substances 0.000 description 4
• 229910052749 magnesium Inorganic materials 0.000 description 4
• DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
• UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 4
• FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 4
• SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
• 150000002815 nickel Chemical class 0.000 description 4
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
• 229920002223 polystyrene Polymers 0.000 description 4
• 229960004063 propylene glycol Drugs 0.000 description 4
• 235000013772 propylene glycol Nutrition 0.000 description 4
• 230000009182 swimming Effects 0.000 description 4
• 238000009864 tensile test Methods 0.000 description 4
• ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
• 229910052725 zinc Inorganic materials 0.000 description 4
• 239000011701 zinc Substances 0.000 description 4
• DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 4
• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 3
• RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 3
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
• 239000005977 Ethylene Substances 0.000 description 3
• CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
• 239000004952 Polyamide Substances 0.000 description 3
• 229920002873 Polyethylenimine Polymers 0.000 description 3
• HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 3
• PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 3
• 239000006096 absorbing agent Substances 0.000 description 3
• 230000001070 adhesive effect Effects 0.000 description 3
• 150000001450 anions Chemical class 0.000 description 3
• 230000000386 athletic effect Effects 0.000 description 3
• 239000004305 biphenyl Substances 0.000 description 3
• 229910052799 carbon Inorganic materials 0.000 description 3
• 229910002091 carbon monoxide Inorganic materials 0.000 description 3
• 239000004568 cement Substances 0.000 description 3
• 239000002131 composite material Substances 0.000 description 3
• 150000001993 dienes Chemical class 0.000 description 3
• 229920006226 ethylene-acrylic acid Polymers 0.000 description 3
• 239000003063 flame retardant Substances 0.000 description 3
• 230000006872 improvement Effects 0.000 description 3
• 238000009413 insulation Methods 0.000 description 3
• 239000011229 interlayer Substances 0.000 description 3
• 239000003446 ligand Substances 0.000 description 3
• 230000007774 longterm Effects 0.000 description 3
• 238000004519 manufacturing process Methods 0.000 description 3
• 150000002739 metals Chemical class 0.000 description 3
• 150000005673 monoalkenes Chemical class 0.000 description 3
• 239000003921 oil Substances 0.000 description 3
• 230000003287 optical effect Effects 0.000 description 3
• 229920002647 polyamide Polymers 0.000 description 3
• 238000006116 polymerization reaction Methods 0.000 description 3
• 239000000843 powder Substances 0.000 description 3
• 150000003254 radicals Chemical class 0.000 description 3
• 238000002601 radiography Methods 0.000 description 3
• 238000010183 spectrum analysis Methods 0.000 description 3
• 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
• 238000003860 storage Methods 0.000 description 3
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
• 239000004753 textile Substances 0.000 description 3
• 239000002699 waste material Substances 0.000 description 3
• GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
• ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 2
• ZQMPWXFHAUDENN-UHFFFAOYSA-N 1,2-bis[(2-methylphenyl)amino]ethane Natural products CC1=CC=CC=C1NCCNC1=CC=CC=C1C ZQMPWXFHAUDENN-UHFFFAOYSA-N 0.000 description 2
• 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
• BUGAMLAPDQMYNZ-UHFFFAOYSA-N 1-(2,4,4-trimethylpentan-2-yl)-10h-phenothiazine Chemical class S1C2=CC=CC=C2NC2=C1C=CC=C2C(C)(C)CC(C)(C)C BUGAMLAPDQMYNZ-UHFFFAOYSA-N 0.000 description 2
• HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
• KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
• BWJKLDGAAPQXGO-UHFFFAOYSA-N 2,2,6,6-tetramethyl-4-octadecoxypiperidine Chemical compound CCCCCCCCCCCCCCCCCCOC1CC(C)(C)NC(C)(C)C1 BWJKLDGAAPQXGO-UHFFFAOYSA-N 0.000 description 2
• GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 2
• KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 2
• SAEZGDDJKSBNPT-UHFFFAOYSA-N 3-dodecyl-1-(1,2,2,6,6-pentamethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)N(C)C(C)(C)C1 SAEZGDDJKSBNPT-UHFFFAOYSA-N 0.000 description 2
• FBIXXCXCZOZFCO-UHFFFAOYSA-N 3-dodecyl-1-(2,2,6,6-tetramethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)NC(C)(C)C1 FBIXXCXCZOZFCO-UHFFFAOYSA-N 0.000 description 2
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 2
• BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• 239000004215 Carbon black (E152) Substances 0.000 description 2
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