RU2357984C2 - Облученные композиции на основе полибутена-1 - Google Patents
Облученные композиции на основе полибутена-1 Download PDFInfo
- Publication number
- RU2357984C2 RU2357984C2 RU2006107559/04A RU2006107559A RU2357984C2 RU 2357984 C2 RU2357984 C2 RU 2357984C2 RU 2006107559/04 A RU2006107559/04 A RU 2006107559/04A RU 2006107559 A RU2006107559 A RU 2006107559A RU 2357984 C2 RU2357984 C2 RU 2357984C2
- Authority
- RU
- Russia
- Prior art keywords
- irradiated
- polybutene
- butene
- homopolymer
- polymer
- Prior art date
Links
- 229920001748 polybutylene Polymers 0.000 title claims abstract description 75
- 230000005855 radiation Effects 0.000 title claims abstract description 14
- 150000001875 compounds Chemical class 0.000 title 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 95
- 229920001519 homopolymer Polymers 0.000 claims abstract description 22
- 238000002425 crystallisation Methods 0.000 claims abstract description 15
- 230000006911 nucleation Effects 0.000 claims abstract description 4
- 238000010899 nucleation Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 76
- 229920000642 polymer Polymers 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 36
- -1 polypropylene Polymers 0.000 claims description 20
- 239000000155 melt Substances 0.000 claims description 16
- 230000008025 crystallization Effects 0.000 claims description 14
- 229920001155 polypropylene Polymers 0.000 claims description 14
- 230000005865 ionizing radiation Effects 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000004711 α-olefin Substances 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 11
- 239000005977 Ethylene Substances 0.000 description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229920001083 polybutene Polymers 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 229920006027 ternary co-polymer Polymers 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002861 polymer material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 230000000171 quenching effect Effects 0.000 description 4
- 239000002667 nucleating agent Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000005482 strain hardening Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000002523 gelfiltration Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49447103P | 2003-08-12 | 2003-08-12 | |
| US60/494,471 | 2003-08-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006107559A RU2006107559A (ru) | 2006-09-10 |
| RU2357984C2 true RU2357984C2 (ru) | 2009-06-10 |
Family
ID=34135342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006107559/04A RU2357984C2 (ru) | 2003-08-12 | 2004-07-26 | Облученные композиции на основе полибутена-1 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20060258766A1 (https=) |
| EP (1) | EP1654320B1 (https=) |
| JP (1) | JP2007502338A (https=) |
| KR (1) | KR20060060685A (https=) |
| CN (1) | CN100480321C (https=) |
| AT (1) | ATE343611T1 (https=) |
| AU (1) | AU2004263737A1 (https=) |
| BR (1) | BRPI0413551A (https=) |
| CA (1) | CA2535444A1 (https=) |
| DE (1) | DE602004002965T2 (https=) |
| ES (1) | ES2273279T3 (https=) |
| PL (1) | PL1654320T3 (https=) |
| RU (1) | RU2357984C2 (https=) |
| WO (1) | WO2005014710A2 (https=) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7372041B1 (en) * | 2007-01-17 | 2008-05-13 | Radiation Monitoring Devices, Inc. | Neutron detectors and related methods |
| CN108250594B (zh) * | 2016-12-28 | 2020-11-03 | 天津大学 | 利用高能电子辐照促进等规聚1-丁烯复合材料中晶型ii-i转变的方法 |
| CN112778621B (zh) * | 2020-12-31 | 2023-01-10 | 安踏（中国）有限公司 | 一种用于制备运动鞋底用高弹记忆eva复合发泡材料的组合物及制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4916198A (en) * | 1985-01-31 | 1990-04-10 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| US5047446A (en) * | 1988-07-22 | 1991-09-10 | Himont Incorporated | Thermal treatment of irradiated propylene polymer material |
| US5508319A (en) * | 1991-06-21 | 1996-04-16 | Montell North America Inc. | High melt strength, ethylene polymer, process for making it, and use thereof |
| US6306970B1 (en) * | 1999-04-19 | 2001-10-23 | Montell Technology Company Bv | Soft propylene polymer blend with high melt strength |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3688258T3 (de) * | 1985-01-31 | 2001-02-22 | Montell North America Inc., Wilmington | Polypropylen mit freier Langkettenverzweigung, Verfahren zur Herstellung und Verwendung davon. |
| US4677025A (en) * | 1985-08-30 | 1987-06-30 | Shell Oil Company | Unique molecular weight distribution polybutylene blend and film |
| US4960820A (en) * | 1988-05-24 | 1990-10-02 | Shell Oil Company | Compositions and articles using high melt flow poly-1-butene and polypropylene blends |
| US5047485A (en) * | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| FI922879A7 (fi) * | 1991-06-21 | 1992-12-22 | Himont Inc | Etenpolymer med hoeg smaelthaollfasthet, foerfarande foer dess framstaellning och dess anvaendning |
| JPH0632929A (ja) * | 1992-07-17 | 1994-02-08 | Sekisui Chem Co Ltd | オレフィン系樹脂発泡体の製造方法 |
| US5368919A (en) * | 1993-05-20 | 1994-11-29 | Himont Incorporated | Propylene polymer compositions containing high melt strength propylene polymer material |
| US5414027A (en) * | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| US5508318A (en) * | 1993-07-15 | 1996-04-16 | Montell North America Inc. | Compositions of irradiated and non-irradiated olefin polymer materials with reduced gloss |
| JPH10298363A (ja) * | 1997-04-22 | 1998-11-10 | Tosoh Corp | 熱可塑性エラストマー樹脂組成物 |
| US6060533A (en) * | 1998-01-09 | 2000-05-09 | Montell North America Inc. | Process for making foam articles having good low temperature toughness from high melt strength propyline polymer materials |
| US6677395B1 (en) * | 2002-11-27 | 2004-01-13 | Basell Poliolefine Italia S.P.A. | Irradiated, oxidized olefin polymer dispersing agents |
| US6869982B2 (en) * | 2002-11-27 | 2005-03-22 | Basell Poliolefine Italia S.P.A. | Irradiated, oxidized olefin polymer coupling agents |
-
2004
- 2004-07-26 DE DE602004002965T patent/DE602004002965T2/de not_active Expired - Fee Related
- 2004-07-26 AU AU2004263737A patent/AU2004263737A1/en not_active Abandoned
- 2004-07-26 CN CNB2004800230116A patent/CN100480321C/zh not_active Expired - Fee Related
- 2004-07-26 AT AT04744134T patent/ATE343611T1/de not_active IP Right Cessation
- 2004-07-26 KR KR1020067002906A patent/KR20060060685A/ko not_active Ceased
- 2004-07-26 RU RU2006107559/04A patent/RU2357984C2/ru not_active IP Right Cessation
- 2004-07-26 BR BRPI0413551-2A patent/BRPI0413551A/pt not_active IP Right Cessation
- 2004-07-26 JP JP2006523067A patent/JP2007502338A/ja active Pending
- 2004-07-26 ES ES04744134T patent/ES2273279T3/es not_active Expired - Lifetime
- 2004-07-26 EP EP04744134A patent/EP1654320B1/en not_active Expired - Lifetime
- 2004-07-26 CA CA002535444A patent/CA2535444A1/en not_active Abandoned
- 2004-07-26 PL PL04744134T patent/PL1654320T3/pl unknown
- 2004-07-26 US US10/567,670 patent/US20060258766A1/en not_active Abandoned
- 2004-07-26 WO PCT/IB2004/002483 patent/WO2005014710A2/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4916198A (en) * | 1985-01-31 | 1990-04-10 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| US5047446A (en) * | 1988-07-22 | 1991-09-10 | Himont Incorporated | Thermal treatment of irradiated propylene polymer material |
| US5508319A (en) * | 1991-06-21 | 1996-04-16 | Montell North America Inc. | High melt strength, ethylene polymer, process for making it, and use thereof |
| US6306970B1 (en) * | 1999-04-19 | 2001-10-23 | Montell Technology Company Bv | Soft propylene polymer blend with high melt strength |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE343611T1 (de) | 2006-11-15 |
| AU2004263737A1 (en) | 2005-02-17 |
| PL1654320T3 (pl) | 2007-01-31 |
| EP1654320B1 (en) | 2006-10-25 |
| ES2273279T3 (es) | 2007-05-01 |
| WO2005014710A3 (en) | 2005-03-31 |
| CN100480321C (zh) | 2009-04-22 |
| CA2535444A1 (en) | 2005-02-17 |
| RU2006107559A (ru) | 2006-09-10 |
| BRPI0413551A (pt) | 2006-10-17 |
| DE602004002965D1 (de) | 2006-12-07 |
| JP2007502338A (ja) | 2007-02-08 |
| DE602004002965T2 (de) | 2007-06-14 |
| EP1654320A2 (en) | 2006-05-10 |
| KR20060060685A (ko) | 2006-06-05 |
| US20060258766A1 (en) | 2006-11-16 |
| WO2005014710A2 (en) | 2005-02-17 |
| CN1836004A (zh) | 2006-09-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20090727 |